CN104568709B - Aeration zone soil adsorption parameter tester based on weak adsorption pollutants - Google Patents
Aeration zone soil adsorption parameter tester based on weak adsorption pollutants Download PDFInfo
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Abstract
本发明提供了一种基于弱吸附污染物的包气带土壤吸附参数测定仪,至少包括密封盖、实验段、取样装置、定水头固定装置、定水头供水装置、定水头供液装置和供水供液切换装置,其中实验段由土柱、纱网、带孔有机玻璃板、石英砂滤层以及土柱支架组成,密封盖安装于土柱的顶端且将土柱的顶部密封;取样装置设置于土柱的上部,定水头供水装置、定水头供液装置均安装与定水头固定装置上且两者的上下位置可调节;定水头供水装置的底部连接有出水管,定水头供液装置的底部连接有出液管,出水管、出液管以及输入管均与供水供液切换装置连接,该装置可准确测定较弱吸附作用污染物在包气带土壤中的阻滞系数及分配系数,同时该方法简单可靠。
The invention provides a vadose zone soil adsorption parameter tester based on weakly adsorbed pollutants, which at least includes a sealing cover, an experimental section, a sampling device, a constant water head fixing device, a constant water head water supply device, a constant water head liquid supply device and a water supply Liquid switching device, wherein the experimental section is composed of soil column, gauze, perforated plexiglass plate, quartz sand filter layer and soil column support, the sealing cover is installed on the top of the soil column and seals the top of the soil column; the sampling device is set at On the upper part of the soil column, the fixed head water supply device and the fixed water head liquid supply device are installed on the fixed water head fixing device, and the upper and lower positions of the two can be adjusted; the bottom of the fixed head water supply device is connected with an outlet pipe, and the bottom of the fixed head liquid supply device It is connected with a liquid outlet pipe, and the water outlet pipe, liquid outlet pipe and input pipe are all connected to the water supply and liquid supply switching device. This device can accurately measure the retardation coefficient and distribution coefficient of weakly adsorbed pollutants in the soil in the vadose zone, and at the same time The method is simple and reliable.
Description
技术领域technical field
本发明涉及一种包气带土壤吸附参数测定装置,具体地说是涉及一种基于弱吸附污染物的包气带土壤吸附参数测定仪。The invention relates to a device for measuring adsorption parameters of vadose zone soil, in particular to a device for measuring adsorption parameters of vadose zone soil based on weakly adsorbed pollutants.
背景技术Background technique
随着近代土壤物理学及电算技术的迅猛发展,当前在溶质运移的定量研究中,愈来愈多地采用数学模型的方法来研究和掌握化肥、农药在非饱和土壤中的迁移过程。为此,正确地确定数学模型中所必需的参数,如溶质运移控制方程——对流扩散方程的阻滞因子、分配系数等就成为一项必须的工作。它对于研究化肥、农药等对地下水的污染,区域水盐运动规律,污水处理及再利用技术来说,具有重要的意义。With the rapid development of modern soil physics and computer technology, more and more mathematical models are used to study and master the migration process of chemical fertilizers and pesticides in unsaturated soil in the quantitative study of solute transport. Therefore, it is necessary to correctly determine the necessary parameters in the mathematical model, such as the retardation factor and partition coefficient of the governing equation of solute transport—the convection-diffusion equation. It is of great significance to the research on the pollution of groundwater by chemical fertilizers and pesticides, the law of regional water and salt movement, and the technology of sewage treatment and reuse.
吸附是土壤中固相、液相之间的物理化学作用的外在表现,它参与了溶质在土壤中的运移过程,对溶质运移起阻滞作用。在求解土壤溶质运移方程时,如果溶质会被土壤吸附,则必须通过实验确定阻滞因子Rd以及溶质在土壤-水体系中的分配系数Kd。溶质运移的阻滞因子Rd,即水流流速与溶质运移速度的比值,无量纲,表征土壤阻滞溶质迁移能力的参数。溶质在土壤-水体系中的分配系数Kd,又称吸附比,是指在土壤-水两相体系中达到平衡状态时,溶质在土壤与水中的浓度比值,常用单位为cm3/g,是描述溶质在土壤中吸附行为的重要物理化学特征参数。Adsorption is an external manifestation of the physical and chemical interaction between the solid and liquid phases in soil. It participates in the migration process of solutes in the soil and blocks the migration of solutes. When solving the soil solute transport equation, if the solute will be adsorbed by the soil, the retardation factor R d and the distribution coefficient K d of the solute in the soil-water system must be determined through experiments. The retardation factor R d of solute migration, that is, the ratio of water flow velocity to solute migration velocity, is dimensionless and is a parameter that characterizes the ability of soil to retard solute migration. The distribution coefficient K d of the solute in the soil-water system, also known as the adsorption ratio, refers to the concentration ratio of the solute in the soil and water when the soil-water two-phase system reaches an equilibrium state, and the common unit is cm 3 /g, It is an important physical and chemical characteristic parameter describing the adsorption behavior of solutes in soil.
在物理化学及土壤学中,常用静态实验测定法确定包气带土壤吸附参数。然而,大量的研究表明,静态实验的测定结果,比渗透条件下的实验结果明显偏高。这是因为,静态实验中,土壤颗粒的全部表面均与溶液相互作用,而在渗透条件下,土样是不搅动的,吸附作用仅在颗粒与溶液接触的那部分表面进行。In physical chemistry and soil science, the static experimental method is often used to determine the soil adsorption parameters in the vadose zone. However, a large number of studies have shown that the results of static experiments are significantly higher than the results of experiments under osmotic conditions. This is because, in a static experiment, the entire surface of the soil particle interacts with the solution, while under osmotic conditions, the soil sample is not stirred, and the adsorption occurs only on the part of the surface of the particle that is in contact with the solution.
发明内容Contents of the invention
本发明提供了一种基于弱吸附污染物的包气带土壤吸附参数测定仪,该装置解决了现有技术存在的问题,可准确测定较弱吸附作用污染物在包气带土壤中的阻滞系数及分配系数,同时该方法简单可靠。The invention provides a vadose zone soil adsorption parameter tester based on weakly adsorbed pollutants. The device solves the problems in the prior art and can accurately measure the retardation of weakly adsorbed pollutants in the vadose zone soil coefficient and distribution coefficient, and the method is simple and reliable.
实现本发明上述目的所采用的技术方案为:The technical scheme adopted to realize the above-mentioned purpose of the present invention is:
一种基于弱吸附污染物的包气带土壤吸附参数测定仪,包括密封盖、实验段、取样装置、定水头固定装置、定水头供水装置、定水头供液装置和供水供液切换装置,其中实验段由土柱、纱网、带孔有机玻璃板、石英砂滤层以及土柱支架组成,土柱为内部放置有土样的圆筒状的有机玻璃柱,土柱支架位于土柱的底部,密封盖安装于土柱的顶端且将土柱的顶部密封;取样装置设置于土柱的上部用于从土柱中取样;纱网、带孔有机玻璃板、石英砂滤层均位于土柱中,且纱网设置有上下两层,土样的下方由上至下依次为上层纱网、石英砂滤层、带孔有机玻璃板以及下层纱网,其中上层纱网与土样相接触,带孔有机玻璃板位于有机玻璃柱的底面的上方8~12cm处,有机玻璃柱的底面上设置有入口,入口处连接有输入管;所述的定水头固定装置由定水头固定架和铁棍组成,铁棍设有4根且竖直安装在定水头固定架上,定水头供水装置、定水头供液装置均安装与定水头固定装置上且两者的上下位置可调节;定水头供水装置的底部连接有出水管,定水头供液装置的底部连接有出液管,出水管、出液管以及输入管均与供水供液切换装置连接,所述的供水供液切换装置由三通接头、控制阀A和控制阀B组成,出水管、出液管以及输入管均与三通接头连接,在出水管上有控制阀A,在出液管上有控制阀B;控制阀A开、控制阀B关,为向土柱供水状态;控制阀A关、控制阀B开,为向土柱供液状态。An instrument for measuring adsorption parameters of vadose zone soil based on weakly adsorbed pollutants, comprising a sealing cover, an experimental section, a sampling device, a constant water head fixing device, a constant water head water supply device, a constant water head liquid supply device, and a water supply liquid supply switching device, wherein The experimental section is composed of soil column, gauze, perforated plexiglass plate, quartz sand filter layer and soil column support. The soil column is a cylindrical plexiglass column with soil samples placed inside, and the soil column support is located at the bottom of the soil column. , the sealing cover is installed on the top of the soil column and seals the top of the soil column; the sampling device is arranged on the upper part of the soil column for sampling from the soil column; gauze, perforated plexiglass plate, and quartz sand filter layer are all located , and the gauze is provided with upper and lower layers, and the bottom of the soil sample is the upper gauze, the quartz sand filter layer, the perforated plexiglass plate and the lower gauze, in which the upper gauze is in contact with the soil sample. The perforated plexiglass plate is located at 8-12 cm above the bottom surface of the plexiglass column. An inlet is arranged on the bottom surface of the plexiglass column, and an inlet is connected to an input pipe; the fixed head fixing device consists of a fixed head fixing frame and an iron bar. It consists of 4 iron rods and is installed vertically on the fixed head fixed frame. The fixed head water supply device and the fixed water head liquid supply device are installed on the fixed water head fixed device, and the upper and lower positions of the two can be adjusted; the fixed water head water supply device The bottom of the fixed head liquid supply device is connected with a water outlet pipe, and the bottom of the fixed water head liquid supply device is connected with a liquid outlet pipe. The water outlet pipe, the liquid outlet pipe and the input pipe are all connected to the water supply and liquid switching device. , control valve A and control valve B, the water outlet pipe, the liquid outlet pipe and the input pipe are all connected to the three-way joint, there is a control valve A on the water outlet pipe, and a control valve B on the liquid outlet pipe; the control valve A is open, When control valve B is closed, it is the state of water supply to the soil column; when control valve A is closed and control valve B is open, it is the state of liquid supply to the soil column.
密封盖由圆形有机玻璃板、硅胶圈以及固定环组成,硅胶圈固定于圆形有机玻璃板的底面上,且硅胶圈的直径与土柱内径相同;固定环为空心圆环有机玻璃板,固定环用氯仿固定在土柱的顶部边沿上;在固定环和圆形有机玻璃板上设有相对应的6个螺孔,将密封盖盖在土柱上,硅胶圈刚好扣入土柱内,通过固定螺丝可保证土柱的密封。The sealing cover is composed of a circular plexiglass plate, a silicone ring and a fixing ring. The silicone ring is fixed on the bottom surface of the circular plexiglass plate, and the diameter of the silicone ring is the same as the inner diameter of the soil column; the fixing ring is a hollow ring plexiglass plate, The fixing ring is fixed on the top edge of the soil column with chloroform; there are 6 corresponding screw holes on the fixing ring and the circular plexiglass plate, and the sealing cover is covered on the soil column, and the silicone ring is just buckled into the soil column. The sealing of the soil column can be guaranteed by fixing screws.
所述的取样装置由铜宝塔和密封头组成,铜宝塔装在距土柱顶部5cm处,密封头上有与铜宝塔相匹配的螺纹。Described sampling device is made up of copper pagoda and sealing head, and copper pagoda is contained in apart from soil column top 5cm place, and the screw thread that matches with copper pagoda is arranged on sealing head.
所述的定水头供水装置由挡板、供水溢流管、供水管、出水管和内旋螺丝组成,定水头供水装置为高10cm的缺顶面的长方体盒,挡板的高度为8cm,挡板竖直固定于长方体盒中,将整个定水头供水装置分为左右两室,左室底部最左边设有出水孔,出水管与出水孔相连;左室底部右侧设有供水孔,供水管与供水孔相连;右室底部设有溢流孔,供水溢流管与溢流孔相连;定水头供水装置的后壁有两个供铁棍通过的孔,通过旋紧内旋螺丝可将定水头供水装置固定在定水头固定架上。The fixed head water supply device is made up of baffle plate, water supply overflow pipe, water supply pipe, water outlet pipe and inner screw. The board is vertically fixed in the cuboid box, and divides the whole constant head water supply device into left and right chambers. There is a water outlet hole on the far left at the bottom of the left chamber, and the outlet pipe is connected to the water outlet hole; there is a water supply hole on the right side of the bottom of the left chamber, and the water supply pipe It is connected with the water supply hole; there is an overflow hole at the bottom of the right chamber, and the water supply overflow pipe is connected with the overflow hole; the rear wall of the fixed head water supply device has two holes for iron bars to pass through, and the fixed head can be fixed by tightening the inner screw. The water head water supply device is fixed on the fixed head fixing frame.
所述的定水头供液装置由挡板、供液溢流管、供液管、出液管和内旋螺丝组成,定水头供液装置为高10cm的缺顶面的长方体盒,挡板的高度为8cm,挡板竖直固定于长方体盒中,将整个定水头供液装置分为左右两室,左室底部最左边设有出液孔,出液管与出液孔相连;左室底部右侧设有供液孔,供液管与供液孔相连;右室底部设有溢流孔,供液溢流管与溢流孔相连;定水头供液装置的后壁有两个供铁棍通过的孔,通过旋紧内旋螺丝可将定水头供液装置固定在定水头固定架上。The fixed water head liquid supply device is composed of a baffle plate, a liquid supply overflow pipe, a liquid supply pipe, a liquid outlet pipe and an inner screw. The fixed water head liquid supply device is a cuboid box with a height of 10 cm without a top surface. The height is 8cm, the baffle is vertically fixed in the cuboid box, and the whole constant water head liquid supply device is divided into left and right chambers, the bottom of the left chamber is equipped with a liquid outlet hole on the far left, and the liquid outlet pipe is connected to the liquid outlet hole; the bottom of the left chamber There is a liquid supply hole on the right side, and the liquid supply pipe is connected with the liquid supply hole; there is an overflow hole at the bottom of the right chamber, and the liquid supply overflow pipe is connected with the overflow hole; there are two iron supply pipes on the rear wall of the constant water head liquid supply device. The hole through which the stick passes, the constant water head liquid supply device can be fixed on the constant water head fixing frame by tightening the inner screw.
本发明的一种基于弱吸附污染物的包气带土壤吸附参数测定仪的工作原理如下:The operating principle of a kind of vadose zone soil adsorption parameter measuring instrument based on weakly adsorbed pollutants of the present invention is as follows:
当溶质的运移速度低于土壤中水分的运动速度时,溶质运移是受阻滞的。土壤中水分的运动速度与溶质的运移速度之间的差是由土壤吸附溶质所引起的,通常用阻滞因子Rd来评估受阻滞的溶质的运移速度:Solute transport is retarded when the rate of movement of solutes is slower than the rate of movement of water in the soil. The difference between the movement speed of water in the soil and the migration speed of solute is caused by the adsorption of solute by the soil, and the retardation factor R d is usually used to evaluate the migration speed of the hindered solute:
式中:Rd—为土壤中溶质运移的阻滞因子;In the formula: R d — is the retardation factor of solute migration in soil;
υw—为土壤中水分的平均孔隙流速,cm/min;υ w — is the average pore flow velocity of water in the soil, cm/min;
υc—为土壤溶质的平均运移速度,cm/min。υ c — is the average migration velocity of soil solute, cm/min.
通过测定υw和υc,即可求算出Rd。然后,利用式(2)可计算出分配系数Kd:By measuring υ w and υ c , R d can be calculated. Then, the distribution coefficient K d can be calculated using formula (2):
式中:Rd—为阻滞因子;In the formula: R d — is the blocking factor;
ρd—为土壤的干密度,g/cm3;ρ d - is the dry density of the soil, g/cm 3 ;
θ—为土壤的体积含水率,cm3/cm3;θ—is the volume moisture content of the soil, cm 3 /cm 3 ;
Kd—为溶质在土壤-水体系中的分配系数,cm3/g。K d ——distribution coefficient of solute in soil-water system, cm 3 /g.
本发明的基于弱吸附污染物的包气带土壤吸附参数测定仪与现有技术相比具有如下的优点:Compared with the prior art, the vadose zone soil adsorption parameter detector based on weakly adsorbed pollutants of the present invention has the following advantages:
(1)本发明的测定仪是通过动态土柱吸附法确定的包气带土壤吸附参数,吸附作用仅在颗粒与溶液接触的那部分表面进行,而静态吸附法土壤颗粒的全部表面均与溶液相互作用,该方法比静态吸附法相比更准确可靠。(1) The measuring instrument of the present invention is the adsorption parameter of aerated zone soil determined by the dynamic soil column adsorption method, and the adsorption is only carried out on that part of the surface where the particle contacts the solution, while the whole surface of the static adsorption method soil particle is in contact with the solution. This method is more accurate and reliable than the static adsorption method.
(2)本发明的测定仪的定水头供水装置与定水头供液装置,通过供水供液切换装置可灵活控制对土柱进行供水和供液。(2) The fixed water head water supply device and the fixed water head liquid supply device of the measuring instrument of the present invention can flexibly control the water supply and liquid supply to the soil column through the water supply and liquid supply switching device.
(3)本发明的测定仪结构简单,使用方便,具有广泛的应用前景。可以广泛用于包气带水文研究中,作为教学仪器有助于学生更好理解弱吸附污染物包气带土壤吸附参数的原理及其适用范围;而在生产中可以用来测定弱吸附污染物包气带土壤吸附参数,为农田土壤改良提供研究参数,为弱吸附污染物在包气带土壤的运移提供研究参数。(3) The measuring instrument of the present invention is simple in structure, easy to use, and has wide application prospects. It can be widely used in the hydrological research of the vadose zone. As a teaching instrument, it can help students better understand the principle and scope of application of soil adsorption parameters in the vadose zone of weakly adsorbed pollutants; and it can be used to measure weakly adsorbed pollutants in production. The adsorption parameters of the vadose zone soil provide research parameters for farmland soil improvement, and provide research parameters for the migration of weakly adsorbed pollutants in the vadose zone soil.
附图说明Description of drawings
图1为一种基于弱吸附污染物的包气带土壤吸附参数测定仪结构示意图。Figure 1 is a schematic diagram of the structure of an instrument for measuring adsorption parameters of vadose zone soil based on weakly adsorbed pollutants.
图2为本发明的顶盖结构示意图。Fig. 2 is a schematic diagram of the top cover structure of the present invention.
图3为本发明中的定水头供水装置俯视图。Fig. 3 is a top view of the constant water head water supply device in the present invention.
图中:1-土柱,2-取样装置,3-密封盖,4-纱网、5-石英砂滤层,6-带孔有机玻璃板,7-三通接头,8-控制阀A,9-控制阀B,10-定水头供液装置,11-挡板,12-供液溢流管,13-供液管,14-出液管,15-定水头供水装置,16-供水溢流管,17-供水管,18-出水管,19-定水头固定架,20-入口,21-土柱支架,22-铜宝塔,23-密封头,24-有机玻璃板,25-硅胶圈,26-固定环,27-螺孔A,28-固定螺丝,29-螺孔B,30-后壁,31-铁棍,32-内旋螺丝,33-溢流孔,34-供水孔,35-出水孔。In the figure: 1-soil column, 2-sampling device, 3-sealing cover, 4-gauze, 5-quartz sand filter layer, 6-perforated plexiglass plate, 7-tee joint, 8-control valve A, 9-control valve B, 10-fixed water head liquid supply device, 11-baffle plate, 12-liquid supply overflow pipe, 13-liquid supply pipe, 14-liquid outlet pipe, 15-fixed water head water supply device, 16-water supply overflow Flow pipe, 17-water supply pipe, 18-outlet pipe, 19-fixed water head fixing frame, 20-inlet, 21-soil column support, 22-copper pagoda, 23-sealing head, 24-plexiglass plate, 25-silicone ring , 26-fixing ring, 27-screw hole A, 28-fixing screw, 29-screw hole B, 30-back wall, 31-iron rod, 32-inner screw, 33-overflow hole, 34-water supply hole, 35-water outlet hole.
具体实施方式detailed description
下面结合具体实施例对本发明做详细具体的说明,但是本发明的保护范围并不局限于以下实施例。The present invention will be described in detail below in conjunction with specific examples, but the protection scope of the present invention is not limited to the following examples.
本发明提供的一种基于弱吸附污染物的包气带土壤吸附参数测定仪,其结构如图1所示。包括密封盖、实验段、取样装置、定水头固定装置、定水头供水装置、定水头供液装置和供水供液切换装置。所述的密封盖由顶盖3、固定环26和固定螺丝28组成,如图2所示。密封盖3的顶部为直径为28cm的圆形有机玻璃板24,下部为与实验土柱内径相同直径为20cm的硅胶圈25;固定环26为内径22cm、外径28cm的空心圆环有机玻璃板,固定环25用氯仿固定在土柱1上;在固定环26设有相对应的6个0.5cm的螺孔A27,在顶盖3有机玻璃板上设有相对应的6个0.5cm的螺孔B29,螺孔A27与螺孔B28的位置相互对应;将顶盖3盖在土柱1上,硅胶圈25刚好扣入土柱1内,通过固定螺丝28可保证土柱1的密封。The present invention provides an instrument for measuring adsorption parameters of vadose zone soil based on weakly adsorbed pollutants, the structure of which is shown in FIG. 1 . It includes a sealing cover, an experiment section, a sampling device, a constant water head fixing device, a constant water head water supply device, a constant water head liquid supply device and a water supply liquid supply switching device. The sealing cover is composed of a top cover 3, a fixing ring 26 and a fixing screw 28, as shown in FIG. 2 . The top of the sealing cover 3 is a circular plexiglass plate 24 with a diameter of 28cm, and the bottom is a silicone ring 25 with the same diameter as the experimental soil column inner diameter as 20cm; the fixed ring 26 is a hollow ring plexiglass plate with an inner diameter of 22cm and an outer diameter of 28cm , the fixed ring 25 is fixed on the soil column 1 with chloroform; the fixed ring 26 is provided with corresponding 6 screw holes A27 of 0.5 cm, and the top cover 3 plexiglass plate is provided with corresponding 6 screw holes of 0.5 cm. The positions of hole B29, screw hole A27 and screw hole B28 correspond to each other; the top cover 3 is covered on the soil column 1, and the silicone ring 25 is just buckled in the soil column 1, and the sealing of the soil column 1 can be guaranteed by the fixing screw 28.
所述的实验段由土柱1、纱网、带孔有机玻璃板6、石英砂滤层5、土柱支架21和入口20组成。土柱1为内径为120cm壁厚1cm的有机玻璃柱,在土柱顶部设有取样装置2;在距土柱底部10cm处设有带孔有机玻璃板6,有机玻璃板下粘有纱网4;在带孔有机玻璃板6上设有5cm厚的石英砂滤层5;石英砂滤层5、带孔有机玻璃6、纱网4可缓冲水流;土柱支架21为四根高5cm的有机玻璃板,通过氯仿与土柱1底部连接;在土柱底部设有入口20,可供水、液供入土柱内。The experimental section is composed of a soil column 1 , a gauze, a perforated organic glass plate 6 , a filter layer of quartz sand 5 , a soil column support 21 and an inlet 20 . The soil column 1 is a plexiglass column with an inner diameter of 120 cm and a wall thickness of 1 cm. A sampling device 2 is arranged on the top of the soil column; a perforated plexiglass plate 6 is arranged at 10 cm from the bottom of the soil column, and a gauze 4 is stuck under the plexiglass plate. ; On the perforated plexiglass plate 6, be provided with 5cm thick quartz sand filter layer 5; Quartz sand filter layer 5, perforated plexiglass 6, gauze 4 can buffer water flow; Soil pillar support 21 is four high 5cm organic The glass plate is connected to the bottom of the soil column 1 through chloroform; an inlet 20 is provided at the bottom of the soil column for water and liquid to enter the soil column.
所述的取样装置2由铜宝塔22和密封头23组成。铜宝塔22装在距土柱1顶部5cm处,密封头23上有与铜宝塔22相匹配的螺纹。The sampling device 2 is composed of a copper pagoda 22 and a sealing head 23 . Copper pagoda 22 is contained in apart from earth column 1 top 5cm places, and the screw thread that matches with copper pagoda 22 is arranged on sealing head 23.
所述的定水头固定装置由定水头固定架19和铁棍31组成。定水头固定架由角钢做成,在定水头固定架19上设有4根铁棍31。Described fixed water head fixing device is made up of fixed water head fixing frame 19 and iron bar 31. Fixed water head fixed mount is made by angle steel, is provided with 4 iron bars 31 on fixed water head fixed mount 19.
所述的定水头供水装置的结构如图3所示,由挡板11、供水溢流管16、供水管17、出水管18、溢流孔33、供水孔34、出水孔35和内旋螺丝32组成。定水头供水装置为高10cm的缺顶面的长方体盒,在定水头供水装置的中部位高8cm的挡板11,将整个定水头供水装置分为左右两室,左室底部最左边设有出水孔35,出水管18与出水孔35相连;左室底部右侧设有供水孔34,供水管17与供水孔34相连;右室底部设有溢流孔33,供水溢流管16与溢流孔33相连;定水头供水装置的后壁30有两个供铁棍31通过的孔,通过旋紧内旋螺丝32可将定水头供水装置固定在定水头固定架19上。所述的定水头供液装置的结构与定水头供水装置的结构相同。The structure of the fixed head water supply device as shown in Figure 3, consists of baffle plate 11, water supply overflow pipe 16, water supply pipe 17, water outlet pipe 18, overflow hole 33, water supply hole 34, water outlet hole 35 and inner screw 32 compositions. The fixed head water supply device is a cuboid box with a height of 10 cm and a top surface missing. In the middle part of the fixed head water supply device, a baffle plate 11 with a height of 8 cm divides the entire fixed head water supply device into two chambers, and the bottom of the left chamber is provided with a water outlet on the far left. Hole 35, water outlet pipe 18 is connected with water outlet hole 35; the right side of the left chamber bottom is provided with water supply hole 34, water supply pipe 17 is connected with water supply hole 34; right chamber bottom is provided with overflow hole 33, water supply overflow pipe 16 and overflow Hole 33 links to each other; The rear wall 30 of fixed water head water supply device has two holes for iron bars 31 to pass through, and fixed water head water supply device can be fixed on the fixed water head fixed mount 19 by tightening inner screw 32. The structure of the constant water head liquid supply device is the same as that of the constant water head water supply device.
所述的供水供液切换装置由三通接头7、控制阀A8、控制阀B9组成。出液管14与出水管18通过三通接头7与土柱入口20相连;在出水管18上有控制阀A8,在出液管上有控制阀B9;控制阀A8开、控制阀B9关,为向土柱供水状态;控制阀A8关、控制阀B9开,为向土柱1供液状态。The water supply and liquid supply switching device is composed of a three-way joint 7, a control valve A8, and a control valve B9. The liquid outlet pipe 14 and the water outlet pipe 18 are connected to the soil column inlet 20 through the three-way joint 7; there is a control valve A8 on the water outlet pipe 18, and a control valve B9 on the liquid outlet pipe; the control valve A8 is opened, and the control valve B9 is closed. It is the state of supplying water to the soil column; the control valve A8 is closed, and the control valve B9 is opened, which is the state of supplying water to the soil column 1.
本发明提供的一种基于弱吸附污染物的包气带土壤吸附参数测定仪的工作步骤及实验结果整理如下:The working steps and experimental results of a vadose zone soil adsorption parameter measuring instrument based on weakly adsorbed pollutants provided by the present invention are organized as follows:
一、工作步骤1. Working steps
1、采集试样1. Collect samples
采集实验所需试样,备用;同时,利用环刀取原状试样,利用烘干-称重法测定其干密度ρ′d。Collect the samples required for the experiment and set them aside; at the same time, use a ring knife to take the original sample, and use the drying-weighing method to measure its dry density ρ′ d .
2、制备试样2. Preparation of samples
把试样风干、捣碎及过筛(孔径为2mm孔径),备用。The sample was air-dried, crushed and sieved (with a pore size of 2mm), and set aside.
3、湿润试样3. Wet sample
在拌土容器中铺一层过筛风干后的试样,用喷壶均匀洒水;然后,再铺一层试样,再洒一层水,以此方法将试样全部湿润,之后加盖闷一夜,外层再套一塑料袋防止蒸发并使水分在试样中重分布。Spread a layer of sieved and air-dried samples in the soil mixing container, and sprinkle water evenly with a watering can; then, spread another layer of samples, and then sprinkle another layer of water, so as to wet the samples completely, and then cover them and keep stuffy overnight , the outer layer is covered with a plastic bag to prevent evaporation and redistribute water in the sample.
4、测试样初始质量含水率4. The initial mass moisture content of the test sample
将湿润好的试样充分混匀,在不同的位置取少量土样装入已知质量的小铝盒中,做5个平行。用天平称重后放入烘箱中105℃烘干12h至恒重,待冷却后称质量,计算质量含水率θm。Fully mix the wet samples, take a small amount of soil samples from different positions and put them into small aluminum boxes of known mass, and make 5 parallel samples. After weighing with a balance, place it in an oven and dry it at 105°C for 12 hours to a constant weight. After cooling, weigh the mass and calculate the mass moisture content θ m .
5、装填土柱5. Filling soil column
距土柱底端10cm处装5cm石英砂滤层;中段为试样段100cm,根据试样的直径D、长度L以及干密度ρ′d、初始含水率θm,按公式m装填=[(πR2)/4]·ρ′d·(1+θm)计算出装填质量,分段(每层5cm)等质量装填土柱,层间打毛,防止层间流失的形成。Install a 5cm quartz sand filter layer at 10cm from the bottom of the soil column; the middle section is a sample section of 100cm, according to the diameter D, length L, dry density ρ′ d and initial moisture content θ m of the sample, fill according to the formula m=[( πR 2 )/4]·ρ′ d ·(1+θ m ) Calculate the filling mass, fill the soil column with equal mass in sections (5cm per layer), and roughen the layers to prevent the formation of loss between layers.
6、饱和土柱6. Saturated soil column
将定水头供液装置与定水头供水装置和土柱下端入口连接,打开控制阀A,关闭控制阀B,用蒸馏水自下而上逐步饱和土柱,以排除土柱内的空气,使土柱孔隙充分饱水。7、淋溶实验Connect the fixed head liquid supply device with the fixed head water supply device and the inlet of the lower end of the soil column, open the control valve A, close the control valve B, and gradually saturate the soil column with distilled water from bottom to top to remove the air in the soil column and make the soil column The pores are fully saturated with water. 7. Leaching experiment
饱和待土柱恒重后,继续定水头供水,待蒸馏水流速稳定后,关闭控制阀A,打开控制阀B,同定水头输入现配的溶质标准工作液(浓度为C入g/L),同时开始收集出流液,输入溶质标准工作液一段时间(输入时间依据溶质类型、试样物性、渗流速度等决定)以后,打开控制阀A,关闭控制阀B,继续定水头供水,用蒸馏水淋溶。记录供水流量Q。Saturated until the soil column has a constant weight, continue to supply water at a fixed head. After the flow rate of distilled water is stable, close the control valve A, open the control valve B, and input the existing solute standard working solution (concentration is C into g/L) at the same constant water head, and at the same time Start to collect the effluent, input the solute standard working solution for a period of time (the input time is determined by the type of solute, the physical properties of the sample, the seepage velocity, etc.), open the control valve A, close the control valve B, continue to supply water at a fixed head, and use distilled water for leaching . Record the water supply flow Q.
8、采集水样8. Collect water samples
在取样装置处定时ti(i=0,1,2,3…)取样,以测定其浓度Ci(i=0,1,2,3…)、绘制其穿透曲线。Samples are taken at timing t i (i=0, 1, 2, 3...) at the sampling device to measure its concentration C i (i=0, 1, 2, 3...) and draw its breakthrough curve.
9、测定试样的干密度和孔隙度9. Determination of dry density and porosity of samples
取样结束后,记录实验结束时间tn;然后,在土柱内,利用环刀取原状试样,利用烘干称重法测定其干密度ρd和孔隙度n。After sampling, record the end time t n of the experiment; then, in the soil column, use the ring knife to take the original sample, and use the drying weighing method to measure its dry density ρ d and porosity n.
10、测定水样10. Determination of water samples
利用离子计测定水样中溶质的浓度Ci。需要预处理的水样或土样,预处理后再进行测定。Use an ion meter to measure the concentration C i of the solute in the water sample. Water samples or soil samples that need to be pretreated shall be measured after pretreatment.
二、实验成果整理2. Arrangement of experimental results
1、计算土柱内水分的平均孔隙流速1. Calculate the average pore velocity of water in the soil column
利用式(3)计算Use formula (3) to calculate
式中:υw—为土柱内水分的平均孔隙流速,cm/min;In the formula: υ w — is the average pore flow velocity of moisture in the soil column, cm/min;
V—为土柱内的平均达西流速,cm/min;V— is the average Darcy velocity in the soil column, cm/min;
n—为土柱内试样的孔隙度,%/%。n—is the porosity of the sample in the soil column, %/%.
2、计算土柱内污染物的平均运移速度2. Calculate the average migration velocity of pollutants in the soil column
(1)根据穿透曲线计算(1) Calculated according to the penetration curve
①以相对浓度Ci/C入为纵坐标(Ci为渗出水中溶质浓度,C入为渗入水中溶质浓度),穿透时间t为横坐标,绘制溶质浓度穿透曲线图。① Take the relative concentration C i /C in as the ordinate (C i is the solute concentration in the seepage water, C in is the solute concentration in the infiltration water), and the breakthrough time t is the abscissa, draw the solute concentration breakthrough curve.
②在浓度穿透曲线图上读出C/C入=0.5时的t0。5值,即为溶质穿透土柱内试样的时间。② Read the t 0.5 value when C/C = 0.5 on the concentration breakthrough curve, which is the time for the solute to penetrate the sample in the soil column.
③利用式(4)计算若吸附污染物的平均运移速度③Use formula (4) to calculate the average migration velocity of the adsorbed pollutants
υc=L/t0.5(4)式中:υc—为土壤中若吸附污染物的平均运移速度,cm/min;υ c =L/t 0.5 (4) In the formula: υ c —— is the average migration speed of the adsorbed pollutants in the soil, cm/min;
L—为土柱中试样长度,cm;L—is the length of the sample in the soil column, cm;
t0.5—与相对浓度C/C入=0.5相对应的时间,min。t 0.5 —time corresponding to relative concentration C/C in =0.5, min.
3、计算阻滞因子3. Calculate the blocking factor
把υw、υc代入式(1),即可计算出阻滞因子Rd。By substituting υ w and υ c into formula (1), the retardation factor R d can be calculated.
4、计算分配系数4. Calculate the distribution coefficient
把Rd、ρd、θ(试样饱水时,其含水率等于其孔隙度n)代入式(2),即可求算出弱吸附污染物在土壤-水体系中的分配系数Kd。Substituting R d , ρ d , θ (when the sample is saturated with water, its moisture content is equal to its porosity n) into formula (2), the distribution coefficient K d of weakly adsorbed pollutants in the soil-water system can be calculated.
本发明的测定仪结构简单,使用方便,具有广泛的应用前景。如可以广泛用于包气带水文研究中,作为教学仪器有助于学生更好理解弱吸附污染物包气带土壤吸附参数的原理及其适用范围;而在生产中可以用来测定弱吸附污染物包气带土壤吸附参数,为农田土壤改良提供研究参数,为弱吸附污染物在包气带土壤的运移提供研究参数。The measuring instrument of the invention is simple in structure, easy to use and has wide application prospects. If it can be widely used in hydrological research in the vadose zone, as a teaching instrument, it will help students better understand the principle and scope of application of soil adsorption parameters in the vadose zone of weakly adsorbed pollutants; and it can be used to measure weakly adsorbed pollution in production The adsorption parameters of the soil in the aerated zone provide research parameters for farmland soil improvement, and provide research parameters for the migration of weakly adsorbed pollutants in the aerated zone soil.
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