CN104561616A - Method for producing aluminium alloy ingots from abandoned pop cans - Google Patents
Method for producing aluminium alloy ingots from abandoned pop cans Download PDFInfo
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- CN104561616A CN104561616A CN201310474780.9A CN201310474780A CN104561616A CN 104561616 A CN104561616 A CN 104561616A CN 201310474780 A CN201310474780 A CN 201310474780A CN 104561616 A CN104561616 A CN 104561616A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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Abstract
The invention discloses a method for producing aluminium alloy ingots from abandoned pop cans. The method is characterized by comprising the following technological steps: (1) crushing: abandoned pop cans are crushed to particles of 300-500 micron meshes; (2) cleaning; (3) depainting; (4) smelting and deslagging; (5) grain refinement; (6) degassing; and (7) ingot casting. The technology is reasonable and concise. Technological flow is greatly shortened. As abandoned pop cans are used as a technological raw material, waste materials are changed into valuable things, and environment pollution caused by depainting in the technology is minimized. By the method, quality of aluminium alloy ingots is raised, and reutilization rate of aluminium is enhanced. The method provided by the invention has a wide market prospect.
Description
Technical field
The present invention relates to a kind of method of discarded pop can regenerative ratio aluminum alloy ingot.
Background technology
Aluminium and aluminium alloy thereof are starting material conventional in industrial production, be widely used in the industries such as machinery, building, aircraft, household electrical appliances and wrapping material, pop can as aluminium alloy important production product have quality light, pack the advantages such as effect is better and be widely used, but the effect of the recycling of discarded pop can is poor, pop can material therefor is the aluminium alloy that a kind of class is higher, but due to backward in technique, waste top-pop is all used by degradation, and the quality of aluminium alloy worse and worse.Up to the present, China does not also utilize waste top-pop to produce the enterprise of former grade aluminium alloy.Application number is: CN201210177835.5 discloses a kind of production technique of aluminum alloy ingot, and raw material is carried out proportioning by each element ratio according to product, and raw material good for proportioning is dropped into melting in smelting furnace, sample examination, add Pure Silicon Metal according to result of laboratory test, add cooling material, aluminium liquid is lowered the temperature, abundant stirring makes uniform composition, add al-sr alloy, Al-Ti-B alloy and innocuous refining flux, impurity removing refining also carries out degasification, leaves standstill, skim, ingot casting.Adopt the product of this explained hereafter, ingot casting cold shut, crackle are few, and toughness, intensity are high, but material choice does not have environmental benefit, and cost is high, and the wasting of resources is comparatively large, the aluminum alloy ingot of production of low quality, and impurity is more.
Summary of the invention
For the deficiency that prior art exists, the invention provides a kind of method of discarded pop can regenerative ratio aluminum alloy ingot.
To achieve these goals, the present invention realizes by the following technical solutions:
A method for discarded pop can regenerative ratio aluminum alloy ingot,
(1) pulverize: discarded pop can is ground into 300 ~ 500um object particle;
(2) cleaning: particle is used respectively successively the mixture of ethanol and ether, acetone and deionized water ultrasound filtration cleaning 30min in industrial ultrasonic machine respectively, then clean three times by 93# gasoline and deionized water order;
(3) depainting: cleaned granular powder is added the mixing solutions that methane amide-ethyl ketone and water configures and carry out depainting, the allocation ratio of described methane amide-ethyl ketone is 1:(1 ~ 2), the allocation ratio of described methane amide-ethyl ketone and water is 1:9;
(4) melting slagging-off: the object particle after depainting is put into melting reactor, high melt 2h, the demagging refining agent mix and blend adding 1% ~ 2% in reactor removes the gred, and described demagging refining agent is aluminium demagging agent GD-ACM;
(5) grain refining: add grain-refining agent in the molten aluminum liquid after melting being removed the gred;
(6) degasification: pass into the hydrogen in degasifier removal aluminium liquid and sodium, calcium etc. in molten aluminum liquid;
(7) ingot bar: molten aluminum liquid is put into pig moulding machine ingot bar shaping.
In the method for above-mentioned a kind of discarded pop can regenerative ratio aluminum alloy ingot, in described step (2), in the mixture of described ethanol and ether, ethanol: ether=4:3.
In the method for above-mentioned a kind of discarded pop can regenerative ratio aluminum alloy ingot, in described step (4), described in add the condition that demagging refining agent carries out except Slag treatment be vacuum stirring.
In the method for above-mentioned a kind of discarded pop can regenerative ratio aluminum alloy ingot, in described step (5), described grain-refining agent is Al-Ti-B grain-refining agent or rare earth element grain-refining agent.
In the method for above-mentioned a kind of discarded pop can regenerative ratio aluminum alloy ingot, in described step (6), described degasifier is nitrogen or argon gas.
Beneficial effect: pop can will be discarded through pulverizing, cleaning, depainting, melting removes the gred, grain refining, after the process of degasification and ingot casting seven steps, present invention process is reasonable, succinctly, shortened process greatly, discarded pop can is not only turned waste into wealth as raw materials technology, and reduce the environmental pollution that brings of depainting in the process, improve the quality of aluminum alloy ingot, strengthen the reuse ratio of aluminium, there is very wide city's prospect, pulverized particles particle diameter is suitable, process without the need to using meticulous instrument, water-soluble and the lipid-soluble substance of cleaning removing particle surface, improve the quality of scrap aluminium alloy, in melting slagging-off, under the condition of vacuum stirring, increase the compactness of aluminium, grain-refining agent add the uniform small grains that ensure that aluminum alloy ingot, smooth surface, not only change the adding of nitrogen or argon gas degasifier environmental pollution that traditional chlorine or hexachloroethane degasifier bring but also reach equally and remove hydrogen in molten aluminum liquid and sodium, calcium etc., improve the quality of aluminium alloy.
Embodiment
The technique means realized for making the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with embodiment, setting forth the present invention further.
embodiment 1:
(1) pulverize: discarded pop can is ground into 300 ~ 500um object particle, pulverized particles particle diameter is suitable, processes without the need to using meticulous instrument;
(2) clean: particle is used respectively successively the mixture of ethanol and ether, acetone and deionized water ultrasound filtration cleaning 30min in industrial ultrasonic machine respectively, clean three times by 93# gasoline and deionized water order again, water-soluble and the lipid-soluble substance of cleaning removing particle surface, improves the quality of scrap aluminium alloy;
(3) depainting: cleaned granular powder is added the mixing solutions that methane amide-ethyl ketone and water configures and carry out depainting, the allocation ratio of described methane amide-ethyl ketone is 1:1, and the allocation ratio of described methane amide-ethyl ketone and water is 1:9;
(4) melting slagging-off: the object particle after depainting is put into melting reactor, high melt 2h, the demagging refining agent mix and blend adding 2% in reactor removes the gred, and described demagging refining agent is aluminium demagging agent GD-ACM;
(5) grain refining: add grain-refining agent in the molten aluminum liquid after melting being removed the gred, ensure that the uniform small grains of aluminum alloy ingot, smooth surface;
(6) degasification: pass into the hydrogen in degasifier removal aluminium liquid and sodium, calcium etc. in molten aluminum liquid, not only change the adding of nitrogen degasifier environmental pollution that traditional chlorine or hexachloroethane degasifier bring but also reach equally and remove hydrogen in molten aluminum liquid and sodium, calcium etc., improve the quality of aluminium alloy;
(7) ingot bar: molten aluminum liquid is put into pig moulding machine ingot bar shaping.
embodiment 2: all the other are identical with described embodiment 1, difference is, in step (3), the allocation ratio of methane amide-ethyl ketone is 2:3, in step (4), described to add the condition that demagging refining agent carries out except Slag treatment be vacuum stirring, and changing the content adding demagging refining agent in step (4) is 1.5%.
embodiment 3: all the other are identical with described embodiment 1, difference is, in step (3), the allocation ratio of methane amide-ethyl ketone is 1:2, changing the content adding demagging refining agent in step (4) is 1%, in step (5), described grain-refining agent is Al-Ti-B grain-refining agent or rare earth element grain-refining agent.
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Discarded pop can depainting rate | 98% | 95% | 97.5% |
| The content of aluminium alloy aluminium | 96% | 95.4% | 93% |
By above-mentioned 3 embodiments, from three groups of data in upper table, discard pop can depainting rate when the allocation ratio of methane amide-ethyl ketone is 1:1 higher, and when the content adding demagging refining agent is 2%, the content of aluminium alloy aluminium is higher.
The present embodiment is known in practical application, the present invention will discard pop can through pulverizing, cleaning, depainting, melting removes the gred, grain refining, after the process of degasification and ingot casting seven steps, present invention process is reasonable, succinctly, shortened process greatly, discarded pop can is not only turned waste into wealth as raw materials technology, and reduce the environmental pollution that brings of depainting in the process, improve the quality of aluminum alloy ingot, strengthen the reuse ratio of aluminium, there is very wide city's prospect, pulverized particles particle diameter is suitable, process without the need to using meticulous instrument, water-soluble and the lipid-soluble substance of cleaning removing particle surface, improve the quality of scrap aluminium alloy, in melting slagging-off, under the condition of vacuum stirring, increase the compactness of aluminium, grain-refining agent add the uniform small grains that ensure that aluminum alloy ingot, smooth surface, not only change the adding of nitrogen or argon gas degasifier environmental pollution that traditional chlorine or hexachloroethane degasifier bring but also reach equally and remove hydrogen in molten aluminum liquid and sodium, calcium etc., improve the quality of aluminium alloy.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize specification sheets of the present invention to do equivalent structure or the conversion of equivalent flow process, or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.
Claims (5)
1. a method for discarded pop can regenerative ratio aluminum alloy ingot, is characterized in that,
(1) pulverize: discarded pop can is ground into 300 ~ 500um object particle;
(2) cleaning: object particle is used respectively successively the mixture of ethanol and ether, acetone and deionized water ultrasound filtration cleaning 30min in industrial ultrasonic machine respectively, then clean three times by 93# gasoline and deionized water order;
(3) depainting: cleaned particle is added the mixing solutions that methane amide-ethyl ketone and water configures and carry out depainting, the allocation ratio of described methane amide-ethyl ketone is 1:(1 ~ 2), the allocation ratio of described methane amide-ethyl ketone and water is 1:9;
(4) melting slagging-off: the object particle after depainting is put into melting reactor, high melt 2h, the demagging refining agent mix and blend adding 1% ~ 2% in reactor removes the gred, and described demagging refining agent is aluminium demagging agent GD-ACM;
(5) grain refining: add grain-refining agent in the molten aluminum liquid after melting being removed the gred;
(6) degasification: pass into the hydrogen in degasifier removal aluminium liquid and sodium, calcium etc. in molten aluminum liquid;
(7) ingot bar: molten aluminum liquid is put into pig moulding machine ingot bar shaping.
2. the method for discarded pop can regenerative ratio aluminum alloy ingot according to claim 1, is characterized in that, in described step (2), in the mixture of described ethanol and ether, and ethanol: ether=4:3.
3. the method for discarded pop can regenerative ratio aluminum alloy ingot according to claim 1, is characterized in that, described step (4), described in add the condition that demagging refining agent carries out except Slag treatment be vacuum stirring.
4. the method for discarded pop can regenerative ratio aluminum alloy ingot according to claim 1, is characterized in that, in described step (5), described grain-refining agent is Al-Ti-B grain-refining agent or rare earth element grain-refining agent.
5. the method for discarded pop can regenerative ratio aluminum alloy ingot according to claim 1, is characterized in that, in described step (6), described degasifier is nitrogen or argon gas.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310474780.9A CN104561616A (en) | 2013-10-12 | 2013-10-12 | Method for producing aluminium alloy ingots from abandoned pop cans |
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| CN201310474780.9A CN104561616A (en) | 2013-10-12 | 2013-10-12 | Method for producing aluminium alloy ingots from abandoned pop cans |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105567965A (en) * | 2015-12-30 | 2016-05-11 | 石嘴山市宝马兴庆特种合金有限公司 | Method for producing multi-element alloy by means of ring-pull cans |
| CN106002295A (en) * | 2016-06-25 | 2016-10-12 | 诸葛杨杨 | Aluminum waste depainting machining production line capable of achieving uniform mixing of reactants |
| CN108374109A (en) * | 2018-02-27 | 2018-08-07 | 西安理工大学 | A method of preparing secondary aluminium alloy with discarded pop can |
| CN111020256A (en) * | 2019-12-11 | 2020-04-17 | 山东创新金属科技有限公司 | Production process for producing electronic aluminum alloy by using secondary aluminum |
| CN111926186A (en) * | 2020-07-14 | 2020-11-13 | 优浦帅翼驰(苏州)新材料有限公司 | Aluminum alloy recovery process |
| CN112228484A (en) * | 2020-10-14 | 2021-01-15 | 湖北飞龙摩擦密封材料股份有限公司 | Environment-friendly friction material and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101921933A (en) * | 2010-06-03 | 2010-12-22 | 怡球金属资源再生（中国）股份有限公司 | High-purity stabilized aluminum alloy ingot and production method thereof |
| CN102912140A (en) * | 2012-07-26 | 2013-02-06 | 北京科技大学 | Method for recycling waste aluminum ring-pull cans in green circular relegation way |
-
2013
- 2013-10-12 CN CN201310474780.9A patent/CN104561616A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921933A (en) * | 2010-06-03 | 2010-12-22 | 怡球金属资源再生（中国）股份有限公司 | High-purity stabilized aluminum alloy ingot and production method thereof |
| CN102912140A (en) * | 2012-07-26 | 2013-02-06 | 北京科技大学 | Method for recycling waste aluminum ring-pull cans in green circular relegation way |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105567965A (en) * | 2015-12-30 | 2016-05-11 | 石嘴山市宝马兴庆特种合金有限公司 | Method for producing multi-element alloy by means of ring-pull cans |
| CN106002295A (en) * | 2016-06-25 | 2016-10-12 | 诸葛杨杨 | Aluminum waste depainting machining production line capable of achieving uniform mixing of reactants |
| CN108374109A (en) * | 2018-02-27 | 2018-08-07 | 西安理工大学 | A method of preparing secondary aluminium alloy with discarded pop can |
| CN111020256A (en) * | 2019-12-11 | 2020-04-17 | 山东创新金属科技有限公司 | Production process for producing electronic aluminum alloy by using secondary aluminum |
| CN111020256B (en) * | 2019-12-11 | 2020-12-11 | 山东创新金属科技有限公司 | Production process for producing electronic aluminum alloy by using secondary aluminum |
| CN111926186A (en) * | 2020-07-14 | 2020-11-13 | 优浦帅翼驰(苏州)新材料有限公司 | Aluminum alloy recovery process |
| CN112228484A (en) * | 2020-10-14 | 2021-01-15 | 湖北飞龙摩擦密封材料股份有限公司 | Environment-friendly friction material and preparation method and application thereof |
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