CN104671758B - A kind of low bulk building ceramics utilizing desert yellow sand and waste material to prepare and manufacture method thereof - Google Patents
A kind of low bulk building ceramics utilizing desert yellow sand and waste material to prepare and manufacture method thereof Download PDFInfo
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- CN104671758B CN104671758B CN201510082698.0A CN201510082698A CN104671758B CN 104671758 B CN104671758 B CN 104671758B CN 201510082698 A CN201510082698 A CN 201510082698A CN 104671758 B CN104671758 B CN 104671758B
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- Prior art keywords
- waste material
- yellow sand
- prepare
- low bulk
- building ceramics
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- 239000004576 sand Substances 0.000 title claims abstract description 32
- 239000002699 waste material Substances 0.000 title claims abstract description 28
- 239000000919 ceramic Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 title abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 239000010438 granite Substances 0.000 claims abstract description 8
- 239000004927 clay Substances 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- 229910001570 bauxite Inorganic materials 0.000 claims abstract description 5
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 5
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 5
- 235000014380 magnesium carbonate Nutrition 0.000 claims abstract description 5
- 238000000498 ball milling Methods 0.000 claims description 6
- 229910052878 cordierite Inorganic materials 0.000 claims description 6
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 230000014759 maintenance of location Effects 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims 1
- 229910010293 ceramic material Inorganic materials 0.000 abstract description 11
- 238000005516 engineering process Methods 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 230000035939 shock Effects 0.000 abstract description 5
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000000454 talc Substances 0.000 abstract description 3
- 229910052623 talc Inorganic materials 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 24
- 239000000203 mixture Substances 0.000 description 6
- 238000011161 development Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012761 high-performance material Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation
Abstract
The invention discloses a kind of low bulk building ceramics utilizing desert yellow sand and waste material to prepare, its raw material consists of: desert yellow sand 10～20wt%, western ore deposit potter's clay 10～20wt%, granite waste material 10～20wt%, black talc 6～15wt%, magnesite 10～20wt%, bauxite 20～40wt%.Additionally, also disclose the manufacture method of the above-mentioned low bulk building ceramics utilizing desert yellow sand and waste material to prepare.Resulting materials of the present invention has the characteristics such as thermal coefficient of expansion is low, thermal shock resistance good, length in service life；Preparation technology is simple, and raw material is easy to get, and energy consumption cost is low, beneficially the realization of industrialization.The present invention not only reduces the use of Ceramic Material in short supply, and takes full advantage of land resource and regenerated resources, and the utilization for waste material resources such as the Northwest's Desert Sands provides new technical thought and scheme, significant simultaneously for environmental improvement and protection.
Description
Technical field
The present invention relates to building ceramics technical field, particularly relate to a kind of utilize desert yellow sand and waste material to prepare
Low bulk building ceramics and manufacture method thereof.
Background technology
Traditional architecture ceramic material is owing to thermal coefficient of expansion is relatively big, thermal shock resistance is poor, therefore at the environment of variations in temperature
Median year uses, and easily occurs that the phenomenons such as blank cracking cause shorten service life.Thermal expansivity is ceramic material
One main performance, the performance relevant to thermal expansion include the thermal shock resistance of material, the mechanical property of composite,
Plated film and coating, sealing-in and gradient function and measure of precision etc..When material bears bigger variations in temperature, heat
The size of the coefficient of expansion directly affects the serviceability of material, and therefore exploitation expansion ceramic material has important meaning
Justice.But, expansion ceramic material research in terms of architectural pottery is few, main reason is that material cost is relatively
High, synthesis energy consumption is bigger so that low bulk architectural pottery industrialization is walked with difficulty.And China is architectural pottery disappears
Take and big export country, and along with industrial development, the requirement to properties of product is more and more higher, to this end,
Improve architectural pottery heat stability, extend its service life and require with the use reaching green building material imperative.
Cordierite expansion ceramic material purposes ratio is wide, and correlational study also compares many, but the most most
Research is all to use traditional raw material composition i.e. Kaolin-talc-alumina or use chemical pure series of oxidation
Thing prepares cordierite, and its production cost is higher, and firing temperature the highest (generally 1350～1400 DEG C).Closely
Nian Lai, along with the Ceramic Material resources such as Kaolin are the deficientest, utilizes industrial waste or new raw material to prepare high-performance material
The research of material is the most gradually developed, and this not only contributes to environmental conservation, meets the development strategy requirement of country, with
Time be also the development trend of novel environment friendly ceramic material, and China set up resource, energy conservation type society urgent
Requirement.Desert yellow sand abundance, China's desert gross area about 700,000 sq-km, if flat together with more than 50 ten thousand
The Gobi desert of side's km is 1,280,000 sq-kms at the interior gross area, accounts for the 13% of land, the whole nation gross area.Wherein, in
State northwest arid area is the area that Deserts in China is concentrated the most, accounts for the 80% of desert, the whole nation gross area, soil
Desertification causes soil cannot cultivate utilization, thus is faced with sand and dust and the problems concerning land resources of sternness.As utilized
Yellow sand resource and the Northwest's waste material prepare low bulk building ceramics, can not only save production cost,
Avoid the scarcity of Ceramic Material resource in short supply, and land resource can be made full use of, and be sand prevention, sand control and use
The new thinking of husky offer and method, development and environmental conservation to new ceramic material all have great significance.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of thermal coefficient of expansion is low and has good anti-
Thermal shock resistance, utilize low bulk building ceramics prepared by desert yellow sand and waste material, to make full use of desert yellow sand
And waste material resource, thus better adapt to the development of novel environment friendly building ceramics and the demand of environmental improvement.
Another object of the present invention is to provide the above-mentioned low bulk building ceramics utilizing desert yellow sand and waste material to prepare
Manufacture method.
The purpose of the present invention is achieved by the following technical programs:
A kind of low bulk building ceramics utilizing desert yellow sand and waste material to prepare that the present invention provides, its raw material group
Become: desert yellow sand 10～20wt%, western ore deposit potter's clay 10～20wt%, granite waste material 10～20wt%, black
Talcum 6～15wt%, magnesite 10～20wt%, bauxite 20～40wt%.
Further, material of the present invention is with cordierite as principal crystalline phase.Described material room temperature～800 DEG C average
Thermal coefficient of expansion is 3.00 × 10-6/ DEG C～5.4 × 10-6/ DEG C, rupture strength is 55.00～95.00Mpa, water absorption rate ＜
4%.
Another object of the present invention is achieved by the following technical programs:
The manufacturer of the above-mentioned low bulk building ceramics utilizing desert yellow sand and waste material to prepare that the present invention provides
Method is as follows: described raw material through dispensing, ball milling, sieve, be dried, pelletize, dry-pressing formed after, at 1160～1230 DEG C
At a temperature of sinter, temperature retention time is 10～30min, i.e. obtains described low bulk building ceramics.
In such scheme, Ball-milling Time described in preparation method of the present invention is 30～90min.
The method have the advantages that
The present invention with the twice laid of desert, Inner Mongol yellow sand as breach, be equipped with the Northwest's granite waste material,
One of clay raw materials western ore deposit potter's clay, magnesite, bauxite, prepare cordierite low bulk building ceramics,
Resulting materials thermal coefficient of expansion is low, has the characteristics such as thermal shock resistance is good, service life is longer, it is possible to meet green
The use requirement of construction material.Preparation technology of the present invention is simple, and raw material is easy to get, and reduces sintering temperature, energy consumption
Low cost, has the highest use value, and the realization of beneficially industrialization.The present invention has not only saved and has produced into
Basis and the use of Ceramic Material in short supply, and take full advantage of land resource and regenerated resources, for desert, the Northwest
The utilization of the waste material resources such as sand provides new technical thought and scheme, has weight simultaneously for environmental improvement and protection
Want meaning.
Accompanying drawing explanation
Below in conjunction with embodiment and accompanying drawing, the present invention is described in further detail:
Fig. 1 is the material phase analysis diffraction pattern of the low bulk building ceramics that the embodiment of the present invention prepares.
Detailed description of the invention
A kind of low bulk building ceramics utilizing desert yellow sand and waste material to prepare of the embodiment of the present invention, its raw material group
Become: desert yellow sand 10～20wt%, western ore deposit potter's clay 10～20wt%, granite waste material 10～20wt%, black
Talcum 6～15wt%, magnesite 10～20wt%, bauxite 20～40wt%.
Wherein desert yellow sand from storehouse, Inner Mongol cloth its.The chemical composition of desert yellow sand and granite waste material such as table 1
Shown in.
The chemical composition (%) of table 1 embodiment of the present invention desert yellow sand and granite waste material
| Chemical composition | SiO2 | Al2O3 | Fe2O3 | TiO2 | CaO | MgO | Na2O | K2O | Burn and lose |
| Desert yellow sand | 75.95 | 12.68 | 2.08 | 0.29 | 2.09 | 0.72 | 1.54 | 2.02 | 2.63 |
| Granite waste material | 72.21 | 14.11 | 2.70 | 0.40 | 2.39 | 0.46 | 3.23 | 3.79 | 0.71 |
The manufacture method of the above-mentioned low bulk building ceramics utilizing desert yellow sand and waste material to prepare is as follows: each raw material
Through dispensing, ball milling (Ball-milling Time 30～90min), sieve, be dried, pelletize, dry-pressing formed after, 1160～
Sintering at a temperature of 1230 DEG C, temperature retention time is 10～30min, i.e. obtains low bulk building ceramics.
The raw material composition of various embodiments of the present invention and preparation technology parameter are as shown in table 2.
The raw material composition of table 2 various embodiments of the present invention and preparation technology parameter
Performance test:
The low bulk building ceramics that the embodiment of the present invention prepares (see Fig. 1), uses long with cordierite as principal crystalline phase
What Metrologic Instr Inc. produced made every effort to achieve in RPZ-01 type thermal coefficient of expansion tester and Xi'an that husky instrument plant produces
WOW-10 microcomputer controlled electro power universal testing machine, tests the thermal coefficient of expansion of material, rupture strength, and utilization is boiled
Method measures the water absorption rate of material.Test result is as shown in table 3.
The low bulk building ceramics performance indications that table 3 various embodiments of the present invention prepare
Claims (5)
1. the low bulk building ceramics utilizing desert yellow sand and waste material to prepare, it is characterised in that raw material forms
For: desert yellow sand 10～20wt%, western ore deposit potter's clay 10～20wt%, granite waste material 10～20wt%, black cunning
Stone 6～15wt%, magnesite 10～20wt%, bauxite 20～40wt%.
The low bulk building ceramics utilizing desert yellow sand and waste material to prepare the most according to claim 1, its
It is characterised by: described material is with cordierite as principal crystalline phase.
The low bulk architectural pottery material utilizing desert yellow sand and waste material to prepare the most according to claim 1 and 2
Material, it is characterised in that: the mean thermal expansion coefficients of described material room temperature～800 DEG C is 3.00 × 10-6/ DEG C～5.4 ×
10-6/ DEG C, rupture strength is 55.00～95.00Mpa, water absorption rate ＜ 4%.
4. the system of the described low bulk building ceramics utilizing desert yellow sand and waste material to prepare of one of claim 1-3
Preparation Method, it is characterised in that: described raw material through dispensing, ball milling, sieve, be dried, pelletize, dry-pressing formed after,
Sintering at a temperature of 1160～1230 DEG C, temperature retention time is 10～30min, i.e. obtains described low bulk architectural pottery
Material.
The system of the low bulk building ceramics utilizing desert yellow sand and waste material to prepare the most according to claim 4
Make method, it is characterised in that: described Ball-milling Time is 30～90min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510082698.0A CN104671758B (en) | 2015-02-14 | 2015-02-14 | A kind of low bulk building ceramics utilizing desert yellow sand and waste material to prepare and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510082698.0A CN104671758B (en) | 2015-02-14 | 2015-02-14 | A kind of low bulk building ceramics utilizing desert yellow sand and waste material to prepare and manufacture method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN104671758A CN104671758A (en) | 2015-06-03 |
| CN104671758B true CN104671758B (en) | 2016-08-17 |
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| CN201510082698.0A Expired - Fee Related CN104671758B (en) | 2015-02-14 | 2015-02-14 | A kind of low bulk building ceramics utilizing desert yellow sand and waste material to prepare and manufacture method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106396637B (en) * | 2016-09-06 | 2019-12-31 | 景德镇陶瓷大学 | Preparation method of light low-expansion porcelain building ceramic tile and product prepared by preparation method |
| CN111153681A (en) * | 2020-01-07 | 2020-05-15 | 湖南泰鑫瓷业有限公司 | Argil prepared from waste materials and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10231166A (en) * | 1997-02-18 | 1998-09-02 | Tokyo Yogyo Co Ltd | Baked building material block utilizing waste |
| JP2006206390A (en) * | 2005-01-28 | 2006-08-10 | National Institute Of Advanced Industrial & Technology | Ceramic body, ceramic carrier having catalyst carrying capacity, ceramic catalyst body and method for producing the same |
| CN103253930B (en) * | 2013-06-08 | 2014-08-06 | 景德镇陶瓷学院 | Vitreous building sanitary ceramic with low-expansion and high-infrared function prepared by waste gangue and preparation method of vitreous building sanitary ceramic |
| CN104016658B (en) * | 2014-06-17 | 2015-07-29 | 马东升 | A kind of local waste material in the Inner Mongol that utilizes prepares the method for internal wall brick and obtained internal wall brick product thereof |
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| CN104671758A (en) | 2015-06-03 |
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Address after: 333001 Jingdezhen Tao Yang University, Jingdezhen South Road, pearl mountain, Jiangxi Applicant after: JINGDEZHEN CERAMIC INSTITUTE Address before: 333001 Tao Yang Road, Jingdezhen, Jiangxi Province, Jingdezhen Ceramic Institute Applicant before: Jingdezhen Ceramic Institute |
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