Air ion Mobility Spectrum Analysis method and instrument
Technical field
The present invention relates to the methods and instrument of charged particle in a kind of measurement air, especially measure the instrument of air ion
Device.
Background technique
Small charged particle in air is known as air ion or air ion.Air ion is at unit strength (1V/m)
Movement speed under electric field action is known as ionic mobility.Ionic mobility is to differentiate an important ginseng of air ion size
Number.In general, ionic mobility is smaller, the partial size of ion is bigger.According in the past few decades come the researcher of many countries
The research of suspended particle size size relation in mobility and air for air ion.It can be by air ion according to moving
The of different sizes of shifting rate is divided into following a few classes (mobility is average mobility):
Small ion 1. (small cluster) mobility K=1.3cm2/VS diameter 0.85nm
Small ion group 2. (big cluster) mobility K=0.5cm2/ VS diameter 1.6nm
3. intermediate ion (intermediate) mobility K=0.034cm2/ VS diameter 7.4nm
4. light-duty big ion (light large) mobility K=0.0042cm2/ VS diameter 22nm
5. heavy big ion (heavy large) mobility K=0.00041cm2/ VS diameter 79nm
Superheavy ion 6. (super heavy) mobility K=0.00005cm20.4 μm of/VS diameter
The size of air ion partial size and the clean-up performance of ambient air are closely related.In clean atmosphere,
Air ion has bigger mobility, they belong to small ion.And then there is many gas in the air for having received pollution
Migration can be become after charge entrained by colloidal sol and the biggish particulate matter of partial size, these aerosols or particulate matter capture small ion
During rate is lower, big ion or heavy ion or even superheavy ion.The mobility that different air pollutants are formed by ion is
Different;Observe, study under the conditions of various Different climates and when various air pollutants occur air ion mobility spectrometry change
Change and can be used as a kind of foundation analyzed air quality, evaluate atmospheric pollution level.
According to the structure of the definition of ionic mobility and air ion collector, the meter of available air ion mobility
Calculate formula:
In formula: the K- collector ionic mobility limit (cm2/cm2/V·S);
The distance between d- collecting board and polarising sheet (cm);
VxAir velocity (cm/S) in collector;
L- collecting board length (cm);
U- polarizing voltage (V).
Existing air ion measuring instrument is made of ion trap, micro current amplifier, polarization power supply and air exhauster etc..
Ion trap includes ioncollection plate, polarising sheet;The polarity for changing polarizing voltage can change the polarity of measured ion;
The length for changing the amplitude of polarizing voltage, the air velocity in collector and collecting board can change ionic mobility.
The covered ionic mobility of existing air ion measuring instrument institute can only achieve in small ion and sub-fraction from
The range of son;There are sizable gaps between complete air ion mobility spectrum.Scientific research the result shows that, to human body
Most of the air pollutants of health hazard especially severe are distributed in the scope of big ion, superheavy ion.Obviously, existing air from
The test result of sub- measuring instrument cannot reflect the quality status of air.It needs to be improved.
Summary of the invention
It is an object of that present invention to provide the methods and instrument of the measurement of air ion mobility spectrum.This measurement method is not according to
Air ion mobility spectrum is divided into several paragraphs (section) by same ionic mobility value, is based on MCU technology, is controlled, is surveyed respectively
Measure the airion concentration value in each paragraph section;And then form complete ion mobility spectrometry.This measuring instrument is adopted
With capacitor suction-type air ion collector, single channel and the various various forms of ion traps of multichannel are used in combination, it is complete
, until the air ion test of all kinds of different ions mobility values of superheavy ion, complete Ion transfer is made at from small ion
Rate spectrum.This measuring instrument can both measure cation, can also measure anion;Also accommodate the high humidity environment in field
In test.
The present invention is implemented as follows:
A kind of air ion Mobility Spectrum Analysis method, including following items content:
1. air ion mobility spectrum is divided into several sections according to different ionic mobility values by this method, and every section
The air ion in ionic mobility section is collected by a section ion trap;The collecting board connection of every section ion trap is micro- all the way
Current amplifier, each road micro current amplifier are connected to MCU by variable connector;The polarising sheet of every section ion trap is connected to
One group of polarization power supply;It is controlled by MCU, measures the airion concentration value in each section of section respectively, and complete air is consequently formed
Ion mobility spectrometry data.
2. being limit mobility measured by first segment ion trap, the second section and later each section ion trap are surveyed
Amount is interval migration rate.
3. having collector insulation performance to determine measure, by detecting the leakage current of collecting board insulating support, it is judged
Insulation performance.
A kind of single channel tandem air ion Mobility Spectrum Analysis instrument, by sucking condenser type ion trap, micro-current
Amplifier, polarization power supply, MCU etc. are constituted, it is characterized in that: the ion trap of the analyzer is the collection of single-channel air ion
Device, each channel are made of several section ion traps, and every section collector all includes one group of collecting board, polarising sheet;Each section is received
Storage is connected in series, and is mounted in a metal shell, is followed by air exhauster;The speed of exhaust of each section collector is identical;Each section is received
The collecting board of storage is connected respectively to mutually independent micro current amplifier, and polarising sheet is connected respectively to mutually independent polarization electricity
Source, each output for saving micro current amplifier are connected by variable connector with MCU.
The collecting board and polarising sheet of each section collector are fixed on the metal shell of ion trap by insulating support respectively;
Insulating support is made of high insulating property material, is fitted with electrical heating type moisture separating device;It is equipped on collector metal shell
Electrical heating type moisture separating device.
The instrument has the measure of insulating support insulating properties detection;The insulating support insulating properties detection measure is using short
The sampling high resistant short circuit of micro current amplifier is cooperated the polarity for changing polarizing voltage defeated on micro current amplifier by way switch
The reading variable quantity that outlet obtains judges insulation performance.
A kind of Multi-channel parallel connection formula air ion Mobility Spectrum Analysis instrument, by sucking condenser type ion trap, micro-current
Amplifier, polarization power supply, MCU etc. are constituted, it is characterized in that:
The ion trap of the analyzer is multi-channel type air ion collector;Air ion collector is divided into several logical
Road, at least there are two channels, and each channel, which includes at least, one group of collecting board-polarising sheet pair, and each channel is mutually indepedent, is mounted on
In respective metal shell channel, it is followed by air exhauster;The speed of exhaust in each channel can it is identical can also be different;Second channel and
First segment collector in later each channel collects plate earthing as ion filter;The collecting board in each channel is separately connected
To mutually independent micro current amplifier, polarising sheet is connected respectively to mutually independent polarization power supply, each micro current amplifier
Output is connected by variable connector with MCU.
It can be with areal survey opposed polarity, different ions according to the air ion Mobility Spectrum Analysis method and instrument
The airion concentration value in mobility section makes complete air ion mobility spectrogram.
Detailed description of the invention
Fig. 1 is the schematic diagram of air ion Mobility measurement.
Fig. 2 single channel (tandem) air ion mobility spectrum measuring instrument functional block diagram.
Fig. 3 multichannel (parallel) air ion mobility spectrum measuring instrument functional block diagram
Fig. 4 insulating support and drive damp resistance wire, electric heating device scheme of installation.
The circuit diagram of Fig. 5 micro current amplifier A and short switch S
Specific embodiment
The present invention will be further described with reference to the accompanying drawing.
1. polarising sheet, 2. collecting board, 3. insulating support, 4. collector metal shell 5. drives damp 6. electricity of resistance wire in attached drawing
7. micro current amplifier of heating device, 8. short switch 9. is evacuated 10. polarization power supply of blower, 11. variable connector 12.MCU
13.LCD
Embodiment 1: single channel tandem air ion collector is used, one is divided into three section collectors, is mounted on one
In metal shell channel;The limit mobility of first segment collector is 0.4 (cm2/ VS), for collecting small ion;Second section
The interval migration rate of collector is 0.4~0.04 (cm2/ VS) for collecting intermediate ion;The interval migration of third section collector
Rate is 0.04~0.002 (cm2/ VS), for collecting big ion.Every section collector all includes one group of " collecting board-polarization
Plate " is right;The collecting board and polarising sheet of collector are parallel to each other along the direction of pumping airflow, and each collector that saves is connected in series, after
Connect air exhauster.The speed of exhaust of each section collector is identical.
The collecting board and polarising sheet of each section collector are fixed on the metal shell of ion trap by insulating support respectively;
Fig. 4 is insulating support and drives damp resistance wire, electric heating device scheme of installation, and insulating support is by poly- the four of heat-resisting high insulating property
Fluoride material is made, and is fitted with and drives lake resistance wire [5].Electric heating device is installed inside collector metal channel envelope
[6], once collector makes moist, wet steam can be driven away with heating power by driving damp resistance wire [5] and electric heating device [6].
The collecting board of each section collector is connected respectively to mutually independent micro current amplifier [7], and polarising sheet is separately connected
To mutually independent polarization power supply [10], each output for saving micro current amplifier is connected by variable connector [11] with MCU.
The polarising sheet of each section collector is connected with corresponding polarization power supply, and each polarizing voltage that saves is according to corresponding ion
Mobility and be arranged, each collecting board for saving collector, polarising sheet length be arranged according to corresponding ionic mobility.
Each component of the instrument is uniformly controlled by MCU.
The instrument has insulating support dampness, detection of electrical leakage measure.Fig. 5 is the electricity of micro current amplifier A and short switch S
Road connection figure.The input terminal of micro current amplifier [7] is connected with high resistant G and short switch S [8], and short switch S [8] is one
The special switching device with superelevation insulation;The switch is controlled by MCU, for detecting the zero point and insulation of micro current amplifier
The electric leakage degree of bracket.When short switch S [8] is closed, the reading zero of micro current amplifier output end;When it is decontroled, if
Air exhauster [9] does not start to be evacuated (sampling), then the variable quantity of the reading of micro current amplifier output end just represents insulating support
Electric leakage degree.When electric leakage degree is more than certain numerical value, MCU, which may turn on moisture separating device, makes insulating support restore insulation performance.
In addition, being formed by voltage in the output end of micro current amplifier if applying the polarizing voltage of opposed polarity on polarising sheet
It would also vary from, the difference of this voltage and the electric leakage degree of insulating support are related.Insulating support can be judged with it
Whether insulation performance is normal.
Embodiment 2 uses the parallel air ion collector of binary channels, and first passage includes three section collectors, is mounted on
In one metal shell channel;The limit mobility of first segment collector is 0.4 (cm2/cm2/ VS), for collecting small ion;
The interval migration rate of second section collector is 0.4~0.04 (cm2/ VS) for collecting intermediate ion;The area of third section collector
Between mobility be 0.04~0.004 (c m2/ VS), for collecting big ion.Second channel also includes three section collectors, and first
The collection plate earthing of collector is saved, limit mobility is 0.004 (cm2/cm2/ VS), for filtering collected by first passage
Air ion;The interval migration rate of second section collector is 0.004~0.0004 (cm2/ VS) for collect it is heavy greatly from
Son;The interval migration rate of third section collector is 0.0004~0.00005 (c m2/ VS) for collecting superheavy ion.Every section
Collector all includes one group " collecting board-polarising sheet " right;The collecting board and polarising sheet of collector along pumping airflow direction
Parallel to each other, each collector that saves is connected in series, and is followed by air exhauster.Each channel uses the different speed of exhausts.
Embodiment 1 can carry out it is small, in, big measuring ion, achievement unit ion mobility spectrogram;Embodiment 2 can be real
Now complete ionic mobility spectrometry makes complete ionic mobility spectrogram.