CN104642530B - A kind of method of comprehensive utilization of Enteromorpha - Google Patents
A kind of method of comprehensive utilization of Enteromorpha Download PDFInfo
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- CN104642530B CN104642530B CN201510065595.3A CN201510065595A CN104642530B CN 104642530 B CN104642530 B CN 104642530B CN 201510065595 A CN201510065595 A CN 201510065595A CN 104642530 B CN104642530 B CN 104642530B
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- enteromorpha
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Abstract
The present invention relates to biomass resource utilization field, and in particular to a kind of method of comprehensive utilization of Enteromorpha.It is an object of the invention to provide a kind of full utilization, the Enteromorpha high added value method of comprehensive utilization of nil waste, for the characteristic of Enteromorpha, by aerobic fermentation and anaerobic fermentation, fruit antistaling agent, biogas, organic fertilizer is produced using Enteromorpha, realizes that pipeline system produces.The protrusion application value of the present invention is cmpletely to make use of this resource of Enteromorpha, both the marine ecology problem that Enteromorpha largely grows initiation had been eliminated, three kinds of high fruit antistaling agent of commodity value, biogas, organic fertilizer commodity are developed again, and there is sufficient commercialized development value.
Description
Technical field
The present invention relates to biomass resource utilization field, and in particular to a kind of method of comprehensive utilization of Enteromorpha.
Background technology
Enteromorpha is called tongue bar, green laver etc., is a kind of widely distributed tangleweed.Enteromorpha is nutritious, and protein contains
Measure 9%-14%, fatty 0.9%-2%, crude fibre 8%-12%, ash content 18%-25%.In addition, the fertility of Enteromorpha is extremely strong, from
Since 2007, Enteromorpha " green tide " repeatedly occurs for Shandong Province of China marine site, and substantial amounts of Enteromorpha drifts to Qingdao from the Central Yellow Sea area
Surrounding waters floating gathers bank, and not only rot smelly, pollution environment, and the Enteromorpha of these aggregations can block the fairway, sternly
Weight has threatened inshore fishing, the development of tourist industry.2008 Qingdao marine site green tide area coverages are beaten more than 2 × 10 k m2
Drag for 8 × l0 of Enteromorpha 7kg.In recent years, scientists actively study the application value of Enteromorpha, be widely used in food,
Agricultural and medicine and other fields.
The patent No. CN101418315, CN102876727, CN101665807, biogas is produced using fermenting enteromorpha, but fermented
Time is longer, time consumption and energy consumption, and no effective Application way for providing biogas residue, fails the value of full-scale development Enteromorpha,
The patent No. CN103772073, CN103772012A, CN103352016 make one kind using aerobic fermentation and favorably use crop and soil
The organic fertilizer of earth, but it has carried out single product obtained from complex processing to Enteromorpha, it is impossible to Enteromorpha is played completely dives
Power.Patent No. CN103583683A, CN103040075 proposes a kind of method that antistaling agent is produced using Enteromorpha, but it is sharp
Single with method, utilization is not thorough.In terms of scientific paper《The research of fresh fermenting enteromorpha production its biogas potentiality at room temperature》、《Particle
The influence of size and several preprocess methods to Enteromorpha producing methane through anaerobic fermentation》,《Different pretreatments and fermentation condition are to Enteromorpha natural pond
The influence of gas yield》There is excellent production its biogas potentiality Deng Enteromorpha is demonstrated, but the pretreatment in its technique be entirely in order to
Anaerobic fermentation and prepare, and product can not be obtained, can not therefrom develop potential value, it is considerable more to provide value to biogas residue
Land use systems, be unable to reach the purpose of full-scale development.
The content of the invention
It is an object of the invention to provide it is a kind of be fully utilized, the Enteromorpha high added value method of comprehensive utilization of nil waste,
While reducing Enteromorpha " green tide " disaster, preferable environmental benefit and higher economic benefit are obtained.
The present invention is realized by the following technical programs, is comprised the steps of:
(1)Fresh Enteromorpha or dry Enteromorpha are rinsed with water, remove the impurity in Enteromorpha, or are not rinsed and directly carried out step
(2);
(2)Enteromorpha is pre-processed, it is 0.5-10 millimeters that Enteromorpha, which is ground into particle diameter, or Enteromorpha is cut into 1-10
Centimetre waterside tongue bar;
(3)Pretreated Enteromorpha is put into aerobic fermentation equipment, adds water to make the total solids content in installation for fermenting be
0.5-5%, inoculum is added, inoculum concentration 0.2-2% carries out ferment at constant temperature, and fermentation temperature is 25-35 DEG C;
(4)Fermenting enteromorpha filters after 6-10 days, and filtrate separates supernatant and Enteromorpha residue, supernatant are directly made through centrifugation
For fruit antistaling agent use, or by supernatant it is concentrated after prepare concentrate, freeze-drying after pulvis is made;
(5)With step(4)The Enteromorpha residue of separation is that raw material carries out anaerobic fermentation, and centrifugation gained Enteromorpha residue input is detested
In aerobe fermentation tank, biogas slurry or biogas residue are added, the total solids content into anaerobic fermentation tank plus in water regulation installation for fermenting is
5-25%, it is 6.5-8.5 to control pH value, is sealed by fermentation, and fermentation temperature is 30-58 DEG C, every 5-15 days, discharges 10-50% natural pond
Slag, and add the raw material of identical dry matter content;
(6)Use step(5)The biogas residue production organic fertilizer of discharge.
Wherein:Step(3)It is thin comprising acidfast bacilli door, actinomyces door, Bacteroidetes, green curved bacterium door, indigo plant in inoculum used
Two or more microorganisms in bacterium door, Firmicutes, bud monad door, floating mould door, protein fungus door, wart germ door.
Step(4)The supernatant contains trehalose and glycine betaine.
The method of the biogas residue production organic fertilizer of discharge is as follows:Biogas residue is dried to moisture 10%-20%.And then it is crushed to
It is adapted to the granularity being granulated.Add acid-base modifier, inorganic fertilizer(Different special fertilizers are obtained by increasing certain nutritional ingredient), it is micro-
Biological agent(Also can spray after the pelletizing)Deng auxiliary material, be well mixed, comminutor granulation, shaping, sieving, packaging, inspection, into
Product.
The protrusion application value of the present invention is cmpletely to make use of this resource of Enteromorpha, had both eliminated Enteromorpha and largely grown
The raw marine ecology problem triggered, develops three kinds of high fruit antistaling agent of commodity value, biogas, organic fertilizer commodity again, has
There is the commercialized development value of abundance.
Specific implementation method:
A kind of specific implementation method of the present invention is expanded on further with reference to application example, the present invention includes but is not limited to
Implementation in detail below.
Embodiment 1
(1)10 tons of 85% fresh Enteromorphas of water content are carried out with rinsing 3 times with fresh water, removes part salinity and mud in Enteromorpha
The impurity such as sand;
(2)Enteromorpha is pre-processed, Enteromorpha is cut into 5 centimetres of waterside tongue bar;
(3)Enteromorpha is put into aerobic fermentation equipment, adding fresh water makes total solids content in installation for fermenting be 5%, adds
Inoculum(EM-W microbial inoculums), inoculum concentration 2%.It is placed in fermentation bed and carries out ferment at constant temperature, cultivation temperature is 35 DEG C.
(4)Fermenting enteromorpha filters after 10 days, and filtrate separates supernatant and Enteromorpha residue through centrifugation.After supernatant is packed
Cook fruit liquidpreservatives.
(5)With step(4)The fermentation residue of separation is that raw material carries out anaerobic methane fermentation.Centrifugation gained Enteromorpha residue is thrown
Enter in anaerobic fermentation tank, add biogas slurry or biogas residue, the total solid into anaerobic fermentation tank plus in water regulation installation for fermenting contains
Measure as 5%;It is 7 to control pH value.It is sealed by fermentation, fermentation temperature is 37 DEG C.Every 10 days, 20% biogas residue is discharged, and is added identical
The raw material of dry matter content.
(6)Use step(5)The biogas residue production organic fertilizer of discharge.Biogas residue is dried to moisture 15%.And then it is crushed to suitable
Close the granularity being granulated.Add acid-base modifier, inorganic fertilizer(Different special fertilizers are obtained by increasing certain nutritional ingredient), micro- life
Thing preparation(Also can spray after the pelletizing)Deng auxiliary material, it is well mixed.Comminutor is granulated.Shaping, sieving, packaging, inspection, finished product.
In this example, the fresh Enteromorpha of 10 tons of water content 85% can produce 30 tons of liquid fruit antistaling agents, 600 cubic metres
Biogas and 1.2 tons of organic fertilizers, substantially increase the economic value of Enteromorpha.
Embodiment 2
(1)To pre-processing, the half-dried Enteromorpha of 10 tons of water content 40% is crushed to particle diameter as 5 millimeters;
(2)Enteromorpha is put into aerobic fermentation equipment, adding water makes total solids content in installation for fermenting be 0.5%, adds
Inoculum(Fermenting microbial inoculum), inoculum concentration 0.2%.It is placed in fermentation bed and carries out ferment at constant temperature, cultivation temperature is 25 DEG C.
(3)Fermenting enteromorpha filters after 6 days, and filtrate separates supernatant and Enteromorpha residue through centrifugation.Done after supernatant is packed
Fruit liquidpreservatives.
(4)With step(3)The fermentation residue of separation is that raw material carries out anaerobic fermentation.Centrifugation gained Enteromorpha residue input is detested
In aerobe fermentation tank, biogas slurry is added, the total solids content into anaerobic fermentation tank plus in water regulation installation for fermenting is 5%;Control PH
It is worth for 6.5.It is sealed by fermentation, fermentation temperature is 30 DEG C.Every 15 days, 10% biogas residue is discharged, and adds identical dry matter content
Raw material.
(5)Use step(4)The biogas residue production organic fertilizer of discharge.Biogas residue is dried to moisture 10%.And then it is crushed to suitable
Close the granularity being granulated.Add acid-base modifier, inorganic fertilizer(Different special fertilizers are obtained by increasing certain nutritional ingredient), micro- life
Thing preparation(Also can spray after the pelletizing)Deng auxiliary material, it is well mixed.Comminutor is granulated.Shaping, sieving, packaging, inspection, finished product.
In this example, the half-dried Enteromorpha of 10 tons of water content 40% can produce 63 tons of liquid fruit antistaling agents, 1150 cubes
Meter Zhao Qi and 1.2 ton of organic fertilizer, substantially increase the economic value of Enteromorpha.
Embodiment 3
(1)10 tons of dry Enteromorphas are rinsed with water, the impurity such as part salinity and silt in removing Enteromorpha;
(2)Enteromorpha is pre-processed, Enteromorpha is crushed to particle diameter as 10 millimeters;
(3)Enteromorpha is put into aerobic fermentation equipment, adding water makes total solids content in installation for fermenting be 2%, and addition connects
Kind thing(Bacillus subtilis, Pseudoalteromonas, bacillus pumilus, bacillus licheniformis, Trichoderma viride composite bacteria agent), connect
Kind amount is 1%.It is placed in fermentation bed and carries out ferment at constant temperature, cultivation temperature is 30 DEG C.
(4)Fermenting enteromorpha filters after 8 days, and filtrate separates supernatant and Enteromorpha residue through centrifugation.Done after supernatant is packed
Fruit liquidpreservatives.
(5)With step(4)The fermentation residue of separation is that raw material carries out anaerobic fermentation.Centrifugation gained Enteromorpha residue input is detested
In aerobe fermentation tank, biogas slurry is added, the total solids content into anaerobic fermentation tank plus in water regulation installation for fermenting is 25%;Control
PH value is 8.5.It is sealed by fermentation, fermentation temperature is 55 DEG C.Every 5 days, 50% biogas residue is discharged, and adds identical dry matter content
Raw material.
(6)Use step(5)The biogas residue production organic fertilizer of discharge.Biogas residue is dried to moisture 20%.And then it is crushed to suitable
Close the granularity being granulated.Add acid-base modifier, inorganic fertilizer(Different special fertilizers are obtained by increasing certain nutritional ingredient), micro- life
Thing preparation(Also can spray after the pelletizing)Deng auxiliary material, it is well mixed.Comminutor is granulated.Shaping, sieving, packaging, inspection, finished product.
In this example, 10 tons of dry Enteromorphas can produce 250 tons of liquid fruit antistaling agents, 4200 cubic metres of biogas and 4.5
Ton organic fertilizer, substantially increase the economic value of Enteromorpha.
Claims (3)
- A kind of 1. method of comprehensive utilization of Enteromorpha, it is characterised in that:It the described method comprises the following steps:(1)Fresh Enteromorpha or dry Enteromorpha are rinsed with water, remove the impurity in Enteromorpha, or are not rinsed and directly carried out step(2);(2)Enteromorpha is pre-processed, it is 0.5-10 millimeters that Enteromorpha, which is ground into particle diameter, or Enteromorpha is cut into 1-10 lis The waterside tongue bar of rice;(3)Pretreated Enteromorpha is put into aerobic fermentation equipment, adds water to make total solids content in installation for fermenting be 0.5- 5%, inoculum is added, inoculum concentration 0.2-2% carries out ferment at constant temperature, and fermentation temperature is 25-35 DEG C;(4)Fermenting enteromorpha filters after 6-10 days, and filtrate separates supernatant and Enteromorpha residue, supernatant is directly as water through centrifugation Fresh-keeping agent of fruits use, or by supernatant it is concentrated after prepare concentrate, freeze-drying after pulvis is made;(5)With step(4)The Enteromorpha residue of separation is that raw material carries out anaerobic fermentation, by centrifugation gained Enteromorpha residue input anaerobism hair In fermentation tank, biogas slurry or biogas residue are added, the total solids content into anaerobic fermentation tank plus in water regulation installation for fermenting is 5- 25%, it is 6.5-8.5 to control PH values, is sealed by fermentation, and fermentation temperature is 30-58 DEG C, every 5-15 days, discharges 10-50% natural pond Slag, and add the raw material of identical dry matter content;(6)Use step(5)The biogas residue production organic fertilizer of discharge;Step(3)Acidfast bacilli door, actinomyces door, Bacteroidetes, green curved bacterium door, cyanobacteria door, heavy wall are included in inoculum used Two or more microorganisms in bacterium door, bud monad door, floating mould door, protein fungus door, wart germ door.
- A kind of 2. method of comprehensive utilization of Enteromorpha according to claim 1, it is characterised in that:Step(4)The supernatant Contain trehalose and glycine betaine.
- A kind of 3. method of comprehensive utilization of Enteromorpha according to claim 1, it is characterised in that:The biogas residue production of discharge has The method of machine fertilizer is as follows:Biogas residue is dried to moisture 10%-20%, and then is crushed to the granularity for being adapted to granulation, and is added auxiliary Material, it is well mixed, comminutor granulation, shaping, sieving, packaging, inspection, finished product.
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CN105265792A (en) * | 2015-10-27 | 2016-01-27 | 盐城工学院 | Alga fermentation feed additive and preparation method of alga fermentation feed additive |
CN107746296A (en) * | 2017-08-17 | 2018-03-02 | 江西涞腾实业有限公司 | A kind of preparation method of alga fertilizer |
CN107640982A (en) * | 2017-10-09 | 2018-01-30 | 南昌大学 | A kind of alga fertilizer preparation method using yellow tang as raw material |
CN107793214A (en) * | 2017-10-09 | 2018-03-13 | 南昌大学 | A kind of alga fertilizer preparation method using sargassum fusifome as raw material |
CN108002954B (en) * | 2017-12-12 | 2021-08-10 | 农业部规划设计研究院 | Anaerobic-aerobic balanced fermentation method for agricultural wastes |
CN110881360A (en) * | 2019-12-27 | 2020-03-17 | 董霞 | Process method for producing edible fungi by utilizing enteromorpha |
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