CN104645763A - Method for treating waste gas produced by indium refining - Google Patents

Method for treating waste gas produced by indium refining Download PDF

Info

Publication number
CN104645763A
CN104645763A CN201410167434.0A CN201410167434A CN104645763A CN 104645763 A CN104645763 A CN 104645763A CN 201410167434 A CN201410167434 A CN 201410167434A CN 104645763 A CN104645763 A CN 104645763A
Authority
CN
China
Prior art keywords
gas
indium
waste gas
refinery
spray scrubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410167434.0A
Other languages
Chinese (zh)
Other versions
CN104645763B (en
Inventor
粟红卫
刘小明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hanwa Technology Co ltd
Original Assignee
Guangxi Yin Tai Science And Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi Yin Tai Science And Technology Ltd filed Critical Guangxi Yin Tai Science And Technology Ltd
Priority to CN201410167434.0A priority Critical patent/CN104645763B/en
Publication of CN104645763A publication Critical patent/CN104645763A/en
Application granted granted Critical
Publication of CN104645763B publication Critical patent/CN104645763B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Treating Waste Gases (AREA)

Abstract

The invention discloses a method for treating waste gas produced by indium refining, and relates to the technical field of waste gas treatment. A device for treating the waste gas produced by indium refining is used by the method; the method comprises the steps of A. collecting waste gas to be treated by suction hoods arranged above a plurality of pot bodies; B. inputting the collected waste gas to be treated into a filter through an exhaust pipe, and carrying out adsorption treatment on the waste gas by filter material in the filter; C. carrying out spray washing treatment and cooling treatment on the gas subjected to adsorption treatment by a water solution in a primary spray washing tower; D. carrying out activated carbon adsorption treatment on the washed and cooled gas by activated carbon in an activated carbon adsorption tower; and E. carrying out spray washing treatment on the gas which is adsorbed by the activated carbon by washing liquid in a secondary spray washing tower to complete the treatment for the waste gas produced by indium refining. Compared with the prior art, the method is capable of absorbing the waste gas produced in the indium refining process, and the treated gas is in accordance with the relevant regulation of emission in China and can be directly discharged into the atmosphere.

Description

Indium refinery-off gas administering method
Technical field
The present invention relates to waste gas pollution control and treatment technical field, especially a kind of for the administering method producing waste gas in indium refining process.
Background technology
Indium refining is one of important step of indium ingot ingot casting production, and smart indium refining is the process of being carried out by low-purity finished product indium purifying; By electrolysis low-purity finished product indium is out placed in the pot body of molten indium pot, add the organic solvents such as glycerine, KI, sal-ammoniac and inolrganic chemicals and finished product indium and carry out refining, make indium in the molten state with cast highly purified indium ingot after magazins' layout; But indium is in molten indium pot heating refining process, the waste gas be made up of gas and vapor permeation such as glycerine, iodine vapor, hydrogen chloride and ammonias in a large number can be produced, the current governance approach to indium refining generation waste gas on the factory building wall laying multiple molten indium pot, installs the exhaust duct being provided with air exhauster, by exhaust duct directly to outer discharging waste gas.Due to by waste gas directly to outer discharge, these waste gas volatilize in atmosphere disperse produce foul odour, not only can endanger the health of operator, also can cause severe contamination to environment.
Summary of the invention
The object of this invention is to provide a kind of indium refinery-off gas administering method, to solve in existing indium refining process directly to the problem of outer discharging waste gas to environment.
In order to solve the problem, the technical solution used in the present invention is: a kind of indium refinery-off gas administering method, use a kind of indium refinery-off gas controlling device, this indium refinery-off gas controlling device includes the multiple molten indium pot and the exhaust duct that are provided with pot body, an air-suction cover be communicated with described exhaust duct is equipped with above multiple described pot body, described exhaust duct is connected with by the air inlet of filter with one-level spray scrubber, the described gas outlet of one-level spray scrubber is connected with the air inlet of activated carbon adsorber, the gas outlet of described activated carbon adsorber is connected by the air inlet of centrifugal blower with secondary spray scrubber,
Operating procedure comprises:
A, collect pending waste gas by the described air-suction cover be located at above multiple described pot body;
B, inputting described filter by collecting pending waste gas by described exhaust duct, using the filtering material in described filter to carry out adsorption treatment to waste gas;
C, use the aqueous solution in described one-level spray scrubber to the gas completing adsorption treatment carry out spray washing process and cooling process;
D, use the active carbon in described activated carbon adsorber to washing cooling after gas carry out charcoal absorption process;
E, the cleaning solution in described secondary spray scrubber is used to carry out to the gas completing charcoal absorption process the improvement that namely spray washing process completes indium refinery-off gas.
In technique scheme, technical scheme is more specifically: the described filtering material in step B is non-woven fabrics of synthetic fiber; The sodium hydroxide solution of to be concentration the be 0.25mol/L ~ 1.25mol/L of the described cleaning solution in E step.
Further, the described one-level spray scrubber in described indium refinery-off gas controlling device and described secondary spray scrubber include cylindrical shell and are located at the liquid reserve tank of described cylinder body bottom; Described cylindrical shell is divided into upper spray chamber and lower spray chamber by the baffle for separating with through hole, the shower tray be communicated with successively by water pipe is equipped with on the top of each spray chamber, the below of the described shower tray in each spray chamber is equipped with adsorption stuffing, and the described shower tray be communicated with successively by water pipe is communicated with described liquid reserve tank by water pump; The air inlet of described one-level spray scrubber and described secondary spray scrubber is all located at the top of described liquid reserve tank, and the gas outlet of described one-level spray scrubber and described secondary spray scrubber is all located at the top of described cylindrical shell.
Owing to have employed technique scheme, the present invention compared with prior art has following beneficial effect: administer the waste gas that indium refining process produces owing to employing a kind of indium refinery-off gas controlling device of crossing at indium refining process, first the waste gas that molten refining produces is collected, by filter, the waste gas of collection is carried out adsorption treatment successively and remove flue dust and water smoke, by the aqueous solution of one-level spray scrubber, EGT is reduced to gas shower washing, the stench in waste gas is removed by activated carbon adsorber adsorption treatment, the odor molecules of poisoning, by the washing of secondary spray scrubber washing agent, the malodorous elements in waste gas gas phase is transferred to liquid phase, wherein concentration is that the washing agent of the sodium hydroxide solution of 0.25mol/L ~ 1.25mol/L and malodorous elements occur to neutralize and chemical reaction removes stench smell substance in waste gas, gas after improvement meets the relevant regulations of country's discharge, can directly be discharged in air, eliminates waste gas pollution on the environment.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention.
Fig. 2 is the structural representation of one-level spray scrubber of the present invention.
Fig. 3 is the structural representation of secondary spray scrubber of the present invention.
Detailed description of the invention
Below in conjunction with accompanying drawing embodiment, the invention will be further described:
Embodiment 1:
A kind of indium refinery-off gas administering method, use indium refinery-off gas controlling device as shown in Figure 1, this indium refinery-off gas controlling device includes molten indium pot and the exhaust duct 3 that three are provided with pot body 1, the present embodiment is equipped with an air-suction cover 2 be communicated with exhaust duct 3 by pipeline above three molten indium pot pot bodies 1, exhaust duct 3 is connected by the air inlet 401 of pipe-and-filter 4, the gas outlet 402 of filter 4 is connected with the air inlet 501 of one-level spray scrubber 5 by pipeline, the gas outlet 502 of one-level spray scrubber 5 is connected with the air inlet 701 of activated carbon adsorber 7 by pipeline, the gas outlet 702 of activated carbon adsorber 7 is connected with the air inlet 901 of secondary spray scrubber 9 by centrifugal blower 8, volume damper 6 is connected with by pipeline between activated carbon adsorber 4 and the air inlet 901 of secondary spray scrubber 9, the aperture of control valve 6 is regulated according to the condition of production of molten indium pot.The liquid reserve tank 505 that one-level spray scrubber 5 as shown in Figure 2 includes cylindrical shell 506 and is contained in bottom cylindrical shell 506, fills the aqueous solution that scrubbing exhaust gas is used in liquid reserve tank 505; Cylindrical shell 506 is divided into upper spray chamber and lower spray chamber by two pieces of dividing plates 511 with multiple through hole respectively, the upper shower tray 510 and lower shower tray 508 that are communicated with successively by water pipe are housed respectively on upper spray chamber and the top of lower spray chamber, below the upper shower tray 510 in upper spray chamber and in lower spray chamber and below lower shower tray 508, all adsorption stuffing are housed; The upper shower tray 510 be communicated with successively by water pipe is communicated with water pump 12 by the water pipe be communicated with water inlet 503 with lower shower tray 508, and water pump 12 is communicated with the delivery port 504 of liquid reserve tank 505 by water pipe; The air inlet 501 of one-level spray scrubber is arranged on the top of liquid reserve tank 505, and the gas outlet 502 of one-level spray scrubber is arranged on the top of cylindrical shell 506.
The liquid reserve tank 905 that secondary spray scrubber 9 as shown in Figure 3 includes cylindrical shell 906 and is contained in bottom cylindrical shell 906, fills the NaOH washing liquid that scrubbing exhaust gas is used in liquid reserve tank 905; Cylindrical shell 906 is divided into upper spray chamber and lower spray chamber by two pieces of dividing plates 911 with multiple through hole respectively, the upper shower tray 910 and lower shower tray 908 that are communicated with successively by water pipe are housed respectively on upper spray chamber and the top of lower spray chamber, below the upper shower tray 910 in upper spray chamber and in lower spray chamber and below lower shower tray 908, all adsorption stuffing are housed; The upper shower tray 910 be communicated with successively by water pipe is communicated with water pump 10 by the water pipe be communicated with water inlet 903 with lower shower tray 908, water pump 10 is communicated with the delivery port 904 of liquid reserve tank 905 by water pipe, the sodium hydroxide solution of to be concentration the be 0.25mol/L of the washing agent in liquid reserve tank 905; The air inlet 901 of secondary spray scrubber is arranged on the top of liquid reserve tank 905, and the gas outlet 902 of secondary spray scrubber is arranged on the top of cylindrical shell 906.
Indium refinery-off gas is administered operating procedure and is comprised:
A, collect pending waste gas by the air-suction cover 2 be contained in above three pot bodies 1;
B, will collect pending waste gas by exhaust duct 3 input filter 4, use the filtering material in filter 4 to carry out adsorption treatment to waste gas, the filtering material of the present embodiment is non-woven fabrics of synthetic fiber;
The aqueous solution in C, use one-level spray scrubber 5 carries out spray washing process and cooling process to the gas completing adsorption treatment;
Active carbon in D, use activated carbon adsorber 7 carries out charcoal absorption process to the gas after washing cooling;
The sodium hydroxide solution that concentration in E, use secondary spray scrubber 5 is 0.25mol/L carries out to the gas completing charcoal absorption process the improvement that namely spray washing process completes indium refinery-off gas.
Embodiment 2:
The sodium hydroxide solution of to be concentration the be 0.25mol/L of the washing agent in liquid reserve tank 905; Other features are identical with embodiment 1.
Indium refinery-off gas is administered operating procedure and is comprised:
A, collect pending waste gas by the air-suction cover 2 be contained in above three pot bodies 1;
B, will collect pending waste gas by exhaust duct 3 input filter 4, use the filtering material in filter 4 to carry out adsorption treatment to waste gas, the filtering material of the present embodiment is non-woven fabrics of synthetic fiber;
The aqueous solution in C, use one-level spray scrubber 5 carries out spray washing process and cooling process to the gas completing adsorption treatment;
Active carbon in D, use activated carbon adsorber 7 carries out charcoal absorption process to the gas after washing cooling;
The sodium hydroxide solution that concentration in E, use secondary spray scrubber 9 is 0.25mol/L carries out to the gas completing charcoal absorption process the improvement that namely spray washing process completes indium refinery-off gas.

Claims (3)

1. an indium refinery-off gas administering method, is characterized in that:
Use a kind of indium refinery-off gas controlling device, this indium refinery-off gas controlling device includes the multiple molten indium pot and the exhaust duct (3) that are provided with a pot body (1), an air-suction cover (2) be communicated with described exhaust duct (3) is equipped with in the top of multiple described pot body (1), described exhaust duct (3) is connected with by the air inlet of filter (4) with one-level spray scrubber (5), the gas outlet of described one-level spray scrubber (5) is connected with the air inlet of activated carbon adsorber (7), the gas outlet of described activated carbon adsorber (7) is connected by the air inlet of centrifugal blower (8) with secondary spray scrubber (9),
Operating procedure comprises:
A, collect pending waste gas by the described air-suction cover (2) being located at multiple described pot body (1) top;
B, inputting described filter (4) by collecting pending waste gas by described exhaust duct (3), using the filtering material in described filter (4) to carry out adsorption treatment to waste gas;
C, use the aqueous solution in described one-level spray scrubber (5) to the gas completing adsorption treatment carry out spray washing process and cooling process;
D, use the active carbon in described activated carbon adsorber (7) to washing cooling after gas carry out charcoal absorption process;
E, the cleaning solution in described secondary spray scrubber (5) is used to carry out to the gas completing charcoal absorption process the improvement that namely spray washing process completes indium refinery-off gas.
2. according to claim 1 at indium refinery-off gas administering method, it is characterized in that: the described filtering material in step B is non-woven fabrics of synthetic fiber; The sodium hydroxide solution of to be concentration the be 0.25mol/L ~ 1.25mol/L of the described cleaning solution in E step.
3. according to claim 1 at indium refinery-off gas administering method, it is characterized in that: the described one-level spray scrubber in described indium refinery-off gas controlling device and described secondary spray scrubber include cylindrical shell and be located at the liquid reserve tank of described cylinder body bottom; Described cylindrical shell is divided into upper spray chamber and lower spray chamber by the baffle for separating with through hole, the shower tray be communicated with successively by water pipe is equipped with on the top of each spray chamber, the below of the described shower tray in each spray chamber is equipped with adsorption stuffing, and the described shower tray be communicated with successively by water pipe is communicated with described liquid reserve tank by water pump; The air inlet of described one-level spray scrubber and described secondary spray scrubber is all located at the top of described liquid reserve tank, and the gas outlet of described one-level spray scrubber and described secondary spray scrubber is all located at the top of described cylindrical shell.
CN201410167434.0A 2014-04-24 2014-04-24 Indium refinery-off gas administering method Active CN104645763B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410167434.0A CN104645763B (en) 2014-04-24 2014-04-24 Indium refinery-off gas administering method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410167434.0A CN104645763B (en) 2014-04-24 2014-04-24 Indium refinery-off gas administering method

Publications (2)

Publication Number Publication Date
CN104645763A true CN104645763A (en) 2015-05-27
CN104645763B CN104645763B (en) 2017-04-05

Family

ID=53237704

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410167434.0A Active CN104645763B (en) 2014-04-24 2014-04-24 Indium refinery-off gas administering method

Country Status (1)

Country Link
CN (1) CN104645763B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105169894A (en) * 2015-07-21 2015-12-23 天津霍普环保科技有限公司 Sulfur-containing exhaust gas disposal system
CN108355459A (en) * 2017-12-08 2018-08-03 中国电子科技集团公司第十三研究所 The processing unit of gas soot dust granule tail gas

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0848640B1 (en) * 1995-09-07 1999-03-31 AUSTRIAN ENERGY & ENVIRONMENT SGP/WAAGNER-BIRO GmbH Process and device for scrubbing acidic gases
CN202224049U (en) * 2011-09-15 2012-05-23 常州天兴环保科技有限公司 Acid and hydrocarbon mixed waste gas treatment equipment
CN202538579U (en) * 2012-03-09 2012-11-21 贝格工业涂料(广州)有限公司 Industrial coating waste gas treatment system
CN202683025U (en) * 2012-06-04 2013-01-23 遵化市北方锅炉有限公司 Garbage incineration flue gas purification device
CN203139853U (en) * 2013-01-31 2013-08-21 绍兴新宇环保设备有限公司 Water spray purification tower

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0848640B1 (en) * 1995-09-07 1999-03-31 AUSTRIAN ENERGY & ENVIRONMENT SGP/WAAGNER-BIRO GmbH Process and device for scrubbing acidic gases
CN202224049U (en) * 2011-09-15 2012-05-23 常州天兴环保科技有限公司 Acid and hydrocarbon mixed waste gas treatment equipment
CN202538579U (en) * 2012-03-09 2012-11-21 贝格工业涂料(广州)有限公司 Industrial coating waste gas treatment system
CN202683025U (en) * 2012-06-04 2013-01-23 遵化市北方锅炉有限公司 Garbage incineration flue gas purification device
CN203139853U (en) * 2013-01-31 2013-08-21 绍兴新宇环保设备有限公司 Water spray purification tower

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
何长顺等编著: "《突发性环境污染事故应急处置手册》", 30 April 2011, article "第十七节 铟冶炼工艺环境污染事故及应急" *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105169894A (en) * 2015-07-21 2015-12-23 天津霍普环保科技有限公司 Sulfur-containing exhaust gas disposal system
CN108355459A (en) * 2017-12-08 2018-08-03 中国电子科技集团公司第十三研究所 The processing unit of gas soot dust granule tail gas
CN108355459B (en) * 2017-12-08 2024-05-03 中国电子科技集团公司第十三研究所 Treatment device for tail gas of gas smoke dust particles

Also Published As

Publication number Publication date
CN104645763B (en) 2017-04-05

Similar Documents

Publication Publication Date Title
CN206746314U (en) A kind of foul gas processing unit
CN202893157U (en) Movable waste gas collecting and treating device
CN204395758U (en) The waste gas treatment device of a kind of VOCs
CN202224049U (en) Acid and hydrocarbon mixed waste gas treatment equipment
CN206793295U (en) A kind of industrial mix waste gas processing equipment
CN105582804B (en) A kind of organic exhaust gas biological treatment reactor and its application method
CN204816223U (en) Industrial waste gas purifies drying device
CN104645763A (en) Method for treating waste gas produced by indium refining
CN211358269U (en) Kitchen garbage leachate odour removal device
CN206535372U (en) New waste gas filtration and adsorption treatment device
CN211025674U (en) Exhaust emission device for printing and dyeing
CN204429042U (en) A kind of active carbon inhales circulated sprinkling air peculiar smell scavenge unit
CN211753956U (en) Ozone catalytic tower for treating industrial waste gas
CN210079234U (en) Deodorization equipment for garbage disposal
CN205570096U (en) Circulation exhaust -gas treatment equipment
CN203842490U (en) Indium refining waste gas treatment device
CN105413419B (en) Refuse landfill odor treating device
CN205095624U (en) Low concentration waste gas pollution control and treatment and deodorization system
CN210993566U (en) Water smoke oil smoke air purifier
CN107551786A (en) A kind of deodorization treatment device for exhaust
CN208694662U (en) A kind of photooxidation catalytic waste gas processing unit
CN207928933U (en) A kind of non-woven fabric production equipment emission-control equipment
CN204261548U (en) Poultry farms waste gas photocatalysis treatment device
CN206715663U (en) A kind of environmentally friendly exhaust gas processing device for factory of painting
CN205235730U (en) Landfill odor treatment device

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20210928

Address after: 510700 public space office card booth B030 of youth home innovation and entrepreneurship incubation base, unit 1004, No. 182, science Avenue, Huangpu District, Guangzhou, Guangdong Province

Patentee after: Guangzhou Hanpu Technology Co.,Ltd.

Address before: 545212 No.1 Jian'an Road, Liutang Industrial Zone, Liutang Town, Liucheng County, Liuzhou City, Guangxi Zhuang Autonomous Region

Patentee before: GUANGXI YINTAI TECHNOLOGY Co.,Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20221117

Address after: 510670 room 229, annex building, No. 111, Kexue Avenue, Huangpu District, Guangzhou City, Guangdong Province (office only)

Patentee after: Hanwa Technology Co.,Ltd.

Address before: 510700 public space office card booth B030 of youth home innovation and entrepreneurship incubation base, unit 1004, No. 182, science Avenue, Huangpu District, Guangzhou, Guangdong Province

Patentee before: Guangzhou Hanpu Technology Co.,Ltd.