CN104561403A - Environment-friendly leather care agent - Google Patents
Environment-friendly leather care agent Download PDFInfo
- Publication number
- CN104561403A CN104561403A CN201410776166.2A CN201410776166A CN104561403A CN 104561403 A CN104561403 A CN 104561403A CN 201410776166 A CN201410776166 A CN 201410776166A CN 104561403 A CN104561403 A CN 104561403A
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- CN
- China
- Prior art keywords
- parts
- oil
- leather
- sulfonic acid
- sodium salt
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
- C14C11/003—Surface finishing of leather using macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
- C14C9/02—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes using fatty or oily materials, e.g. fat liquoring
Abstract
The invention discloses an environment-friendly leather care agent which is prepared from the following raw materials in parts by weight: 20-45 parts of vegetable fat, 20-35 parts of polyether modified hydrophilic silicone oil, 6-15 parts of organic silicone oil, 30-55 parts of polyethylene glycol, 10-20 parts of sodium tetra(propylene benzene) sulfonate, 1-5 parts of twain 80, 0-3 parts of plant aromatic essential oil, and 0-2 parts of a brightener. The environment-friendly leather care agent disclosed by the invention can penetrate into leather for filling or lubricating gaps among fibers, so that the fibers regain the elasticity and are not bonded, therefore, the internal fiber structure of the leather is re-adjusted, and the softness of the leather is restored; in the process of preparing, by ultrasonic treatment, aliphatic long-chain molecules and fat in the vegetable fat are broken into small molecules, so that after being sprayed to the surface of leather, the leather care agent penetrates into the leather more easily; and leather treated by using the care agent disclosed by the invention has good air permeability, softness, rebound resilience and smooth feel.
Description
Technical field
The present invention relates to a kind of leather care products, specifically a kind of environmental-friendly leather nursing agent, belongs to technical field of fine.
Background technology
Leatherware is at present extensive to live central use people.But along with the use of leather in the middle of daily life, due to environmental change, as moisture, temperature etc. can cause the grease of leather inside or oil film to be destroyed, grease volatilizees, make will mutually be bonded together between leather internal fiber, thus make corium hardening, become fragile.
This series products such as leather cleaning agent, leather care products, bating agent is often by again filling the object that grease reaches softening leather to leather.CN 103669002A discloses a kind of following raw material comprised according to mass fraction meter: hydroxy silicon oil 20-25 part, vinylformic acid 0.5-1 part, polyethylene wax 0.2-0.3 part, myristamide propyl group hydroxypropyl sultaine 2-5 part, ethanol 30-40 part, water 40-45 part, wherein, the leather softening agent made of the linear polydimethylsiloxane of hydroxy silicon oil to be end group be hydroxyl.CN1253980 discloses soft dose of a kind of leather, wherein include wax emulsion and methyl-silicone oil mixture, and with macromolecular material with 1: 1: 1 volume ratio be at room temperature fully uniformly mixed into milky white liquid, its macromolecular material is the synthetic chemical extract from fish oil, vegetables oil and mineral oil.It is prepared by following composition by weight by each material that CN104032049A discloses a kind of leather fat: lard 0-400 part, sweet oil macrogol ester 10-400 part, alkyl sodium sulfonate 50-100 part, polyoxyethylene alkyl phosphate 0-100 part, 52# clorafin 60-80 part, softening agent 1-5 part.CN 102965921 A discloses the soft agent of a kind of imitation leather, component and number as follows: 25 ~ 40 parts, animal oil, Microcrystalline Wax 10 ~ 15 parts, organic silicone oil 15 ~ 25 parts, sodium lauryl sulfate 5 ~ 8 parts.Described organic silicone oil is hydroxy silicon oil or amino-modified silicone oil.Described animal oil be butter or sheep oil or lard in one or more.
Along with the requirement to environmental protection, the selection of existing leather care products is tended to select aqueous product often, or oil-containing but can hydrolysis prods.Vegetables oil liposoluble point is low, be rich in unsaturated fatty acids and vitamin-E, lipid content more than 99%, to the protein fibre of leather, there is good repair.
Summary of the invention
The object of this invention is to provide a kind of based on Vegetable oil lipoprotein, the environmental-friendly leather nursing agent of environmental protection.
Technical scheme of the present invention is as follows: a kind of environmental-friendly leather nursing agent, it is by the raw material of following parts by weight: Vegetable oil lipoprotein 20 ~ 45 parts, polyether-modified hydrophilic silicon oil 20 ~ 35 parts, organic silicone oil 6 ~ 15 parts, polyoxyethylene glycol 30 ~ 55 parts, tetrapropylene benzene sulfonic acid sodium salt 10 ~ 20 parts, tween 80 1 ~ 5 part, plant fragrance essential oil 0 ~ 3 part, brightening agent 0 ~ 2 part, prepared by employing following steps: by Vegetable oil lipoprotein, organic silicone oil, the half of polyoxyethylene glycol consumption mixes, and be heated to 30 ~ 35 DEG C, then supersound process 5 ~ 10min under the ultrasonic wave of 25-45kHz is placed in, add polyether-modified hydrophilic silicon oil, the half of tetrapropylene benzene sulfonic acid sodium salt consumption, remaining polyoxyethylene glycol, be warming up to 35 ~ 40 DEG C, supersound process 3 ~ 5min is continued under identical frequency, add remaining tetrapropylene benzene sulfonic acid sodium salt again, plant fragrance essential oil, brightening agent, tween 80, be warming up to 40 ~ 45 DEG C, supersound process 3 ~ 5min is continued under identical frequency, .
Described Vegetable oil lipoprotein can be by one or more in Viscotrol C, Oleum Cocois, soybean oil, sunflower seed oil.
Described brightening agent can be lustering agent, brightener etc. in leather industry for the processing aid of polishing leather or product.
Described plant fragrance essential oil is the natural essential oil being extracted into plant, having Titian or flavouring effect, as lemon quintessence oil, Flos Rosae Rugosae quintessence oil, lily essential oil etc., for giving product special plant fragrance in product of the present invention.
In technique scheme, described leather care products is preferably prepared by the raw material of following parts by weight: Vegetable oil lipoprotein 20 ~ 40 parts, polyether-modified hydrophilic silicon oil 20 ~ 30 parts, organic silicone oil 6 ~ 10 parts, polyoxyethylene glycol 30 ~ 45 parts, tetrapropylene benzene sulfonic acid sodium salt 10 ~ 15 parts, plant fragrance essential oil 0 ~ 5 part, brightening agent 0 ~ 4 part.
Preferred further, described leather care products is prepared by the raw material of following parts by weight: Vegetable oil lipoprotein 35 parts, polyether-modified hydrophilic silicon oil 25 parts, organic silicone oil 9 parts, polyoxyethylene glycol 44 parts, tetrapropylene benzene sulfonic acid sodium salt 12 parts, plant fragrance essential oil 1.5 parts, brightening agent 0.5 part.
The present invention is relative to the beneficial effect of prior art: the unsaturated fatty acids that the present invention utilizes Vegetable oil lipoprotein to enrich and vitamin-E and high lipid content, leather inside can be penetrated into, fill or lubricant fiber between space, it is made to recover elasticity, not bond, thus the acquisition of leather internal fiber structure is readjusted, leather recovers soft; By ultrasonication, make the lipid acid long chain molecule in Vegetable oil lipoprotein, fat is broken into small molecules, spray to leather surface, be easier to penetrate into leather inside; Vitamin-E also has good repair to protein; Leather after nursing agent process of the present invention has good ventilation property, flexibility, rebound resilience and smooth feel.
Embodiment
Be described in further details the present invention below by embodiment, these embodiments are only used for the present invention is described, do not limit the scope of the invention.
Embodiment 1 is by the raw material of following parts by weight: soybean oil 15 parts, Oleum Cocois 10 parts, Viscotrol C 10 parts, polyether-modified hydrophilic silicon oil 25 parts, organic silicone oil 9 parts, polyoxyethylene glycol 44 parts, tetrapropylene benzene sulfonic acid sodium salt 12 parts, Flos Rosae Rugosae quintessence oil 1.5 parts, brightening agent 0.5 part, following steps are adopted to prepare a kind of environmental-friendly leather nursing agent: by soybean oil, Oleum Cocois, Viscotrol C, organic silicone oil, polyoxyethylene glycol 22 parts mixes, and be heated to 30 DEG C, then supersound process 5min under the ultrasonic wave of 30kHz is placed in, add polyether-modified hydrophilic silicon oil, tetrapropylene benzene sulfonic acid sodium salt 6 parts, remaining polyoxyethylene glycol, be warming up to 35 DEG C, supersound process 3min is continued under identical frequency, add remaining tetrapropylene benzene sulfonic acid sodium salt again, Flos Rosae Rugosae quintessence oil, brightening agent, tween 80, be warming up to 40 DEG C, supersound process 3min is continued under identical frequency, .
Embodiment 2 is by the raw material of following parts by weight: Oleum Gossypii semen 12 parts, Viscotrol C 10 parts, Oleum Cocois 23 parts, polyether-modified hydrophilic silicon oil 35 parts, organic silicone oil 65 parts, polyoxyethylene glycol 30 parts, tetrapropylene benzene sulfonic acid sodium salt 10 parts, tween 80 5 parts, brightening agent 1 part, prepared by employing following steps: by Vegetable oil lipoprotein, organic silicone oil, polyoxyethylene glycol 15 parts mixes, and be heated to 35 DEG C, then supersound process 10min under the ultrasonic wave of 35kHz is placed in, add polyether-modified hydrophilic silicon oil, tetrapropylene benzene sulfonic acid sodium salt 5 parts, remaining polyoxyethylene glycol, be warming up to 40 DEG C, supersound process 5min is continued under identical frequency, add remaining tetrapropylene benzene sulfonic acid sodium salt again, brightening agent, tween 80, be warming up to 45 DEG C, supersound process 5min is continued under identical frequency, .
Embodiment 3 is by the raw material of following parts by weight: soybean oil 15 parts, Oleum Cocois 5 parts, polyether-modified hydrophilic silicon oil 30 parts, organic silicone oil 10 parts, polyoxyethylene glycol 55 parts, tetrapropylene benzene sulfonic acid sodium salt 16 parts, tween 80 2 parts, lemon quintessence oil 2 parts, prepared by employing following steps: by Vegetable oil lipoprotein, organic silicone oil, polyoxyethylene glycol 27.5 parts mixes, and be heated to 30 DEG C, then supersound process 6min under the ultrasonic wave of 25kHz is placed in, add polyether-modified hydrophilic silicon oil, tetrapropylene benzene sulfonic acid sodium salt 8 parts, remaining polyoxyethylene glycol, be warming up to 40 DEG C, supersound process 3min is continued under identical frequency, add remaining tetrapropylene benzene sulfonic acid sodium salt again, lemon quintessence oil, tween 80, be warming up to 45 DEG C, supersound process 3min is continued under identical frequency, .
Embodiment 4 is by the raw material of following parts by weight: Trisun Oil R 80 30 parts, Castor oil 10 parts, polyether-modified hydrophilic silicon oil 20 parts, organic silicone oil 15 parts, polyoxyethylene glycol 46 parts, tetrapropylene benzene sulfonic acid sodium salt 20 parts, tween 80 1 part, plant fragrance essential oil 2 parts, brightening agent 1 part, prepared by employing following steps: by Vegetable oil lipoprotein, organic silicone oil, polyoxyethylene glycol 23 parts mixes, and be heated to 35 DEG C, then supersound process 10min under the ultrasonic wave of 45kHz is placed in, add polyether-modified hydrophilic silicon oil, tetrapropylene benzene sulfonic acid sodium salt 10 parts, remaining polyoxyethylene glycol, be warming up to 40 DEG C, supersound process 5min is continued under identical frequency, add remaining tetrapropylene benzene sulfonic acid sodium salt again, plant fragrance essential oil, brightening agent, tween 80, be warming up to 45 DEG C, supersound process 5min is continued under identical frequency, .
Claims (5)
1. an environmental-friendly leather nursing agent, it is characterized in that: be former by following parts by weight: Vegetable oil lipoprotein 20 ~ 45 parts, polyether-modified hydrophilic silicon oil 20 ~ 35 parts, organic silicone oil 6 ~ 15 parts, polyoxyethylene glycol 30 ~ 55 parts, tetrapropylene benzene sulfonic acid sodium salt 10 ~ 20 parts, tween 80 1 ~ 5 part, plant fragrance essential oil 0 ~ 3 part, brightening agent 0 ~ 2 part, prepared by employing following steps: by Vegetable oil lipoprotein, organic silicone oil, the half of polyoxyethylene glycol consumption mixes, and be heated to 30 ~ 35 DEG C, then supersound process 5 ~ 10min under the ultrasonic wave of 25-45kHz is placed in, add polyether-modified hydrophilic silicon oil, the half of tetrapropylene benzene sulfonic acid sodium salt consumption, remaining polyoxyethylene glycol, be warming up to 35 ~ 40 DEG C, supersound process 3 ~ 5min is continued under identical frequency, add remaining tetrapropylene benzene sulfonic acid sodium salt again, plant fragrance essential oil, brightening agent, tween 80, be warming up to 40 ~ 45 DEG C, supersound process 3 ~ 5min is continued under identical frequency, .
2. environmental-friendly leather nursing agent according to claim 1, is characterized in that: described Vegetable oil lipoprotein is by one or more in Viscotrol C, Oleum Cocois, soybean oil, sunflower seed oil.
3. environmental-friendly leather nursing agent according to claim 1, is characterized in that: described plant fragrance essential oil is the one in lemon quintessence oil, Flos Rosae Rugosae quintessence oil, lily essential oil.
4. environmental-friendly leather nursing agent according to claim 1, is characterized in that: described leather care products is prepared by the raw material of following parts by weight: Vegetable oil lipoprotein 20 ~ 40 parts, polyether-modified hydrophilic silicon oil 20 ~ 30 parts, organic silicone oil 6 ~ 10 parts, polyoxyethylene glycol 30 ~ 45 parts, tetrapropylene benzene sulfonic acid sodium salt 10 ~ 15 parts, plant fragrance essential oil 0 ~ 5 part, brightening agent 0 ~ 4 part.
5. environmental-friendly leather nursing agent according to claim 1, it is characterized in that: described leather care products is by the raw material of following parts by weight: soybean oil 15 parts, Oleum Cocois 10 parts, Viscotrol C 10 parts, polyether-modified hydrophilic silicon oil 25 parts, organic silicone oil 9 parts, polyoxyethylene glycol 44 parts, tetrapropylene benzene sulfonic acid sodium salt 12 parts, Flos Rosae Rugosae quintessence oil 1.5 parts, brightening agent 0.5 part, prepared by employing following steps: by soybean oil, Oleum Cocois, Viscotrol C, organic silicone oil, the half of polyoxyethylene glycol consumption mixes, and be heated to 30 DEG C, then supersound process 5min under the ultrasonic wave of 30kHz is placed in, add polyether-modified hydrophilic silicon oil, the half of tetrapropylene benzene sulfonic acid sodium salt consumption, remaining polyoxyethylene glycol, be warming up to 35 DEG C, supersound process 3min is continued under identical frequency, add remaining tetrapropylene benzene sulfonic acid sodium salt again, Flos Rosae Rugosae quintessence oil, brightening agent, tween 80, be warming up to 40 DEG C, supersound process 3min is continued under identical frequency, .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410776166.2A CN104561403A (en) | 2014-12-17 | 2014-12-17 | Environment-friendly leather care agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410776166.2A CN104561403A (en) | 2014-12-17 | 2014-12-17 | Environment-friendly leather care agent |
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| CN104561403A true CN104561403A (en) | 2015-04-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410776166.2A Pending CN104561403A (en) | 2014-12-17 | 2014-12-17 | Environment-friendly leather care agent |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105039610A (en) * | 2015-06-30 | 2015-11-11 | 深圳市艾思生物技术有限公司 | Leather care solution and preparation method thereof |
| CN106893467A (en) * | 2017-03-29 | 2017-06-27 | 安徽月娇家具有限公司 | A kind of preparation method of fibroin aqueous polyurethane nano composite water-proof leather finishing agent |
| CN108148508A (en) * | 2017-11-12 | 2018-06-12 | 孝感市锐思新材科技有限公司 | A kind of preparation method for leather and fur products brightener new material |
| CN108396083A (en) * | 2018-02-26 | 2018-08-14 | 合肥远科服装设计有限公司 | A kind of environmental-friendly leather care agent and preparation method thereof |
| CN109504810A (en) * | 2018-12-04 | 2019-03-22 | 浙江纳巍负离子科技有限公司 | A kind of negative oxygen ion multiple-effect corium and leather product curing agent and preparation method |
| CN111493473A (en) * | 2020-06-15 | 2020-08-07 | 杭州天龙手袋股份有限公司 | Waterproof antibacterial soft material handbag |
| CN115247029A (en) * | 2022-06-06 | 2022-10-28 | 浙江遂昌奥美化工科技有限公司 | Surface brightening agent for leather and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4285688A (en) * | 1979-03-28 | 1981-08-25 | Leather Life, Inc. | Saddle oil |
| CN1071677A (en) * | 1991-10-21 | 1993-05-05 | 白瑛 | A kind of coating and decorating agent for leather |
-
2014
- 2014-12-17 CN CN201410776166.2A patent/CN104561403A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4285688A (en) * | 1979-03-28 | 1981-08-25 | Leather Life, Inc. | Saddle oil |
| CN1071677A (en) * | 1991-10-21 | 1993-05-05 | 白瑛 | A kind of coating and decorating agent for leather |
Non-Patent Citations (1)
| Title |
|---|
| 张洪萍等: "绿色化皮革清洗保养剂及皮革制品保养工艺的研究", 《中 国 皮 革》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105039610A (en) * | 2015-06-30 | 2015-11-11 | 深圳市艾思生物技术有限公司 | Leather care solution and preparation method thereof |
| CN106893467A (en) * | 2017-03-29 | 2017-06-27 | 安徽月娇家具有限公司 | A kind of preparation method of fibroin aqueous polyurethane nano composite water-proof leather finishing agent |
| CN108148508A (en) * | 2017-11-12 | 2018-06-12 | 孝感市锐思新材科技有限公司 | A kind of preparation method for leather and fur products brightener new material |
| CN108396083A (en) * | 2018-02-26 | 2018-08-14 | 合肥远科服装设计有限公司 | A kind of environmental-friendly leather care agent and preparation method thereof |
| CN109504810A (en) * | 2018-12-04 | 2019-03-22 | 浙江纳巍负离子科技有限公司 | A kind of negative oxygen ion multiple-effect corium and leather product curing agent and preparation method |
| CN111493473A (en) * | 2020-06-15 | 2020-08-07 | 杭州天龙手袋股份有限公司 | Waterproof antibacterial soft material handbag |
| CN111493473B (en) * | 2020-06-15 | 2022-07-12 | 杭州天龙手袋股份有限公司 | Waterproof antibacterial soft material handbag |
| CN115247029A (en) * | 2022-06-06 | 2022-10-28 | 浙江遂昌奥美化工科技有限公司 | Surface brightening agent for leather and preparation method thereof |
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Application publication date: 20150429 |