CN104559766A - Antifouling compound for ceramic tiles and preparation method thereof - Google Patents
Antifouling compound for ceramic tiles and preparation method thereof Download PDFInfo
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- CN104559766A CN104559766A CN201510026840.XA CN201510026840A CN104559766A CN 104559766 A CN104559766 A CN 104559766A CN 201510026840 A CN201510026840 A CN 201510026840A CN 104559766 A CN104559766 A CN 104559766A
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Abstract
The invention discloses an antifouling compound for ceramic tiles and a preparation method thereof. The antifouling compound is prepared from the following raw materials in percentage by mass: 6-16% of methyl high-hydrogen-content silicone oil, 2-12% of low-hydrogen-content silicone oil, 4-12% of 107 silicon rubber, 0.1-1% of silane coupling agent and 65-85% of 120# solvent oil. The preparation method comprises the following steps: S100. sequentially adding the methyl high-hydrogen-content silicone oil, low-hydrogen-content silicone oil and 107 silicon rubber into 120# solvent oil, and stirring for 1-5 minutes; S200. adding the silane coupling agent while stirring, and continuing stirring for 1-5 minutes; and S300. standing to react for 2-5 days. The antifouling compound is especially developed for ceramic tiles, and has the advantages of no toxicity and no corrosion; the ceramic tile can be effectively protected by simple painting on the surface; the film of the antifouling compound is bright and beautiful, and can well prevent oil pens, inks, coffee, tea and other pollutants from infiltration on the premise of not influencing the surface gloss of the ceramic tile; and the ceramic tiles can not be sticky after being packed.
Description
Technical field
The invention belongs to ceramic tile anti-soil technology field, particularly a kind of ceramic tile antifouling agent and preparation method thereof.
Background technology
In order to improve the anti-pollution characteristic of ceramic tile, many ceramic tile manufacturers all use ceramic tile antifouling agent to carry out antifouling process to its surface before ceramic tile dispatches from the factory.Through the development of technology for many years, current ceramic tile antifouling agent is mainly divided into water-based stain control agent and oiliness stain control agent two kinds, water-based stain control agent is mainly by the product of organosilicon composition emulsion dispersion in water, and organosilicon composition is mainly dissolved in the product in petroleum solvent by oiliness stain control agent.Although cost is lower, the antifouling power of water-based stain control agent is slightly weak, and operation technological requirement is higher, so use range is subject to certain restrictions.And antifouling rapid-action, the antifouling power of oiliness stain control agent is strong, so market acceptance is higher.
But the formula of the oiliness stain control agent on market is multifarious, also there is various problem: such as reducing costs, in stain control agent, add cheap noxious solvent; Stain control agent is scrubbing resistance not, and antifouling power is not lasting; Stain control agent becomes dry hardening after smearing the solidification of rear rete, have impact on ceramic tile surface perception and glossiness; Stain control agent is smeared opposite below and is folded packing, there will be sticky brick (ceramic tile cannot be opened) the even serious problems such as variable color after putting in storage after a time.
Summary of the invention
Based on above technical problem, the invention discloses a kind of ceramic tile antifouling agent and preparation method thereof;
Described ceramic tile antifouling agent is made up of following raw material by mass percentage: the methyl height containing hydrogen silicone oil of 6 ~ 16%, the silicon oil of low hydrogen content of 2 ~ 12%, 107 silicon rubber of 4 ~ 12%, the silane coupling agent of 0.1 ~ 1%, No. 120 solvent oils of 65 ~ 85%.
The described method preparing ceramic tile antifouling agent comprises the following steps,
S100, under stirring methyl height containing hydrogen silicone oil, silicon oil of low hydrogen content, 107 silicon rubber are added in No. 120 solvent oils successively, stir 1 ~ 5 minute;
S200, continue to add silane coupling agent while stirring, then stir 1 ~ 5 minute;
S300, standing himself reaction 2 ~ 5 days generation ceramic stain control agents that allow.
Present invention produces following beneficial effect:
The present invention is organically combined by high containing hydrogen silicone oil, silicon oil of low hydrogen content, 107 silicon rubber, silane coupling agent and No. 120 solvent oils, has both ensured didirtresistance and outward appearance, and in turn ensure that the quality problems that there will not be sticky brick and variable color.Nontoxic corrosion-free, its surface is simply smeared and effectively can be protected it, the rete of stain control agent is glossy attractive in appearance, while not affecting ceramic tile surface glossiness, resist the infiltration of the pollutents such as oil pen, ink, coffee, tea well, after ceramic tile packing, do not have the risk of sticky brick.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but the present invention's scope required for protection is not limited to the scope involved by embodiment.
Ceramic tile antifouling agent described in the disclosure is made up of following raw material by mass percentage: the methyl height containing hydrogen silicone oil of 6 ~ 16%, the silicon oil of low hydrogen content of 2 ~ 12%, 107 silicon rubber of 4 ~ 12%, the silane coupling agent of 0.1 ~ 1%, No. 120 solvent oils of 65 ~ 85%.
Described methyl height containing hydrogen silicone oil hydrogen content is 1.4% ~ 1.6%, 25 DEG C of viscosity is 15 ~ 30mm
2s
-1.
Described silicon oil of low hydrogen content hydrogen content is 0.1% ~ 1%, 25 DEG C of viscosity is 80 ~ 300mm
2s
-1.
107 described silicon rubber are 5000 ~ 50000mm 25 DEG C of viscosity
2s
-1.
Described silane coupling agent is one or more in γ-aminopropyl triethoxysilane (KH-550), γ-glycidyl ether oxygen propyl trimethoxy silicane (KH-560), γ-(methacryloxypropyl) propyl trimethoxy silicane (KH-570), N-β-(aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane (DL602), N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS (KH792).
The mass percent summation of each raw material of described stain control agent is 100%.
Ceramic tile antifouling agent of the present invention is under the driving of No. 120 solvent oils, and organosilicon composition can penetrate in the minute aperture of ceramic tile fast, and solvent volatilizees fast.The a large amount of active Si-H key of methyl height containing hydrogen silicone oil can form antifouling rete with silane coupling agent cross-linking and curing reaction; Silicon oil of low hydrogen content also participates in reaction containing a small amount of active Si-H bond energy, but because hydrogen content is few, and the viscosity ratio height containing hydrogen silicone oil of silicon oil of low hydrogen content is large many, so while keeping antifouling rete oiliness, can greatly can also improve the erasibility of antifouling rete on the one hand as far as possible; 107 silicon rubber contain a small amount of terminal hydroxy group, also can participate in crosslinking reaction, are combined with antifouling rete, the more important thing is that full-bodied 107 silicon rubber are keeping rete glossy while, can increase the viscosity of stain control agent film greatly.Stain control agent viscosity increases, and after packing, after stacking pressurized, oil film can not flow and local accumulation, can not cause the problem of sticky brick, more can not because of oil film became uneven and cause ceramic tile variable color everywhere.
Embodiment 1
Under stirring by the methyl height containing hydrogen silicone oil of 6% mass parts, the silicon oil of low hydrogen content of 6% mass parts, 5% mass parts 5000mm
2s
-1107 silicon rubber add in No. 120 solvent oils of 82.7% mass parts successively, stir 5 minutes, last γ-the glycidyl ether oxygen propyl trimethoxy silicane adding 0.3% mass parts more while stirring, continue stirring 5 minutes, leave standstill and allow himself reaction can obtain ceramic tile antifouling agent of the present invention after 2 days.
Embodiment 2
Under stirring by the methyl height containing hydrogen silicone oil of 12% mass parts, the silicon oil of low hydrogen content of 6% mass parts, 8% mass parts 2000mm
2s
-1107 silicon rubber add in No. 120 solvent oils of 73.8% mass parts successively, stir 5 minutes, the last γ-aminopropyl triethoxysilane adding 0.2% mass parts more while stirring, continues stirring 5 minutes, leaves standstill and allows himself reaction can obtain ceramic tile antifouling agent of the present invention after 2 days.
Embodiment 3
Under stirring by the methyl height containing hydrogen silicone oil of 8% mass parts, the silicon oil of low hydrogen content of 12% mass parts, 10% mass parts 50000mm
2s
-1107 silicon rubber add in No. 120 solvent oils of 69.6% mass parts successively, stir 5 minutes, last N-β-(aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane adding 0.4% mass parts more while stirring, continue stirring 5 minutes, leave standstill and allow himself reaction can obtain ceramic tile antifouling agent of the present invention after 2 days.
Each embodiment in this specification sheets all adopts the mode of going forward one by one to describe, and what each embodiment stressed is the difference with other embodiments, between each embodiment identical similar part mutually see.For system embodiment, due to itself and embodiment of the method basic simlarity, so description is fairly simple, relevant part illustrates see the part of embodiment of the method.
Above to method provided by the present invention, be described in detail, apply specific case herein and set forth principle of the present invention and embodiment, the explanation of above embodiment just understands method of the present invention and core concept thereof for helping; Meanwhile, for one of ordinary skill in the art, according to thought of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (10)
1. a ceramic tile antifouling agent, it is characterized in that: described ceramic tile antifouling agent is made up of following raw material by mass percentage: the methyl height containing hydrogen silicone oil of 6 ~ 16%, the silicon oil of low hydrogen content of 2 ~ 12%, 107 silicon rubber of 4 ~ 12%, the silane coupling agent of 0.1 ~ 1%, No. 120 solvent oils of 65 ~ 85%.
2. stain control agent according to claim 1, is characterized in that: preferred, described methyl height containing hydrogen silicone oil hydrogen content is 1.4% ~ 1.6%, 25 DEG C of viscosity is 15 ~ 30mm
2s
-1.
3. stain control agent according to claim 1, is characterized in that: described silicon oil of low hydrogen content hydrogen content is 0.1% ~ 1%, 25 DEG C of viscosity is 80 ~ 300mm
2s
-1.
4. stain control agent according to claim 1, is characterized in that: 107 described silicon rubber are 5000 ~ 50000mm 25 DEG C of viscosity
2s
-1.
5. stain control agent according to claim 1, is characterized in that: one or more in described silane coupling agent γ-aminopropyl triethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-(methacryloxypropyl) propyl trimethoxy silicane, N-β-(aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS.
6. stain control agent according to claim 1, is characterized in that: the mass percent summation of each raw material of described stain control agent is 100%.
7. stain control agent according to claim 1, is characterized in that: described stain control agent is made up of No. 120 solvent oils of the silicon oil of low hydrogen content of the methyl height containing hydrogen silicone oil of 6% mass parts, 6% mass parts, 107 silicon rubber of 5% mass parts, the γ-glycidyl ether oxygen propyl trimethoxy silicane of 0.3% mass parts and 82.7% mass parts.
8. stain control agent according to claim 1, is characterized in that: described stain control agent is made up of the γ-aminopropyl triethoxysilane of the silicon oil of low hydrogen content of the methyl height containing hydrogen silicone oil of 12% mass parts, 6% mass parts, 107 silicon rubber of 8% mass parts, No. 120 solvent oils of 73.8% mass parts and 0.2% mass parts.
9. stain control agent according to claim 1, is characterized in that: described stain control agent is made up of N-β-(aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane of the silicon oil of low hydrogen content of the methyl height containing hydrogen silicone oil of 8% mass parts, 12% mass parts, 107 silicon rubber of 10% mass parts, No. 120 solvent oils of 69.6% mass parts and 0.4% mass parts.
10. prepare a method for ceramic tile antifouling agent, described method prepares the arbitrary stain control agent described in claim 1-9, it is characterized in that: said method comprising the steps of,
S100, under stirring methyl height containing hydrogen silicone oil, silicon oil of low hydrogen content, 107 silicon rubber are added in No. 120 solvent oils successively, stir 1 ~ 5 minute;
S200, continue to add silane coupling agent while stirring, then stir 1 ~ 5 minute;
S300, standing himself reaction 2 ~ 5 days generation ceramic stain control agents that allow.
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| CN201510026840.XA CN104559766B (en) | 2015-01-19 | 2015-01-19 | Antifouling compound for ceramic tiles and preparation method thereof |
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| CN201510026840.XA CN104559766B (en) | 2015-01-19 | 2015-01-19 | Antifouling compound for ceramic tiles and preparation method thereof |
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| CN104559766A true CN104559766A (en) | 2015-04-29 |
| CN104559766B CN104559766B (en) | 2017-01-18 |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105907298A (en) * | 2016-05-25 | 2016-08-31 | 郑州翱翔医药科技股份有限公司 | Grafted rubber plug spraying fluid and treatment method of grafted rubber plug spraying fluid on surface of rubber plug |
| CN108911787A (en) * | 2017-03-26 | 2018-11-30 | 沈开湘 | A kind of protective process technology of stone surface |
| CN110499098A (en) * | 2019-09-09 | 2019-11-26 | 佛山市大幸新材料有限公司 | A kind of antifouling protective agent of dumb light sheen ceramic tile |
| CN111004575A (en) * | 2019-12-19 | 2020-04-14 | 清远市宏图助剂有限公司 | Durable antifouling liquid and preparation method thereof |
| CN111019352A (en) * | 2019-11-26 | 2020-04-17 | 东莞市朗晟材料科技有限公司 | Silica gel for electric wire without sticking to conductor, preparation method and use method |
| CN111019521A (en) * | 2019-12-02 | 2020-04-17 | 广东新翔星科技股份有限公司 | Adhesive organic silicon protective agent and preparation method thereof |
| CN111363473A (en) * | 2020-02-18 | 2020-07-03 | 清远市宏图助剂有限公司 | Ceramic tile antifouling agent and preparation method thereof |
| CN112063298A (en) * | 2020-09-18 | 2020-12-11 | 上海承一化学科技有限公司 | Multifunctional antifouling agent and preparation method thereof |
| CN112063299A (en) * | 2020-09-27 | 2020-12-11 | 广东粤固建材科技有限公司 | Ceramic tile antifouling agent and preparation method thereof |
| CN112143276A (en) * | 2020-08-28 | 2020-12-29 | 佛山市思特四通科技有限公司 | Antifouling auxiliary agent for automobile varnish and preparation method and application thereof |
| CN116217179A (en) * | 2023-03-24 | 2023-06-06 | 佛山市维配可建材有限公司 | High-cohesiveness anti-aging tile adhesive and preparation method thereof |
| CN117025094A (en) * | 2023-10-09 | 2023-11-10 | 广东纳德新材料有限公司 | Preparation method and application of low-cost anti-seepage ceramic tile anti-fouling agent |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105907298B (en) * | 2016-05-25 | 2017-12-22 | 郑州翱翔医药科技股份有限公司 | A kind of graft type plug spray coating liquor and its processing method to plug surface |
| CN105907298A (en) * | 2016-05-25 | 2016-08-31 | 郑州翱翔医药科技股份有限公司 | Grafted rubber plug spraying fluid and treatment method of grafted rubber plug spraying fluid on surface of rubber plug |
| CN108911787A (en) * | 2017-03-26 | 2018-11-30 | 沈开湘 | A kind of protective process technology of stone surface |
| CN110499098A (en) * | 2019-09-09 | 2019-11-26 | 佛山市大幸新材料有限公司 | A kind of antifouling protective agent of dumb light sheen ceramic tile |
| CN111019352A (en) * | 2019-11-26 | 2020-04-17 | 东莞市朗晟材料科技有限公司 | Silica gel for electric wire without sticking to conductor, preparation method and use method |
| CN111019521A (en) * | 2019-12-02 | 2020-04-17 | 广东新翔星科技股份有限公司 | Adhesive organic silicon protective agent and preparation method thereof |
| CN111004575A (en) * | 2019-12-19 | 2020-04-14 | 清远市宏图助剂有限公司 | Durable antifouling liquid and preparation method thereof |
| CN111363473A (en) * | 2020-02-18 | 2020-07-03 | 清远市宏图助剂有限公司 | Ceramic tile antifouling agent and preparation method thereof |
| CN112143276A (en) * | 2020-08-28 | 2020-12-29 | 佛山市思特四通科技有限公司 | Antifouling auxiliary agent for automobile varnish and preparation method and application thereof |
| CN112063298A (en) * | 2020-09-18 | 2020-12-11 | 上海承一化学科技有限公司 | Multifunctional antifouling agent and preparation method thereof |
| CN112063299A (en) * | 2020-09-27 | 2020-12-11 | 广东粤固建材科技有限公司 | Ceramic tile antifouling agent and preparation method thereof |
| CN116217179A (en) * | 2023-03-24 | 2023-06-06 | 佛山市维配可建材有限公司 | High-cohesiveness anti-aging tile adhesive and preparation method thereof |
| CN116217179B (en) * | 2023-03-24 | 2023-08-08 | 佛山市维配可建材有限公司 | High-cohesiveness anti-aging tile adhesive and preparation method thereof |
| CN117025094A (en) * | 2023-10-09 | 2023-11-10 | 广东纳德新材料有限公司 | Preparation method and application of low-cost anti-seepage ceramic tile anti-fouling agent |
| CN117025094B (en) * | 2023-10-09 | 2023-12-26 | 广东纳德新材料有限公司 | Preparation method and application of low-cost anti-seepage ceramic tile anti-fouling agent |
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