CN104588129A - Dry-process regeneration system and method of honeycomb type denitration catalyst module - Google Patents

Dry-process regeneration system and method of honeycomb type denitration catalyst module Download PDF

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Publication number
CN104588129A
CN104588129A CN201410854934.1A CN201410854934A CN104588129A CN 104588129 A CN104588129 A CN 104588129A CN 201410854934 A CN201410854934 A CN 201410854934A CN 104588129 A CN104588129 A CN 104588129A
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China
Prior art keywords
catalyst module
honeycomb
guide rod
denitrification catalyst
honeycomb type
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CN201410854934.1A
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Chinese (zh)
Inventor
杨建�
林湖
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China Security and Surveillance Technology PRC Inc
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China Security and Surveillance Technology PRC Inc
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Priority to CN201410854934.1A priority Critical patent/CN104588129A/en
Publication of CN104588129A publication Critical patent/CN104588129A/en
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Abstract

The invention discloses a dry-process regeneration system and method of a honeycomb type denitration catalyst module. The dry-process regeneration method comprises the following steps: conveying a honeycomb type denitration catalyst module to a clamping device by virtue of a material conveying device; clamping the honeycomb type denitration catalyst module at a specified position by using the clamping device; pulling a brush body to extend into a honeycomb pore of the honeycomb type denitration catalyst module to perform reciprocating motion by using a first guide rod of a scraping device so as to scrap off a denitration catalysis deactivation layer on the inner wall of the honeycomb pore of a honeycomb type denitration catalyst; and purging gas by using a gas purging device to remove scraped objects in the honeycomb pore of the honeycomb type denitration catalyst module. According to the dry-process regeneration system and method disclosed by the invention, a liquid such as a regenerative reagent is not needed for cleaning, so that the overall activity of the honeycomb type denitration catalyst module can be ensured, the regeneration cost can be saved, and the regeneration treatment speed can be increased; secondary pollution cannot be caused in a regeneration process; and the contact area between the denitration catalyst module and denitration gas can be increased, and the denitration effect of the denitration catalyst module can be improved.

Description

Honeycomb type denitrification catalyst module dry reclamation system and method
Technical field
The present invention relates to desulphurization denitration technical field, particularly relate to a kind of honeycomb type denitrification catalyst module dry reclamation system and method.
Background technology
At industrial circles such as electric power, cement, iron and steel, coal is all by as main energy and material, a large amount of pollutants can be discharged during coal burning, mainly comprise Absorbable rod and enter solid particulate matter, carbon dioxide, sulfur dioxide and nitrogen oxide (NOX) etc., bring the problem of environmental pollutions such as greenhouse effects, acid rain, photochemical fog thus.Nitrogen oxide (NOX) has stronger stimulation and injury effect to eye and respiratory system, also participates in the formation of acid rain and photochemical fog.
The control of polluting for the NOX of burning generation mainly contains 3 kinds of methods: 1. fuel denitrogenation; 2. combustion system and production technology is improved; 3. denitrating flue gas.Fuel denitride technology is developed so far not yet very well, awaits continuing research from now on.A large amount of research work is done to the improvement of combustion system both at home and abroad, develop many lower NOx combustion technology and equipments, and apply on some boilers and other stoves, but because some lower NOx combustion technology and equipments reduce efficiency of combustion sometimes, cause imperfect combustion, the energy can not make full use of, and equipment scale increases thereupon, the reduced rate of NOX is also limited, so lower NOx combustion technology and equipment not yet reaches the comprehensively practical stage at present.Denitrating flue gas is most important method in NOX control measure at no distant date, and SCR (SCR) denitration technology is remarkable to the removal effect of NOX, and technology maturation is one of current most widely used gas denitrifying technology.In the out of stock system of whole SCR, catalyst is core material, and the proportion accounted in equipment direct investment is larger.Wherein using maximum is vanadium titanium base honeycomb-shaped SCR denitrating catalyst.The scheme that the catalyst module major part of SCR denitrating system takes high dirt to arrange, run the denitration performance of a period of time rear catalyst can decline, show as that reducing agent consumption increases, the oxygenation efficiency of sulfur dioxide rises, denitration amount declines, the resistance rising etc. of denitrating system.Catalyst activity reduction, when not reaching denitration requirement, will more catalyst changeout.Catalyst under changing will carry out regenerating or discarding, and discarded mode generally processes according to danger wastes, and such as broken landfill, melting are reclaimed and be used as the processing modes such as construction material.Consider that the price of denitrating catalyst is higher, if realize catalyst regeneration efficiently, will greatly save denitration cost.
During SCR denitrating system runs, in flue gas, Cucumber can deposit at catalyst surface gradually.The alkali metal wherein existed with aerosol form and the compound of the element such as arsenic can make catalyst lose activity, and block, cover, the reason such as erosion can make catalyst generation physics inactivation.Existing catalyst recovery process, is generally through dry type and purges and the pre-treatment of wet dip two step, then carries out the process such as active physical load and drying.The device of a set of regeneration is provided in a prior art, comprises the equipment carrying out compressed air purging, cleaning, spark etc.In another prior art, give a kind of being reached by bubbling flowing wash out pollutant, recover the device of catalyst denitration activity.In another prior art, mainly give a kind of technique adopting autoclave to carry out catalyst reaming in regenerative process, but the expanding agent used in this technique such as methyl alcohol etc. can cause secondary pollution, and under Elevated Temperature Conditions, realize release rapidly there is hidden danger in safety and this technique exists the processing time waits so long problem.
In prior art, all there is denitration speed slow, the problems such as denitration effect is not good in no matter wet denitration or Dry denitration, and wherein wet denitration also exists the problem reducing denitration anti-oxidant active and reduce, and easily produces secondary pollution in denitrification process.So provide a kind of novel denitration mode to be this area problem demanding prompt solution.
Summary of the invention
Main purpose of the present invention gets involved cleaning for providing a kind of without the need to liquid, quick, free of contaminationly can complete the honeycomb type denitrification catalyst module dry reclamation system and method for honeycomb type denitrification catalyst module regeneration.
In order to realize foregoing invention object, first the present invention provides a kind of honeycomb type denitrification catalyst module dry reclamation system, comprising: clamping device, feeding device, removing device and gas purging device; Wherein, described removing device comprises brush body and the first guide rod, and described brush body side is fixedly connected with the front end of described first guide rod; Described brush body is identical with the shape of cross section of described honeycomb hole perpendicular to the cross sectional shape of the first guide rod axis direction, and brush body is greater than the cross-sectional area of described honeycomb hole perpendicular to the area in the cross section of the first guide rod axis direction, and can be set in described honeycomb hole mobile; The length of described first guide rod is greater than the length of described honeycomb hole;
Honeycomb type denitrification catalyst module is delivered to described clamping device place by described feeding device, and described honeycomb type denitrification catalyst module is fixedly clamped by clamping device; Described first guide rod traction brush body stretches in described honeycomb hole and moves back and forth; When brush body detaches honeycomb hole, the scrapings in honeycomb hole is removed by described gas purging device purge gas.
Further, described removing device also comprises:
Connecting plate and connector; On described connecting plate, the position of the honeycomb hole of corresponding described honeycomb type denitrification catalyst module and quantity arrange described connector, connector are installed the tail end being connected with the first guide rod of brush body, form brush body bundle.
Further, described removing device also comprises and strikes off drive unit;
The described drive unit that strikes off drives described connecting plate along the first guide rod axis direction straight reciprocating motion.
Further, described removing device also comprises guide rod location-plate;
The cover of described guide rod location-plate adaptation is connected on the end face of described honeycomb type denitrification catalyst module, and described guide rod location-plate is provided with and the honeycomb hole of honeycomb type denitrification catalyst module bullport one to one.
Further, described removing device also comprises the second guide rod;
Corresponding described first guide rod of described second guide rod is connected to the opposite side of described brush body; The length of described second guide rod is greater than the length of described honeycomb hole.
Further, described clamping device comprises driving clamping device and U-shaped lower platen;
Described driving clamping device drives described U-shaped lower platen linearly to move; Described denitrification catalyst module is limited between two sidewalls by described U-shaped lower platen.
Further, described feeding device comprises conveying drive unit and hard conveyer belt;
Described conveying drive unit drives described hard conveyer belt to move, and described hard conveyer belt is positioned at immediately below described U-shaped lower platen.
Further, described gas purging device comprises gas compressing apparatus, air intake drainage hood and air-out drainage hood; Described gas compressing apparatus connects the first air inlet of described air intake drainage hood, and the first air outlet of described air intake drainage hood is socketed an end of described honeycomb type denitrification catalyst module; Second air inlet of described air-out drainage hood is socketed the other end of described honeycomb type denitrification catalyst module;
The area of the first air inlet of described air intake drainage hood is less than the first air outlet area of described air intake drainage hood; Second air inlet of described air-out drainage hood is greater than the second air outlet of air-out drainage hood.
The present invention also provides a kind of honeycomb type denitrification catalyst module dry reclamation method, comprises step:
Use feeding device that honeycomb type denitrification catalyst module is delivered to clamping device place;
Use clamping device that described honeycomb type denitrification catalyst module is clamped in assigned address;
Move back and forth in the honeycomb hole using the first guide rod traction brush body of removing device to stretch into honeycomb type denitrification catalyst module, the denitration catalyst deactivating layer of the honeycomb hole inwall of described honeycomb fashion denitration catalyst is struck off; Wherein, in described removing device, brush body side is connected to the front end of described first guide rod; Described brush body is identical with the shape of cross section of the honeycomb hole of described honeycomb type denitrification catalyst module perpendicular to the cross sectional shape of the first guide rod axis direction, and brush body is greater than the cross-sectional area of described honeycomb hole perpendicular to the area in the cross section of the first guide rod axis direction, and can be set in honeycomb hole mobile; The length of described first guide rod is greater than 1/2nd length of described honeycomb hole;
Gas purging device purge gas is used to be removed by scrapings in the honeycomb hole of described honeycomb type denitrification catalyst module.
Further, move back and forth in the honeycomb hole that the first guide rod traction brush body of described use removing device stretches into honeycomb type denitrification catalyst module, before the step that the denitration catalyst deactivating layer of the honeycomb hole inwall of described honeycomb fashion denitration catalyst is struck off, comprising:
Gas purging device purge gas is used to be removed by the impurity of the honeycomb hole of described honeycomb fashion denitration catalyst.
Honeycomb type denitrification catalyst module dry reclamation system and method for the present invention, by clamping device, denitrification catalyst module is fixedly clamped, then by special removing device, the denitration catalyst deactivating layer of the honeycomb hole inwall of honeycomb fashion denitration catalyst is struck off, the catalyst of non-inactivation is revealed, without the need to liquid rinse such as regenerative agents, thus ensure that the overall activity of honeycomb type denitrification catalyst module, and saving regeneration cost, improve the speed of regeneration process; The mode of striking off is physical method, and non-secondary pollution produces.
Accompanying drawing explanation
Fig. 1 is the structural representation of the honeycomb type denitrification catalyst module dry reclamation system of one embodiment of the invention;
Fig. 2 is the structural representation of the honeycomb type denitrification catalyst module dry reclamation system of one embodiment of the invention;
Fig. 3 is the structural representation of the brush body of one embodiment of the invention and the first guide rod, the second guide rod;
Fig. 4 is the structural representation of the brush body bundle of one embodiment of the invention;
Fig. 5 is the structural representation of the guide rod location-plate of one embodiment of the invention;
Fig. 6 is the structural representation being fixed denitrification catalyst module of one embodiment of the invention;
Fig. 7 is the structural representation of the air intake drainage hood of one embodiment of the invention;
Fig. 8 is the structural representation that the air intake drainage hood of one embodiment of the invention is connected with denitrification catalyst module with air-out drainage hood;
Fig. 9 is the flow chart of the honeycomb type denitrification catalyst module dry reclamation method of one embodiment of the invention.
The realization of the object of the invention, functional characteristics and advantage will in conjunction with the embodiments, are described further with reference to accompanying drawing.
Detailed description of the invention
Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Referring to figs. 1 through Fig. 4, the embodiment of the present invention proposes a kind of honeycomb type denitrification catalyst module 50 dry reclamation system, comprising: feeding device 10, clamping device 20, removing device 30 and gas purging device 40; Wherein, described removing device 30 comprises brush body 31 and the first guide rod 33, and described brush body 31 side is fixedly connected with the front end of described first guide rod 33; Described brush body 31 is identical with the shape of cross section of the honeycomb hole 51 of described honeycomb type denitrification catalyst module 50 perpendicular to the cross sectional shape of the first guide rod 33 axis direction, and brush body 31 is greater than the cross-sectional area of described honeycomb hole 51 perpendicular to the area in the cross section of the first guide rod 33 axis direction, and can be set in honeycomb hole 51 mobile; The length of described first guide rod 33 is greater than the length of described honeycomb hole 51; Honeycomb type denitrification catalyst module 50 is delivered to described clamping device 20 place by described feeding device 10, and described honeycomb type denitrification catalyst module 50 is fixedly clamped by clamping device 20; Described first guide rod 33 draws in honeycomb hole 51 that brush body 31 stretches into honeycomb type denitrification catalyst module 50 and moves back and forth; When brush body 31 detaches honeycomb hole 51, scrapings in honeycomb hole 51 is removed by described gas purging device 40 purge gas, scrapings in the honeycomb hole 51 of described honeycomb type denitrification catalyst module 50 is removed, the catalytic efficiency of denitrification catalyst module 50 can be improved.
In the present embodiment, described brush body 31 refers to the brush that the catalysqt deactivation layer brush that honeycomb hole 51 inwall of honeycomb type denitrification catalyst module 50 is formed can be fallen, the brush teeth of brush body 31 is generally the metals such as steel wire and makes, be distributed in all sides along the first guide rod 33 axis, can fully and honeycomb hole 51 contact internal walls, easy to use, scraping effect is good.Described first guide rod 33, its effect is fixing brush body 31, and hence brush member 31 is mobile in honeycomb hole 51, to complete the action of striking off.
In the present embodiment, when the length of the first guide rod 33 is greater than 1/2nd length of described honeycomb hole 51, when being less than the length of honeycomb hole 51, described brush body 31 can be goed deep into respectively respectively from the both sides of honeycomb hole 51, any one section of inwall in honeycomb hole 51 can not be omitted, because the length of the first guide rod 33 is short, so not easily bend when using.When the length of the first guide rod 33 is greater than the length of described honeycomb hole 51, brush body 31 can be stretched into from one end of honeycomb hole 51 and directly move to the other end, realize one-sided movement, and do not omit any one section of inwall in honeycomb hole 51, abrading process is simple, quick.
In the present embodiment, because brush body 31 is identical with the shape of cross section of the honeycomb hole 51 of described honeycomb type denitrification catalyst module 50 perpendicular to the cross sectional shape of the first guide rod 33 axis direction, namely when the cross section of honeycomb hole 51 is circular, the straight cross sectional shape in the first guide rod 33 axis direction of described brush body 31 is also circular, and brush body 31 is greater than the cross-sectional area of described honeycomb hole 51 perpendicular to the area in the cross section of axis direction, and can be set in honeycomb hole 51 mobile, so when brush body 31 moves back and forth in honeycomb hole 51, the inwall top layer of honeycomb hole 51 can be scraped, this inwall top layer scraped is then deactivated catalyst coating, thus the catalyst of non-inactivation is revealed, without the need to liquid rinse such as regenerative agents, thus ensure that the overall activity of honeycomb type denitrification catalyst module 50, and saving regeneration cost, the mode of striking off is physical method, and non-secondary pollution produces, because denitrification catalyst module 50 deactivating layer struck off, increase the aperture of honeycomb hole 51, so improve denitrification catalyst module 50 and the contact area of denitration gas, further improve denitrification catalyst module 50 denitration effect.
In the embodiment of the present invention, above-mentioned removing device 30 also comprises connecting plate 34 and connector 35; On described connecting plate 34, the position of the honeycomb hole 51 of corresponding described honeycomb type denitrification catalyst module 50 and quantity arrange described connector 35, connector 35 are installed the tail end being connected with the first guide rod 33 of brush body 31, form brush body bundle 36.Whole honeycomb holes 51 of honeycomb type denitrification catalyst module 50 once can be carried out scraper action by brush body bundle 36, improve and strike off efficiency.Brush body 31 on brush body bundle 36 mutually can restrict, make it move along honeycomb hole 51 after all entering corresponding honeycomb hole 51, not easily occurs that the situation that the first independent guide rod 33 bends occurs, improves the safe handling of the first guide rod 33.
In the embodiment of the present invention, above-mentioned removing device 30 also comprises and strikes off drive unit (scheming not shown), the described drive unit that strikes off drives described connecting plate 34 along the first guide rod 33 axis direction straight reciprocating motion, strike off drive unit to be controlled by control panel, without the need to the manual mobile brush body bundle 36 of staff, honeycomb hole 51 on the honeycomb type denitrification catalyst module 50 that only brush body bundle 36 aligning need be had clamping device 20 fixing once, next time without the need to contraposition, directly can carry out scraper action to the honeycomb type denitrification catalyst module 50 that the next one is fixed on the same model at clamping device 20 place, save manpower, contraposition is accurate, translational speed uniform, controllable, improve the quality struck off.The described drive unit that strikes off can be the motive power outputting apparatus such as cylinder, electric pushrod or stepper motor.
With reference to Fig. 5, in the embodiment of the present invention, above-mentioned removing device 30 also comprises two pieces of guide rod location-plates 37; Two pieces of guide rod location-plates 37 cover adaptedly respectively and are connected on two end faces of described honeycomb type denitrification catalyst module 50, and described guide rod location-plate 37 are provided with and the honeycomb hole 51 of honeycomb type denitrification catalyst module 50 bullport 371 one to one.Bullport 371 on described guide rod location-plate 37 is with the measure-alike of honeycomb hole 51 and corresponding setting.During scraper action, guide rod location-plate 37 is arranged on denitrification catalyst module 50 two ends, brush body 31 enters in honeycomb hole 51 along the bullport 371 on guide rod location-plate 37, locates both can to brush body 31, can prevent again the end face of denitrification catalyst module 50 from being swiped by brush body 31 and damaging.
With reference to Fig. 2, in the embodiment of the present invention, above-mentioned removing device 30 also comprises the second guide rod 32, and corresponding described first guide rod 33 of described second guide rod 32 is connected to the opposite side of described brush body 31; The length of described second guide rod 32 is greater than the length of described honeycomb hole 51.Second guide rod 32 at work, when brush body 31 enters stressed in honeycomb hole 51, the other end of honeycomb hole 51 has been stretched out in the end of second guide rod 32 one end, so, if when there are obstacle foreign material in honeycomb hole 51, can be cleared out of honeycomb hole 51 in advance, that improves brush body 31 strikes off quality, can also the moving direction of correct guiding brush body 31, and avoid causing damage because the second guide rod 32 moves to the inwall of honeycomb hole 51.
With reference in Fig. 2 and Fig. 6 embodiment of the present invention, above-mentioned clamping device 20 comprises driving clamping device (scheming not shown) and U-shaped lower platen 22; Described driving clamping device drives described U-shaped lower platen 22 linearly to move; Described U-shaped lower platen 22 is arranged at the top of described feeding device 10, when described honeycomb type denitrification catalyst module 50 is delivered to immediately below U-shaped lower platen 22, driving clamping device drives U-shaped lower platen 22 to move down and compresses honeycomb type denitrification catalyst module 50 and described feeding device 10.When U-shaped lower platen 22 presses down, between two side denitrification catalyst module 50 being limited in U-shaped lower platen 22, and by the bottom of U-shaped lower platen 22, denitrification catalyst module 50 is pressed on described feeding device 10.Leave working space can between the two side of U-shaped lower platen 22 removing device 30, easy to use.In the present embodiment, the bottom outside of described U-shaped lower platen 22 generally can utilize a pole 21 to connect described driving clamping device, thus drives U-shaped lower platen 22 to move.
In the embodiment of the present invention, above-mentioned feeding device 10 comprises conveying drive unit (scheming not shown) and hard conveyer belt 11; Described conveying drive unit drives described hard conveyer belt 11 to move, and described hard conveyer belt 11 is positioned at immediately below described U-shaped lower platen 22.Hard conveyer belt 11 can accept certain downforce, so denitrification catalyst module 50 can compress with on hard conveyer belt 11 by U-shaped lower platen 22.
With reference to Fig. 7 and Fig. 8, in the embodiment of the present invention, above-mentioned gas blow device 40 comprises gas compressing apparatus (scheming not shown), air intake drainage hood 41 and air-out drainage hood 42; Described gas compressing apparatus connects the first air inlet 412 of described air intake drainage hood 41, and the first air outlet 411 of described air intake drainage hood 41 is socketed an end of described honeycomb type denitrification catalyst module 50; Second air inlet 422 of described air-out drainage hood 42 is socketed the other end of described honeycomb type denitrification catalyst module 50; The area of the first air inlet 412 of described air intake drainage hood 41 is less than the first air outlet 411 area of described air intake drainage hood 41; Second air inlet 422 of described air-out drainage hood 42 is greater than the second air outlet 421 of air-out drainage hood 42.In purge, the first air outlet 411 of air intake drainage hood 41 is covered on one end of honeycomb type denitrification catalyst module 50, removing work can be carried out to whole honeycomb holes 51 of honeycomb type denitrification catalyst module 50 simultaneously.And the first air outlet 411 of air intake drainage hood 41 is greater than the first air inlet 412.And in order to protection of the environment and minimizing later stage work amount, also air-out drainage hood 42 can be set at the other end of honeycomb type denitrification catalyst module 50, by the unified recycling of scrapings purged out.In the present embodiment, air intake drainage hood 41 is identical with the structure of air-out drainage hood 42, but the position of air inlet and gas outlet is contrary.
In one embodiment, the regeneration of honeycomb type denitrification catalyst module 50 is treated to:
1, the hard conveyer belt 11 of feeding device 10 is used to be delivered to by honeycomb type denitrification catalyst module 50 immediately below the U-shaped lower platen 22 of clamping device 20;
2, U-shaped lower platen 22 moves down, and between two side honeycomb type denitrification catalyst module 50 being limited in U-shaped lower platen 22, and is pressed in by denitrification catalyst module 50 on described hard conveyer belt 11;
3, the first air outlet 411 of air intake drainage hood 41 and the second air inlet 422 of air-out drainage hood 42 are covered on respectively the both sides of honeycomb type denitrification catalyst module 50, jet to the first air inlet 412 of air intake drainage hood 41 by gas compressing apparatus, thus remove the foreign material in honeycomb hole 51;
4, remove air intake drainage hood 41 and air-out drainage hood 42, and be socketed corresponding guide rod location-plate 37 at the two ends of honeycomb type denitrification catalyst module 50 respectively;
5, by multiple tail end being provided with the first guide rod 33 of the brush body 31 of the first guide rod 33 and the second guide rod 32, the honeycomb hole 51 of corresponding honeycomb type denitrification catalyst module 50 is arranged on location-plate 1 and forms brush body bundle 36, and is inserted in the honeycomb hole 51 of honeycomb type denitrification catalyst module 50 by the bullport 371 on the corresponding guide rod location-plate 37 of the second guide rod 32.
6, use and strike off drive unit and drive connecting plate 34, make the brush body 31 on brush body bundle 36 strike off catalysqt deactivation layer on honeycomb hole 51 inwall respectively, and move back and forth repeatedly.
7, brush body bundle 36 is detached honeycomb type denitrification catalyst module 50;
8, remove guide rod location-plate 37, air intake drainage hood 41 and air-out drainage hood 42 are covered on respectively the both sides of honeycomb type denitrification catalyst module 50, jet removing scrapings;
9, U-shaped lower platen 22 moves, the honeycomb type denitrification catalyst module 50 processed is delivered to recovery place by feeding device 10 by feeding device 10.
Wherein, the process of above-mentioned installation and removal guide rod location-plate 37, can put upside down with step air intake drainage hood 41 and air-out drainage hood 42 being covered on respectively the both sides of honeycomb type denitrification catalyst module 50 and carry out, according to actual mechanical process, can determine.
Wherein, the process of above-mentioned installation and removal guide rod location-plate 37, can put upside down with step air intake drainage hood 41 and air-out drainage hood 42 being covered on respectively the both sides of honeycomb type denitrification catalyst module 50 and carry out, according to actual mechanical process, can determine.
With reference to Fig. 9, in the embodiment of the present invention, a kind of honeycomb type denitrification catalyst module 50 dry reclamation method is also provided, comprises step:
Honeycomb type denitrification catalyst module 50 is delivered to clamping device 20 place by S1, use feeding device 10;
Described honeycomb type denitrification catalyst module 50 is clamped in assigned address by S2, use clamping device 20;
Move back and forth in S3, use the first guide rod 33 of removing device 30 to draw honeycomb hole 51 that brush body 31 stretches into honeycomb type denitrification catalyst module 50, the denitrating catalyst deactivating layer of honeycomb hole 51 inwall of described honeycomb type denitrification catalyst is struck off; Wherein, in described removing device 30, described brush body 31 side is connected to the front end of described first guide rod 33; Described brush body 31 is identical with the shape of cross section of the honeycomb hole 51 of described honeycomb type denitrification catalyst module 50 perpendicular to the cross sectional shape of the first guide rod 33 axis direction, and brush body 31 is greater than the cross-sectional area of described honeycomb hole 51 perpendicular to the area in the cross section of the first guide rod 33 axis direction; The length of described first guide rod 33 is greater than 1/2nd length of described honeycomb hole 51; Described brush body 31 is stretched in the honeycomb hole 51 of honeycomb type denitrification catalyst module 50 by the first guide rod 33 traction and moves back and forth;
Scrapings in the honeycomb hole 51 of described honeycomb fashion denitration catalyst is removed by S4, use gas purging device 40 purge gas.
The honeycomb type denitrification catalyst module 50 dry reclamation method of the present embodiment, blows agent by mechanical transfer and fixing denitration, saves manpower and exports, increase work efficiency, because brush body 31 is identical with the shape of cross section of the honeycomb hole 51 of described honeycomb type denitrification catalyst module 50 perpendicular to the cross sectional shape of the first guide rod 33 axis direction, and brush body 31 is greater than the cross-sectional area of described honeycomb hole 51 perpendicular to the area in the cross section of axis direction, and can be set in honeycomb hole 51, so when brush body 31 moves back and forth in honeycomb hole 51, the inwall top layer of honeycomb hole 51 can be scraped, and this inwall top layer scraped, it is then deactivated catalyst coating, thus the catalyst of non-inactivation is revealed, without the need to liquid rinse such as regenerative agents, thus ensure that the overall activity of honeycomb type denitrification catalyst module 50, and saving regeneration cost, the mode of striking off is physical method, and non-secondary pollution produces, because denitrification catalyst module 50 deactivating layer struck off, increase the aperture of honeycomb hole 51, so improve denitrification catalyst module 50 and the contact area of denitration gas, further improve denitrification catalyst module 50 denitration effect.
As described in above-mentioned steps S1 and S2, above-mentioned clamping device 20 comprises driving clamping device and U-shaped lower platen 22; Described driving clamping device drives described U-shaped lower platen 22 linearly to move; Above-mentioned feeding device 10 comprises conveying drive unit and hard conveyer belt 11; Described U-shaped lower platen 22 is arranged at the top of described hard conveyer belt 11, when described honeycomb type denitrification catalyst module 50 is delivered to immediately below U-shaped lower platen 22, driving clamping device drives U-shaped lower platen 22 to move down and compresses honeycomb type denitrification catalyst module 50 in described hard conveyer belt 11.U-shaped lower platen 22 presses down, between two side denitrification catalyst module 50 being limited in U-shaped lower platen 22, and denitrification catalyst module 50 is pressed on described feeding device 10, the bottom outside of described U-shaped lower platen 22 generally can utilize pole 21 connecting drive device, thus drives U-shaped lower platen 22 to move.Leave working space can between the two side of U-shaped lower platen 22 removing device 30, easy to use.Described hard conveyer belt 11 can accept certain downforce, so denitrification catalyst module 50 can compress with on hard conveyer belt 11 by U-shaped lower platen 22.In the present embodiment, use machinery conveying denitrification catalyst module 50 and the denitrification catalyst module 50 that is fixed and clamped, accurate positioning, save manpower and export, increase work efficiency.
As described in above-mentioned steps S3, described brush body 31 refers to the brush that the catalysqt deactivation layer brush that honeycomb hole 51 inwall of honeycomb type denitrification catalyst is formed can be fallen, the brush teeth of brush body 31 is generally the metals such as steel wire and makes, be distributed in all sides along the first guide rod 33 axis, can fully and honeycomb hole 51 contact internal walls, easy to use, scraping effect is good.Described first guide rod 33, its effect is fixing brush body 31, and hence brush member 31 is mobile in honeycomb hole 51, to complete the action of striking off.When the length of the first guide rod 33 is greater than 1/2nd length of described honeycomb hole 51, when being less than the length of honeycomb hole 51, described brush body 31 can be goed deep into respectively respectively from the both sides of honeycomb hole 51, any one section of inwall in honeycomb hole 51 can not be omitted, because the length of the first guide rod 33 is short, so not easily bend when using.When the length of the first guide rod 33 is greater than the length of described honeycomb hole 51, brush body 31 can be stretched into from one end of honeycomb hole 51 and directly move to the other end, realize one-sided movement, and do not omit any one section of inwall in honeycomb hole 51, abrading process is simple, quick.
As described in above-mentioned steps S3, above-mentioned removing device 30 also comprises connecting plate 34 and connector 35; On described connecting plate 34, the position of the honeycomb hole 51 of corresponding described honeycomb type denitrification catalyst module 50 and quantity arrange described connector 35, connector 35 are installed the tail end being connected with the first guide rod 33 of brush body 31, form brush body bundle 36.Whole honeycomb holes 51 of honeycomb type denitrification catalyst module 50 once can be carried out scraper action by brush body bundle 36, improve and strike off efficiency.Brush body 31 on brush body bundle 36 mutually can restrict, make it move along honeycomb hole 51 after all entering corresponding honeycomb hole 51, not easily occurs that the situation that the first independent guide rod 33 bends occurs, improves the safe handling of the first guide rod 33.
As as described in above-mentioned steps S3, above-mentioned removing device 30 also comprises and strikes off drive unit, the described drive unit that strikes off drives described connecting plate 34 along the first guide rod 33 axis direction straight reciprocating motion, strike off drive unit to be controlled by control panel, without the need to the manual mobile brush body bundle 36 of staff, honeycomb hole 51 on the honeycomb type denitrification catalyst module 50 that only brush body bundle 36 aligning need be had clamping device 20 fixing once, next time without the need to contraposition, directly can carry out scraper action to the honeycomb type denitrification catalyst module 50 that the next one is fixed on the same model at clamping device 20 place, save manpower, contraposition is accurate, translational speed uniform, controllable, improve the quality struck off.The described drive unit that strikes off can be the motive power outputting apparatus such as cylinder, electric pushrod or stepper motor.
As described in above-mentioned steps S3, above-mentioned removing device 30 also comprises two pieces of guide rod location-plates 37; Two pieces of guide rod location-plates 37 cover adaptedly respectively and are connected on two end faces of described honeycomb type denitrification catalyst module 50, and described guide rod location-plate 37 are provided with and the honeycomb hole 51 of honeycomb type denitrification catalyst module 50 bullport 371 one to one.Bullport 371 on described guide rod location-plate 37 is with the measure-alike of honeycomb hole 51 and corresponding setting.During scraper action, guide rod location-plate 37 is arranged on denitrification catalyst module 50 two ends, brush body 31 enters in honeycomb hole 51 along the bullport 371 on guide rod location-plate 37, locate both can to brush body 31, and the end face of denitrification catalyst module 50 can have been prevented again by brush body 31 and guide dry scraping and damage.
As described in above-mentioned steps S3, above-mentioned removing device 30 also comprises the second guide rod 32, and corresponding described first guide rod 33 of described second guide rod 32 is connected to the opposite side of described brush body 31; The length of described second guide rod 32 is greater than the length of described honeycomb hole 51.Second guide rod 32 at work, when brush body 31 enters stressed in honeycomb hole 51, the other end of honeycomb hole 51 has been stretched out in the end of second guide rod 32 one end, so, if when there are obstacle foreign material in honeycomb hole 51, can be cleared out of honeycomb hole 51 in advance, that improves brush body 31 strikes off quality, can also the moving direction of correct guiding brush body 31, and avoid causing damage because the second guide rod 32 moves to the inwall of honeycomb hole 51.
As described in above-mentioned steps S4, above-mentioned gas blow device 40 above-mentioned gas blow device 40 comprises gas compressing apparatus, air intake drainage hood 41 and air-out drainage hood 42; Described gas compressing apparatus connects the first air inlet 412 of described air intake drainage hood 41, and the first air outlet 411 of described air intake drainage hood 41 is socketed an end of described honeycomb type denitrification catalyst module 50; Second air inlet 422 of described air-out drainage hood 42 is socketed the other end of described honeycomb type denitrification catalyst module 50; The area of the first air inlet 412 of described air intake drainage hood 41 is less than the first air outlet 411 area of described air intake drainage hood 41; Second air inlet 422 of described air-out drainage hood 42 is greater than the second air outlet 421 of air-out drainage hood 42.In purge, the first air outlet 411 of air intake drainage hood 41 is covered on one end of honeycomb type denitrification catalyst module 50, removing work can be carried out to whole honeycomb holes 51 of honeycomb type denitrification catalyst module 50 simultaneously.And the first air outlet 411 of air intake drainage hood 41 is greater than the first air inlet 412.And in order to protection of the environment and minimizing later stage work amount, also air-out drainage hood 42 can be set at the other end of honeycomb type denitrification catalyst module 50, by the unified recycling of scrapings purged out.In the present embodiment, air intake drainage hood 41 is identical with the structure of air-out drainage hood 42, but the position of air inlet and gas outlet is contrary.
In the embodiment of the present invention, before above-mentioned steps S3, comprising:
The impurity of the honeycomb hole 51 of described honeycomb fashion denitration catalyst is removed by S3`, use gas purging device 40.Removed by the impurity of the honeycomb hole 51 of honeycomb fashion denitration catalyst, that can improve step S3 strikes off efficiency.
In one embodiment, the renovation process of honeycomb type denitrification catalyst module 50 is:
1, the hard conveyer belt 11 of feeding device 10 is used to be delivered to by honeycomb type denitrification catalyst module 50 immediately below the U-shaped lower platen 22 of clamping device 20;
2, U-shaped lower platen 22 moves down, and between two side honeycomb type denitrification catalyst module 50 being limited in U-shaped lower platen 22, and is pressed in by denitrification catalyst module 50 on described hard conveyer belt 11;
3, the first air outlet 411 of air intake drainage hood 41 and the second air inlet 422 of air-out drainage hood 42 are covered on respectively the both sides of honeycomb type denitrification catalyst module 50, jet to the first air inlet 412 of air intake drainage hood 41 by gas compressing apparatus, thus remove the foreign material in honeycomb hole 51;
4, remove air intake drainage hood 41 and air-out drainage hood 42, and be socketed corresponding guide rod location-plate 37 at the two ends of honeycomb type denitrification catalyst module 50 respectively;
5, by multiple tail end being provided with the first guide rod 33 of the brush body 31 of the first guide rod 33 and the second guide rod 32, the honeycomb hole 51 of corresponding honeycomb type denitrification catalyst module 50 is arranged on location-plate 1 and forms brush body bundle 36, and is inserted in the honeycomb hole 51 of honeycomb type denitrification catalyst module 50 by the bullport 371 on the corresponding guide rod location-plate 37 of the second guide rod 32.
6, use and strike off drive unit and drive connecting plate 34, make the brush body 31 on brush body bundle 36 strike off catalysqt deactivation layer on honeycomb hole 51 inwall respectively, and move back and forth repeatedly.
7, brush body bundle 36 is detached honeycomb type denitrification catalyst module 50;
8, remove guide rod location-plate 37, air intake drainage hood 41 and air-out drainage hood 42 are covered on respectively the both sides of honeycomb type denitrification catalyst module 50, jet removing scrapings;
9, U-shaped lower platen 22 moves, the honeycomb type denitrification catalyst module 50 processed is delivered to recovery place by feeding device 10 by feeding device 10.
Wherein, the process of above-mentioned installation and removal guide rod location-plate 37, can put upside down with step air intake drainage hood 41 and air-out drainage hood 42 being covered on respectively the both sides of honeycomb type denitrification catalyst module 50 and carry out, according to actual mechanical process, can determine.
The foregoing is only the preferred embodiments of the present invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention and accompanying drawing content to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.

Claims (10)

1. a honeycomb type denitrification catalyst module dry reclamation system, is characterized in that, comprising: clamping device, feeding device, removing device and gas purging device; Wherein, described removing device comprises brush body and the first guide rod, and described brush body side is fixedly connected with the front end of described first guide rod; Described brush body is identical with the shape of cross section of described honeycomb hole perpendicular to the cross sectional shape of the first guide rod axis direction, and brush body is greater than the cross-sectional area of described honeycomb hole perpendicular to the area in the cross section of the first guide rod axis direction, and can be set in described honeycomb hole mobile; The length of described first guide rod is greater than the length of described honeycomb hole;
Honeycomb type denitrification catalyst module is delivered to described clamping device place by described feeding device, and described honeycomb type denitrification catalyst module is fixedly clamped by clamping device; Described first guide rod traction brush body stretches in described honeycomb hole and moves back and forth; When brush body detaches honeycomb hole, the scrapings in honeycomb hole is removed by described gas purging device purge gas.
2. honeycomb type denitrification catalyst module dry reclamation system according to claim 1, it is characterized in that, described removing device also comprises:
Connecting plate and connector; On described connecting plate, the position of the honeycomb hole of corresponding described honeycomb type denitrification catalyst module and quantity arrange described connector, connector are installed the tail end being connected with the first guide rod of brush body, form brush body bundle.
3. honeycomb type denitrification catalyst module dry reclamation system according to claim 2, is characterized in that, described removing device also comprises and strikes off drive unit;
The described drive unit that strikes off drives described connecting plate along the first guide rod axis direction straight reciprocating motion.
4. honeycomb type denitrification catalyst module dry reclamation system according to claim 1, it is characterized in that, described removing device also comprises guide rod location-plate;
The cover of described guide rod location-plate adaptation is connected on the end face of described honeycomb type denitrification catalyst module, and described guide rod location-plate is provided with and the honeycomb hole of honeycomb type denitrification catalyst module bullport one to one.
5. honeycomb type denitrification catalyst module dry reclamation system according to claim 1, it is characterized in that, described removing device also comprises the second guide rod;
Corresponding described first guide rod of described second guide rod is connected to the opposite side of described brush body; The length of described second guide rod is greater than the length of described honeycomb hole.
6. honeycomb type denitrification catalyst module dry reclamation system according to claim 1, is characterized in that, described clamping device comprises driving clamping device and U-shaped lower platen;
Described driving clamping device drives described U-shaped lower platen linearly to move; Described denitrification catalyst module is limited between two sidewalls by described U-shaped lower platen.
7. honeycomb type denitrification catalyst module dry reclamation system according to claim 6, is characterized in that, described feeding device comprises conveying drive unit and hard conveyer belt;
Described conveying drive unit drives described hard conveyer belt to move, and described hard conveyer belt is positioned at immediately below described U-shaped lower platen.
8. honeycomb type denitrification catalyst module dry reclamation system according to claim 1, is characterized in that, described gas purging device comprises gas compressing apparatus, air intake drainage hood and air-out drainage hood; Described gas compressing apparatus connects the first air inlet of described air intake drainage hood, and the first air outlet of described air intake drainage hood is socketed an end of described honeycomb type denitrification catalyst module; Second air inlet of described air-out drainage hood is socketed the other end of described honeycomb type denitrification catalyst module;
The area of the first air inlet of described air intake drainage hood is less than the first air outlet area of described air intake drainage hood; Second air inlet of described air-out drainage hood is greater than the second air outlet of air-out drainage hood.
9. a honeycomb type denitrification catalyst module dry reclamation method, is characterized in that, comprises step:
Use feeding device that honeycomb type denitrification catalyst module is delivered to clamping device place;
Use clamping device that described honeycomb type denitrification catalyst module is clamped in assigned address;
Move back and forth in the honeycomb hole using the first guide rod traction brush body of removing device to stretch into honeycomb type denitrification catalyst module, the denitration catalyst deactivating layer of the honeycomb hole inwall of described honeycomb fashion denitration catalyst is struck off; Wherein, in described removing device, brush body side is connected to the front end of described first guide rod; Described brush body is identical with the shape of cross section of the honeycomb hole of described honeycomb type denitrification catalyst module perpendicular to the cross sectional shape of the first guide rod axis direction, and brush body is greater than the cross-sectional area of described honeycomb hole perpendicular to the area in the cross section of the first guide rod axis direction, and can be set in honeycomb hole mobile; The length of described first guide rod is greater than 1/2nd length of described honeycomb hole;
Gas purging device purge gas is used to be removed by scrapings in the honeycomb hole of described honeycomb type denitrification catalyst module.
10. honeycomb type denitrification catalyst module dry reclamation method according to claim 9, it is characterized in that, move back and forth in the honeycomb hole that first guide rod traction brush body of described use removing device stretches into honeycomb type denitrification catalyst module, before the step that the denitration catalyst deactivating layer of the honeycomb hole inwall of described honeycomb type denitrification catalyst is struck off, comprising:
Gas purging device purge gas is used to be removed by the impurity of the honeycomb hole of described honeycomb fashion denitration catalyst.
CN201410854934.1A 2014-12-31 2014-12-31 Dry-process regeneration system and method of honeycomb type denitration catalyst module Pending CN104588129A (en)

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CN105056761A (en) * 2015-08-26 2015-11-18 浙江浙能催化剂技术有限公司 Ash removing device of SCR denitration catalyst
CN109110866A (en) * 2018-09-03 2019-01-01 冷应杰 A kind of sewage disposal system that photochemical catalytic oxidation is decomposed
CN111097289A (en) * 2019-12-30 2020-05-05 苏州华乐大气污染控制科技发展有限公司 Through hole tool for denitration catalyst
CN114904590A (en) * 2022-05-05 2022-08-16 安徽工程大学 Honeycomb type SCR catalyst repairing device and splicing repairing method

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EP0241310A2 (en) * 1986-04-11 1987-10-14 Kawasaki Jukogyo Kabushiki Kaisha Method for the dry regeneration of a catalyst
CN202315706U (en) * 2011-10-18 2012-07-11 北京北科欧远科技有限公司 Ash removing device for regenerating flue gas denitrifying catalyst
CN103813857A (en) * 2011-05-04 2014-05-21 施蒂格能源服务有限责任公司 Pluggage removal method for SCR catalysts and systems

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EP0241310A2 (en) * 1986-04-11 1987-10-14 Kawasaki Jukogyo Kabushiki Kaisha Method for the dry regeneration of a catalyst
CN103813857A (en) * 2011-05-04 2014-05-21 施蒂格能源服务有限责任公司 Pluggage removal method for SCR catalysts and systems
CN202315706U (en) * 2011-10-18 2012-07-11 北京北科欧远科技有限公司 Ash removing device for regenerating flue gas denitrifying catalyst

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105056761A (en) * 2015-08-26 2015-11-18 浙江浙能催化剂技术有限公司 Ash removing device of SCR denitration catalyst
CN109110866A (en) * 2018-09-03 2019-01-01 冷应杰 A kind of sewage disposal system that photochemical catalytic oxidation is decomposed
CN111097289A (en) * 2019-12-30 2020-05-05 苏州华乐大气污染控制科技发展有限公司 Through hole tool for denitration catalyst
CN114904590A (en) * 2022-05-05 2022-08-16 安徽工程大学 Honeycomb type SCR catalyst repairing device and splicing repairing method
CN114904590B (en) * 2022-05-05 2023-09-22 安徽工程大学 Honeycomb SCR catalyst repairing device and splicing repairing method

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Application publication date: 20150506