CN104629400A - Resin liquid and preparation method thereof - Google Patents
Resin liquid and preparation method thereof Download PDFInfo
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- CN104629400A CN104629400A CN201510046043.8A CN201510046043A CN104629400A CN 104629400 A CN104629400 A CN 104629400A CN 201510046043 A CN201510046043 A CN 201510046043A CN 104629400 A CN104629400 A CN 104629400A
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Abstract
The invention discloses a resin liquid and relates to an organic compound. The resin liquid is prepared from the following raw materials in parts by weight: 8.5-25.5 parts of resin powder, 5-15 parts of ethyl ester, 0.5-1.5 parts of additives, 6.5-19.5 parts of cyclohexanone, 22-66 parts of toluene and 7.5-22.5 parts of butanone. The invention discloses a preparation method of the resin liquid. The preparation method comprises the following steps: (1) uniformly stirring the corresponding parts of ethyl ester, cyclohexanone, toluene and butanone to obtain a mixed solvent; (2), pouring 45wt% of the mixed solvent obtained in the step (1) and the corresponding parts of resin powder into a stirring barrel and stirring for 1 hour at a speed of 2500r/s; (3), adding the corresponding parts of the additives into the mixture obtained in the step (2) and stirring until the additives are dissolved; and (4), adding the residual mixed solvent in the step (1) into the solution in the step (3) and stirring for 10 minutes at a speed of 2500r/s to obtain the resin liquid. By the resin liquid, the problem that the fluidity of the resin liquid for a refractory material becomes poor at lower temperature which is not conducive to mixing operation is solved; the excellent plasticizing effect is achieved; and the stability and the impact strength of a product are greatly improved.
Description
Technical field
The present invention relates to a kind of organic compound, be specifically related to a kind of resin liquid.
Background technology
Resin liquid is purposes very extensive in the prior art, the application resin liquid on diamond wheel can strengthen working lining when sintering and aluminum substrate cohesive strength high; Carbon-containing refractory article, as goods such as magnesium carbon, aluminium carbon, magnesium calcium carbon, also extensively adopts resin liquid to make binding agent; Good and the solid polyelectrolyte membrane that fold is few of weather resistance or catalyst layer can also be formed for weather resistance and the good solid polymer fuel cell of power generation characteristics by resin liquid.Even can soft filming emulsion, high gloss, waterproof, for oil polish.
Resin liquid used for refractory material mobility when temperature is lower is deteriorated, and is unfavorable for mixing operation.Prior art is all the rear use of heating to resin liquid, and technique is original, and operation bothers; In addition resin liquid be made into product quality also more secondary, stability is poor, shock resistance intensity is weak; In making processes, plasticizing effect is poor.
Summary of the invention
Technical problem to be solved by this invention is to provide that a mobility is strong, the resin liquid of excellent properties.
For solving the problems of the technologies described above, the technical solution used in the present invention is: this resin liquid is formed by the material mixture ratio of following portions by weight: resin-oatmeal 8.5-25.5 part, ethyl ester 5-15 part, auxiliary agent 0.5-1.5 part, pimelinketone 6.5-19.5 part, toluene 22-66 part, butanone 7.5-22.5 part.
Further technical scheme is, this resin liquid is formed by the material mixture ratio of following portions by weight: resin-oatmeal 8.5 parts, ethyl ester 5 parts, auxiliary agent 0.5 part, pimelinketone 6.5 parts, toluene 22 parts, butanone 7.5 parts.
Further technical scheme is, this resin liquid is formed by the material mixture ratio of following portions by weight: resin-oatmeal 25.5 parts, ethyl ester 15 parts, auxiliary agent 1.5 parts, pimelinketone 19.5 parts, toluene 66 parts, butanone 22.5 parts.
Further technical scheme is, this resin liquid is formed by the material mixture ratio of following portions by weight: resin-oatmeal 17 parts, ethyl ester 10 parts, auxiliary agent 1 part, pimelinketone 13 parts, toluene 44 parts, butanone 15 parts.
Further technical scheme is, described auxiliary agent is thermo-stabilizer, and described thermo-stabilizer is Ca/Zn stablizer.
Further technical scheme is, described auxiliary agent is the mixture of thermo-stabilizer and auxiliary stabilizer, and its ratio is 2:3; Described thermo-stabilizer is Ca/Zn stablizer, and described auxiliary stabilizer is phosphorous acid ester.
Further technical scheme is, described auxiliary agent is the mixture of thermo-stabilizer, auxiliary stabilizer and lubricant, and its ratio is 2:2:1; Described thermo-stabilizer is Ca/Zn stablizer, and described auxiliary stabilizer is phosphorous acid ester, and described lubricant is fatty acid ester.
Further technical scheme is, described auxiliary agent is the mixture of thermo-stabilizer, auxiliary stabilizer, lubricant and processing aid, and its ratio is 12:8:3:3; Described thermo-stabilizer is Ca/Zn stablizer, and described auxiliary stabilizer is phosphorous acid ester, and described lubricant is fatty acid ester, and described processing aid is acrylic process aids.
Further technical scheme is, the preparation method of this resin liquid is as follows:
(1), the ethyl ester of corresponding number, pimelinketone, toluene, butanone are stirred into mixed solvent.
(2), get the mixed solvent of 45% weight and the resin-oatmeal of corresponding number in step (1) to pour in agitation vat and stir 1 hour with speed 2500r/s
(3), by the auxiliary agent of corresponding number be added in step (2) gained solution, be stirred to dissolving;
(4), remaining mixed solvent in step (1) is joined in step (3) gained solution to stir with speed 2500r/s within 10 minutes, namely obtain resin liquid.
The beneficial effect adopting technique scheme to produce is: solve resin liquid used for refractory material mobility when temperature is lower and be deteriorated, be unfavorable for the problem of mixing operation; Be made into the process of product from resin liquid in addition, there is plasticizing effect splendid; Stability, the resistance to impact shock of product improve all greatly.
Embodiment
Below in conjunction with embodiment, the present invention is further detailed explanation, but not as a limitation of the invention.
Main raw material:
Resin-oatmeal, ethyl ester, pimelinketone, toluene, butanone, phosphorous acid ester, acrylic process aids, commercially available;
Ca/Zn stablizer, CZ2390T, Shanghai Lujiu Rubber Plastic New Material Co., Ltd;
Ca/Zn stablizer, BAEROPANMC9398, German Xiong Pai company;
Fatty acid ester, Shanghai Yan'an Oil Chemical Plant.
Embodiment 1
Formula: resin-oatmeal 10 parts, ethyl ester 13 parts, Ca/Zn stablizer 0.5 part, pimelinketone 18 parts, toluene 30 parts, butanone 10 parts.
Preparation method:
(1), by ethyl ester 13 parts, pimelinketone 18 parts, toluene 30 parts, butanone 10 parts is stirred into mixed solvent;
(2), get the mixed solvent of 45% weight in step (1) and resin-oatmeal 10 parts to pour in agitation vat and stir 1 hour with speed 2500r/s;
(3), Ca/Zn stablizer 0.5 part is added in step (2) gained solution is stirred to dissolving;
(4), remaining mixed solvent in step (1) is joined in step (3) gained solution, stir with speed 2500r/s and namely obtain resin liquid in 10 minutes.
Embodiment 2
Formula: resin-oatmeal 10 parts, ethyl ester 13 parts, Ca/Zn stablizer 0.2 part, phosphorous acid ester 0.3 part, pimelinketone 18 parts, toluene 30 parts, butanone 10 parts.
Preparation method:
(1), by ethyl ester 13 parts, pimelinketone 18 parts, toluene 30 parts, butanone 10 parts is stirred into mixed solvent;
(2), get the mixed solvent of 45% weight in step (1) and resin-oatmeal 10 parts to pour in agitation vat and stir 1 hour with speed 2500r/s;
(3), by Ca/Zn stablizer 0.2 part, phosphorous acid ester 0.3 part is added in step (2) gained solution and is stirred to dissolving;
(4), remaining mixed solvent in step (1) is joined in step (3) gained solution, stir with speed 2500r/s and namely obtain resin liquid in 10 minutes.
Embodiment 3
Formula: resin-oatmeal 10 parts, ethyl ester 13 parts, Ca/Zn stablizer 0.2 part, phosphorous acid ester 0.2 part, fatty acid ester 0.1 part, pimelinketone 18 parts, toluene 30 parts, butanone 10 parts.
Preparation method:
(1), by ethyl ester 13 parts, pimelinketone 18 parts, toluene 30 parts, butanone 10 parts is stirred into mixed solvent;
(2), get the mixed solvent of 45% weight in step (1) and resin 10 parts to pour in agitation vat and stir 1 hour with speed 2500r/s;
(3), by Ca/Zn stablizer 0.2 part, phosphorous acid ester 0.2 part, fatty acid ester 0.1 part is added in step (2) gained solution and is stirred to dissolving;
(4), remaining mixed solvent in step (1) is joined in step (3) gained solution, stir with speed 2500r/s and namely obtain resin liquid in 10 minutes.
Embodiment 4
Formula: resin-oatmeal 10 parts, ethyl ester 13 parts, Ca/Zn stablizer 0.25 part, phosphorous acid ester 0.15 part, fatty acid ester 0.05 part, acrylic process aids 0.05 part, pimelinketone 18 parts, toluene 30 parts, butanone 10 parts.
Preparation method:
(1), by ethyl ester 13 parts, pimelinketone 18 parts, toluene 30 parts, butanone 10 parts is stirred into mixed solvent;
(2), get the mixed solvent of 45% weight in step (1) and resin-oatmeal 10 parts to pour in agitation vat and stir 1 hour with speed 2500r/s;
(3), by Ca/Zn stablizer 0.23 part, phosphorous acid ester 0.15 part, fatty acid ester 0.06 part, acrylic process aids 0.06 part is added in step (2) gained solution and is stirred to dissolving;
(4), remaining mixed solvent in step (1) is joined in step (3) gained solution, stir with speed 2500r/s and namely obtain resin liquid in 10 minutes.
Embodiment 5
Formula: resin-oatmeal 17 parts, ethyl ester 10 parts, Ca/Zn stablizer 0.5 part, phosphorous acid ester 0.3 part, fatty acid ester 0.1 part, acrylic process aids 0.1 part, pimelinketone 13 parts, toluene 44 parts, butanone 15 parts.
Preparation method:
(1), by ethyl ester 10 parts, pimelinketone 13 parts, toluene 44 parts, butanone 15 parts is stirred into mixed solvent;
(2), get the mixed solvent of 45% weight in step (1) and resin-oatmeal 17 parts to pour in agitation vat and stir 1 hour with speed 2500r/s;
(3), by Ca/Zn stablizer 0.5 part, phosphorous acid ester 0.3 part, fatty acid ester 0.1 part, acrylic process aids 0.1 part, is added in step (2) gained solution, is stirred to dissolving;
(4), remaining mixed solvent in step (1) is joined in step (3) gained solution, stir with speed 2500r/s and namely obtain resin liquid in 10 minutes.
Claims (9)
1. a resin liquid, is characterized in that: this resin liquid is formed by the material mixture ratio of following portions by weight: resin-oatmeal 8.5-25.5 part, ethyl ester 5-15 part, auxiliary agent 0.5-1.5 part, pimelinketone 6.5-19.5 part, toluene 22-66 part, butanone 7.5-22.5 part.
2. a kind of resin liquid according to claim 1, is characterized in that: this resin liquid is formed by the material mixture ratio of following portions by weight: resin-oatmeal 8.5 parts, ethyl ester 5 parts, auxiliary agent 0.5 part, pimelinketone 6.5 parts, toluene 22 parts, butanone 7.5 parts.
3. a kind of resin liquid according to claim 1, is characterized in that: this resin liquid is formed by the material mixture ratio of following portions by weight: resin-oatmeal 25.5 parts, ethyl ester 15 parts, auxiliary agent 1.5 parts, pimelinketone 19.5 parts, toluene 66 parts, butanone 22.5 parts.
4. a kind of resin liquid according to claim 1, is characterized in that: this resin liquid is formed by the material mixture ratio of following portions by weight: resin-oatmeal 17 parts, ethyl ester 10 parts, auxiliary agent 1.4 parts, pimelinketone 13 parts, toluene 44 parts, butanone 15 parts.
5. a kind of resin liquid according to any one of claim 1-4 claim, is characterized in that: described auxiliary agent is thermo-stabilizer, and described thermo-stabilizer is Ca/Zn stablizer.
6. a kind of resin liquid according to any one of claim 1-4 claim, is characterized in that: described auxiliary agent is the mixture of thermo-stabilizer and auxiliary stabilizer, and its ratio is 2:3; Described thermo-stabilizer is Ca/Zn stablizer, and described auxiliary stabilizer is phosphorous acid ester.
7. a kind of resin liquid according to any one of claim 1-4 claim, is characterized in that: described auxiliary agent is the mixture of thermo-stabilizer, auxiliary stabilizer and lubricant, and its ratio is 2:2:1; Described thermo-stabilizer is Ca/Zn stablizer, and described auxiliary stabilizer is phosphorous acid ester, and described lubricant is fatty acid ester.
8. a kind of resin liquid according to any one of claim 1-4 claim, is characterized in that: described auxiliary agent is the mixture of thermo-stabilizer, auxiliary stabilizer, lubricant and processing aid, and its ratio is 12:8:3:3; Described thermo-stabilizer is Ca/Zn stablizer, and described auxiliary stabilizer is phosphorous acid ester, and described lubricant is fatty acid ester, and described processing aid is acrylic process aids.
9. the preparation method of a kind of resin liquid according to any one of claim 1-4 claim, is characterized in that:
(1), the ethyl ester of corresponding number, pimelinketone, toluene, butanone are stirred into mixed solvent;
(2), get the mixed solvent of 45% weight and the resin-oatmeal of corresponding number in step (1) to pour in agitation vat and stir 1 hour with speed 2500r/s;
(3), the auxiliary agent of corresponding number is added in step (2) gained solution is stirred to dissolving;
(4), join in step (3) gained solution by remaining mixed solvent in step (1), speed 2500r/s stirs and namely obtains resin liquid in 10 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510046043.8A CN104629400A (en) | 2015-01-29 | 2015-01-29 | Resin liquid and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510046043.8A CN104629400A (en) | 2015-01-29 | 2015-01-29 | Resin liquid and preparation method thereof |
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| CN104629400A true CN104629400A (en) | 2015-05-20 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1133333A (en) * | 1995-04-08 | 1996-10-16 | 元文学 | Shoes adhesion agent and treating liquid and preparation method |
| CN1789355A (en) * | 2004-12-15 | 2006-06-21 | 沈阳建筑大学 | Mono-component anti-corrosion polyurethane coating and its preparation method |
| CN101302306A (en) * | 2008-05-28 | 2008-11-12 | 江南大学 | Preparation of high temperature resistant, anti-precipitation liquid rare earth/barium/zinc composite heat stabilizer |
| CN102276952A (en) * | 2011-08-30 | 2011-12-14 | 山东金天成塑料制品有限公司 | Chlorinated polyvinyl chloride board |
| CN102850914A (en) * | 2012-09-29 | 2013-01-02 | 杭州中粮包装有限公司 | Coating composition and application of coating composition to metal base material |
-
2015
- 2015-01-29 CN CN201510046043.8A patent/CN104629400A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1133333A (en) * | 1995-04-08 | 1996-10-16 | 元文学 | Shoes adhesion agent and treating liquid and preparation method |
| CN1789355A (en) * | 2004-12-15 | 2006-06-21 | 沈阳建筑大学 | Mono-component anti-corrosion polyurethane coating and its preparation method |
| CN101302306A (en) * | 2008-05-28 | 2008-11-12 | 江南大学 | Preparation of high temperature resistant, anti-precipitation liquid rare earth/barium/zinc composite heat stabilizer |
| CN102276952A (en) * | 2011-08-30 | 2011-12-14 | 山东金天成塑料制品有限公司 | Chlorinated polyvinyl chloride board |
| CN102850914A (en) * | 2012-09-29 | 2013-01-02 | 杭州中粮包装有限公司 | Coating composition and application of coating composition to metal base material |
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Application publication date: 20150520 |
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