CN1046547C - Anti-creasing and anti-yellowing detergent for silk and wool - Google Patents
Anti-creasing and anti-yellowing detergent for silk and wool Download PDFInfo
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- CN1046547C CN1046547C CN94112299A CN94112299A CN1046547C CN 1046547 C CN1046547 C CN 1046547C CN 94112299 A CN94112299 A CN 94112299A CN 94112299 A CN94112299 A CN 94112299A CN 1046547 C CN1046547 C CN 1046547C
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Abstract
The present invention relates to creasing resistant and yellowing resistant detergent for silks and wool. The present invention is mainly composed of coconut oil diethyl acetal acid amide, polyvinylpyrrolidone, C12 to C15 fatty alcohol oxyethene ether (n is equal to 7), glycidol sorbierite laurinol monoester polyethenoxy ether, a TAB-12 (1231) quaternary ammonium salt type cationic surface active agent and water. Because the components of the detergent do not contain chemical products which impair to real silks and wool, such as fluorescent whitening agents, bleaching agents, etc. but contain flexible increase, electrostatic resistance and scale prevention redeposit surface active ingredients, the present invention has functions of the spongy keep, the creasing resistance and the yellowing resistance of the silks and the wool and has a certain recovery function on a wool fabric which is shrunk.
Description
A kind of anti-creasing and anti-yellowing detergent for silk and wool of the present invention relates to washing composition.
Along with fashionable dress develops to middle and high shelves, real silk, hair, linen have become day by day for making the main lining of middle and high shelves fashionable dress.Yet there are problems such as easily aging, wrinkling, embrittlement, yellowing in the clothes that these linings are made, have occurred with the insoluble new contradiction of common detergent washing.
Existing common detergent for silk and wool is mainly by anion surfactant and auxiliary agent thereof, promptly by formations such as sodium alkyl benzene sulfonate, Xylo-Mucine, tripoly phosphate sodium STPP, alkyl benzene sulphonate (ABS) trolamine, Sodium hexametaphosphate 99, sodium sulfate, fatty alcohol-polyoxyethylene ether, water glass (modulus 3), white dyes, soap stocks.This washing composition is easily manufactured, highly versatile, but real silk and wool fiber are all had certain infringement.To real silk fabric, it is wrinkling to wash the back, with the passing of time yellowing; Wool fabric then causes shrink.
The objective of the invention is to provide a kind of crease-resistant, anti-yellowing that has, the washing composition of protection silk, hair function.
The present invention realizes like this, washing composition is mainly formed by positively charged ion and nonionogenic tenside mechanically mixing, component mainly comprises: coconut oil diethanol amide, polyvinylpyrrolidone, C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ether (n=7), shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7, Trimethyllaurylammonium bromide quaternary ammonium salt cationic surfactant and water are formed, and its weight percent consists of: coconut oil diethanol amide 2~7 polyvinylpyrrolidones 0.1~0.5C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ethers (n=7) 1~6 shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7 1~8 Trimethyllaurylammonium bromide quaternary ammonium salt cationic surfactant 0.5~4 essence suitable quantity of water surplus
Each component of aforementioned proportion by mixing, is promptly got the liquid detergent for silk and wool of the present invention with following proterties:
Outward appearance: no suspended substance or heavy dirt;
Smell: odorless, do not have other irritating smell, odor type up to specification;
Stability: (liquid)-3~-5 ℃, 24 hours are non-crystallizable;
PH value: (25 ℃, 1% solution)≤9;
Tensio-active agent total content: 〉=12;
Detersive power: greater than standard specimen washing powder;
Capacity and tolerance thereof: 300 ± 4.5 milliliters.
Washing composition of the present invention owing to do not contain white dyes, SYNTHETIC OPTICAL WHITNER etc. real silk, wool are not had the chemical of damage in the moiety, thereby has prolonged work-ing life of silk, woolen.Increase gentle, antistatic, the anti-dirt surface active ingredient of deposit again owing to contain in the detergent component, not only has function to soft crease-resistant, the anti-yellowing of silk hair, and the wool fabric that has shunk there is to a certain degree reactivation, also to the level and smooth performance effect of increasing significantly of synthon, mixed fibre.
Following examples will be described further technical scheme of the present invention:
Embodiment 1, washing composition of the present invention mainly is made up of following material: coconut oil diethanol amide 2 grams, polyvinylpyrrolidone 0.5 gram, C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ether (n=7) 2 grams, shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7 7 grams, Trimethyllaurylammonium bromide quaternary ammonium salt cationic surfactant 0.5 gram, essence is an amount of, and surplus is a deionized water.
Its preparation technology is: in reactor, earlier with the Povidone deionized water dissolving, be warming up to 40 ℃, stir half, add coconut oil diethanol amide, C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ether and shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7 again to 1 hour, stir on the limit, heat up in the limit, the limit adds water to preset value, be cooled to 40 ℃ in insulation under 70 ℃ after 1 hour, add essence and stirred for 1 quarter, blowing, cooling, can every other day.Embodiment 2, the main component of washing composition is: coconut oil diethanol amide 3 grams, polyvinylpyrrolidone 0.2 gram, C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ether (n=7) 6 grams, shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7 6 grams, Trimethyllaurylammonium bromide quaternary ammonium salt cationic surfactant 4 grams, essence is an amount of, and surplus is a deionized water 1.The preparation method is with embodiment 1.
Embodiment 3, the main component of washing composition is: coconut oil diethanol amide 7 grams, polyvinylpyrrolidone 0.5 gram, C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ether (n=7) 1 gram, shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7 8 grams, Trimethyllaurylammonium bromide quaternary ammonium salt cationic surfactant 4 grams, essence is an amount of, and surplus is a deionized water.Preparation technology is with embodiment 1.
Embodiment 4, main component of the present invention is: coconut oil diethanol amide 5 grams, polyvinylpyrrolidone 0.3 gram, C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ether (n=7) 5 grams, shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7 1 gram, Trimethyllaurylammonium bromide quaternary ammonium salt cationic surfactant 3 grams, essence is an amount of, and surplus is a deionized water.Preparation technology is with embodiment 1.
Embodiment 5, main component of the present invention is: coconut oil diethanol amide 4 grams, polyvinylpyrrolidone 0.4 gram, C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ether (n=7) 4 grams, shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7 4 grams, Trimethyllaurylammonium bromide quaternary ammonium salt cationic surfactant 2 grams, essence is an amount of, and surplus is a deionized water.Preparation technology is with embodiment 1.
Embodiment 6, main component of the present invention is: coconut oil diethanol amide 5 grams, polyvinylpyrrolidone 0.3 gram, C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ether (n=7) 5 grams, shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7 5 grams, Trimethyllaurylammonium bromide quaternary ammonium salt cationic surfactant 3 grams, essence is an amount of, and surplus is a deionized water.Preparation technology is with embodiment 1.
Embodiment 7, main component of the present invention is: coconut oil diethanol amide 4 grams, polyvinylpyrrolidone 0.2 gram, C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ether (n=7) 6 grams, shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7 1 gram, Trimethyllaurylammonium bromide quaternary ammonium salt cationic surfactant 1 gram, essence is an amount of, and surplus is a deionized water.Preparation technology is with embodiment 1.
Embodiment 8, main component of the present invention is: coconut oil diethanol amide 6 grams, polyvinylpyrrolidone 0.5 gram, C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ether (n=7) 3 grams, shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7 7 grams, Trimethyllaurylammonium bromide quaternary ammonium salt cationic surfactant 4 grams, essence is an amount of, and surplus is a deionized water.Preparation technology is with embodiment 1.
Embodiment 9, use the present invention real silk, wool knitting yarn, nylon taffeta, polyester taffeta, polyester cotton are washed, and do the product performance test:
(1) yellowness index is measured:
Get wool knitting yarn, each 100 gram of real silk are one group, totally two groups, be that 12% washing composition of the present invention and common washing composition respectively wash 10 times at normal temperatures with 30 milliliters of surfactant content respectively, each with 30 liters in tap water, yellowness index b value is measured with colour-difference meter in air-dry back, and the result is:
Fabric b value | Wool knitting yarn | Real silk | ||
Washing composition | Common washing composition washing composition of the present invention | 5.0 1.8 | 7.0 2.5 | The b value is big more, and the fabric xanthochromia is heavy more. |
(2) level and smooth performance evaluation: get test cloth: nylon taffeta, polyester taffeta, polyester cotton 65/35, degree of input is to stir 3 minutes in 5% common washing composition and the washing composition of the present invention respectively, takes out, air-dry, 25 ℃, under relative humidity 65% condition, place after 24 hours, be folded into rectangle respectively, be folded in half into eighty percent discount, a hand-held end slides the other end, the sliding sense of contrast, as a result grade as:
The nylon taffeta | The polyester taffeta | Polyester cotton 65/35 | |
Common washing composition | In | In | In |
Washing composition of the present invention | Excellent | Excellent | Excellent |
Claims (2)
1, a kind of anti-creasing and anti-yellowing detergent for silk and wool, it is characterized in that, comprise coconut oil diethanol amide 2~7%, polyvinylpyrrolidone 0.1%, C12-15 Fatty Alcohol(C12-C14 and C12-C18) oxygen Vinyl Ether (n=7) 1~6%, shrink sorbyl alcohol lauric acid monoester Soxylat A 25-7 1~8%, Trimethyllaurylammonium bromide quaternary ammonium salt cationic surfactant 0.5~4%, surplus are water.
2, a kind of anti-creasing and anti-yellowing detergent for silk and wool according to claim 1 is characterized in that, also contains an amount of essence in the composition.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN94112299A CN1046547C (en) | 1994-09-02 | 1994-09-02 | Anti-creasing and anti-yellowing detergent for silk and wool |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN94112299A CN1046547C (en) | 1994-09-02 | 1994-09-02 | Anti-creasing and anti-yellowing detergent for silk and wool |
Publications (2)
Publication Number | Publication Date |
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CN1117996A CN1117996A (en) | 1996-03-06 |
CN1046547C true CN1046547C (en) | 1999-11-17 |
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CN94112299A Expired - Fee Related CN1046547C (en) | 1994-09-02 | 1994-09-02 | Anti-creasing and anti-yellowing detergent for silk and wool |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103451943A (en) * | 2013-08-21 | 2013-12-18 | 吴江市七都镇庙港雅迪针织制衣厂 | Treating agent for wool fabric and preparation method of treating agent |
CN104389164A (en) * | 2014-11-28 | 2015-03-04 | 何庆堃 | Printing and dyeing pretreatment aid for silk fabric finishing |
DE102016213568A1 (en) * | 2016-07-25 | 2018-01-25 | Henkel Ag & Co. Kgaa | Polymers of vinylpyrrolidone and / or vinyl acetate as textilpflegende ingredients |
CN106434031A (en) * | 2016-08-31 | 2017-02-22 | 胡小丽 | Preparation method of detergent capable of preventing clothes from yellowing and fading |
CN106434032A (en) * | 2016-08-31 | 2017-02-22 | 胡小丽 | Detergent for preventing yellowing and color fading of clothes |
CN109679772A (en) * | 2019-02-19 | 2019-04-26 | 上海皇宇科技发展有限公司 | A kind of silk dry cleaning agent |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1078996A (en) * | 1992-05-19 | 1993-12-01 | 呼和浩特市合成洗涤剂厂 | Cashmere detergent and making method |
CN1088252A (en) * | 1992-12-09 | 1994-06-22 | 中国科学院新疆化学研究所 | Carpet cleaner |
-
1994
- 1994-09-02 CN CN94112299A patent/CN1046547C/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1078996A (en) * | 1992-05-19 | 1993-12-01 | 呼和浩特市合成洗涤剂厂 | Cashmere detergent and making method |
CN1088252A (en) * | 1992-12-09 | 1994-06-22 | 中国科学院新疆化学研究所 | Carpet cleaner |
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CN1117996A (en) | 1996-03-06 |
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