CN104672658A - Environment-friendly PVC hose material - Google Patents

Environment-friendly PVC hose material Download PDF

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Publication number
CN104672658A
CN104672658A CN201310622953.7A CN201310622953A CN104672658A CN 104672658 A CN104672658 A CN 104672658A CN 201310622953 A CN201310622953 A CN 201310622953A CN 104672658 A CN104672658 A CN 104672658A
Authority
CN
China
Prior art keywords
parts
pvc
environment
hose
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310622953.7A
Other languages
Chinese (zh)
Inventor
李宝聪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QINGDAO HAIFALI CEREAL AND OIL MACHINERY Co Ltd
Original Assignee
QINGDAO HAIFALI CEREAL AND OIL MACHINERY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QINGDAO HAIFALI CEREAL AND OIL MACHINERY Co Ltd filed Critical QINGDAO HAIFALI CEREAL AND OIL MACHINERY Co Ltd
Priority to CN201310622953.7A priority Critical patent/CN104672658A/en
Publication of CN104672658A publication Critical patent/CN104672658A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/017Additives being an antistatic agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides an environment-friendly PVC hose material. The material is prepared from the following components in parts by weight: 40-80 parts of polyvinyl chloride (PVC) resin, 10-15 parts of thermoplastic polyurethane elastomer, 0.1-1.5 parts of antimonous oxide, 0.1-0.3 part of sodium silicate, 1-3 parts of ethylene glycol butyl ether, 1-2 parts of lauryl alcohol polyoxyethylene ether, 1-5 parts of carbon black, 10-20 parts of polycarbonate and 2-4 parts of nano-calcium carbonate. According to the material, the thermoplastic polyurethane elastomer, plasticizer, thermal stabilizer, antistatic agent and flame retardant are added into the PVC resin, so that the low-temperature resistance, flexibility, electrostatic resistance and flame retardance of the PVC hose can be improved, and the prepared PVC composite hose has good comprehensive performance, cannot be easily aged, and can be applied to storage and use processes of low-temperature oil, gas or liquid.

Description

A kind of environment-friendlyPVC PVC hosepipe material
Technical field
The present invention relates to a kind of environment-friendlyPVC PVC hosepipe material.
Background technology
Polyvinyl chloride (PVC) for micro-yellow translucent, glossy.Transparency is better than polyethylene, polyphenyl alkene, is worse than polystyrene, different with auxiliary dosage, and be divided into soft, rigid polyvinyl chloride, soft goods is soft and tough, feel glues, the hardness of boardy product is higher than Low Density Polyethylene, and lower than polypropylene, in flexion, place there will be albinism.The Performance comparision of polyvinyl chloride is stablized, and not easily by acid, caustic corrosion, comparatively tolerates ratio of specific heat; Have fire-retardant, chemical proofing is high, physical strength and electrical insulation capability advantages of higher.Polyvinyl chloride (PVC) for the manufacture of various soft or hard tubing, and is widely applied in industry, agricultural and vast resident living.Along with socioeconomic development, also more and more higher to the requirement of polyvinyl chloride quality.Polychlorostyrene of the prior art
Vinyl hose, the resistance to low temperature of conventional PVC flexible pipe is poor, fragility is large, ductile strength is low, ageing resistance is poor, safety performance is low, transport and install inconvenience, cost of manufacture is high, do not reach produce and life requirement.Mention combination room of the nono calcium carbonate modified spiral winded PVC flexible pipe of a kind of sanitary ware and preparation method thereof in prior art, but the flexible pipe resistance toheat that this material obtains is better, resistance to low temperature is poor.
Summary of the invention
For the deficiency that prior art exists, technical problem to be solved by this invention is, provides a kind of low temperature resistant, excellent property, effective high tenacity environment-friendlyPVC PVC hosepipe material improving PVC hose work-ing life.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of environment-friendlyPVC PVC hosepipe material, is grouped into by the one-tenth of following weight part:
Polyvinyl chloride (PVC) RESINS 40 ~ 80;
Polyurethane Thermoplastic Elastomer 10 ~ 15;
Antimonous oxide 0.1 ~ 1.5;
Water glass 0.1 ~ 0.3;
Butyl glycol ether 1 ~ 3;
Ethoxylated dodecyl alcohol 1 ~ 2;
Carbon black 1 ~ 5;
Polycarbonate 10 ~ 20;
Nano-calcium carbonate 2 ~ 4.
The advantage of high tenacity environment-friendlyPVC PVC hosepipe material of the present invention is: the present invention adopts and add Polyurethane Thermoplastic Elastomer, softening agent, thermo-stabilizer, static inhibitor, fire retardant in PVC resin, enhance the resistance to low temperature of PVC flexible pipe, snappiness, antistatic property and flame retardant resistance, the PVC composite soft tube good combination property of preparation, not easily aging, low-temperature oil can be applied to, in the storage of gas or liquid and use procedure.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further details;
A kind of environment-friendlyPVC PVC hosepipe material, is grouped into by the one-tenth of following weight part:
Polyvinyl chloride (PVC) RESINS 40 ~ 80;
Polyurethane Thermoplastic Elastomer 10 ~ 15;
Antimonous oxide 0.1 ~ 1.5;
Water glass 0.1 ~ 0.3;
Butyl glycol ether 1 ~ 3;
Ethoxylated dodecyl alcohol 1 ~ 2;
Carbon black 1 ~ 5;
Polycarbonate 10 ~ 20;
Nano-calcium carbonate 2 ~ 4.
Certainly, above-mentioned explanation is not limitation of the present invention, and the present invention is also not limited to above-mentioned citing; those skilled in the art; in essential scope of the present invention, the change made, remodeling, interpolation or replacement, all should belong to protection scope of the present invention.

Claims (1)

1. an environment-friendlyPVC PVC hosepipe material, is characterized in that, is grouped into by the one-tenth of following weight part:
Polyvinyl chloride (PVC) RESINS 40 ~ 80;
Polyurethane Thermoplastic Elastomer 10 ~ 15;
Antimonous oxide 0.1 ~ 1.5;
Water glass 0.1 ~ 0.3;
Butyl glycol ether 1 ~ 3;
Ethoxylated dodecyl alcohol 1 ~ 2;
Carbon black 1 ~ 5;
Polycarbonate 10 ~ 20;
Nano-calcium carbonate 2 ~ 4.
CN201310622953.7A 2013-11-30 2013-11-30 Environment-friendly PVC hose material Pending CN104672658A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310622953.7A CN104672658A (en) 2013-11-30 2013-11-30 Environment-friendly PVC hose material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310622953.7A CN104672658A (en) 2013-11-30 2013-11-30 Environment-friendly PVC hose material

Publications (1)

Publication Number Publication Date
CN104672658A true CN104672658A (en) 2015-06-03

Family

ID=53308275

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310622953.7A Pending CN104672658A (en) 2013-11-30 2013-11-30 Environment-friendly PVC hose material

Country Status (1)

Country Link
CN (1) CN104672658A (en)

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Legal Events

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C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150603