CN104629131A - Rubber composition for auto tyres - Google Patents

Rubber composition for auto tyres Download PDF

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Publication number
CN104629131A
CN104629131A CN201510048981.1A CN201510048981A CN104629131A CN 104629131 A CN104629131 A CN 104629131A CN 201510048981 A CN201510048981 A CN 201510048981A CN 104629131 A CN104629131 A CN 104629131A
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CN
China
Prior art keywords
parts
rubber
styrene
butadiene rubber
doughnut
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510048981.1A
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Chinese (zh)
Inventor
陈永亮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LIUZHOU ZHONGPEI RUBBER PARTS MANUFACTURING Co Ltd
Original Assignee
LIUZHOU ZHONGPEI RUBBER PARTS MANUFACTURING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LIUZHOU ZHONGPEI RUBBER PARTS MANUFACTURING Co Ltd filed Critical LIUZHOU ZHONGPEI RUBBER PARTS MANUFACTURING Co Ltd
Priority to CN201510048981.1A priority Critical patent/CN104629131A/en
Publication of CN104629131A publication Critical patent/CN104629131A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a rubber composition for auto tyres and belongs to the technical field of auto tyres. According to the invention, the rubber composition for auto tyres is mainly compounded of butadiene styrene rubber, styrene-isoprene-butadiene rubber and butadiene rubber in the presence of linseed oil, aromatic modified terpene resin, light calcium carbonate, silica, zinc stearate, dibutyl ester, magnesium oxide, methyl 2,2-dithienylglycolate and sodium pyrosulfite; and the heat generation property of the rubber composition can b reduced effectively.

Description

Doughnut rubber combination
Technical field
The present invention relates to doughnut technical field, particularly relate to a kind of doughnut rubber combination.
Background technology
Tire is one of vitals of automobile, and it directly contacts with road surface, and impact suffered when automotive suspension relaxes running car jointly, ensures that automobile has good driving comfort and ride performance; Ensure that there is good tack on wheel and road surface, improve the traction property of automobile, braking and the property passed through; Subject the weight of automobile, tire on automobile the vital role that rises more and more be subject to people's attention, cause the requirement of people to its various aspects of performance also more and more higher, and the low heating property improving tyre element rubber combination is one of them.
Summary of the invention
The invention provides a kind of doughnut rubber combination, this doughnut rubber combination has lower heat generation.
In order to solve the problems of the technologies described above, the technical solution adopted in the present invention is:
It is made up of the component of following weight part:
35 parts ~ 46 parts, styrene-butadiene rubber(SBR), styrene isoprene butadiene rubber (SIBR) 20 parts ~ 30 parts, cis-1,4-polybutadiene rubber 20 parts ~ 30 parts, linseed oil 18 parts ~ 22 parts, aromatic modified terpine resin 20 parts ~ 26 parts, light calcium carbonate 8 parts ~ 12 parts, silicon-dioxide 5 parts ~ 8 parts, Zinic stearas 2 parts ~ 4 parts, dibutylester 1 part ~ 5 parts, 1 part ~ 3 parts, magnesium oxide, 2,2-dithienyl methyl glycolate 3 parts ~ 4 parts and Sodium Pyrosulfite 1 part ~ 5 parts.
In technique scheme, technical scheme is more specifically: 35 parts, styrene-butadiene rubber(SBR), styrene isoprene butadiene rubber (SIBR) 20 parts, cis-1,4-polybutadiene rubber 20 parts, linseed oil 22 parts, aromatic modified terpine resin 26 parts, light calcium carbonate 10 parts, silicon-dioxide 6 parts, Zinic stearas 2 parts, dibutylester 1 part, 3 parts, magnesium oxide, 2,2-dithienyl methyl glycolate 4 parts and Sodium Pyrosulfite 3 parts.
Further, 46 parts, styrene-butadiene rubber(SBR), styrene isoprene butadiene rubber (SIBR) 30 parts, cis-1,4-polybutadiene rubber 30 parts, linseed oil 18 parts, aromatic modified terpine resin 20 parts, light calcium carbonate 8 parts, silicon-dioxide 5 parts, Zinic stearas 3 parts, dibutylester 3 parts, 1 part, magnesium oxide, 2,2-dithienyl methyl glycolate 3 parts and Sodium Pyrosulfite 1 part.
Further, 40 parts, styrene-butadiene rubber(SBR), styrene isoprene butadiene rubber (SIBR) 25 parts, cis-1,4-polybutadiene rubber 26 parts, linseed oil 20 parts, aromatic modified terpine resin 24 parts, light calcium carbonate 12 parts, silicon-dioxide 8 parts, Zinic stearas 4 parts, dibutylester 5 parts, 2 parts, magnesium oxide, 2,2-dithienyl methyl glycolate 4 parts and Sodium Pyrosulfite 5 parts.
Owing to adopting technique scheme, the beneficial effect that the present invention obtains is:
The present invention mainly selects styrene-butadiene rubber(SBR), styrene isoprene butadiene rubber (SIBR), and cis-1,4-polybutadiene rubber three kinds of rubber are composite, be equipped with linseed oil again, aromatic modified terpine resin, light calcium carbonate, silicon-dioxide, Zinic stearas, dibutylester, magnesium oxide, 2,2-dithienyl methyl glycolate and Sodium Pyrosulfite make doughnut rubber combination together, can effectively reduce its heat generation.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, and protection scope of the present invention is not only confined to following examples.
Embodiment 1
This doughnut rubber combination is made up of following component: styrene-butadiene rubber(SBR) 3.5kg, styrene isoprene butadiene rubber (SIBR) 2.0kg, cis-1,4-polybutadiene rubber 2.0kg, linseed oil 2.2kg, aromatic modified terpine resin 2.6kg, light calcium carbonate 1.0kg, silicon-dioxide 0.6kg, Zinic stearas 0.2kg, dibutylester 0.1kg, magnesium oxide 0.3kg, 2,2-dithienyl methyl glycolate 0.4kg and Sodium Pyrosulfite 0.3kg.
Compared with the doughnut rubber combination product that existing market is sold, the heat generation of the doughnut rubber combination that the present embodiment obtains reduces 52%.
Embodiment 2
This doughnut rubber combination is made up of following component: styrene-butadiene rubber(SBR) 4.6kg, styrene isoprene butadiene rubber (SIBR) 3.0kg, cis-1,4-polybutadiene rubber 3.0kg, linseed oil 1.8kg, aromatic modified terpine resin 2.0kg, light calcium carbonate 0.8kg, silicon-dioxide 0.5kg, Zinic stearas 0.3kg, dibutylester 0.3kg, magnesium oxide 0.1kg, 2,2-dithienyl methyl glycolate 0.3kg and Sodium Pyrosulfite 0.1kg.
Compared with the doughnut rubber combination product that existing market is sold, the heat generation of the doughnut rubber combination that the present embodiment obtains reduces 52.1%.
Embodiment 3
This doughnut rubber combination is made up of following component: styrene-butadiene rubber(SBR) 4.0kg, styrene isoprene butadiene rubber (SIBR) 2.5kg, cis-1,4-polybutadiene rubber 2.6kg, linseed oil 2.0kg, aromatic modified terpine resin 2.4kg, light calcium carbonate 1.2kg, silicon-dioxide 0.8kg, Zinic stearas 0.4kg, dibutylester 0.5kg, magnesium oxide 0.2kg, 2,2-dithienyl methyl glycolate 0.4kg and Sodium Pyrosulfite 0.5kg.
Compared with the doughnut rubber combination product that existing market is sold, the heat generation of the doughnut rubber combination that the present embodiment obtains reduces 52.5%.

Claims (4)

1. a doughnut rubber combination, is characterized in that being made up of the component of following weight part:
35 parts ~ 46 parts, styrene-butadiene rubber(SBR), styrene isoprene butadiene rubber (SIBR) 20 parts ~ 30 parts, cis-1,4-polybutadiene rubber 20 parts ~ 30 parts, linseed oil 18 parts ~ 22 parts, aromatic modified terpine resin 20 parts ~ 26 parts, light calcium carbonate 8 parts ~ 12 parts, silicon-dioxide 5 parts ~ 8 parts, Zinic stearas 2 parts ~ 4 parts, dibutylester 1 part ~ 5 parts, 1 part ~ 3 parts, magnesium oxide, 2,2-dithienyl methyl glycolate 3 parts ~ 4 parts and Sodium Pyrosulfite 1 part ~ 5 parts.
2. doughnut rubber combination according to claim 1, is characterized in that: 35 parts, styrene-butadiene rubber(SBR), styrene isoprene butadiene rubber (SIBR) 20 parts, cis-1,4-polybutadiene rubber 20 parts, linseed oil 22 parts, aromatic modified terpine resin 26 parts, light calcium carbonate 10 parts, silicon-dioxide 6 parts, Zinic stearas 2 parts, dibutylester 1 part, 3 parts, magnesium oxide, 2,2-dithienyl methyl glycolate 4 parts and Sodium Pyrosulfite 3 parts.
3. doughnut rubber combination according to claim 1, is characterized in that: 46 parts, styrene-butadiene rubber(SBR), styrene isoprene butadiene rubber (SIBR) 30 parts, cis-1,4-polybutadiene rubber 30 parts, linseed oil 18 parts, aromatic modified terpine resin 20 parts, light calcium carbonate 8 parts, silicon-dioxide 5 parts, Zinic stearas 3 parts, dibutylester 3 parts, 1 part, magnesium oxide, 2,2-dithienyl methyl glycolate 3 parts and Sodium Pyrosulfite 1 part.
4. doughnut rubber combination according to claim 1, is characterized in that: 40 parts, styrene-butadiene rubber(SBR), styrene isoprene butadiene rubber (SIBR) 25 parts, cis-1,4-polybutadiene rubber 26 parts, linseed oil 20 parts, aromatic modified terpine resin 24 parts, light calcium carbonate 12 parts, silicon-dioxide 8 parts, Zinic stearas 4 parts, dibutylester 5 parts, 2 parts, magnesium oxide, 2,2-dithienyl methyl glycolate 4 parts and Sodium Pyrosulfite 5 parts.
CN201510048981.1A 2015-01-30 2015-01-30 Rubber composition for auto tyres Pending CN104629131A (en)

Priority Applications (1)

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CN201510048981.1A CN104629131A (en) 2015-01-30 2015-01-30 Rubber composition for auto tyres

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CN201510048981.1A CN104629131A (en) 2015-01-30 2015-01-30 Rubber composition for auto tyres

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CN104629131A true CN104629131A (en) 2015-05-20

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867052A (en) * 2015-12-10 2017-06-20 北京橡胶工业研究设计院 Using SIS as compatilizer green tire rubber composition for tire tread

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5859133A (en) * 1996-03-18 1999-01-12 The Goodyear Tire & Rubber Company Tire tread compound
US20030127169A1 (en) * 2001-10-30 2003-07-10 Bridgestone/Firestone, Inc. Elastomers with long chain crosslinks to increase abrasion resistance
CN1452647A (en) * 2000-07-31 2003-10-29 米其林技术公司 Running tread for tyre
CN102093606A (en) * 2009-12-10 2011-06-15 横滨橡胶株式会社 Rubber composition for use in tires
CN103492471A (en) * 2011-04-22 2014-01-01 横滨橡胶株式会社 Tire rubber composition and studless tire

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5859133A (en) * 1996-03-18 1999-01-12 The Goodyear Tire & Rubber Company Tire tread compound
CN1452647A (en) * 2000-07-31 2003-10-29 米其林技术公司 Running tread for tyre
US20030127169A1 (en) * 2001-10-30 2003-07-10 Bridgestone/Firestone, Inc. Elastomers with long chain crosslinks to increase abrasion resistance
CN102093606A (en) * 2009-12-10 2011-06-15 横滨橡胶株式会社 Rubber composition for use in tires
CN103492471A (en) * 2011-04-22 2014-01-01 横滨橡胶株式会社 Tire rubber composition and studless tire

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
吴世敏 等,: "《简明精细化工大辞典》", 30 June 1999, 辽宁科学技术出版社 *
张洪雁 等,: "《高性能橡胶密封材料》", 31 July 2007, 化学工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867052A (en) * 2015-12-10 2017-06-20 北京橡胶工业研究设计院 Using SIS as compatilizer green tire rubber composition for tire tread
CN106867052B (en) * 2015-12-10 2018-09-18 北京橡胶工业研究设计院有限公司 Green tire rubber composition for tire tread using SIS as compatilizer

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Application publication date: 20150520