CN104560099A - Preparation technology for preparing fuel oil by utilizing waste rubber - Google Patents
Preparation technology for preparing fuel oil by utilizing waste rubber Download PDFInfo
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- CN104560099A CN104560099A CN201410831397.9A CN201410831397A CN104560099A CN 104560099 A CN104560099 A CN 104560099A CN 201410831397 A CN201410831397 A CN 201410831397A CN 104560099 A CN104560099 A CN 104560099A
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- waste rubber
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- 239000002699 waste material Substances 0.000 title claims abstract description 28
- 238000005516 engineering process Methods 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000000295 fuel oil Substances 0.000 title claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 28
- 238000005336 cracking Methods 0.000 claims abstract description 23
- 239000003054 catalyst Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 9
- 230000000536 complexating effect Effects 0.000 claims abstract description 8
- 238000000605 extraction Methods 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003921 oil Substances 0.000 claims description 30
- 239000002283 diesel fuel Substances 0.000 claims description 20
- 238000010792 warming Methods 0.000 claims description 15
- 239000000446 fuel Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 239000003513 alkali Substances 0.000 claims description 10
- 238000010504 bond cleavage reaction Methods 0.000 claims description 6
- 230000007017 scission Effects 0.000 claims description 6
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 238000003763 carbonization Methods 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 5
- 150000002910 rare earth metals Chemical class 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 4
- 230000001476 alcoholic effect Effects 0.000 claims description 2
- 238000011010 flushing procedure Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 238000009924 canning Methods 0.000 abstract 1
- 239000000571 coke Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 8
- 239000003502 gasoline Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 238000007233 catalytic pyrolysis Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- -1 and easily blast Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001574 biopsy Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000010092 rubber production Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/006—Combinations of processes provided in groups C10G1/02 - C10G1/08
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/008—Controlling or regulating of liquefaction processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1003—Waste materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
Abstract
The invention discloses a preparation technology for preparing fuel oil by utilizing waste rubber. The preparation technology comprises the following steps: washing the waste rubber, airing the washed waste rubber, cutting up the aired waste rubber, placing the cut-up waste rubber in a cracking kettle, adding a catalyst in the cracking kettle, uniformly mixing and stirring the cut-up waste rubber and the catalyst, and slowly raising the temperature; controlling the temperature to heat materials in the cracking kettle in different temperature sections so as to enable the materials react slowly, sufficiently condensing cracked gases, and respectively acquiring condensed liquids in different temperature sections; recycling the catalyst after the cracking reaction ends; respectively performing extraction separation on coarse light diesel and coarse heavy diesel by an extraction complexing solvent under the condition of the room temperature, performing alkaline wash through an alkaline liquor and washing through water so as to obtain refined diesel, canning the refined diesel, and storing the canned refined diesel. In the technology disclosed by the invention, the self-prepared catalyst is used in the reaction, so that the situation that the materials stick on walls and coke at high temperature is effectively reduced; the fuel oil is high in yield and stable in quality; the catalyst can be recycled; the technology is simple to operate and is easy to produce in a large scale.
Description
Technical field
The present invention relates to a kind of preparation technology utilizing waste rubber to produce oil fuel, belong to petrochemical complex refining field.
Background technology
Rubber industry is one of important foundation industry of national economy.It is not only the light industry rubber product such as daily, medical that people provide daily life indispensable, and provides various rubber production unit or rubber components to the heavy industry such as digging, traffic, building, machinery, electronics and new industry.In recent years, rubber industry was much developed, and the existing segmented industry is steadily increasing, the then develop rapidly of the new untreated rubber segmented industry, but simultaneously, rubber industry yet exists the problems such as environment, resource, disaster, innovation.
At present, waste rubber because of measure large, take up room, contaminate environment becomes current urgent need to solve the problem.The method of usually conduct waste rubber mainly contains landfill, granulation regeneration and cracking.Directly being processed into rubber powder after being pulverized by waste rubber product is international method.Make rubber powder and have four Lung biopsies, but the most frequently used be normal temperature crushing up and pulverize at low temperature method.The application of rubber powder widely, is broadly divided into three large fields: chemical industry, building materials and field of traffic.Mix the product that rubber powder makes, use properties has reduction in various degree, and more easily produces secondary environmental pollution problem.Waste rubber is become gasoline by fragmentation pattern, diesel oil is the maximum modes of current research and development: it is higher that thermo-cracking exists cracking temperature, general at 600 DEG C, scission reaction speed is slow, in cracking process, the side reactions such as aromizing, condensation, polymerization are comparatively strong, and splitting gas easy blocking pipe when condensation, affects quality product, and easily blast, fuel consumption is large; Catalytic pyrolysis main drawback is that oil yield lower production cost is high, and quality product difficulty is up to state standards.
Chinese patent CN201110236077 provides a kind of method utilizing plastics and rubber to produce mixing oil, and this method palladium catalyst carries out catalytic pyrolysis, catalyst recovery, regeneration difficulty, and carries out the mode products obtained therefrom poor stability of filtering product with purification medium.Chinese patent CN201110034668 discloses a kind of method of environment-friendly type waste rubber renewable diesel, and this method complex process, gained processed oil boiling spread is wide, and product stability is poor.
Summary of the invention
Goal of the invention: the defect existed for prior art, the invention provides a kind of technological operation simple, product is stablized, and the waste rubber that yield is high produces the preparation technology of oil fuel.
For achieving the above object, the present invention is by the following technical solutions: a kind of preparation technology utilizing waste rubber to produce oil fuel, comprises following technological step:
(1) after the flushing of waste old water being dried, chopping, insert in sealable cracking still, add catalyzer, after being uniformly mixed, cracking still and condenser are coupled together, heated material, slowly heats up;
(2) control temperature of reaction at 150 ~ 180 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains raw gasline;
(3) continue to be warming up to 180 ~ 350 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains thick LIGHT DIESEL OIL;
(4) continue to be warming up to 350 ~ 420 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains heavy gas oil;
(5) continue to be warming up to more than 420 DEG C, gather the cut of this temperature section, obtain heavy oil fraction;
(6) after scission reaction terminates, in cracking reactor, add the vitriol oil, make organic detritus carbonization in still, then residue is first burned, then proceed to retort furnace section and burn, reclaim catalyzer;
(7) at ambient temperature, respectively thick LIGHT DIESEL OIL, heavy gas oil extraction complexing solvent are carried out extracting and separating, then through alkali lye alkali cleaning, washing, obtains refined diesel oil, tinning stores.
As preferably, in described step (1), catalyzer is ultra-fine alumina, chromic oxide upgrading rare earth catalyst.
As preferably, described catalyzer adopts co-precipitation-calcination method to obtain.
As preferably, in described step (6), calcining temperature is 360 ~ 400 DEG C.
As preferably, in described step (7), extract the alcoholic solution that complexing solvent is concentration 50 ~ 90%.
A kind of preparation technology utilizing waste rubber to produce oil fuel provided by the invention, compared to existing technology, has following beneficial effect:
Present invention process uses from controlling catalyst in reaction, effectively reduces material high temperature and glues wall coking; Oil fuel yield is high, stay in grade; Catalyzer is recyclable; Technological operation is simple, is easy to large-scale production.
Specific embodiment
By the following examples the present invention is further explained:
Embodiment 1
Utilize waste rubber to produce a preparation technology for oil fuel, the present invention includes following technological step:
(1), by waste old water rinse after drying, chopping, weighs 1000kg, inserts in sealable cracking still, add ultra-fine alumina, chromic oxide upgrading rare earth catalyst 2.5kg, after being uniformly mixed, cracking still and condenser are coupled together, heated material, slowly heats up;
(2), control temperature of reaction at 150 ~ 180 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains raw gasline;
(3), continue to be warming up to 180 ~ 350 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains thick LIGHT DIESEL OIL;
(4), continue to be warming up to 350 ~ 420 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains heavy gas oil;
(5), continue to be warming up to more than 420 DEG C, gather the cut of this temperature section, obtain heavy oil fraction;
(6), after scission reaction terminates, in cracking reactor, add the vitriol oil, make organic detritus carbonization in still, then residue is first burned, then proceed to 380 DEG C of sections in retort furnace and burn, reclaim catalyzer;
(7), at ambient temperature, respectively thick LIGHT DIESEL OIL, the heavy gas oil ethanolic soln extraction complexing solvent of 75% are carried out extracting and separating, then through alkali lye alkali cleaning, washing, obtains refined diesel oil, tinning stores;
Obtain gasoline 401.7 kg, LIGHT DIESEL OIL 382.8 kg, heavy diesel 92.3kg.
Embodiment 2
(1), by waste old water rinse after drying, chopping, weighs 1000kg, inserts in sealable cracking still, add ultra-fine alumina, chromic oxide upgrading rare earth catalyst 2.0kg, after being uniformly mixed, cracking still and condenser are coupled together, heated material, slowly heats up;
(2), control temperature of reaction at 150 ~ 180 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains raw gasline;
(3), continue to be warming up to 180 ~ 350 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains thick LIGHT DIESEL OIL;
(4), continue to be warming up to 350 ~ 420 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains heavy gas oil;
(5), continue to be warming up to more than 420 DEG C, gather the cut of this temperature section, obtain heavy oil fraction;
(6), after scission reaction terminates, in cracking reactor, add the vitriol oil, make organic detritus carbonization in still, then residue is first burned, then proceed to 400 DEG C of sections in retort furnace and burn, reclaim catalyzer;
(7), at ambient temperature, respectively thick LIGHT DIESEL OIL, the heavy gas oil ethanolic soln extraction complexing solvent of 80% are carried out extracting and separating, then through alkali lye alkali cleaning, washing, obtains refined diesel oil, tinning stores;
Obtain gasoline 400.3 kg, LIGHT DIESEL OIL 392.8 kg, heavy diesel 89.3kg.
Embodiment 3
(1), by waste old water rinse after drying, chopping, weighs 1000kg, inserts in sealable cracking still, add ultra-fine alumina, chromic oxide upgrading rare earth catalyst 1.8kg, after being uniformly mixed, cracking still and condenser are coupled together, heated material, slowly heats up;
(2), control temperature of reaction at 150 ~ 180 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains raw gasline;
(3), continue to be warming up to 180 ~ 350 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains thick LIGHT DIESEL OIL;
(4), continue to be warming up to 350 ~ 420 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains heavy gas oil;
(5), continue to be warming up to more than 420 DEG C, gather the cut of this temperature section, obtain heavy oil fraction;
(6), after scission reaction terminates, in cracking reactor, add the vitriol oil, make organic detritus carbonization in still, then residue is first burned, then proceed to 400 DEG C of sections in retort furnace and burn, reclaim catalyzer;
(7), at ambient temperature, respectively thick LIGHT DIESEL OIL, the heavy gas oil ethanolic soln extraction complexing solvent of 70% are carried out extracting and separating, then through alkali lye alkali cleaning, washing, obtains refined diesel oil, tinning stores;
Obtain gasoline 399.3 kg, LIGHT DIESEL OIL 381.8 kg, heavy diesel 91.3kg.
Embodiment 4
As embodiment 1, wherein 60% of catalyst levels replace with reclaiming catalyzer, all the other operations are constant, obtain gasoline 399.3 kg, LIGHT DIESEL OIL 381.3kg, heavy diesel 90.1kg.
The above is only the preferred embodiment of the present invention; be noted that for those skilled in the art; under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (5)
1. utilize waste rubber to produce a preparation technology for oil fuel, it is characterized in that, comprise following technological step:
(1) after the flushing of waste old water being dried, chopping, insert in sealable cracking still, add catalyzer, after being uniformly mixed, cracking still and condenser are coupled together, heated material, slowly heats up;
(2) control temperature of reaction at 150 ~ 180 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains raw gasline;
(3) continue to be warming up to 180 ~ 350 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains thick LIGHT DIESEL OIL;
(4) continue to be warming up to 350 ~ 420 DEG C, reaction 0.5 ~ 1.5h, gathers the cut of this temperature section, obtains heavy gas oil;
(5) continue to be warming up to more than 420 DEG C, gather the cut of this temperature section, obtain heavy oil fraction;
(6) after scission reaction terminates, in cracking reactor, add the vitriol oil, make organic detritus carbonization in still, then residue is first burned, then proceed to retort furnace section and burn, reclaim catalyzer;
(7) at ambient temperature, respectively thick LIGHT DIESEL OIL, heavy gas oil extraction complexing solvent are carried out extracting and separating, then through alkali lye alkali cleaning, washing, obtains refined diesel oil, tinning stores.
2. waste rubber produces the preparation technology of oil fuel as claimed in claim 1, it is characterized in that, in described step (1), catalyzer is ultra-fine alumina, chromic oxide upgrading rare earth catalyst.
3. utilize waste rubber to produce the preparation technology of oil fuel as claimed in claim 2, it is characterized in that, described catalyzer adopts co-precipitation-calcination method to obtain.
4. utilize waste rubber to produce the preparation technology of oil fuel as claimed in claim 1, it is characterized in that, in described step (6), calcining temperature is 360 ~ 400 DEG C.
5. utilize waste rubber to produce the preparation technology of oil fuel as claimed in claim 1, it is characterized in that, in described step (7), extraction complexing solvent is the alcoholic solution of concentration 50 ~ 90%.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104910947A (en) * | 2015-06-01 | 2015-09-16 | 安徽科茂能源科技有限公司 | Safe environment-friendly oil refining device and technique for continuous-feeding/deslagging waste organic matter cracking regeneration |
| CN113004939A (en) * | 2021-03-09 | 2021-06-22 | 青岛科技大学 | Waste tire derived oil gradient high-valued utilization method |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084546A (en) * | 1992-09-23 | 1994-03-30 | 陈太庸 | Waste plastic is changed into the method and apparatus of oil fuel |
| CN1236804A (en) * | 1999-05-06 | 1999-12-01 | 杨健 | Process and apparatus for preparing petroleum products from waste plastics and rubber |
| CN1869160A (en) * | 2006-05-25 | 2006-11-29 | 丁清云 | Method of making fuel oil by catalytic cracking of waste tyre |
| CN101050372A (en) * | 2007-04-29 | 2007-10-10 | 清华大学 | Method for full constituent utilizing resources of wastes of plastic containing chlorine in fluid bed |
| CN101544781A (en) * | 2008-03-26 | 2009-09-30 | 北京天海元科技有限公司 | Method for treating waste tire |
| JP2013028687A (en) * | 2011-07-27 | 2013-02-07 | Sumitomo Osaka Cement Co Ltd | Method of liquefying waste plastic |
| CN103484146A (en) * | 2013-06-06 | 2014-01-01 | 河南科技大学 | Method used for preparing liquid hydrocarbon from polydicyclopentadiene by cracking reaction |
| WO2014040634A1 (en) * | 2012-09-14 | 2014-03-20 | Outotec Oyj | Method and apparatus for recycling plastic wastes |
-
2014
- 2014-12-29 CN CN201410831397.9A patent/CN104560099B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084546A (en) * | 1992-09-23 | 1994-03-30 | 陈太庸 | Waste plastic is changed into the method and apparatus of oil fuel |
| CN1236804A (en) * | 1999-05-06 | 1999-12-01 | 杨健 | Process and apparatus for preparing petroleum products from waste plastics and rubber |
| CN1869160A (en) * | 2006-05-25 | 2006-11-29 | 丁清云 | Method of making fuel oil by catalytic cracking of waste tyre |
| CN101050372A (en) * | 2007-04-29 | 2007-10-10 | 清华大学 | Method for full constituent utilizing resources of wastes of plastic containing chlorine in fluid bed |
| CN101544781A (en) * | 2008-03-26 | 2009-09-30 | 北京天海元科技有限公司 | Method for treating waste tire |
| JP2013028687A (en) * | 2011-07-27 | 2013-02-07 | Sumitomo Osaka Cement Co Ltd | Method of liquefying waste plastic |
| WO2014040634A1 (en) * | 2012-09-14 | 2014-03-20 | Outotec Oyj | Method and apparatus for recycling plastic wastes |
| CN103484146A (en) * | 2013-06-06 | 2014-01-01 | 河南科技大学 | Method used for preparing liquid hydrocarbon from polydicyclopentadiene by cracking reaction |
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| CN104910947B (en) * | 2015-06-01 | 2016-07-06 | 安徽科茂能源科技有限公司 | A kind of continuous feed, the safety and environmental protection oil refining apparatus of the waste and old organic cracking regeneration of deslagging and technique |
| CN113004939A (en) * | 2021-03-09 | 2021-06-22 | 青岛科技大学 | Waste tire derived oil gradient high-valued utilization method |
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