CN104559262B - Energy-saving environment-friendly asphalt and preparation method thereof - Google Patents
Energy-saving environment-friendly asphalt and preparation method thereof Download PDFInfo
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- CN104559262B CN104559262B CN201510018950.1A CN201510018950A CN104559262B CN 104559262 B CN104559262 B CN 104559262B CN 201510018950 A CN201510018950 A CN 201510018950A CN 104559262 B CN104559262 B CN 104559262B
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Abstract
The invention belongs to the technical field of materials for road engineering, and provides energy-saving environment-friendly asphalt which is characterized by consisting of the following components in parts by weight: 100 parts of soft asphalt, 20-35 parts of natural asphalt, 10-20 parts of biological asphalt, 5-10 parts of a diluting agent, 2-5 parts of a tackifier and 1-3 parts of a plasticizer. The invention also provides a preparation process of the energy-saving environment-friendly asphalt. The process is simple and convenient to operate, can be used for reducing the mixing temperature and is beneficial for energy conservation and environmental protection. According to the energy-saving environment-friendly asphalt provided by the invention, the high-temperature viscosity is reduced and the fluidity is improved, so that the mixing and construction temperatures are reduced by 10-20 DEG C, energy sources are saved, the discharge of polluting gases is reduced, the environmental protection performance is good, and meanwhile, the pavement performance of an asphalt mixture is improved, and the high-temperature rut resistance, low-temperature cracking resistance and water stability are significantly improved.
Description
Technical field
The invention belongs to road engineering uses field of material technology, and in particular to a kind of energy saving and environment friendly pitch and its preparation
Technique.
Background technology
It is one long-term strategic task of China to build a resource-conserving and environment-friendly society, in road project
In, China《Communications and transportation " 12 " development plan》Warm-mixed asphalt is paved the way technology as highway construction energy-saving and emission-reduction demonstration
Promote engineering.But at present both at home and abroad warm mix technology is while bituminous mixture construction temperature is reduced, also can necessarily journey
The part pavement performance of compound is damaged on degree, and warm-mixing agent price is generally expensive, while the production for needing addition special sets
It is standby, hinder its popularization and application.Simultaneously substantial amounts of CO is also discharged in construction in bituminous paving2、CO、SO2And NOxDeng gas and
Dust, and more multi-energy is consumed in bituminous mixture, thus exacerbates the destruction to environment and to can not be again
The consumption in production-goods source, along with serious waste of resources such as straw, animal wastes, white garbage cannot be recycled, these
The theory of sustainable development is not necessarily met.Additionally, urban road is typically all constructed at night, temperature is relatively low, cold district and
Highlands, also than relatively low, the construction temperature having high demands in low ambient temperature conditions must be paid more its environment temperature
Big cost.So, using a kind of energy saving and environment friendly pitch, waste resource is made full use of, asphalt pavement construction temperature is reduced, subtract
The discharge of of low pollution gas, energy saving and resource, so as to effectively alleviate deficiency above, while improving the road of asphalt
Use performance.
The content of the invention
For the deficiencies in the prior art, it is an object of the present invention to provide a kind of low energy-saving ring of construction temperature
Guarantor's type pitch and its preparation technology.
In order to realize object above, the technical scheme of energy saving and environment friendly pitch of the invention is：
In terms of parts by weight, including consisting of part：
Described fluxed bitumen is in Liaohe River petrochemical industry 110# matrix pitch, 130# matrix pitches and 160# matrix pitches
Kind.
Described bitumen is kir or lake asphalt；Wherein lake asphalt is Trinidad Lake Asphalt.
Described Biological asphalt is obtained by biological reduced fuel oil, and 15 DEG C of needle penetrations are 6.0～7.0mm, and softening point is 40
～50 DEG C, 15 DEG C of ductilities are 6～12cm.
Described diluent is the one kind or several in waste lubricating oil, waste oil, vegetable oil, turpentine oil and furfural extract oil
Kind.
Described tackifier are epoxy resin, polyurethane, polyamide, Petropols and PET
In one or several.
Described plasticizer is waste rubber powder, waste or used plastics, cellulose powder, powder styrene butadiene rubber sbr and powder heat
One or several in plasticity butadiene-styrene rubber SBS.
The technical scheme of preparation technology of the present invention is：
Comprise the following steps：
1) in terms of parts by weight, in order successively by 10～20 parts of Biological asphalt, 2～5 parts of tackifier and 1～3 part
Plasticizer be mixed and stirred for uniformly, obtaining mixture A；
2) 100 parts of fluxed bitumens are taken and is heated to molten condition, then the fluxed bitumen of molten condition is poured in mixing plant；
3) 5～10 parts of diluent is added to into step 2) fluxed bitumen in, stir, obtain mixture B；
4) 20～35 parts of bitumens are added in mixture B, are stirred in the molten state, obtain mixture C；
5) again by mixture A be added to stirring in mixture C in, be uniformly mixing to obtain mixture D；
6) mixture D is taken out, 50～70min is developed in 140～160 DEG C of constant temperature oven, obtain energy saving and environment friendly drip
It is blue or green.
The step 2) in fluxed bitumen 140～160 DEG C melting.
The rotating speed of the mixing plant be 300～500r/min, step 4) in 145～150 DEG C stir 25～35min,
Step 5) 8～12min of middle stirring.
Compared with prior art, beneficial has the technical effect that the present invention：
Biological asphalt and bitumen in instant component is brought into its flourishing network structure in fluxed bitumen, improves
Molecular separating force based on hydrogen bond, enhances polar bond, is chemically crosslinked, be polymerized macromolecular network structure, so that
The viscosity of compound cementitious matter increases, and toughness strengthens, and anti-aging and anti-fatigue performance is improved；Tackifier and plasticizer not only change
It has been apt to the adhesiveness and mobility of fluxed bitumen, Biological asphalt and bitumen these three material asphalts, and ensure that it is high,
Cryogenic property, it is ensured that the stability of three kinds of material asphalts, plasticizer also have slacken the capillary of material asphalt molecule
Effect, so that the original micelle state of three kinds of material asphalts is destroyed, intermolecular friction is reduced, and plays plasticization.This
Bright energy saving and environment friendly pitch can reduce the high temperature viscosity of pitch, improve the mobility of pitch, can be with identical mobility
The construction temperature of reduction pitch, energy saving, and relatively low construction temperature so that dusty gas discharge capacity is few in work progress,
Good environmental protection.The energy saving and environment friendly pitch of the present invention can reduce the high temperature viscosity of pitch, improve the mobility of pitch, while
The performance of asphalt is improved, compared with common 160～180 DEG C of compound mix temperature, the energy-saving ring of the present invention
Guarantor's type pitch can reduce by 10～20 DEG C of mix and construction temperature, and high temperature anti-rut behavior, low temperature anti-cracking performance and water are steady
It is qualitative to be significantly increased；With energy-saving and emission-reduction, function admirable, with low cost, easy to operate, reliable in quality and can improve
The advantages such as the pavement performance of asphalt.
Further, energy saving and environment friendly pitch of the invention take full advantage of biological reduced fuel oil, waste lubricating oil, waste oil,
The waste resources such as waste rubber powder, waste or used plastics, turn waste into wealth, and economize on resources, reduces cost.
First Biological asphalt and tackifier, plasticizer mix are uniformly obtained into mixture A in preparation technology of the present invention, then will
The bitumen of molten condition is added after fluxed bitumen, diluent mixing, mix uniformly obtains mixture C, then mixture A
It is added in mixture C and is sufficiently stirred for so as to which mix uniformly obtains mixture D, finally develop complete in insulating box, obtains institute
Want energy saving and environment friendly pitch.Stir in the present invention sufficient, it is ensured that the uniformity of mixture D, it is ensured that energy saving and environment friendly pitch
Can be stable；Mixture D is developed completely in constant temperature oven, and its pavement performance is effectively ensured；Technological operation is easy, effectively reduces mixing
Temperature is closed, beneficial to energy-conserving and environment-protective.
Specific embodiment
Above-mentioned technical proposal is deferred to, following embodiments provide a kind of energy saving and environment friendly pitch, it is characterised in that with weight portion
Number meter, including consisting of part：100 parts of fluxed bitumens, 20～35 parts of bitumens, 10～20 parts of Biological asphalts, 5～10 parts
Diluent, 2～5 parts of tackifier, 1～3 part of plasticizer.
Wherein, fluxed bitumen is in 110# matrix pitches, 130# matrix pitches and the 160# matrix pitches of Liaohe River petrochemical industry
It is a kind of.
Bitumen is kir or lake asphalt；Lake asphalt used is Trinida (TLA) lake asphalt.
Biological asphalt, is obtained by biological reduced fuel oil, biological reduced fuel oil wide material sources, such as straw, animal wastes
The heavy oil fraction of biomass material thermal cracking, and the Biological asphalt for adopting in 15 DEG C of needle penetrations for 6.0～7.0mm, softening point
For 40～50 DEG C, 15 DEG C of ductilities are 6～12cm.
Diluent is the one kind in waste lubricating oil, waste oil, vegetable oil, turpentine oil and furfural extract oil or several groups
Into mixture.
Tackifier are in epoxy resin, polyurethane, polyamide, Petropols and PET
The mixture of kind or several compositions, epoxy resin is using domestic.
Plasticizer is waste rubber powder, waste or used plastics, cellulose powder, powder styrene butadiene rubber sbr and powder thermoplasticity fourth
The mixture of one or several compositions of benzene rubber SBS.
The energy saving and environment friendly pitch of the present invention takes full advantage of the biomass material thermal cracking such as straw, animal wastes
The waste resources such as heavy oil fraction, waste lubricating oil, waste oil, waste rubber powder and waste or used plastics, turn waste into wealth, and save money
Source, reduces cost.
The present invention also disclosed a kind of preparation technology of energy saving and environment friendly pitch, comprise the following steps：
1) in terms of parts by weight, in order successively by 10～20 parts of Biological asphalt, 2～5 parts of tackifier and 1～3 part
Plasticizer be mixed and stirred for uniformly, obtaining mixture A；
2) 100 parts of fluxed bitumens are taken and is warming up to 140～160 DEG C, make fluxed bitumen be heated to molten condition, then by molten
The fluxed bitumen of state is poured in the mixing plant that rotating speed is 300～500r/min；Shear in the range of 300～500r/min of rotating speed
Just can guarantee that raw material stirs with stirring compound, product property can just stablized；
3) 5～10 parts of diluent is added in the fluxed bitumen in mixing plant, is sufficiently stirred for, obtain mixture B；
4) 20～35 parts of bitumens are added in mixture B, at 145～150 DEG C mixture are kept molten by,
Persistently stir 25～35min to stir, obtain mixture C；
5) again by mixture A be added to stirring in mixture C in, stirring 8～12min be well mixed after obtain mixture
D；
6) mixture D is taken out, 50～70min is developed in 140～160 DEG C of constant temperature oven, development is complete, is guaranteed
The energy saving and environment friendly pitch of performance.
Mixing time of the present invention is sufficient, it is ensured that the uniformity of compound, it is ensured that energy saving and environment friendly asphalt performance is stablized；It is mixed
Close material and develop complete in insulating box, its pavement performance is effectively ensured；Technological operation is easy, effectively reduces mix temperature, is beneficial to
Energy-conserving and environment-protective；Obtained energy saving and environment friendly pitch can reduce the high temperature viscosity of pitch, improve the mobility of pitch, reduce mix
With 10～20 DEG C of construction temperature, energy saving, dusty gas discharge, good environmental protection, while improving asphalt are reduced
Performance, high temperature anti-rut behavior, low temperature anti-cracking performance and water stability are significantly increased.
With reference to China《Highway engineering pitch and Asphalt Mixture Experiment code》(JTJ 052-2000), is obtained pitch mixing
Material：Using basalt breeze, AC-13 mineral aggregate gradations, 4.3% bitumen aggregate ratio；First by energy saving and environment friendly pitch obtained in the present invention and
Gather materials and mix and stir 60s, add breeze to mix and stir 90s again, make asphalt.And surveyed using YLDCZ-8S full automatic vehicles track tester
Examination asphalt high temperature anti-rut behavior, using LETRY electro-hydraulic servos fatigue machine Asphalt Mixture at Low Temperature splitting resistance is tested
Can, stability of asphalt mixture energy is tested using the full-automatic Marshall tester of AMS-C types.
Embodiment 1：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 130# matrix pitches, 20 parts
Kir, 15 parts of Biological asphalts, 5 parts of diluents, and diluent adopt vegetable oil, 3 parts of polyamides as tackifier, 2 parts
Cellulose powder is used as plasticizer.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 15 parts of Biological asphalt, 3 parts of tackifier and 2 parts of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 130# matrix pitches are taken and is warming up to 140 DEG C, be heated to molten condition, then by the 130# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 130# matrix pitches 5 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture B；
4) 20 parts of kir are added in mixture B, persistently stir 25min at 145 DEG C and be well mixed, obtain mixture
C；
5) mixture A is added in the mixture C in stirring again, stirring 12min is well mixed and obtains mixture D；
6) mixture D is taken out, in 150 DEG C of constant temperature oven 70min is developed, obtain energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, (SBS changes for energy saving and environment friendly performance of asphalt mixture and SBS modified asphalt mixtures
Property asphalt be that current highway industry is most widely used, the best Load materials of performance) quite；Mix with 90# pitches
Material is compared, and high temperature anti-rut behavior improves 16%, and low temperature maximum flexural-tensile strain can improve 41%, and the full water Marshall of vacuum is steady
Fixed degree improves 4.8%.
Embodiment 2：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 110# matrix pitches, 25
Part Trinida (TLA) lake asphalt, 10 parts of Biological asphalt, 6 parts of waste lubricating oil as diluent, 3 parts of tackifier, 3
Part plasticizer.
Using 1 part of epoxy resin and the mixture of 2 parts of polyurethane, plasticizer adopts 0.5 part of waste old to wherein tackifier
Powder, 1 part of waste or used plastics, 0.5 part of cellulose powder, 0.5 part of powder styrene butadiene rubber sbr and 0.5 part of powder thermoplastic styrene butadiene rubber
The mixture of SBS.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 10 parts of Biological asphalt, 3 parts of tackifier and 3 parts of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 110# matrix pitches are taken and is warming up to 145 DEG C, be heated to molten condition, then by the 110# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 110# matrix pitches 6 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture B；
4) 25 parts of Trinida (TLA) lake asphalt are added in mixture B, persistently stir 25～35min at 150 DEG C straight
To being well mixed, mixture C is obtained；
5) mixture A is added in the mixture C in stirring again, stirring 8～12min until be well mixed is mixed
Thing D；
6) mixture D is taken out, in 142 DEG C of constant temperature oven 70min is developed, obtain energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, energy saving and environment friendly performance of asphalt mixture is suitable with SBS modified asphalt mixtures；With
90# asphalts are compared, and high temperature anti-rut behavior improves 22%, and low temperature maximum flexural-tensile strain can improve 37%, very
The full water Marshall stability of sky improves 3.8%.
Embodiment 3：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 160# matrix pitches, 30
Trinida (TLA) lake asphalt of part, 20 parts of Biological asphalt, 9 parts of diluents, 5 parts of tackifier, 3 parts of waste or used plastics are used as increasing
Modeling agent.
Wherein diluent is using 8 parts of waste oils and 1 part of terebinthine mixture, and tackifier are using 2 parts of polyurethane and 3 parts
The mixture of Petropols.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 20 parts of Biological asphalt, 5 parts of tackifier and 3 parts of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 160# matrix pitches are taken and is warming up to 150 DEG C, be heated to molten condition, then by the 160# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 160# matrix pitches 9 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture B；
4) 30 parts of Trinida (TLA) lake asphalt are added in mixture B, at 148 DEG C 35min is persistently stirred, obtained
Mixture C；
5) mixture A is added in the mixture C in stirring again, stirring 8～12min until be well mixed is mixed
Thing D；
6) mixture D is taken out, in 144 DEG C of constant temperature oven 65min is developed, obtain energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, energy saving and environment friendly performance of asphalt mixture is suitable with SBS modified asphalt mixtures；With
90# asphalts are compared, and high temperature anti-rut behavior improves 34%, and low temperature maximum flexural-tensile strain can improve 18%, very
The full water Marshall stability of sky improves 2.1%.
Embodiment 4：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 110# matrix pitches, 35
The kir of part, 13 parts of Biological asphalt, used as diluent, 5 parts of PETs are used as thickening for 7 parts of turpentine oil
Agent, 2 parts of plasticizer.
Wherein plasticizer is using 1 part of powder styrene butadiene rubber sbr and the mixture of 1 part of powder thermoplastic styrene butadiene rubber SBS.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 13 parts of Biological asphalt, 5 parts of tackifier and 2 parts of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 110# matrix pitches are taken and is warming up to 155 DEG C, be heated to molten condition, then by the 110# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 110# matrix pitches 7 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture B；
4) 35 parts of kir are added in mixture B, at 147 DEG C 32min is persistently stirred, obtain mixture C；
5) again by mixture A be added to stirring in mixture C in, stirring 10min obtain mixture D；
6) mixture D is taken out, in 160 DEG C of constant temperature oven 50min is developed, obtain energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, energy saving and environment friendly performance of asphalt mixture is suitable with SBS modified asphalt mixtures；With
90# asphalts are compared, and high temperature anti-rut behavior improves 37%, and low temperature maximum flexural-tensile strain can improve 13%, very
The full water Marshall stability of sky improves 6.5%.
Embodiment 5：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 130# matrix pitches, 22
Part Trinida (TLA) lake asphalt, 17 parts of Biological asphalt, 10 portions of furfural extract oils as diluent, 4 parts of tackifier, 3 parts
Plasticizer.
Using 2 parts of polyamides and the mixture of 2 parts of Petropols, plasticizer adopts 2 parts of waste and old modelings to wherein tackifier
The mixture of material and 1 part of cellulose powder.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 17 parts of Biological asphalt, 4 parts of tackifier and 3 parts of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 130# matrix pitches are taken and is warming up to 160 DEG C, be heated to molten condition, then by the 130# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 130# matrix pitches 10 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture
B；
4) 22 parts of Trinida (TLA) lake asphalt are added in mixture B, persistently stir 25～35min at 150 DEG C straight
To being well mixed, mixture C is obtained；
5) again by mixture A be added to stirring in mixture C in, stirring 10min obtain mixture D；
6) mixture D is taken out, in 148 DEG C of constant temperature oven 55min is developed, obtain energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, energy saving and environment friendly performance of asphalt mixture is suitable with SBS modified asphalt mixtures；With
90# asphalts are compared, and high temperature anti-rut behavior improves 18%, and low temperature maximum flexural-tensile strain can improve 35%, very
The full water Marshall stability of sky improves 8.4%.
Embodiment 6：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 160# matrix pitches, 28
Part kir, 12 parts of Biological asphalt, 9 parts of diluents, 2 parts of epoxy resin as tackifier, 2 parts of plasticizer.
Using 2 parts of vegetable oil and the mixture of 7 portions of furfural extract oils, plasticizer adopts 1 part of waste old to wherein diluent
The mixture of powder and 1 part of powder thermoplastic styrene butadiene rubber SBS.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 12 parts of Biological asphalt, 2 parts of tackifier and 2 parts of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 160# matrix pitches are taken and is warming up to 160 DEG C, be heated to molten condition, then by the 160# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 160# matrix pitches 9 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture B；
4) 28 parts of kir are added in mixture B, at 145 DEG C 34min is persistently stirred, obtain mixture C；
5) again by mixture A be added to stirring in mixture C in, stirring 11min obtain mixture D；
6) mixture D is taken out, in 153 DEG C of constant temperature oven 60min is developed, obtain energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, energy saving and environment friendly performance of asphalt mixture is suitable with SBS modified asphalt mixtures；With
90# asphalts are compared, and high temperature anti-rut behavior improves 33%, and low temperature maximum flexural-tensile strain can improve 28%, very
The full water Marshall stability of sky improves 7.9%.
Embodiment 7：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 110# matrix pitches, 24
Trinida (TLA) lake asphalt of part, 14 parts of Biological asphalt, 5 parts of diluents, 4 parts of tackifier, 3 parts of plasticizer.
Wherein diluent using 3 parts of waste lubricating oils and 2 parts of waste oils mixture, tackifier using 2 parts of polyurethane, 1
The mixture of part polyamide and 1 part of Petropols, plasticizer adopts 1 part of waste rubber powder, 1 part of waste or used plastics and 1 part of powder
The mixture of last cellulose.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 14 parts of Biological asphalt, 4 parts of tackifier and 3 parts of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 110# matrix pitches are taken and is warming up to 158 DEG C, be heated to molten condition, then by the 110# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 110# matrix pitches 5 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture B；
4) 24 parts of Trinida (TLA) lake asphalt are added in mixture B, are persistently stirred within the temperature range of 146 DEG C
30min is mixed, mixture C is obtained；
5) again by mixture A be added to stirring in mixture C in, stirring 9min obtain mixture D；
6) mixture D is taken out, in 158 DEG C of constant temperature oven 62min is developed, obtain energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, energy saving and environment friendly performance of asphalt mixture is suitable with SBS modified asphalt mixtures；With
90# asphalts are compared, and high temperature anti-rut behavior improves 35%, and low temperature maximum flexural-tensile strain can improve 15%, very
The full water Marshall stability of sky improves 6.2%.
Embodiment 8：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 110# matrix pitches, 26
Trinida (TLA) lake asphalt of part, 11 parts of Biological asphalt, 8 parts of diluents, 2 parts of tackifier, 3 parts of plasticizer.
Wherein diluent adopts 3 parts of waste lubricating oils, 4 parts of vegetable oil and 1 part of terebinthine mixture, tackifier to adopt 1
The mixture of part epoxy resin and 1 part of PET, plasticizer adopts 1 part of cellulose powder, 1 part of powder butylbenzene
The mixture of rubber SBR and 1 part of powder thermoplastic styrene butadiene rubber SBS.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 11 parts of Biological asphalt, 2 parts of tackifier and 3 parts of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 110# matrix pitches are taken and is warming up to 153 DEG C, be heated to molten condition, then by the 110# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 110# matrix pitches 8 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture B；
4) 26 parts of Trinida (TLA) lake asphalt are added in mixture B, are persistently stirred within the temperature range of 146 DEG C
28min is mixed, mixture C is obtained；
5) mixture A is added in the mixture C in stirring again, stirring 8～12min until be well mixed is mixed
Thing D；
6) mixture D is taken out, in 156 DEG C of constant temperature oven 53min is developed, obtain energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, energy saving and environment friendly performance of asphalt mixture is suitable with SBS modified asphalt mixtures；With
90# asphalts are compared, and high temperature anti-rut behavior improves 37%, and low temperature maximum flexural-tensile strain can improve 15%, very
The full water Marshall stability of sky improves 6.2%.
Embodiment 9：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 130# matrix pitches, 29
The kir of part, 16 parts of Biological asphalt, 6 parts of diluents, 3 parts of tackifier, 3 parts of powder thermoplastic styrene butadiene rubber SBS are used as increasing
Modeling agent.
Using 4 parts of waste oils and the mixture of 2 portions of furfural extract oils, tackifier adopt 2 parts of epoxy resin to wherein diluent
With the mixture of 1 part of Petropols.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 26 parts of Biological asphalt, 3 parts of tackifier and 3 parts of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 130# matrix pitches are taken and is warming up to 148 DEG C, be heated to molten condition, then by the 130# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 130# matrix pitches 6 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture B；
4) 29 parts of kir are added in mixture B, persistently 25～35min is stirred until being well mixed at 149 DEG C, obtained
To mixture C；
5) again by mixture A be added to stirring in mixture C in, stirring 8min obtain mixture D；
6) mixture D is taken out, in 146 DEG C of constant temperature oven 57min is developed, obtain wanted energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, energy saving and environment friendly performance of asphalt mixture is suitable with SBS modified asphalt mixtures；With
90# asphalts are compared, and high temperature anti-rut behavior improves 16%, and low temperature maximum flexural-tensile strain can improve 32%, very
The full water Marshall stability of sky improves 2.9%.
Embodiment 10：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 130# matrix pitches, 31
Trinida (TLA) lake asphalt of part, 18 parts of Biological asphalt, 8 parts of diluents, 5 parts of tackifier, 2 parts of plasticizer.
Using 4 parts of waste lubricating oils and 4 parts of terebinthine mixtures, tackifier adopt 3 parts of polyurethane and 2 to wherein diluent
The mixture of part polyamide, plasticizer is using 1 part of waste or used plastics and the mixture of 1 part of powder styrene butadiene rubber sbr.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 18 parts of Biological asphalt, 5 parts of tackifier and 2 parts of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 130# matrix pitches are taken and is warming up to 146 DEG C, be heated to molten condition, then by the 130# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 130# matrix pitches 8 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture B；
4) 31 parts of Trinida (TLA) lake asphalt are added in mixture B, persistently stir 25～35min at 149 DEG C straight
To being well mixed, mixture C is obtained；
5) mixture A is added in the mixture C in stirring again, stirring 8～12min until be well mixed is mixed
Thing D；
6) mixture D is taken out, in 155 DEG C of constant temperature oven 64min is developed, obtain energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, energy saving and environment friendly performance of asphalt mixture is suitable with SBS modified asphalt mixtures；With
90# asphalts are compared, and high temperature anti-rut behavior improves 33%, and low temperature maximum flexural-tensile strain can improve 38%, very
The full water Marshall stability of sky improves 7.1%.
Embodiment 11：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 160# matrix pitches, 33
Part kir, 19 parts of Biological asphalt, 9 parts of vegetable oil as diluent, 5 parts of tackifier, 3 parts of waste rubber powders are used as plasticising
Agent.
Wherein tackifier adopt epoxy resin, polyurethane, polyamide, Petropols and PET
Each 1 part of mixture.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 19 parts of Biological asphalt, 5 parts of tackifier and 3 parts of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 160# matrix pitches are taken and is warming up to 144 DEG C, be heated to molten condition, then by the 160# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 160# matrix pitches 9 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture B；
4) 33 parts of kir are added in mixture B, persistently 25～35min is stirred until being well mixed at 148 DEG C, obtained
To mixture C；
5) again by mixture A be added to stirring in mixture C in, stirring 9min obtain mixture D；
6) mixture D is taken out, in 151 DEG C of constant temperature oven 66min is developed, obtain wanted energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, energy saving and environment friendly performance of asphalt mixture is suitable with SBS modified asphalt mixtures；With
90# asphalts are compared, and high temperature anti-rut behavior improves 34%, and low temperature maximum flexural-tensile strain can improve 11%, very
The full water Marshall stability of sky improves 4.8%.
Embodiment 12：
A kind of energy-conserving and environment-protective pitch, in terms of parts by weight, including consisting of raw material：100 parts of 160# matrix pitches, 32
The kir of part, 10 parts of Biological asphalt, 7 parts of diluents, 4 parts of tackifier, 1 part of waste rubber powder is used as plasticizer.
Wherein diluent is using 4 parts of waste lubricating oils, the mixture of 1 portion of waste oil, 1 portion of plant and 1 portion of furfural extract oil；
Tackifier are using 4 parts of epoxy resin and the mixture of 1 part of polyamide.
The environment-friendly type pitch of the present embodiment is prepared according to following steps：
1) in terms of parts by weight, in order 10 parts of Biological asphalt, 4 parts of tackifier and 1 part of plasticizer mixed successively
Merging stirs, and obtains mixture A；
2) 100 parts of 160# matrix pitches are taken and is warming up to 142 DEG C, be heated to molten condition, then by the 160# bases of molten condition
Matter pitch is poured in the mixing plant that rotating speed is 300～500r/min；
3) in the 160# matrix pitches 7 parts of diluent being added in mixing plant, it is sufficiently stirred for, obtains mixture B；
4) 32 parts of kir are added in mixture B, at 147 DEG C 27min is persistently stirred, obtain mixture C；
5) again by mixture A be added to stirring in mixture C in, stirring 10min obtain mixture D；
6) mixture D is taken out, in 140 DEG C of constant temperature oven 68min is developed, obtain energy saving and environment friendly pitch.
7) asphalt is prepared, and is tested, performance test result such as table 2, table 3 and the table of asphalt
Shown in 4, the testing result from table draws, energy saving and environment friendly performance of asphalt mixture is suitable with SBS modified asphalt mixtures；With
90# asphalts are compared, and high temperature anti-rut behavior improves 37%, and low temperature maximum flexural-tensile strain can improve 13%, very
The full water Marshall stability of sky improves 3.7%.
The needle penetration of energy saving and environment friendly pitch, softening point, ductility and viscosity index are referred to obtained in various embodiments of the present invention
Table 1.
Asphalt, the corresponding drip of each embodiment are obtained according to energy saving and environment friendly pitch prepared by various embodiments of the present invention
The performance test result of blue or green compound is as shown in table 2, table 3 and table 4；The preparation side of wherein each embodiment Asphalt Mixture
The method of testing all same of method and properties.
The index test result of table 1
The asphalt high temperature anti-rut behavior test result of table 2
| 45min deformations/mm | 60min deformations/mm | Dynamic stability/(secondary .mm-1) | |
| Embodiment 1 | 1.750 | 1.900 | 3343.9 |
| Embodiment 2 | 1.339 | 1.450 | 3526.3 |
| Embodiment 3 | 1.650 | 1.750 | 3875 |
| Embodiment 4 | 1.574 | 1.652 | 3952.3 |
| Embodiment 5 | 1.550 | 1.800 | 3400.9 |
| Embodiment 6 | 1.350 | 1.480 | 3826.4 |
| Embodiment 7 | 1.656 | 1.790 | 3885 |
| Embodiment 8 | 1.594 | 1.552 | 3950.3 |
| Embodiment 9 | 1.800 | 1.575 | 3343.9 |
| Embodiment 10 | 1.567 | 1.450 | 3826.8 |
| Embodiment 11 | 1.657 | 1.650 | 3852.1 |
| Embodiment 12 | 1.584 | 1.365 | 3952.4 |
| 90# asphalts | 3.356 | 3.845 | 2883.3 |
| SBS asphalts | 1.6 | 1.317 | 4384.6 |
The Asphalt Mixture at Low Temperature anti-cracking performance test result of table 3
| Maximum flexural-tensile strain/μ ε | Bending tensile strength/MPa | Stiffness modulus/MPa | |
| Embodiment 1 | 2445.55 | 9.77 | 3558.99 |
| Embodiment 2 | 2381.29 | 9.23 | 3875.86 |
| Embodiment 3 | 2044.39 | 8.62 | 4638.61 |
| Embodiment 4 | 1965.22 | 8.42 | 4944.42 |
| Embodiment 5 | 2345.32 | 9.52 | 3623.24 |
| Embodiment 6 | 2221.32 | 9.41 | 3677.86 |
| Embodiment 7 | 2000.39 | 8.99 | 4352.61 |
| Embodiment 8 | 1995.22 | 8.95 | 4844.55 |
| Embodiment 9 | 2300.58 | 9.25 | 3421.56 |
| Embodiment 10 | 2391.32 | 9.65 | 3656.38 |
| Embodiment 11 | 1922.41 | 8.82 | 4253.32 |
| Embodiment 12 | 1956.75 | 9.02 | 4744.56 |
| 90# asphalts | 1738.96 | 9.24 | 3639.41 |
| SBS asphalts | 3283.31 | 11.63 | 3543.29 |
The stability of asphalt mixture energy test result of table 4
Claims (4)
1. a kind of energy saving and environment friendly pitch, it is characterised in that in terms of parts by weight, including consisting of part：
Described diluent is one or more in waste lubricating oil, waste oil, vegetable oil, turpentine oil and furfural extract oil；
Described tackifier are in epoxy resin, polyurethane, polyamide, Petropols and PET
One or several；Described fluxed bitumen is Liaohe River petrochemical industry 110# matrix pitch, 130# matrix pitches and 160# matrix pitches
In one kind；Biological asphalt is 6.0～7.0mm in 15 DEG C of needle penetrations, and softening point is 40～50 DEG C, and 15 DEG C of ductilities are 6～12cm；
Described plasticizer is waste rubber powder, waste or used plastics, cellulose powder, powder styrene butadiene rubber sbr and powder thermoplasticity butylbenzene
One or several in rubber SBS.
2. energy saving and environment friendly pitch as claimed in claim 1, it is characterised in that：Described bitumen is that kir or lake drip
It is blue or green；Wherein lake asphalt is Trinidad Lake Asphalt.
3. energy saving and environment friendly pitch as claimed in claim 1, it is characterised in that：Described Biological asphalt is by biological reduced fuel oil
It is obtained.
4. a kind of energy saving and environment friendly pitch preparation technology, it is characterised in that comprise the steps of：
1) in terms of parts by weight, in order successively by 10～20 parts of Biological asphalt, 2～5 parts of tackifier and 1～3 part of increasing
Modeling agent is mixed and stirred for uniformly, obtaining mixture A；
2) 100 parts of fluxed bitumens are taken and is warming up to 140～160 DEG C, make fluxed bitumen be heated to molten condition, then by molten condition
Fluxed bitumen is poured in the mixing plant that rotating speed is 300～500r/min；
3) 5～10 parts of diluent is added to into step 2) fluxed bitumen in, stir, obtain mixture B；
4) 20～35 parts of bitumens are added in mixture B, at 145～150 DEG C mixture B is kept molten by, held
25～35min of continuous stirring stirs, and obtains mixture C；
5) mixture A is added in the mixture C in stirring again, 8～12min of stirring is well mixed and obtains mixture D；
6) mixture D is taken out, 50～70min is developed in 140～160 DEG C of constant temperature oven, obtain energy saving and environment friendly pitch.
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| CN102408735B (en) * | 2011-10-12 | 2013-01-16 | 交通运输部公路科学研究所 | Composite asphalt modifier, composite modified asphalt and preparation method thereof |
| CN102766340A (en) * | 2012-08-13 | 2012-11-07 | 交通运输部公路科学研究所 | Modified biological asphalt material, biological asphalt mixture, preparation method thereof and applications |
| CN102796547B (en) * | 2012-08-13 | 2014-07-16 | 交通运输部公路科学研究所 | Biological asphalt, biological asphalt composition and preparation method |
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