CN104610555A - Preparation method of flexible abrasive-blasting material with fibers embedded - Google Patents
Preparation method of flexible abrasive-blasting material with fibers embedded Download PDFInfo
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- CN104610555A CN104610555A CN201510029882.9A CN201510029882A CN104610555A CN 104610555 A CN104610555 A CN 104610555A CN 201510029882 A CN201510029882 A CN 201510029882A CN 104610555 A CN104610555 A CN 104610555A
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Abstract
The invention relates to a preparation method of a flexible abrasive-blasting material with fibers embedded. An even mixing device for prepolymers, cellulose fibers, fully hygroscopic water-absorbent polymers and abrasive materials is adopted, water released by the water-absorbent polymers is used for catalyzing the prepolymers, a chemical reaction occurs, the reaction mixture is processed, a flexible abrasive-blasting material containing the complete cellulose fibers is formed, and then the flexible abrasive-blasting material is granulated. The method can effectively control the chemical reaction speed, overcome defects of traditional flexible abrasive-blasting material production technologies and guarantee production of high-quality polyurethane flexible abrasive materials.
Description
Technical field
The present invention relates to a kind of flexible abrasive blasting material preparation method for sandblasting, be specifically related to a kind of hygroscopic material of organic macromolecule, the organic and/or inorganic abradant compounded elastic sponge abrasive material preparation method that adopt prepolymer, cellulosic fibre, fully moisture absorption, belong to environmental protection abrasive manufacturing techniques field.
Background technology
Sandblasting is widely used in the field such as metal-derusting, building surface process.For facilities such as shipbuilding, petrochemical equipment repairing, offshore drilling platform, the workload of its removing surface and maintenance is increasing, and specification of quality is more and more higher, and the technology, safety, environmental protection etc. of effects on surface cleaning technology require also more and more higher.Existing technique mainly adopts the rigidity such as steel sand or corundum abrasive material, in conjunction with vapour blasting, water sandblasting, the sandblasting of wheel machinery, pressurized air sandblasting or vacuum machine blasting method, is ejected into the degree of cleaning needed for the acquisition of processed surface or roughness.But rigidity abrasive material very easily produces serious dust and noise at above-mentioned sandblasting procedures, not only contaminate environment, cause the new problems such as base material is moist, equipment is complicated, cooling water pollution, and abrasive material loss is large.
The sponge abrasive material that late 1980s succeeds in developing, alleged in the industry at once " green abrasive material ", contaminate environment in traditional technology can be solved, healthy hidden danger, the problems such as abrasive material utilization ratio is low, it can adsorb the dust produced in more than 90% abrasive blasting process in scale removal process, the ability of cleaning muriate and other pollutents is stronger than other conventional abrasive materials, have and splash less, not damages peripheral working-surface, the advantage such as repeatedly can to reuse, contribute to alleviating the injury of dust to human body, environmental protect Air quality, thus in the U.S., the developed countries such as Japan obtain and apply more and more widely.But do not obtain enough attention and popularization yet in China, relevant patent is few, only there is several flexible abrasive blasting material patent such as ZL 92108180.4, ZL201010261370.2, ZL 201110328945.2, ZL201410153335.7, from technology contents analysis disclosed in it, do not exceed same kind of products at abroad state of the art, outside energy subrogate country, the flexible sponge abrasive blasting material of the high-quality of goods and preparation technology thereof have no report.
US Patent No. 6767488 provides a kind of polyurethane sponge abrasive material production method embedding fiber, water and cellulosic fibre are pre-mixed by the method, make cellulosic fibre even suspension in water, again by the mixture made and prepolymer, abrasive grain Quick uniform mixes, there is violent chemical reaction in free free water and prepolymer, release a large amount of heats simultaneously, impel free water rapid evaporation, participate in reaction, and the water that cellulosic fibre draws slowly releases because being heated, thus delay the speed of sponge formation reaction, improve the workmanship of sponge.The cellulosic fibre be embedded in sponge greatly increases the intensity of sponge abrasive grain, weather resistance and abrasive properties.This technology utilizes hydrophilic cellulose fiber can absorb the water of the manyfold of himself weight and the characteristic that can discharge of being heated, the water adsorbed slowly releases and participates in sponge manufacture reaction, delay the speed of sponge formation reaction, improve the manufacturing process of sponge abrasive material, quality.But it also has certain limitation: when water and performed polymer mixing, it is the chemical reaction that may control hardly, because chemical reaction occurs immediately in mixing complete process, and self―sustaining, chemical reaction velocity is very fast, and process control needs is high; Free water and prepolymer rapid reaction easily generate larger closed hole, reduce sponge quality; Water and cellulosic fibre must Homogeneous phase mixing in advance, and cellulosic fibre must have wetting ability.
Therefore the range of choice how solving above-mentioned prior art Problems existing, delay the speed of sponge formation reaction, improve manufacturing process, improve sponge abrasive properties, expand cellulosic fibre, becomes the difficult point of this area research.
Summary of the invention
The present invention is for solving prior art Problems existing, a kind of flexible abrasive blasting material preparation method is provided, for the preparation of the flexible abrasive blasting material of excellent performance, thus comparable product outside subrogate country, reach the speed delaying sponge formation reaction, the object improved manufacturing process, improve sponge abrasive properties.
The object of the invention is to be realized by following measures:
Embed a flexible abrasive blasting material preparation method for fiber, it is characterized in that:
Water-absorbing polymer, the abrasive material of mixed prepolymer, cellulosic fibre, fully moisture absorption; Also there is chemical reaction thus in the water catalysis prepolymer discharged with above-mentioned water-absorbing polymer; The above-mentioned reaction mixture of processing treatment forms the polyurethane sponge abrasive material comprising intact fibre cellulose fiber, the more above-mentioned sponge abrasive material of granulation.
Described prepolymer includes but not limited to the polyisocyanates of water catalysis, oxy-compound and/or aminocompound, its mix with water can there is heat release chemical reaction, discharge CO
2, volume of mixture expands and produces and has elastic polyurethane sponge.
Described polyisocyanates include but not limited in following substances one or more: tolylene diisocyanate (TDI), TDI 2, 4-and 2, the mixture (TDI-80/20) of 6-isomer 80:20, TDI 2, 4-and 2, the mixture (TDI-65/35) of 6-isomer 65:35, ditane-4, 4 '-vulcabond (MDI), poly methylene poly phenyl poly isocyanate (PAPI), liquefaction type '-diphenylmethane diisocyanate (LMDI), urethane-modified diphenylmethanediisocyanate, isophorone diisocyanate (IPDI), hexamethylene diisocyanate (HDI), phenylenedimethylidyne isocyanic ester (XDI), tetramethylxylylene diisocyanate (TMXDI), cyclohexanedimethyleterephthalate vulcabond (H
6xDI), HMDI (H
12mDI).
Described oxy-compound include but not limited in following substances one or more: polyoxytrimethylene ethoxylated polyhydric alcohol (PPG), polybutadiene polyol (HTPB), poly-epsilon-caprolactone polyvalent alcohol (PCL), glycerin polyether, polytetrahydrofuran polyol (PTMG).
Described aminocompound include but not limited in following substances one or more: diethyl toluene diamine (DETDA), 3, 3 '-two chloro-4, 4 '-diaminodiphenylmethane (MOCA), 3, 5-dimethythiotoluene diamine (DMTDA), N, N '-dialkyl methyl diamines, N, N '-dialkyl phenylene diamine, isophorone diamine (IPDA), 4, 4'-di-secondary fourth aminodiphenylmethane (MBDA), quadrol, triethylamine (TEA), triethylenediamine (TEDA), 1, 2-diaminopropanes, 2, 5-diamino-2, 5-dimethylhexane, 2, 4-or 2, 6-diaminotoluene, 2, 4 '-or 4, 4 '-diaminodiphenyl methane.
Described cellulosic fibre refers to hydrophilic cellulose fiber, hydrophobic fiber cellulose fiber or man-made fiber, and the size range of cellulosic fibre is at 32 ~ 200 microns.
Described water-absorbing polymer refers to the water-absorbing resin with high wettability power or the porous polymer produced by the water-absorbing resin of high wettability power, can absorb and keep own wt several times to the moisture of thousands of times, and the moisture of absorption can be discharged when being heated or there is uneven potential difference.
The compounded abrasive that described abrasive material comprises inorganic abradant, Organic abrasive or mixed by organic-inorganic material, as corundum, plastics, glass, steel sand, trimeric cyanamide, granulated glass sphere etc., both may be used for the slight cleaning in surface, and also may be used for the pollutent removed on surface and also leave certain roughness from the teeth outwards.
Described polyurethane sponge forms by polyurethane material and honeycomb structure the sponge that has elastic force or softness, be wrapped in wherein or the abrasive material that exposes of part as sponge blast media wash zone for clearance surperficial time, be easy to compression, and can repeatedly reuse.
Significant in polyurethane sponge is be embedded in the cellulosic fibre in sponge polymer matrix, cellulosic fibre drastically increases the abrasive properties of the intensity of sponge abrasive material, weather resistance and sponge particles, the simultaneously also perfect manufacturing process of sponge itself.
Described polyurethane material such as polyurethane forms foam matrix, and matrix comprises small holes or honeycomb, and matrix and honeycomb structure form resilient or soft sponge.
As preferably, after prepolymer and cellulosic fibre are pre-mixed, then with water-absorbing polymer, the abrasive material Homogeneous phase mixing of abundant moisture absorption, also there is chemical reaction thus in the water catalysis prepolymer discharged with above-mentioned water-absorbing polymer; The above-mentioned reaction mixture of processing treatment forms the polyurethane sponge abrasive material comprising intact fibre cellulose fiber, and the above-mentioned sponge abrasive material of granulation.
Preferred as another kind, after described prepolymer and cellulosic fibre are pre-mixed, more successively with the water-absorbing polymer Homogeneous phase mixing of abrasive material, fully moisture absorption, also there is chemical reaction thus in the water catalysis prepolymer discharged with above-mentioned water-absorbing polymer; The above-mentioned reaction mixture of processing treatment forms the polyurethane sponge abrasive material comprising intact fibre cellulose fiber, and the above-mentioned sponge abrasive material of granulation.
Preferred as another kind, described prepolymer and cellulosic fibre are pre-mixed, heat after, again with the abrasive material of heating, the water-absorbing polymer Homogeneous phase mixing of fully moisture absorption, also there is chemical reaction in the water catalysis prepolymer discharged with above-mentioned water-absorbing polymer thus; The above-mentioned reaction mixture of processing treatment forms the polyurethane sponge abrasive material comprising intact fibre cellulose fiber, and the above-mentioned sponge abrasive material of granulation.
Preferred as another kind, described prepolymer and cellulosic fibre are pre-mixed, heat after, again successively with the water-absorbing polymer Homogeneous phase mixing of the abrasive material of heating, fully moisture absorption, also there is chemical reaction thus in the water catalysis prepolymer discharged with above-mentioned water-absorbing polymer; The above-mentioned reaction mixture of processing treatment forms the polyurethane sponge abrasive material comprising intact fibre cellulose fiber, and the above-mentioned sponge abrasive material of granulation.
Preferred as another kind, described prepolymer and cellulosic fibre are pre-mixed, be heated to about 37.8 DEG C after, again successively with the water-absorbing polymer Homogeneous phase mixing of abrasive material, fully moisture absorption being heated to about 37.8 DEG C, also there is chemical reaction thus in the water catalysis prepolymer discharged with above-mentioned water-absorbing polymer; The above-mentioned reaction mixture of processing treatment forms the polyurethane sponge abrasive material comprising intact fibre cellulose fiber, and the above-mentioned sponge abrasive material of granulation.
Preferred as another kind, described abrasive grain, prepolymer, the water-absorbing polymer of fully moisture absorption, cellulosic fibre weight ratio are respectively 78%, 18%, 3%, 1%.
Preferred as another kind, described prepolymer comprises tolylene diisocyanate, polyurethane.
Preferred as another kind, described abrasive material and coupling agent as after silane Homogeneous phase mixing, then with water-absorbing polymer, the cellulosic fibre Homogeneous phase mixing of prepolymer, abundant moisture absorption.
Preferred as another kind, when the water catalysis prepolymer discharged with described water-absorbing polymer also carries out chemical reaction thus, prepolymer, abrasive material, cellulosic fibre, the water-absorbing polymer mixture extruded with elongated cake bread shape at the conveying belt top of movement.
Described prepolymer, cellulosic fibre, the water-absorbing polymer of abundant moisture absorption, abrasive material is uniformly mixed to form the polyurethane sponge abrasive material comprising intact fibre cellulose fiber in mixing extruder 63, elongated bread-like sponge abrasive material 79 is extruded by the discharge nozzle of mixing extruder 63, after sending into the abundant maintenance of curing room 64, undertaken being ground into less fritter by crusher 65, as 4*8*10cm, less particle is broken into again through tablets press 66, the particle of gained by another tape transport to sieve apparatus 67, the final sponge abrasive grain 69 of very uniform-dimension is obtained according to size screening particle.The particle 68 of the oversize that sieve apparatus sifts out is back to tablets press and reduces size further, also removes the small sized particles that can be used alone simultaneously.Through sieving desired size sponge abrasive material 69 particle size that obtains at bucket, bag, box or other suitable containers to transport.
Preferred as one, described prepolymer, cellulosic fibre, the water-absorbing polymer of fully moisture absorption, abrasive material are uniformly mixed to form the polyurethane sponge abrasive material comprising intact fibre cellulose fiber in mixing extruder 63, elongated bread-like sponge abrasive material 79 is extruded by the discharge nozzle of mixing extruder 63, transported by the conveying belt 77 of a movement, conveying belt has suitable length.Because bread-like polyurethane sponge abrasive material is that tool is sticking at first, polyethylene plastic film 78 can be selected as the spacer between elongated bread-like polyurethane sponge abrasive material and conveying belt, in case bread-like polyurethane sponge abrasive material is sticky on the conveyor belt.At the afterbody of conveying belt 77; elongated bread-like sponge abrasive material is cut into shorter cake bread sheet together with plastic film below; collect after sending into the abundant maintenance of curing room 64; undertaken being ground into less fritter by crusher 65; as 4*8*10cm; be broken into less particle through tablets press 66 again, the particle of gained to sieve apparatus 67, obtains the final sponge abrasive grain 69 of very uniform-dimension by another tape transport according to size screening particle.The particle 68 of the oversize that sieve apparatus sifts out is back to tablets press and reduces size further, also removes the small sized particles that can be used alone simultaneously.Through sieving desired size sponge abrasive material 69 particle size that obtains at bucket, bag, box or other suitable containers to transport.
Preferred as another kind, described prepolymer, cellulosic fibre in prepolymer storage tank 61 after Homogeneous phase mixing, then are uniformly mixed to form with the water-absorbing polymer of abundant moisture absorption, abrasive material the polyurethane sponge abrasive material comprising intact fibre cellulose fiber in mixing extruder 63.
Preferred as another kind, described prepolymer, cellulosic fibre in prepolymer storage tank 61 after Homogeneous phase mixing, then with the water-absorbing polymer of abundant moisture absorption, abrasive material in mixing extruder 63 Homogeneous phase mixing, add the polyurethane sponge abrasive material that thermosetting comprises intact fibre cellulose fiber.
Preferred as another kind, described prepolymer, cellulosic fibre are in prepolymer storage tank 61 after Homogeneous phase mixing, again with abrasive material in mixing machine 74 Homogeneous phase mixing, then in mixing extruder 63, be uniformly mixed to form with the water-absorbing polymer of abundant moisture absorption the polyurethane sponge abrasive material comprising intact fibre cellulose fiber.
Preferred as another kind, described prepolymer, cellulosic fibre in prepolymer storage tank 61 Homogeneous phase mixing, prepolymer heating unit 83 heat after, again with abrasive material Homogeneous phase mixing in mixing machine 74 of heating through abrasive material heating unit 81 in abrasive material storage tank 62, then in mixing extruder 63, be uniformly mixed to form with the water-absorbing polymer of abundant moisture absorption the polyurethane sponge abrasive material comprising intact fibre cellulose fiber.
Preferred as another kind, described prepolymer, cellulosic fibre are after in prepolymer storage tank 61, Homogeneous phase mixing, prepolymer heating unit 83 are heated to about 38 DEG C, to be heated to abrasive material Homogeneous phase mixing in mixing machine 74 of about 37.8 DEG C through abrasive material heating unit 81 again with abrasive material storage tank 62, then in mixing extruder 63, to be uniformly mixed to form with the water-absorbing polymer of abundant moisture absorption the polyurethane sponge abrasive material comprising intact fibre cellulose fiber.
Preferred as another kind, be provided with well heater 76: the water-absorbing polymer of performed polymer and high moisture absorption introduces mixing extruder 63 respectively, by starting the well heater 76 being coated on mixing extruder 63 conveyor screw shell, heated mixt, water-absorbing polymer is made to discharge the water of absorption and initiating chamical reaction, the water that the heat of chemical reaction release impels water-absorbing polymer to continue to discharge absorption participates in chemical reaction, chemical reaction is spontaneous to carry out, now can stop using well heater 76, the effect starting well heater 76 is similar to the electric furnace that goes into operation in synthetic ammonia ammonia synthesis operation.
Controller 80 is for controlling the mixture control with operating pumps, metering conveyor screw and system component, and have speed control different separately because it is each, flow velocity, temperature and mixing time all can adjust according to desired component requirements.
For improving the performance of flexible abrasive blasting material, also other auxiliary agents for conventional foam and color stuffing can be comprised in its composition, as one or more in softening agent, coupling agent, stablizer, tensio-active agent, pigment, filler, wherein coupling agent is for increasing the cohesive force between abrasive material and elastic foam, can add in oxy-compound and/or amide components, first mix with prepolymer, also can add in rigidity abrasive material, first mix with rigidity abrasive material.
The representative example of described softening agent comprise following in one or more, but be not limited to these: dibutyl phthalate (DBP), propyl carbonate (PC), dioctyl phthalate (DOP) (DOP), ethyl-carbonate (EC) etc.As the propyl carbonate Jeffsol of Huntsman company of the U.S.
tMpC and ethyl-carbonate (EC).
Described stablizer include but not limited in following substances one or more: silicone oil, Silicone suds stablizer SF-1034, organic foam stabilizer L-520.
Described coupling agent include but not limited in following substances one or more: γ-aminopropyl triethoxysilane (KH550), vinyltrimethoxy silane (A-171), N-β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane (KH602), γ-glycidyl ether oxygen propyl trimethoxy silicane (KH560), γ-methacryloxypropyl trimethoxy silane (KH570).Coupling agent can add in oxy-compound and/or amide components, first mixes with prepolymer, also can add in rigidity abrasive material, first mixes with rigidity abrasive material.
Described pigment include but not limited in following substances one or more: calcium carbonate, silica powder, glass microballon, titanium white, lithopone, stibium trioxide, vulcanized white, carbon black, titanium are black, Cadmium oxide (green), phthalocyanine blue, cadmium orange, cadmium yellow, iron oxide yellow, zinc-chrome yellow, iron oxide red, cadmium red, molybdenum red.
the present invention compared to existing technology tool has the following advantages:
1, the water utilizing the water-absorbing polymer of high moisture absorption to slowly release and prepolymer carry out chemical reaction, the speed of effective control chemical reaction, ensure gained mixture evenly, and prevent too early chemical reaction from affecting the final performance of sponge particles, provide Reliable guarantee for producing high-quality polyurethane flexible abrasive material; Eliminate in traditional sponge abrasive material production technique, when water and performed polymer mixing, it is the chemical reaction that may control hardly, the shortcoming that chemical reaction velocity is exceedingly fast, process control needs is high, may cause the unnecessary blocking of mixing extruder delivery pipe;
When 2, adopting prepolymer, abrasive material heating process, technique of the present invention is without the need to supporting cooling apparatus, and traditional technology then needs to carry out cooling process to the mixture of water and cellulosic fibre, and then controls chemical reaction velocity, thus simplify production technique, general facilities facility investment effectively reduces;
3, under meeting the prerequisite of polyurethane flexible abrasive material quality control requirement, mixing equipment and processing requirement thereof is simplified;
4, while the advantage retaining cellulosic fibre, expand the selection face of cellulosic fibre, as selecting hydrophobic fiber cellulose fiber, man-made fiber creates condition.
Accompanying drawing explanation
Fig. 1 is a kind of flexible abrasive blasting material preparation method process flow diagram embedding fiber of the present invention;
In Fig. 1: 59-cellulosic fibre, 60-water absorbent polymer storage tank, 61-prepolymer storage tank, 62-abrasive material storage tank, 63-mixing extruder, 64-curing room, 65-crusher, 66-tablets press, 67-sieve apparatus, 68-macrobead sponge abrasive material, 69-desired size sponge abrasive material, 70-store holder, 71-measures conveyor screw, 72-positive displacement spiral pump, 73-abrasive metering conveyor screw, 74-mixing machine, 75-mixing machine discharging spiral, 76-well heater, 77-conveying belt, 78-polyethylene film, 79-elongated bread-like sponge abrasive material, 80-controller, 81-abrasive material heating unit, 82-abrasive material well heater, 83-prepolymer heating unit, 84-prepolymer well heater.
Embodiment
Below in conjunction with the drawings and specific embodiments, the present invention is described in further detail.
embodiment 1:
As shown in Figure 1, a kind of flexible media abrasive blasting preparation method process flow diagram embedding fiber of the present invention.In this flexible abrasive blasting material preparation process, prepolymer adopts tolylene diisocyanate, and cellulosic fibre adopts hydrophobic fiber cellulose fiber, and abrasive material adopts aluminium dioxide, and water-absorbing polymer adopts the polymethyl acrylic acid water-absorbing resin of abundant moisture absorption.Described abrasive grain, prepolymer, the water-absorbing polymer of fully moisture absorption, cellulosic fibre weight ratio are respectively 78%, 18%, 3%, 1%.Described prepolymer, cellulosic fibre are in prepolymer storage tank 61 after Homogeneous phase mixing, after prepolymer heating unit 83 is heated to about 38 DEG C, mixing machine 74 is delivered to through positive displacement spiral pump 72, with the abrasive material Homogeneous phase mixing in mixing machine 74 being heated to about 37.8 DEG C through abrasive material heating unit 81 in abrasive material storage tank 62, sent by abrasive metering conveyor screw 73, again with water-absorbing polymer 60 Homogeneous phase mixing in mixing extruder 63 of abundant moisture absorption, form the polyurethane sponge abrasive material comprising intact fibre cellulose fiber.Extrude elongated bread-like sponge abrasive material 79 by the discharge nozzle of mixing extruder 63, transported by the conveying belt 77 of a movement.Because bread-like polyurethane sponge abrasive material is that tool is sticking at first, polyethylene plastic film 78 can be selected as the spacer between elongated bread-like polyurethane sponge abrasive material and conveying belt, in case bread-like polyurethane sponge abrasive material is sticky on the conveyor belt, the elongated bread-like polyurethane sponge abrasive material generated is allowed to stop time enough on the conveyor belt to treat final processing treatment.At the afterbody of conveying belt 77; elongated bread-like sponge abrasive material is cut into shorter cake bread sheet together with plastic film below; collect after sending into curing room 64 sufficient time maintenance; undertaken being ground into less fritter by crusher 65; as 4*8*10cm; be broken into less particle through tablets press 66 again, the particle of gained to sieve apparatus 67, obtains the final sponge abrasive grain 69 of very uniform-dimension by another tape transport according to size screening particle.The particle 68 of the oversize that sieve apparatus sifts out is back to tablets press and reduces size further, also removes the small sized particles that can be used alone simultaneously.Through sieving desired size sponge abrasive material 69 particle size that obtains at bucket, bag, box or other suitable containers to transport.
As preferably, be provided with well heater 76: the water-absorbing polymer of performed polymer and high moisture absorption introduces mixing extruder 63 respectively, by starting the well heater 76 being coated on mixing extruder 63 conveyor screw shell, heated mixt, water-absorbing polymer is made to discharge the water of absorption and initiating chamical reaction, the water that the heat of chemical reaction release impels water-absorbing polymer to continue to discharge absorption participates in chemical reaction, and chemical reaction is spontaneous to carry out, well heater 76 of now can stopping using.
Controller 80 is for controlling the mixture control with operating pumps, metering conveyor screw and system component, and have speed control different separately because it is each, flow velocity, temperature and mixing time all can adjust according to desired component requirements.
Although the present invention with preferred embodiment openly as above; but they are not for limiting the present invention, being anyly familiar with this area technical professional, without departing from the spirit and scope of the invention; various simple modification, equivalent variations can be made, still belong to the protection domain of technical solution of the present invention.
Claims (10)
1. embed a flexible abrasive blasting material preparation method for fiber, it is characterized in that:
Water-absorbing polymer, the abrasive material of mixed prepolymer, cellulosic fibre, fully moisture absorption; Also there is chemical reaction thus in the water catalysis prepolymer discharged with above-mentioned water-absorbing polymer; The above-mentioned reaction mixture of processing treatment forms the polyurethane sponge abrasive material comprising intact fibre cellulose fiber, the more above-mentioned sponge abrasive material of granulation.
2. method according to claim 1, is characterized in that:
After described prepolymer and cellulosic fibre are pre-mixed, then with water-absorbing polymer, the abrasive material Homogeneous phase mixing of abundant moisture absorption.
3. method according to claim 1, is characterized in that:
After described prepolymer and cellulosic fibre are pre-mixed, more successively with the water-absorbing polymer Homogeneous phase mixing of abrasive material, fully moisture absorption.
4. method according to claim 1, is characterized in that:
Described prepolymer and cellulosic fibre are pre-mixed, heat after, then with the water-absorbing polymer Homogeneous phase mixing of the abrasive material of heating, fully moisture absorption.
5. method according to claim 1, is characterized in that:
Described prepolymer and cellulosic fibre are pre-mixed, heat after, more successively with the water-absorbing polymer Homogeneous phase mixing of the abrasive material of heating, fully moisture absorption.
6. method according to claim 5, is characterized in that:
Described prepolymer and cellulosic fibre are pre-mixed, be heated to about 37.8 DEG C after, more successively with the water-absorbing polymer Homogeneous phase mixing of abrasive material, fully moisture absorption being heated to about 37.8 DEG C.
7. method according to claim 1, is characterized in that:
Described cellulosic fibre refers to hydrophilic cellulose fiber, hydrophobic fiber cellulose fiber or man-made fiber, and the size range of cellulosic fibre is at 15 ~ 200 microns.
8. method according to claim 1, is characterized in that:
Described abrasive grain, prepolymer, the water-absorbing polymer of fully moisture absorption, cellulosic fibre weight ratio are respectively 78%, 18%, 3%, 1%.
9. method according to claim 1, is characterized in that:
After described abrasive material and coupling agent Homogeneous phase mixing, then with water-absorbing polymer, the cellulosic fibre Homogeneous phase mixing of prepolymer, fully moisture absorption.
10. method according to claim 1, is characterized in that:
Be provided with well heater (76): the water-absorbing polymer of performed polymer and high moisture absorption introduces mixing extruder (63) respectively, by starting the well heater (76) being coated on mixing extruder (63) conveyor screw shell, heated mixt, water-absorbing polymer is made to discharge the water of absorption and initiating chamical reaction, the water that the heat of chemical reaction release impels water-absorbing polymer to continue to discharge absorption participates in chemical reaction, chemical reaction is spontaneous to carry out, now inactive well heater (76), well heater (76) plays initiating chamical reaction.
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|---|---|---|---|---|
| CN1070923A (en) * | 1992-06-17 | 1993-04-14 | 刘玉文 | Polyurethane foam sand and production technique thereof |
| CN1164243A (en) * | 1994-11-22 | 1997-11-05 | 帝国化学工业公司 | Process for making flexible foams |
| CN1563234A (en) * | 2004-03-22 | 2005-01-12 | 江苏省化工研究所有限公司 | Structural flame retardant type spray coating material of polyurethane elastomer and construction method |
| CN101287783A (en) * | 2005-10-14 | 2008-10-15 | 陶氏环球技术公司 | Composite article and method of manufacture using an isocyanate-terminated prepolymer as binder |
| WO2014181036A1 (en) * | 2013-05-08 | 2014-11-13 | Elastopoli Oy | Method and apparatus for the manufacturing of composite material |
-
2015
- 2015-01-21 CN CN201510029882.9A patent/CN104610555A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1070923A (en) * | 1992-06-17 | 1993-04-14 | 刘玉文 | Polyurethane foam sand and production technique thereof |
| CN1164243A (en) * | 1994-11-22 | 1997-11-05 | 帝国化学工业公司 | Process for making flexible foams |
| CN1563234A (en) * | 2004-03-22 | 2005-01-12 | 江苏省化工研究所有限公司 | Structural flame retardant type spray coating material of polyurethane elastomer and construction method |
| CN101287783A (en) * | 2005-10-14 | 2008-10-15 | 陶氏环球技术公司 | Composite article and method of manufacture using an isocyanate-terminated prepolymer as binder |
| WO2014181036A1 (en) * | 2013-05-08 | 2014-11-13 | Elastopoli Oy | Method and apparatus for the manufacturing of composite material |
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Application publication date: 20150513 |