CN104559662A - Wear-resisting type paint for dry bulk carrier cargo hold - Google Patents

Wear-resisting type paint for dry bulk carrier cargo hold Download PDF

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Publication number
CN104559662A
CN104559662A CN201410837970.7A CN201410837970A CN104559662A CN 104559662 A CN104559662 A CN 104559662A CN 201410837970 A CN201410837970 A CN 201410837970A CN 104559662 A CN104559662 A CN 104559662A
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China
Prior art keywords
cargo hold
wear
raw material
type coating
resistant type
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CN201410837970.7A
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Chinese (zh)
Inventor
谢韶春
任卫东
鲁雪明
俞豪
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HILONG PETROLEUM INDUSTRY GROUP Co Ltd
SHANGHAI HILONG SHINE NEW MATERIAL CO Ltd
SHANGHAI HILONG OIL CHEMICAL RESEARCH INSTITUTE
Original Assignee
HILONG PETROLEUM INDUSTRY GROUP Co Ltd
SHANGHAI HILONG SHINE NEW MATERIAL CO Ltd
SHANGHAI HILONG OIL CHEMICAL RESEARCH INSTITUTE
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Priority to CN201410837970.7A priority Critical patent/CN104559662A/en
Publication of CN104559662A publication Critical patent/CN104559662A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses wear-resisting type paint for a dry bulk carrier cargo hold. The wear-resisting paint comprises raw materials of components in percentage by weight as follows: 18%-30% of epoxy resin adopting one of E-54 epoxy resin, E-51 epoxy resin, E-42 epoxy resin and E-20 epoxy resin, 36%-55% of powder filler, 0.2%-5% of an auxiliary adopting one of organobentonite, fumed silica, hydrogenated castor oil or polyamide wax, 0.5%-5% of a tinting pigments adopting one or two of iron oxide red, iron oxide black and titanium dioxide, 10%-20% of solvents adopting one or two of n-butanol, dimethylbenzene and trimethylbenzene as well as 10%-18% of an epoxy curing agent adopting a polyamide curing agent or a phenol-aldehyde amine curing agent. The paint has good mechanical performance, a test result meets and far exceeds GB/T9262 marine cargo hold paint specifications, as a special paint, the wear-resisting type paint can effectively protect steel plates on the bottom layer and side walls of the dry bulk carrier cargo hold for more than five years, the maintenance time of a dry bulk carrier is shortened, and the operation cost is reduced.

Description

Bulk Cargo Ship cargo hold wear-resistant type coating
Technical field
The present invention relates to industrial coating technical field, specifically, is a kind of wear-resistant type coating being applicable to sea-freight Bulk Cargo Ship cargo hold.
Background technology
Will use a large amount of transport ships in sea-freight process, Bulk Cargo Ship is a kind of ship type wherein, is the boats and ships in order to load without packaging bulk supply tariff, is exclusively used in goods and materials in bulk such as transporting coal, sandstone, cereal, chemical fertilizer, cement, iron and steel.In the handling and transportation of described goods; the hard particle of goods can form grazing to cargo hold coatingsurface and scratch, and causes some mechanical injuries, thus affects the protective effect of cargo hold surface oil lacquering; cargo hold steel plates is got rusty, corrodes, cause Ship Life to shorten.Therefore, the wear resisting property of cargo hold coating is to safeguarding that the normal operation of Bulk Cargo Ship has very important effect.
At present, on boats and ships Coating Market, cargo hold coating products is mainly based on alkyd, modified epoxy or pure epoxy product, they can be competent at for delivering in bulk compared with soft goods such as cereal, chemical fertilizer, cement preferably, but harder goods in bulk, such as coal, sandstone, iron and steel etc., the coating on meeting major injury cargo hold surface, if and corrosion occurs for cargo hold bottom and sidewall steel plate, normal operation and the work-ing life of Bulk Cargo Ship can be had a strong impact on.
Summary of the invention
The object of the invention is to solve the problem, provide a kind of Bulk Cargo Ship cargo hold wear-resistant type coating, it uses two component epoxy and solidifying agent to be basic film forming matter, is aided with solid wear resistant powder stuffing, has shock-resistant and wear-resisting better mechanical property.As speciality coating, can be effective protection that Bulk Cargo Ship cargo hold provides more than 5 years.
For achieving the above object, this invention takes following technical scheme.
A kind of Bulk Cargo Ship cargo hold wear-resistant type coating, it is characterized in that, in its component, the weight percent of each raw material is:
Epoxy resin 18 ~ 30%;
Powder stuffing 36 ~ 55%;
Auxiliary agent 0.2 ~ 5%;
Tinting pigment 0.5 ~ 5%;
Solvent 10 ~ 20%;
Epoxy hardener 10 ~ 18%.
A kind of Bulk Cargo Ship cargo hold wear-resistant type coating, it is characterized in that, in its component, the weight percent of each raw material is:
Epoxy resin 21 ~ 25%;
Powder stuffing 40 ~ 50%;
Auxiliary agent 0.2 ~ 2%;
Tinting pigment 2 ~ 4%;
Solvent 12 ~ 15%;
Epoxy hardener 12 ~ 16%.
Further, described coating also comprises the C9 petroleum resin that weight percent is 6.5%.
Further, described epoxy resin is bisphenol A epoxide resin, is selected from the one of E-54, E-51, E-42, E-20 epoxy resin.
Further, described powder stuffing be mica powder, talcum powder, quartz sand, ground barium sulfate, Feldspar Powder, kaolin, aluminium vanadine, iron mica powder one or both.
Further, described auxiliary agent is the one of organobentonite, aerosil, hydrogenated castor oil or polyamide wax.
Further, described tinting pigment be red iron oxide, iron oxide black, titanium dioxide one or both.
Further, described solvent be propyl carbinol, dimethylbenzene, trimethylbenzene one or both.
Further, described epoxy hardener is polyamide curing agent or pnenolic aldehyde amine hardener.
The positively effect of Bulk Cargo Ship cargo hold wear-resistant type coating of the present invention is:
There is excellent mechanical property, its test result meets and considerably beyond the regulation of GB GB/T 9262 cargo hold paint peculiar to vessel, as a kind of speciality coating, can be effective protection that the bottom of Bulk Cargo Ship cargo hold and sidewall steel plate provide more than 5 years, the interval time of Bulk Cargo Ship dock repair can be reduced, be conducive to cutting operating costs.
Embodiment
Below provide the embodiment of Bulk Cargo Ship cargo hold wear-resistant type coating of the present invention, provide 16 embodiments.But it should be pointed out that enforcement of the present invention is not limited to following embodiment.
embodiment 1
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 30%, the E-51 bisphenol A epoxide resin of the NPEL-128 model adopting South Epoxy Resin (Kunshan) Co., Ltd. to produce.
Talcum powder 26%, employing Pingdu City generation outstanding chemical industry stone flour company limited produces, model is the product of PDSJ-150.
Mica powder 10%, adopts the 325 order mica powders that Fuyang mica products factory produces.
Organobentonite 0.5%, employing Zhejiang Fenghong New Material Co., Ltd. produces, model is the organobentonite of HF-120.
Red iron oxide 3%, adopts that Shanghai Yipin Pigments Co., Ltd. produces, that model is S190 red iron oxide product.
Propyl carbinol 3.5%, adopts the product of specialized market supply.
Dimethylbenzene 9%, adopts the product of specialized market supply.
Polyamide curing agent 18%, adopts that Air Products company produces, that model is SUNMIDE 305*70 product.
(2) the Bulk Cargo Ship cargo hold preparation method of wear-resistant type coating of embodiment 1, comprises the following steps:
(1) in clean high speed dispersion cylinder, propyl carbinol and diformazan benzo unlatching high speed dispersor is added by proportioning.
(2) under the rotating speed of 200 ~ 400r/min, slowly epoxy resin is added by proportioning, until epoxy resin dissolves completely.
(3) under the rotating speed of 200 ~ 400r/min, add organobentonite by proportioning, after 10 ~ 20 minutes, detect plastic situation.
(4) add red iron oxide, talcum powder, mica powder successively by proportioning under the rotating speed at 400 ~ 600r/min after plastic is complete, and rotating speed is adjusted to 800 ~ 1000r/min, dispersion 20 ~ 30min, fineness controls within 80 μm.
(5) cool the temperature to less than 35 DEG C, filter and package as first component.
(6) in the high speed dispersion cylinder that other a bite is clean, add polyamide curing agent by proportioning, filter and package as component B.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 1
By the first and second components of preparing of method of describing above by after proportioning mixing, can use Airless spraying, roller coating or brushing method at cargo hold steel plates surface construction wear-resistant paint of the present invention.During construction surface of steel plate should clean, dry and contamination-free, adopt sandblast cleaning process to Sa2.5 (ISO 8501-1:2007 standard).
embodiment 2
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
The raw material that epoxy resin 18%(adopts is with embodiment 1).
The raw material that talcum powder 38%(adopts is with embodiment 1).
The raw material that mica powder 16%(adopts is with embodiment 1).
The raw material that organobentonite 0.5%(adopts is with embodiment 1).
The raw material that red iron oxide 3.5%(adopts is with embodiment 1).
The raw material that propyl carbinol 4%(adopts is with embodiment 1).
The raw material that dimethylbenzene 10%(adopts is with embodiment 1).
The raw material that polyamide curing agent 10%(adopts is with embodiment 1).
(2) the Bulk Cargo Ship cargo hold of embodiment 2 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 2 is with embodiment 1.
embodiment 3
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
The raw material that epoxy resin 25%(adopts is with embodiment 1).
The raw material that talcum powder 28%(adopts is with embodiment 1).
The raw material that mica powder 12%(adopts is with embodiment 1).
The raw material that organobentonite 0.5%(adopts is with embodiment 1).
The raw material that red iron oxide 3.5%(adopts is with embodiment 1).
The raw material that propyl carbinol 4.5%(adopts is with embodiment 1).
The raw material that dimethylbenzene 10.5%(adopts is with embodiment 1).
The raw material that polyamide curing agent 16%(adopts is with embodiment 1).
(2) the Bulk Cargo Ship cargo hold of embodiment 3 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 3 is with embodiment 1.
embodiment 4
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
The raw material that epoxy resin 21%(adopts is with embodiment 1).
The raw material that talcum powder 35%(adopts is with embodiment 1).
The raw material that mica powder 15%(adopts is with embodiment 1).
The raw material that organobentonite 0.5%(adopts is with embodiment 1).
The raw material that red iron oxide 3.5%(adopts is with embodiment 1).
The raw material that propyl carbinol 3%(adopts is with embodiment 1).
The raw material that dimethylbenzene 10%(adopts is with embodiment 1).
The raw material that polyamide curing agent 12%(adopts is with embodiment 1).
(2) the Bulk Cargo Ship cargo hold of embodiment 4 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 4 is with embodiment 1.
embodiment 5
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
The raw material that epoxy resin 21%(adopts is with embodiment 1).
C9 petroleum resin 6.5%, employing Shandong Qi Long Chemical Co., Ltd. produces, model is the product of PR-130.
The raw material that talcum powder 31.5%(adopts is with embodiment 1).
The raw material that mica powder 13.5%(adopts is with embodiment 1).
The raw material that organobentonite 0.5%(adopts is with embodiment 1).
The raw material that red iron oxide 3%(adopts is with embodiment 1).
The raw material that propyl carbinol 3%(adopts is with embodiment 1).
The raw material that dimethylbenzene 9%(adopts is with embodiment 1).
The raw material that polyamide curing agent 12%(adopts is with embodiment 1).
(2) the Bulk Cargo Ship cargo hold of embodiment 5 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 5 is with embodiment 1.
embodiment 6
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 21%, the E-54 bisphenol A epoxide resin of the NPEL-127 model adopting South Epoxy Resin (Kunshan) Co., Ltd. to produce.
The raw material that talcum powder 36%(adopts is with embodiment 1).
The raw material that mica powder 15%(adopts is with embodiment 1).
The raw material that organobentonite 0.5%(adopts is with embodiment 1).
The raw material that red iron oxide 3.5%(adopts is with embodiment 1).
Propyl carbinol 3%, adopts the product of specialized market supply.
Dimethylbenzene 10%, adopts the product of specialized market supply.
The raw material that polyamide curing agent 13%(adopts is with embodiment 1).
(2) the Bulk Cargo Ship cargo hold of embodiment 6 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 6 is with embodiment 1.
embodiment 7
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 23%, the E-42 bisphenol A epoxide resin of the NPEL-134 model adopting South Epoxy Resin (Kunshan) Co., Ltd. to produce.
Ground barium sulfate 47%, adopts pause that ultra-fine mineral products company limited produces, model of Yong'an City prestige to be the product of B44.
Organobentonite 0.5%, (raw material of employing is with embodiment 1).
Red iron oxide 3.5%, (raw material of employing is with embodiment 1).
Propyl carbinol 3%, adopts the product of specialized market supply.
Dimethylbenzene 11%, adopts the product of specialized market supply.
Polyamide curing agent 12%, (raw material of employing is with embodiment 1).
(2) the Bulk Cargo Ship cargo hold of embodiment 7 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 7 is with embodiment 1.
embodiment 8
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 25%, the E-20 bisphenol A epoxide resin of the NPES-901 model adopting South Epoxy Resin (Kunshan) Co., Ltd. to produce.
Quartz sand 44%, adopts that silicon is produced than section (Shanghai) mining industry company limited, that model is SILVERBOND 603 product.
Organobentonite 0.5%, (raw material of employing is with embodiment 1).
Red iron oxide 3.5%, (raw material of employing is with embodiment 1).
Propyl carbinol 4%, adopts the product of specialized market supply
Dimethylbenzene 11%, adopts the product of specialized market supply.
Solvent 15%, comprise adopt commercially available with commercially available.
Epoxy hardener 12%, (raw material of employing is with embodiment 1).
(2) the Bulk Cargo Ship cargo hold of embodiment 8 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 8 is with embodiment 1.
embodiment 9
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 25%, (raw material of employing is with embodiment 1).
Feldspar Powder 28%, employing Zhengzhou Jin Yuan micropowder material company limited produces, model is the product of JYJC-18.
Kaolin 15%, employing Zhengzhou Jin Yuan micropowder material company limited produces, model is the product of JYA-15.
Organobentonite 0.5%, (raw material of employing is with embodiment 1).
Red iron oxide 3.5%, (raw material of employing is with embodiment 1).
Propyl carbinol 3%, (raw material of employing is with embodiment 1).
Dimethylbenzene 11%, (raw material of employing is with embodiment 1).
Solvent 14%, comprise adopt commercially available with commercially available.
Polyamide curing agent 14%, (raw material of employing is with embodiment 1).
(2) the Bulk Cargo Ship cargo hold of embodiment 9 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 9 is with embodiment 1.
embodiment 10
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 25%, (raw material of employing is with embodiment 1).
Aluminium vanadine product 28%, employing Zhengzhou Jin Yuan micropowder material company limited produces, model is the product of JYL-18.
Iron mica powder 14%, adopts the 325 order iron mica powder that Tongling spiegel powder factory produces.
Organobentonite 0.5%, (raw material of employing is with embodiment 1).
Red iron oxide 3.5%, (raw material of employing is with embodiment 1).
Propyl carbinol 4%, adopts the product of specialized market supply.
Dimethylbenzene 11%, adopts the product of specialized market supply.
Polyamide curing agent 14%, (raw material of employing is with embodiment 1).
(2) the Bulk Cargo Ship cargo hold of embodiment 10 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 10 is with embodiment 1.
embodiment 11
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 21%, (raw material of employing is with embodiment 1).
Talcum powder 34.5%, (raw material of employing is with embodiment 1).
Mica powder 15%, (raw material of employing is with embodiment 1).
Aerosil 1%, employing WACKER company produces, model is the product of N20.
Red iron oxide 3.5%, (raw material of employing is with embodiment 1).
Propyl carbinol 3%, adopts the product of specialized market supply.
Dimethylbenzene 10%, adopts the product of specialized market supply.
Polyamide curing agent 18%, (raw material of employing is with embodiment 1).
(2) the Bulk Cargo Ship cargo hold of embodiment 11 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 11 is with embodiment 1.
embodiment 12
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 21%, (raw material of employing is with embodiment 1).
Talcum powder 34.5%, (raw material of employing is with embodiment 1).
Mica powder 15%, (raw material of employing is with embodiment 1).
Hydrogenated castor oil 1%, adopts that ELEMENTIS company produces, that model is THIXATROL ST product.
Red iron oxide 3.5%, (raw material of employing is with embodiment 1).
Propyl carbinol 3%, adopts the product of specialized market supply.
Dimethylbenzene 10%, adopts the product of specialized market supply.
Polyamide curing agent 12%, (raw material of employing is with embodiment 1).
(2) the Bulk Cargo Ship cargo hold of embodiment 12 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 12 is with embodiment 1.
embodiment 13
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 21%, (raw material of employing is with embodiment 1).
Talcum powder 34%, (raw material of employing is with embodiment 1).
Mica powder 14.5%, (raw material of employing is with embodiment 1).
Polyamide wax 2%, adopts that ELEMENTIS company produces, that model is DeuRheo 229 product.
Red iron oxide 3.5%, (raw material of employing is with embodiment 1).
Propyl carbinol 3%, (raw material of employing is with embodiment 1).
Dimethylbenzene 10%, (raw material of employing is with embodiment 1).
Pnenolic aldehyde amine hardener 12%, employing Cardolite company produces, model is the product of NX-2036.
(2) the Bulk Cargo Ship cargo hold of embodiment 13 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 13 is with embodiment 1.
embodiment 14
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 21%, (raw material of employing is with embodiment 1).
Talcum powder 35.3%, (raw material of employing is with embodiment 1).
Mica powder 14%, (raw material of employing is with embodiment 1).
Organobentonite 0.5%, (raw material of employing is with embodiment 1).
Iron oxide black 0.8%, employing Shanghai Yipin Pigments Co., Ltd. produces, model is the product of S723.
Titanium dioxide 2%, employing Jiangsu Zhentai Chemical Industry Co., Ltd. produces, model is the product of ZR-969.
Propyl carbinol 3%, adopts the product of specialized market supply
Dimethylbenzene 10%, adopts the product of specialized market supply
The raw material that pnenolic aldehyde amine hardener 13.4%(adopts is with embodiment 13).
(2) the Bulk Cargo Ship cargo hold of embodiment 14 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 14 is with embodiment 1.
embodiment 15
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 21%, (raw material of employing is with embodiment 1).
Talcum powder 35%, (raw material of employing is with embodiment 1).
Mica powder 15%, (raw material of employing is with embodiment 1).
Organobentonite 0.5%, (raw material of employing is with embodiment 1).
Red iron oxide 3.5%, (raw material of employing is with embodiment 1).
Propyl carbinol 3%, (raw material of employing is with embodiment 1).
Trimethylbenzene 10%, adopts the product of specialized market supply.
The raw material that pnenolic aldehyde amine hardener 12%(adopts is with embodiment 13).
(2) the Bulk Cargo Ship cargo hold of embodiment 15 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 15 is with embodiment 1.
embodiment 16
(1) a Bulk Cargo Ship cargo hold wear-resistant type coating, in its component, the weight percent of each raw material is:
Epoxy resin 21%, (raw material of employing is with embodiment 1).
Talcum powder 34%, (raw material of employing is with embodiment 1).
Mica powder 14%, (raw material of employing is with embodiment 1).
Organobentonite 0.5%, (raw material of employing is with embodiment 1).
Red iron oxide 3.5%, (raw material of employing is with embodiment 1).
Propyl carbinol 3%, (raw material of employing is with embodiment 1).
Dimethylbenzene 10%, (raw material of employing is with embodiment 1).
The raw material that pnenolic aldehyde amine hardener 14%(adopts is with embodiment 13).
(2) the Bulk Cargo Ship cargo hold of embodiment 16 by the preparation method of wear-resistant type coating with embodiment 1.
(3) the Bulk Cargo Ship cargo hold using method of wear-resistant type coating prepared of embodiment 16 is with embodiment 1.
By the regulation of the standards such as GB GB/T 9262, Bulk Cargo Ship cargo hold wear-resistant type coating prepared by embodiment 1-embodiment 16 is detected, with the construction of 100 microns of builds in sandblasting to the steel surface of Sa2.5 (ISO 8501-1), its detected result is in table 1.
Bulk Cargo Ship cargo hold wear-resistant type coating property table look-up prepared by table 1. embodiment 1-16
。
By the situation of detected result, the performance of Bulk Cargo Ship cargo hold wear-resistant type coating of the present invention has met and exceeded the standard regulation of standard GB/T/T 9262 cargo hold paint peculiar to vessel, as a kind of wear-resistant type speciality coating, can be effective protection that the bottom of Bulk Cargo Ship cargo hold and sidewall steel plate provide more than 5 years.

Claims (9)

1. a Bulk Cargo Ship cargo hold wear-resistant type coating, is characterized in that, in its component, the weight percent of each raw material is:
2. a Bulk Cargo Ship cargo hold wear-resistant type coating, is characterized in that, in its component, the weight percent of each raw material is:
3. Bulk Cargo Ship cargo hold wear-resistant type coating according to claim 1 and 2, is characterized in that, described coating also comprises the C9 petroleum resin that weight percent is 6.5%.
4. Bulk Cargo Ship cargo hold wear-resistant type coating according to claim 1 and 2, it is characterized in that, described epoxy resin is bisphenol A epoxide resin, is selected from the one of E-54, E-51, E-42, E-20 epoxy resin.
5. Bulk Cargo Ship cargo hold wear-resistant type coating according to claim 1 and 2, is characterized in that, described powder stuffing be mica powder, talcum powder, quartz sand, ground barium sulfate, Feldspar Powder, kaolin, aluminium vanadine, iron mica powder one or more.
6. Bulk Cargo Ship cargo hold wear-resistant type coating according to claim 1 and 2, it is characterized in that, described auxiliary agent is the one of organobentonite, aerosil, hydrogenated castor oil or polyamide wax.
7. Bulk Cargo Ship cargo hold wear-resistant type coating according to claim 1 and 2, is characterized in that, described tinting pigment be red iron oxide, iron oxide black, titanium dioxide one or both.
8. Bulk Cargo Ship cargo hold wear-resistant type coating according to claim 1 and 2, is characterized in that, described solvent be propyl carbinol, dimethylbenzene, trimethylbenzene one or both.
9. Bulk Cargo Ship cargo hold wear-resistant type coating according to claim 1 and 2, it is characterized in that, described epoxy hardener is polyamide curing agent or pnenolic aldehyde amine hardener.
CN201410837970.7A 2014-12-25 2014-12-25 Wear-resisting type paint for dry bulk carrier cargo hold Pending CN104559662A (en)

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CN104877522A (en) * 2015-06-05 2015-09-02 广西大学 Antiseptic and anti-slip coating with sun protection and low heat energy absorption
CN105670225A (en) * 2016-02-19 2016-06-15 厦门冠力塑胶科技有限公司 High-molecular cement-surface moisture-proof agent formula
CN106280898A (en) * 2016-08-29 2017-01-04 天津美士邦涂料化工有限公司 A kind of preparation method of high pressure resistant tough epoxy coating
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Cited By (5)

* Cited by examiner, † Cited by third party
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CN104877522A (en) * 2015-06-05 2015-09-02 广西大学 Antiseptic and anti-slip coating with sun protection and low heat energy absorption
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CN106280898A (en) * 2016-08-29 2017-01-04 天津美士邦涂料化工有限公司 A kind of preparation method of high pressure resistant tough epoxy coating
CN107964325A (en) * 2017-10-09 2018-04-27 江苏海晟涂料有限公司 A kind of wear-resisting ship coating of impact resistance and preparation method thereof

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Application publication date: 20150429