CN104673459A - Vehicle gear oil composition produced by utilizing reclaimed oil - Google Patents
Vehicle gear oil composition produced by utilizing reclaimed oil Download PDFInfo
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- CN104673459A CN104673459A CN201510015795.8A CN201510015795A CN104673459A CN 104673459 A CN104673459 A CN 104673459A CN 201510015795 A CN201510015795 A CN 201510015795A CN 104673459 A CN104673459 A CN 104673459A
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- reclaimed
- vehicle gear
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Abstract
The invention provides a vehicle gear oil composition produced by utilizing reclaimed oil. The lubricating oil vehicle gear oil composition is prepared from the following raw materials in parts by weight: 100.0 parts of reclaimed base oil, 0.01-99.0 parts of other base oil, 0.01-10.0 parts of a viscosity improver, 3-10.0 parts of a clearing agent, 1.0-5.0 parts of a dispersing agent, 0.5-3.0 parts of an oxidation and corrosion inhibitor, 0.01-1.0 part of a pour point reducer, 0.5-10.0 parts of an extreme pressure agent, 1.0-5.0 parts of an antirust agent, 0.5-3.0 parts of a metal deactivator and 0.0001-0.01 part of a defoaming agent. The vehicle gear oil composition has the advantages that all the performances meet GB13895-92 standard requirements, viscosity grades comprise 75W/90, 80W/90, 85W/90, 85W/140, 90, 140 and other marks.
Description
Technical field
The present invention relates to gear of vehicle oil compositions, especially utilize Reclaimed Base Oil and the automotive gear oil being applicable to the hypoid gear drive axle of passenger vehicle and other various vehicles developed.
Background technology
In view of the requirement of environment protection and policies and regulations, the motive force of development of automotive gear oil reduces system cost, economizes on resources under being intended to improve the prerequisite of performance requriements.A large amount of lubricating oil will be consumed every year in the whole world, produce again a large amount of waste lubricating oils, if waste lubricating oil is discarded in environment and goes, Metal Salts wherein, the organic compound such as sulfur-bearing, oxygen phosphorus, severe contamination will be caused to environment, reclaim re-using waste lubricating oil and then can bring huge economic benefit.This technology is just in protection of the environment; make rational use of resources; the technical scheme of actively probing under the situation of refuse reclamation; the each performance index of this gear of vehicle oil compositions all meet GB13895-92 standard-required, and viscosity grade comprises 75W/90,80W/90,85W/90,85W/140, the trades mark such as 90 and 140.
Searching document discloses: [1] patent CN103980987 [2] patent CN10328980 [3] patent CN103509636 [4] patent CN102703181 [5] patent CN103374452 [6] patent CN102533396 [7] patent CN102041147 [8] patent CN101029264 [9] patent CN1727459 relates to document of the present invention.
Current China automotive gear oil mainly contains mineral type, synthesis type and mixed type three types thereof.Synthesis type performance is higher, expensive, though mineral type is involutory shaping cheap, but most of base oil is selected from refined mineral oil, relative Reclaimed Base Oil, and cost is also higher.Reclaimed Base Oil is the regeneration to waste lubricating oil, not only protection of the environment, and low price.The present invention is just under the situation advocating economic environmental protection and refuse reclamation, the automotive gear oil that Fu Ke oil product limited-liability company utilizes reclaimed lubricating base oil to prepare, it is mainly used for the automotive gear oil of the hypoid gear drive axle of passenger vehicle and other various vehicles.
Summary of the invention
The object of the invention is to: a kind of gear of vehicle oil compositions utilizing Reclaimed Base Oil to produce is provided, meets the automotive gear oil performance requriements of each rank.
The object of the present invention is achieved like this: a kind of gear of vehicle oil compositions utilizing recovered oil to produce: this lubricating oil is become by following raw materials in parts by weight array: Reclaimed Base Oil: 100.0 parts, other base oils: 0.01-99.0 part, viscosity modifier: 0.01-10.0 part, purification agent: 3-10.0 part, oxidation and corrosion inhibitor: 0.5-3.0 part, pour point depressant: 0.01-1.0 part, extreme pressure agent: 0.5-10.0 part, rust-preventive agent: 1.0-5.0 part, metal passivator: 0.5-3.0 part, defoamer: 0.0001-0.01 part.
Know-why of the present invention and beneficial effect: regeneration is carried out to waste lubricating oil, not only protection of the environment, and economize on resources, this reclaimed lubricating base oil viscosity index is high, and outward appearance is well-illuminated transparent, and pour point is low; Purification agent is selected to have significant detergent power; Oxidation and corrosion inhibitor is selected to have good antioxidant-anticorrosive properties; Viscosity modifier is selected to have good thickening property; Pour point depressant is selected to have good depression effeCt; Select defoamer to have defoaming, can adjust according to whipability in good time.
The lubricating oil that the present invention produces can not only efficent use of resources, and bring huge economic benefit, utilize automotive gear oil prepared by recovered oil, viscosity index is high, channel point is low, and flash-point is high, and the high temperature resistance property sheared waits excellent properties by force, meet every physical and chemical index of automotive gear oil completely, for industry energy conservation consumption reduction serves exemplary role.
Embodiment
The present invention is described further in conjunction with the embodiments.
Embodiment 1
With parts by weight preparation, automotive gear oil:
Formula 1:
Reclaimed Base Oil 100.0 parts, refining 20.0 parts of 15#, 150BS 30.0 parts, Ethylene-Propylene Copolymers 6.0 parts, middle calcium alkylbenzensulfonates 3.0 parts, the two octyl group basic zinc salt 1.0 parts of sulphur phosphorus, alkylnaphthalene 0.75 part, sulfide isobutene 2.5 parts, tritolyl phosphate 1.0 parts, neutral dinonyl naphthalene sulfonate barium 1.0 parts, 2,6-ditertbutylparacresol 1.5 parts, methyl-silicone oil 0.0004 part.
Formula 2:
Reclaimed Base Oil 100.0 parts, 150BS 13.0 parts, tricarboxymethyl propane oleate 20.0 parts, Ethylene-Propylene Copolymers 5.0 parts, low alkali value calcium alkylbenzenesulfonate 3.0 parts, sulphur phosphorus brothers alcohol radical zinc salt 1.0 parts, polyalphaolefin 0.5 part, sulfide isobutene 2.0 parts, thiophosphoric acid phenyl ester 1.0 parts, barium mahogany sulfonate 1.0 parts, 1.5 parts, 124 Triazole derivative, methyl-silicone oil 0.0005 part.
Formula 3:
Reclaimed Base Oil 100.0 parts, 150BS 5.0 parts, PETO 15.0 parts, PAO100 15.0 parts, polymethacrylate 5.0 parts, middle calcium alkylbenzensulfonates 3.0 parts, the two octyl group basic zinc salt 1.0 parts of sulphur phosphorus, alkylnaphthalene 1.0 parts, sulfide isobutene 2.5 parts, phosphorous acid diisobutyl ester 1.0 parts, neutral dinonyl naphthalene sulfonate barium 1.0 parts, 1.5 parts, 124 Triazole derivative, methyl-silicone oil 0.0004 part.
Formula 4:
Reclaimed Base Oil 100.0 parts, MVI500 10.0 parts, PAO150 20.0 parts, the different monooctyl ester of polyacrylic acid 5.0 parts, middle calcium alkylbenzensulfonates 3.0 parts, the two octyl group basic zinc salt 1.0 parts of sulphur phosphorus, alkylnaphthalene 0.5 part, polyalphaolefin 0.5 part, sulfide isobutene 2.0 parts, positive 2.0 parts, the fourth fat of phosphorous acid two, alkenyl succinic acid ester 1.0 parts, 2,6 ditertiary butyl p cresol 1.5 parts, methyl-silicone oil 0.0005 part.
Above-mentioned preparation 1), 2), 3) ... select its 1, prepare automotive gear oil.
Wherein Reclaimed Base Oil 40 DEG C of kinematic viscosity are 22-1500mm
2﹒ s
-1, viscosity index>=80, acid number≤2, flash-point>=180 DEG C.
Wherein other base oils comprise mineral oil 15# and refine and/or at least one in 150BS and/or MVI400 and/or MVI500 and/or KG18 and/or MVI300 and/or HVIP8 and/or HVIP6 and/or synthesizing ester base oil TriMethylolPropane(TMP) sebate and/or PETO and/or pentaerythritol adipate and/or TriMethylolPropane(TMP) heptanoate and/or neopentyl glycol heptanoate and/or TriMethylolPropane(TMP) oxalic acid ester and/or tricarboxymethyl propane oleate and/or poly-α hydrocarbon synthesis oil PAO40 and/or PAO100 and/or PAO150.
Wherein the purification agent of automotive gear oil comprises at least one in low alkali value calcium alkylbenzenesulfonate and/or middle calcium alkylbenzensulfonates and/or high base number calcium alkylbenzenesulfonate and/or sulfur phosphorization polyisobutylene titanate salt and/or magnesium naphthenate and/or diene base succimide and/or polyene-based succimide.
Wherein the oxidation and corrosion inhibitor of automotive gear oil is at least one in the two octyl group basic zinc salt of sulphur phosphorus alkylphenol zinc salt and/or sulphur phosphorus and/or sulphur phosphorus brothers alcohol radical zinc salt and/or sulphur phosphorus secondary alcohol groups zinc salt.
Wherein the viscosity modifier of automotive gear oil is at least one in polyvinyl n-butyl ether and/or ethylene-propylene copolymer and/or polymethacrylate and/or the different monooctyl ester of polyacrylic acid.
Wherein the extreme pressure agent of automotive gear oil is at least one in the positive fourth fat of phosphorous acid two and/or sulphur phosphoric acid nitrogen containing derivative and/or tritolyl phosphate or thiophosphoric acid amine salt and/or thiophosphoric acid phenyl ester and/or sulfide isobutene and/or phosphorous acid diisobutyl ester and/or boronation thiophosphatephosphorothioate amine salt.
Wherein the pour point depressant of automotive gear oil is at least one in alkylnaphthalene and/or polyalphaolefin.
Wherein the rust-preventive agent of automotive gear oil is at least one in barium mahogany sulfonate and/or petroleum sodium sulfonate zinc naphthenate and/or neutral dinonyl naphthalene sulfonate barium and/or alkenyl succinic acid and/or alkenyl succinic acid ester.
Wherein the metal passivator of automotive gear oil is at least one in 2,6 ditertiary butyl p cresol and/or 124 Triazole derivative and/or thiadiazoles derivative.
In example, every physicochemical property, sees attached list.
The automotive gear oil mixed by Reclaimed Base Oil and other base oils and various additive as can be seen from the table, viscosity index is high, and channel point is low, meets the performance requriements of automotive gear oil viscosity grade 75W/90,80W/90,85W/90,85W/140 completely.
The national standard of product of the present invention is GB13895-92.
Reclaimed Base Oil, synthetic ester lubricant are Fu Ke oil product limited-liability company commercially available prod;
The different monooctyl ester of viscosity modifier polyvinyl n-butyl ether, ethylene-propylene copolymer, polymethacrylate, polyacrylic acid is all purchased from Jinzhou Petrochemical Co.;
Purification agent low alkali value calcium alkylbenzenesulfonate, middle calcium alkylbenzensulfonates, high base number calcium alkylbenzenesulfonate are purchased from Shandong Zibo Hui Hua company limited, and sulfur phosphorization polyisobutylene titanate salt, magnesium naphthenate, diene base succimide, polyene-based succimide are all purchased from Shandong Zibo Hui Hua company limited;
Oxidation and corrosion inhibitor is sulphur phosphorus alkylphenol zinc salt, the two octyl group basic zinc salt of sulphur phosphorus, sulphur phosphorus brothers alcohol radical zinc salt, sulphur phosphorus secondary alcohol groups zinc salt are all purchased from the emerging petroleum additive limited liability company in Jinzhou;
Extreme pressure agent phosphorous acid two positive fourth fat, sulphur phosphoric acid nitrogen containing derivative, tritolyl phosphate or thiophosphoric acid amine salt, thiophosphoric acid phenyl ester, sulfide isobutene, phosphorous acid diisobutyl ester, boronation thiophosphatephosphorothioate amine salt are all purchased from Shandong Zibo Hui Hua Chemical Co., Ltd.;
Rust-preventive agent barium mahogany sulfonate, petroleum sodium sulfonate zinc naphthenate, neutral dinonyl naphthalene sulfonate barium, alkenyl succinic acid, alkenyl succinic acid ester are all purchased from the emerging petroleum additive limited liability company in Jinzhou;
Metal passivator 2,6 ditertiary butyl p cresol, 124 Triazole derivative, thiadiazoles derivative are all purchased from Shandong Zibo Hui Hua Chemical Co., Ltd.;
Pour point depressant, defoamer are all purchased from Shandong Zibo Hui Hua Chemical Co., Ltd.;
Polyalphaolefin class synthetic oil is purchased in Mobil lubricating oil company limited.
Claims (2)
1. utilize the gear of vehicle oil compositions that recovered oil is produced, it is characterized in that: this lubricating oil is become by following raw materials in parts by weight array: Reclaimed Base Oil: 100.0 parts, other base oils: 0.01-99.0 part, viscosity modifier: 0.01-10.0 part, purification agent: 3-10.0 part, oxidation and corrosion inhibitor: 0.5-3.0 part, pour point depressant: 0.01-1.0 part, extreme pressure agent: 0.5-10.0 part, rust-preventive agent: 1.0-5.0 part, metal passivator: 0.5-3.0 part, defoamer: 0.0001-0.01 part.
2. automotive gear oil according to claim 1, is characterized in that:
1) Reclaimed Base Oil 40 DEG C of kinematic viscosity are 22-1500mm
2﹒ s
-1, viscosity index>=80, acid number≤2, flash-point>=180 DEG C 2) other base oils comprise mineral oil 15# and refine and/or at least one in 150BS and/or MVI400 and/or MVI500 and/or KG18 and/or MVI300 and/or HVIP8 and/or HVIP6 and/or synthesizing ester base oil TriMethylolPropane(TMP) sebate and/or PETO and/or pentaerythritol adipate and/or TriMethylolPropane(TMP) heptanoate and/or neopentyl glycol heptanoate and/or TriMethylolPropane(TMP) oxalic acid ester and/or tricarboxymethyl propane oleate and/or poly-α hydrocarbon synthesis oil PAO40 and/or PAO100 and/or PAO150.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510015795.8A CN104673459A (en) | 2015-01-13 | 2015-01-13 | Vehicle gear oil composition produced by utilizing reclaimed oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510015795.8A CN104673459A (en) | 2015-01-13 | 2015-01-13 | Vehicle gear oil composition produced by utilizing reclaimed oil |
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| Publication Number | Publication Date |
|---|---|
| CN104673459A true CN104673459A (en) | 2015-06-03 |
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| CN201510015795.8A Withdrawn CN104673459A (en) | 2015-01-13 | 2015-01-13 | Vehicle gear oil composition produced by utilizing reclaimed oil |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462658A (en) * | 2015-11-23 | 2016-04-06 | 广西大学 | Compression-ignition engine oil suitable for mixed polyoxymethylene dimethyl ether fuel |
| CN105733847A (en) * | 2016-03-16 | 2016-07-06 | 李贵福 | Engine cleaning liquid and preparation and cleaning method thereof |
| CN110643415A (en) * | 2019-10-22 | 2020-01-03 | 新疆福克油品股份有限公司 | Open gear oil composition using regenerated base oil and preparation method thereof |
| CN115011397A (en) * | 2022-06-09 | 2022-09-06 | 统一石油化工有限公司 | Emission-reduction low-carbon CK-4 diesel engine oil composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030207775A1 (en) * | 2002-04-26 | 2003-11-06 | Sullivan William T. | Lubricating fluids with enhanced energy efficiency and durability |
| CN101173202A (en) * | 2006-11-01 | 2008-05-07 | 中国石油化工股份有限公司 | Waste lubricant oil recovery utilization method |
| CN103374452A (en) * | 2012-04-27 | 2013-10-30 | 中国石油化工股份有限公司 | Manual transmission lubricating oil composition |
-
2015
- 2015-01-13 CN CN201510015795.8A patent/CN104673459A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030207775A1 (en) * | 2002-04-26 | 2003-11-06 | Sullivan William T. | Lubricating fluids with enhanced energy efficiency and durability |
| CN101173202A (en) * | 2006-11-01 | 2008-05-07 | 中国石油化工股份有限公司 | Waste lubricant oil recovery utilization method |
| CN103374452A (en) * | 2012-04-27 | 2013-10-30 | 中国石油化工股份有限公司 | Manual transmission lubricating oil composition |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462658A (en) * | 2015-11-23 | 2016-04-06 | 广西大学 | Compression-ignition engine oil suitable for mixed polyoxymethylene dimethyl ether fuel |
| CN105733847A (en) * | 2016-03-16 | 2016-07-06 | 李贵福 | Engine cleaning liquid and preparation and cleaning method thereof |
| CN105733847B (en) * | 2016-03-16 | 2018-03-23 | 李贵福 | Engine washing liquid and its preparation and cleaning method |
| CN110643415A (en) * | 2019-10-22 | 2020-01-03 | 新疆福克油品股份有限公司 | Open gear oil composition using regenerated base oil and preparation method thereof |
| CN110643415B (en) * | 2019-10-22 | 2022-07-29 | 新疆福克油品股份有限公司 | Open gear oil composition using regenerated base oil and preparation method thereof |
| CN115011397A (en) * | 2022-06-09 | 2022-09-06 | 统一石油化工有限公司 | Emission-reduction low-carbon CK-4 diesel engine oil composition |
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Application publication date: 20150603 |