CN104556509A - Tap water sterilization system based on membrane technology - Google Patents

Tap water sterilization system based on membrane technology Download PDF

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Publication number
CN104556509A
CN104556509A CN201410815824.4A CN201410815824A CN104556509A CN 104556509 A CN104556509 A CN 104556509A CN 201410815824 A CN201410815824 A CN 201410815824A CN 104556509 A CN104556509 A CN 104556509A
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water
water tank
tank
membrane
filter
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CN104556509B (en
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王波
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Xinyi stars new Mstar Technology Ltd
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Jiangsu Shuizhile Automation Equipment Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/442Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C02F1/62Heavy metal compounds
    • C02F1/64Heavy metal compounds of iron or manganese
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/10Photocatalysts
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents

Abstract

The invention provides a tap water sterilization system based on a membrane technology. The tap water sterilization system comprises an ozone sterilizer, a raw water tank, a lift pump, an active sand filter and an iron and manganese removing filter, an activated carbon filter, a water softener, a security filter, ultra-filtration equipment, nano-filtration equipment, an ultraviolet sterilizer and a sterile water storage tank which are connected through a pipeline in sequence, wherein a backflow forming device and a water tank filtering screen are arranged inside the raw water tank; the backflow forming device comprises an upper funnel-shaped part and a lower funnel-shaped part, a water flow passage is formed in the middle of the bottom of the upper funnel-shaped part, and the bottom of the lower funnel-shaped part is sealed; the water tank filtering screen is positioned below the backflow forming device; a water outlet is formed in the bottom of the raw water tank, and an ultraviolet lamp is arranged nearby the water outlet. Through the tap water sterilization system based on the membrane technology, the water quality of treated tap water can reach and exceed new edition Hygienic Standards for Drinking Water (GB5749-2006).

Description

A kind of tap water sterilization system based on membrane technique
Technical field
The present invention relates to a kind of tap water sterilization system based on membrane technique, belong to water-treatment technology field.
Background technology
Tap water refers to the water for people's life, production and application meeting respective standard by producing after water treatment plants purification, sterilization.Domestic water draws rivers and lakes and underground water mainly through the water intake pumping station of water factory, surface water, by waterworks according to " national Drinking Water related sanitary standard ", through the process of the technical process such as precipitation, sterilization, filtration, be transported to each user finally by Energy Saving Measures of Pumping Station.
The life of tap water and people is closely bound up, the water quality of tap water and the health of people in close relations.The water quality standard of China also has a certain distance than international standard at present.Current water supply security is faced with the dual-pressure that the day by day serious and water quality standard of tap water of pollution of waterhead improves gradually, and this also just has higher requirement to advanced water treatment technology.
Traditional water technology mainly takes following technique: extract water source → coagulation → precipitation → filtration → feeding clean water basin and to carry out disinfection → input water supply line.But the pollution of water resources is day by day serious at present, especially heavy metal contamination and Organic pollutants, and according to statistics, earth surface water source about 50% water source of China is polluted, and hundreds of organic compound, heavy metal ion enter water source; There is the phenomenons that exceed standard such as fluorine, arsenic, iron, manganese in underground water source.And the current most waterworks of China still uses traditional water technology, if water source by heavy metal ion and organic compound pollute, so above-mentioned traditional technology just seems unable to do what one wishes.Therefore, be necessary to carry out advanced treatment to water supply.
Although source quality pollutes constantly aggravation, along with the raising of living standards of the people, the quality of tap water is had higher requirement.Come into effect " drinking water sanitary standard " (GB5749-2006) on July 1st, 2007, in new standard, water-quality guideline is increased to 106 by 35 of standard in 1985 for this reason, and the limit value of a lot of index is stricter.New standard emphasis strengthens the control overflow to microorganism, heavy metal and organic pollutant, and basic and international organization and developed country water quality standard integrates with.
Therefore, further guarantee, in order to the healthy and social development of people, be necessary, research and develop a kind of novel running water processing system, this system can carry out advanced treatment by tap water supply, makes the water quality after processing reach the new standard of national regulation.
Summary of the invention
Goal of the invention: the object of the invention is to solve the deficiencies in the prior art, provides a kind of tap water sterilization system based on membrane technique.
Technical scheme: in order to realize above object, a kind of tap water sterilization system based on membrane technique of the present invention, it comprises successively by ozone sterilizer that pipeline connects, former water tank, lift pump, active sand filter, iron-manganese removing filter, activated charcoal filter, water softener, cartridge filter, ultrafiltration apparatus, nanofiltration equipment, ultraviolet sterilizer and aseptic water tank, described former water tank inside is provided with adverse current forming apparatus and filter screen of water tank, described adverse current forming apparatus comprises on two, lower two funnel shaped parts, water stream channel is provided with in the middle of the bottom of described upper hopper shape parts, described lower funnel-shaped part sealed bottom, described filter screen of water tank is positioned at the below of described adverse current forming apparatus, described former water tank is divided into, lower two chambers, the bottom of described former water tank is provided with water outlet, ultraviolet lamp is provided with near described water outlet.
The ozone sterilizer be provided with in the present invention can carry out preliminarily pasteurized germicidal treatment to water source, and before ozone sterilizer is placed on follow-up flocculation sediment, can oxidized metal species, improve coagulation and filtration effect, replace chlorination in the past, reduce the toxic side effect of chlorine, also serve the effect of sterilization simultaneously, Organic substance in water can be oxidized, reduce subsequent disposal difficulty, reduce the effect of pollutent;
The subgravity that the lift pump be provided with mainly realizes former water promotes, and to realize the run by gravity of subsequent treatment process, alleviates the pressure of subsequent processing device;
Be provided with active sand filter, active sand filter is a kind of high efficiency filter treatment unit collecting coagulation, clarify, be filtered into one, and active sand filter is for the flocculation sediment filtration treatment device of routine, and it has the following advantages: filter and run continuously, without the need to shutting down back flushing, efficiency is high; Without the need to backwash pump blower fan punching water tank and valve etc.; Integrate coagulating sedimentation and filter, enormously simplify technical process and take up an area space; Operation and maintenance expense is low; Waste water for high SS content does not need pre-treatment (water inlet SS can reach 150mg/L); Compared with conventional sand filtration process, the chemical agent of 30%-40% can be saved; The device space of 70% can be saved; Depth Filtration can be realized; Filter bed loss of pressure head is little, only has 0.5m; Adopt single homogeneous filtering material, need not grating layer; Filtrate is by continuous wash, and good filtration effect, without first filtrate problem; Stable effluent quality; Be easy to reorganization and expansion;
The iron-manganese removing filter be provided with can except unnecessary ferro element and manganese element in anhydrating, although ferrimanganic has irreplaceable effect in the activity of sustaining life, but for human body, the intake of ferro element every day is only 20 mg, and the content of manganese only has 10 ~ 20 mg in human body, for so micro-ferrimanganic demand, the mankind can be made up by diet completely, in order to suppress high-iron and high manganese too to absorb generation human body being produced to potential hazard, then can remove unnecessary ferro element and manganese element by iron-manganese removing filter;
The activated charcoal filter be provided with can make full use of the adsorption of gac, can carry out chemisorption to the material of various character, the object to reach optimizing water quality such as peculiar smell, organism, colloid, chlorine residue in removing water body;
The water softener be provided with can remove scale, incrustation scale and some inorganic salt etc. in former water, to reduce water hardness;
The cartridge filter be provided with is a kind of accurate filter, in pre-treatment program, compare coarse filtration, and cartridge filter can remove the less impurity of some particles in former water further;
The ultrafiltration apparatus be provided with mainly is provided with to adapt to new water quality standard, water treating equipment in the past can remove some organism in water and impurity, but in new standard, to organism, heavy metal, microorganism, even there is strict requirement to turbidity etc., therefore, need to use more superior accommodation, and ultrafiltration can be applied in water treatment because having the advantage of following uniqueness: (1) ultrafiltration is a kind of green Physical Separation Technology, and its separating mechanism mainly sieves and diffusion.Even if do not add coagulating agent, also effectively can remove the suspended substance in former water and colloidalmaterial, delivery turbidity is down to 0. 1 below NTU.Therefore ultrafiltration less with even not using coagulating agent, thus can reduce coagulated agent to the pollution of water quality.(2) ultra-filtration technique effectively can remove almost all pathogenic microorganisms, comprise Cryptosporidium, giardia lamblia, bacterium and virus etc., effluent quality generally can reach the requirement of water quality standard to microbiological indicator, therefore there is no need in principle to carry out sterilization and disinfection to water outlet again.Certainly, also need to add a small amount of sterilizing agent in water, to keep certain continuous disinfection ability, in order to avoid water is subject to secondary pollution in transmission & distribution process.(3) ultrafiltration can retain the material that relative molecular mass scope is 500 ~ 106, and in natural water, organic molecular weight major part is also in this scope, and therefore ultrafiltration can remove the organism in former water more effectively.Consumption simultaneously owing to adopting ultra-filtration technique can reduce sterilizing agent, therefore significantly can reduce the growing amount of disinfection byproduct (DBP) in water, thus improve the chemical safety of water.(4) in the filtration of routine, pollutent is by being adsorbed on filter material surface and removed, is a kind of stochastic process, therefore has fluctuation.Compared with conventional processes, it is directly screen out effect by fenestra that the process of water pollutant is removed in ultrafiltration, therefore has fabulous stability to the removal of pollutent.(5) working pressure that ultrafiltration adopts usually is 0. 1 ~ 0. 4 MPa, and be less than the working pressure of nanofiltration membrane, energy consumption is relatively low.(6) water is very short by the filtration time of ultra-filtration membrane, and this makes the volume of device for ultrafiltration membrane very little, this be other conventional treatment processes far can not and.(7) application scale and processing power can change in the larger context, and equipment can realize suitability for industrialized production and Automated condtrol, day-to-day operation and maintenance management more convenient.
The nanofiltration equipment be provided with is mainly in order to make up the some shortcomings part of ultrafiltration apparatus, it is similar that it acts on reverse osmosis membrane, especially play decolouring, removal natural organic matter and synthesis of organic substance (as agricultural chemicals etc.), three and cause material, disinfection byproduct (DBP) (haloform and halogen acetic acid) and precursor thereof and volatile organic matter, ensure the effect of the biologically stable of tap water etc., with ultrafiltration apparatus with the use of, tap water that can be sufficient carries out advanced treatment;
Although use membrane technique to be in general can not need to carry out germicidal treatment again, tap water is that people drink with water after all, being directly connected to the water safety of people, in order to ensure water safety further, being therefore necessary to strengthen germicidal treatment further, and ultraviolet sterilizer can reach the effect of thorough sterilization, ultraviolet sterilization safety, economical, few to the selectivity of bacterial classification, simultaneously water quality also can not change, and ozone unnecessary when can remove ozonization;
Use aseptic water tank to carry out water storage, the sterilized water processed can be avoided to be polluted in storage;
The adverse current forming apparatus be provided with in former water tank it mainly play dash, cross water, bidirectional flow is formed and the effect of current blending, finally reach the object of the inner water body pressure of regulating tank, stationary flow flow, the sedimentable matter in roof tank water quality can be made fully to precipitate simultaneously, make filter effect better, thus the detergent power of water tank is strengthened; The filtering net be provided with tentatively can filter water, ultraviolet lamp can in and ozone residual in water tank, play germicidal action simultaneously.
The ultra-filtration membrane that described ultrafiltration apparatus adopts to be membrane pore size the be polysulfone hollow fibre ultra-filtration membrane of 0.02-0.1 μm.Tubular fibre is compared to other forms of film, and its bacteria-eliminating efficacy is better, and to have ph stability performance good, anti-oxidant for polysulfone membrane simultaneously, intensity advantages of higher, compared to other mould materials, be longer service life some.
The nanofiltration membrane that described nanofiltration equipment adopts is the hollow fiber nanofiltration membrane of membrane pore size 1.2-2.0 μm.Tubular fibre is compared to other forms of film, and its bacteria-eliminating efficacy is better.
The water inlet of described active sand filter is also connected with dosing tank, and described dosing tank is built with water purification agent, and described water purification agent comprises following components by weight percent:
Deionized water: 100 parts;
Massfraction is the chitosan acetic acid solution of 5%: 4-6 part;
Massfraction is the cyclodextrin soln of 5%: 15-20 part;
Chitin: 0.5-0.7 part;
Citric acid: 0.5-0.7 part;
Calcium oxide: 3-5 part;
Carboxymethyl cellulose: 2-4 part;
Lalgine: 1.5-2.5 part.Can process the medicine added, to be dosing better effects if, dosing of carrying out that can be convenient is tested to find best dosing condition, the amount of such as dosing, time, speed etc., better can control dosing, make follow-up flocculation sediment reach top condition, the water purification agent that the present invention simultaneously adds, have employed chitosan, chitin and cyclodextrin carry out composite, this three is the degerming agent of environment-protecting asepsis, can except the heavy metal in anhydrating and unwanted bacteria, flocculating effect is better compared to traditional PAC simultaneously, can also avoid bringing aluminum ion in degerming process, also counted calcium oxide in this water purification agent simultaneously, carboxymethyl cellulose and Lalgine, this three can produce concerted reaction, strengthen flocculating effect, aluminium salt simultaneously in all right water of decomposition and molysite, reduce the content of aluminium and iron in water, ensure the quality safety of tap water.
The inner-wall material of described aseptic water tank is PE resin, and the outside of described aseptic water tank is provided with PEF thermal insulation layer.PE resin has excellent odorless, nontoxic, resistance to low temperature (minimum use temperature can reach-100 ~-70 ° of C), and chemical stability is good, is good aseptic water storage material; The thermal insulation layer that outside is provided with, can play heat-insulating and cold effect, in order to avoid when the temperature such as winter are too low, the water temperature in water tank is too low.
The top of described former water tank is respectively equipped with water tank inlet, liquid level controller for water tank and water tank inflation exhaust and filtration apparatus, the shower nozzle that at least two levels are installed is provided with below the inner tank water-in of described former water tank, described adverse current forming apparatus is provided with below described shower nozzle, the below of described adverse current forming apparatus is provided with described filter screen of water tank, and the bottom of described former water tank is also provided with water tank sewage draining exit.Shower nozzle makes the tap water that enters more even through adverse current forming apparatus again, makes adverse current forming apparatus better effects if, and then makes filter effect better, finally makes the better effects if that purifies water.Liquid level controller for water tank controls liquid level, is convenient to charge and discharge water at any time, exhaust and filtration apparatus, ensures inner air environmental quality.
The inwall of described former water tank is provided with polytetrafluoroethylene floor, and described polytetrafluoroethylene floor surface is also provided with light-catalyzed reaction rete, and the material of described light-catalyzed reaction rete comprises following components by weight percent:
Methyl acrylate: 100 parts;
Nano titanium oxide: 6-7 part;
Poly(lactic acid): 10-15 part; Safety non-toxic, has good biocompatibility, joins in nano titanium oxide and can increase its germ resistance;
Chitosan: 6-8 part; Environment-friendly type antibiotic agent, except the heavy metal in anhydrating and unwanted bacteria, can increase overall bactericidal properties;
Cellulose acetate: 5-7 part; Increase photocatalysis characteristic and the bactericidal properties of nano titanium oxide;
Epoxypropyltrimethylchloride chloride: 10-15 part; Quaternary ammonium salt, both can react with nano titanium oxide, strengthened photocatalysis characteristic, can, as phase transfer reagent, the entirety of solution be mixed more even again;
Deionized water: 50-100 part.The polytetrafluoroethylene floor be provided with, take full advantage of the physico-chemical property of tetrafluoroethylene, the corrosion that water tank life-time service causes can be prevented, extend water tank work-ing life, the light-catalyzed reaction rete be provided with is under the irradiation of water tank medium ultraviolet lamp, can light-catalyzed reaction be there is, except the objectionable impurities in anhydrating, reach water purification effect.
Beneficial effect: the tap water sterilization system based on membrane technique provided by the invention compared with prior art, has the following advantages:
Tap water sterilization system based on membrane technique of the present invention, active sand filter is adopted to replace conventional flocculation sediment operation, alleviate cost, membrane technique is combined with Ozone-Active Carbon Process simultaneously, the organism, heavy metal, microorganism etc. in former water can be processed fully, reach the advanced treatment to water quality, simultaneously, membrane technique, ozonization are combined with ultraviolet radiation for sterilizing and disinfecting, sterilization and disinfection can be carried out to water quality thoroughly, realize the object that water quality is aseptic.Through the tap water sterilization system based on membrane technique of the present invention, water quality can reach and higher than the standard of new edition " drinking water sanitary standard " (GB5749-2006).
Accompanying drawing explanation
The structural representation of the tap water sterilization system based on membrane technique that Fig. 1 provides for the embodiment of the present invention;
Fig. 2 is the structural representation of embodiment of the present invention Central Plains water tank;
In figure: 1-ozone sterilizer, the former water tank of 2-, 3-lift pump, 4-active sand filter, 5-iron-manganese removing filter, 6-activated charcoal filter, 7-water softener, 8-cartridge filter, 9-ultrafiltration apparatus, 10-nanofiltration equipment, 11-ultraviolet sterilizer, the aseptic water tank of 12-, 21-water tank inlet, 22-high water tank housing, 23-water tank inflation exhaust and filtration apparatus, 24-shower nozzle, 25-adverse current forming apparatus, 26-filter screen of water tank, 27-water outlet of water tank, 28, ultraviolet lamp, 29-water tank sewage draining exit.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; but illustrate that protection scope of the present invention is not limited to the concrete scope of the present embodiment simultaneously; based on the embodiment in the present invention; those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
embodiment 1:
As shown in Figure 1-2: a kind of tap water sterilization system based on membrane technique, it comprises the ozone sterilizer 1 connected by pipeline successively, former water tank 2, lift pump 3, active sand filter 4, iron-manganese removing filter 5, activated charcoal filter 6, water softener 7, cartridge filter 8, ultrafiltration apparatus 9, nanofiltration equipment 10, ultraviolet sterilizer 11 and aseptic water tank 12, described former water tank 2 inside is provided with adverse current forming apparatus 25 and filter screen of water tank 26, and described adverse current forming apparatus 25 comprises on two, lower two funnel shaped parts, be provided with water stream channel, described lower funnel-shaped part sealed bottom in the middle of the bottom of described upper hopper shape parts, described filter screen of water tank 26 is positioned at the below of described adverse current forming apparatus 25, is divided into by described former water tank 2, lower two chambers, the bottom of described former water tank 2 is provided with water outlet 27, ultraviolet lamp 28 is provided with near described water outlet 27, the inwall of described former water tank 2 is provided with polytetrafluoroethylene floor, described polytetrafluoroethylene floor surface is also provided with light-catalyzed reaction rete, and the material of described light-catalyzed reaction rete comprises following components by weight percent:
Methyl acrylate: 100 parts;
Nano titanium oxide: 6 parts;
Poly(lactic acid): 10 parts;
Chitosan: 6 parts;
Cellulose acetate: 5 parts;
Epoxypropyltrimethylchloride chloride: 10 parts;
Deionized water: 50 parts.
The top of described former water tank 2 is respectively equipped with water tank inlet 21, liquid level controller for water tank 22 and water tank inflation exhaust and filtration apparatus 23, the shower nozzle 24 that 5 levels are installed is provided with below the inner tank water-in 21 of described former water tank 2, described adverse current forming apparatus 25 is provided with below described shower nozzle 24, the below of described adverse current forming apparatus 25 is provided with described filter screen of water tank 26, and the bottom of described former water tank 2 is also provided with water tank sewage draining exit 29.
The ultra-filtration membrane that described ultrafiltration apparatus 9 adopts to be membrane pore size the be polysulfone hollow fibre ultra-filtration membrane of 0.02 μm.
The nanofiltration membrane that described nanofiltration equipment 10 adopts is the hollow fiber nanofiltration membrane of membrane pore size 1.2 μm.
The water inlet of described active sand filter 4 is also connected with dosing tank, and described dosing tank is built with water purification agent, and described water purification agent comprises following components by weight percent:
Deionized water: 100 parts;
Massfraction is the chitosan acetic acid solution of 5%: 4 parts;
Massfraction is the cyclodextrin soln of 5%: 15 parts;
Chitin: 0.5 part;
Citric acid: 0.5 part;
Calcium oxide: 3 parts;
Carboxymethyl cellulose: 2 parts;
Lalgine: 1.5 parts.Water purification agent can join in the water-in (entrance) of active sand filter 4 by dosing tank.
The inner-wall material of described aseptic water tank 12 is PE resin, and the outside of described aseptic water tank 12 is provided with PEF thermal insulation layer.
embodiment 2:
As shown in Figure 1-2: a kind of tap water sterilization system based on membrane technique, it comprises the ozone sterilizer 1 connected by pipeline successively, former water tank 2, lift pump 3, active sand filter 4, iron-manganese removing filter 5, activated charcoal filter 6, water softener 7, cartridge filter 8, ultrafiltration apparatus 9, nanofiltration equipment 10, ultraviolet sterilizer 11 and aseptic water tank 12, described former water tank 2 inside is provided with adverse current forming apparatus 25 and filter screen of water tank 26, and described adverse current forming apparatus 25 comprises on two, lower two funnel shaped parts, be provided with water stream channel, described lower funnel-shaped part sealed bottom in the middle of the bottom of described upper hopper shape parts, described filter screen of water tank 26 is positioned at the below of described adverse current forming apparatus 25, is divided into by described former water tank 2, lower two chambers, the bottom of described former water tank 2 is provided with water outlet 27, ultraviolet lamp 28 is provided with near described water outlet 27, the inwall of described former water tank 2 is provided with polytetrafluoroethylene floor, described polytetrafluoroethylene floor surface is also provided with light-catalyzed reaction rete, and the material of described light-catalyzed reaction rete comprises following components by weight percent:
Methyl acrylate: 100 parts;
Nano titanium oxide: 6.5 parts;
Poly(lactic acid): 13 parts;
Chitosan: 7 parts;
Cellulose acetate: 6 parts;
Epoxypropyltrimethylchloride chloride: 13 parts;
Deionized water: 75 parts.
The top of described former water tank 2 is respectively equipped with water tank inlet 21, liquid level controller for water tank 22 and water tank inflation exhaust and filtration apparatus 23, the shower nozzle 24 that 5 levels are installed is provided with below the inner tank water-in 21 of described former water tank 2, described adverse current forming apparatus 25 is provided with below described shower nozzle 24, the below of described adverse current forming apparatus 25 is provided with described filter screen of water tank 26, and the bottom of described former water tank 2 is also provided with water tank sewage draining exit 29.
The ultra-filtration membrane that described ultrafiltration apparatus 9 adopts to be membrane pore size the be polysulfone hollow fibre ultra-filtration membrane of 0.06 μm.The nanofiltration membrane that described nanofiltration equipment 10 adopts is the hollow fiber nanofiltration membrane of membrane pore size 1.6 μm.
The water inlet of described active sand filter 4 is also connected with dosing tank, and described dosing tank is built with water purification agent, and described water purification agent comprises following components by weight percent:
Deionized water: 100 parts;
Massfraction is the chitosan acetic acid solution of 5%: 5 parts;
Massfraction is the cyclodextrin soln of 5%: 18 parts;
Chitin: 0.6 part;
Citric acid: 0.6 part;
Calcium oxide: 4 parts;
Carboxymethyl cellulose: 3 parts;
Lalgine: 2 parts.Water purification agent can join in the water-in (entrance) of active sand filter 4 by dosing tank.
The inner-wall material of described aseptic water tank 12 is PE resin, and the outside of described aseptic water tank 12 is provided with PEF thermal insulation layer.
embodiment 3:
As shown in Figure 1-2: a kind of tap water sterilization system based on membrane technique, it comprises the ozone sterilizer 1 connected by pipeline successively, former water tank 2, lift pump 3, active sand filter 4, iron-manganese removing filter 5, activated charcoal filter 6, water softener 7, cartridge filter 8, ultrafiltration apparatus 9, nanofiltration equipment 10, ultraviolet sterilizer 11 and aseptic water tank 12, described former water tank 2 inside is provided with adverse current forming apparatus 25 and filter screen of water tank 26, and described adverse current forming apparatus 25 comprises on two, lower two funnel shaped parts, be provided with water stream channel, described lower funnel-shaped part sealed bottom in the middle of the bottom of described upper hopper shape parts, described filter screen of water tank 26 is positioned at the below of described adverse current forming apparatus 25, is divided into by described former water tank 2, lower two chambers, the bottom of described former water tank 2 is provided with water outlet 27, ultraviolet lamp 28 is provided with near described water outlet 27, the inwall of described former water tank 2 is provided with polytetrafluoroethylene floor, described polytetrafluoroethylene floor surface is also provided with light-catalyzed reaction rete, and the material of described light-catalyzed reaction rete comprises following components by weight percent:
Methyl acrylate: 100 parts;
Nano titanium oxide: 7 parts;
Poly(lactic acid): 15 parts;
Chitosan: 8 parts;
Cellulose acetate: 7 parts;
Epoxypropyltrimethylchloride chloride: 15 parts;
Deionized water: 100 parts.
The top of described former water tank 2 is respectively equipped with water tank inlet 21, liquid level controller for water tank 22 and water tank inflation exhaust and filtration apparatus 23, the shower nozzle 24 that 5 levels are installed is provided with below the inner tank water-in 21 of described former water tank 2, described adverse current forming apparatus 25 is provided with below described shower nozzle 24, the below of described adverse current forming apparatus 25 is provided with described filter screen of water tank 26, and the bottom of described former water tank 2 is also provided with water tank sewage draining exit 29.
The ultra-filtration membrane that described ultrafiltration apparatus 9 adopts to be membrane pore size the be polysulfone hollow fibre ultra-filtration membrane of 0.1 μm.The nanofiltration membrane that described nanofiltration equipment 10 adopts is the hollow fiber nanofiltration membrane of membrane pore size 2.0 μm.
The water inlet of described active sand filter 4 is also connected with dosing tank, and described dosing tank is built with water purification agent, and described water purification agent comprises following components by weight percent:
Deionized water: 100 parts;
Massfraction is the chitosan acetic acid solution of 5%: 6 parts;
Massfraction is the cyclodextrin soln of 5%: 20 parts;
Chitin: 0.7 part;
Citric acid: 0.7 part;
Calcium oxide: 5 parts;
Carboxymethyl cellulose: 4 parts;
Lalgine: 2.5 parts.Water purification agent can join in the water-in (entrance) of active sand filter 4 by dosing tank.
The inner-wall material of described aseptic water tank 12 is PE resin, and the outside of described aseptic water tank 12 is provided with PEF thermal insulation layer.
Tap water sterilization system based on membrane technique of the present invention, its specific works operational process is as follows:
First former water carry out preliminary sterilization and disinfection process through ozone sterilizer 1; Then entering into former water tank 2, in former water tank 2 under the irradiation of ultraviolet lamp 28, the light-catalyzed reaction rete generation light-catalyzed reaction in former water tank 2 can carry out sterilization and disinfection process; Then carry out gravity by lift pump 3 to promote and enter into that active sand filter 4 carries out flocculating, precipitates, filtering integral process, dosing tank is provided with to add water purification agent in the ingress of active sand filter 4, increase the purifying water effect of active sand filter 4, active sand filter 4 can purify, filter former water; Then former water enters into iron-manganese removing filter 5 to remove the unnecessary ferro element of water quality and manganese element; Then water quality enters into water softener 7 and carries out water demineralization, and the dirt in removing water quality, reduces the hardness of water quality; Then the water after softening enters into cartridge filter 8 and carries out essence filtration, further except the impurity in anhydrating; Then water enters into ultrafiltration apparatus 9 and nanofiltration equipment 10 carries out ultra-filtration membrane and nanofiltration membrane treatment, carry out the degree of depth except the microorganism not easily removed in anhydrating, heavy metal and other some objectionable impuritiess; Water after film process enters into ultraviolet sterilizer 11 and carries out uv sterilisation process, thoroughly except the bacterium in anhydrating, to reach the aseptic object of water quality; Process the sterilized water obtained to be stored in aseptic water tank 12 to carry out next step point water operation.
The flow direction of water in former water tank 2 is: current enter from water tank inlet 21, in the adverse current forming apparatus 25 of flows by action through inside of shower nozzle 24, current are flow through by the intermediate gaps of adverse current forming apparatus 25 upper-part and Bian Bi space, water body is divided into by entirety the current that the slower water yield of flow velocity is less, its object is to change the larger flow direction of middle part flow velocity, the stop being subject to lower component when flowing through region intermediate forms reverse flow, reverse flow and the violent blending of positive flow near limit wall, reach the effect of bidirectional flow energy dissipating, water flow pressure in former water tank 2 keeps stable, current filter through filter screen of water tank 26 after adverse current forming apparatus 25 again, finally flow out former water tank 2.
Through the tap water sterilization system based on membrane technique of the present invention, the tap water quality index after its process can reach the requirement of new standard " drinking water sanitary standard " (GB5749-2006) completely.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its objective is to allow and is familiar with these those skilled in the art and can understands content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalents done by spirit of the present invention or modification, all should be encompassed within protection scope of the present invention.

Claims (7)

1. based on a tap water sterilization system for membrane technique, it is characterized in that: it comprises the ozone sterilizer (1) connected by pipeline successively, former water tank (2), lift pump (3), active sand filter (4), iron-manganese removing filter (5), activated charcoal filter (6), water softener (7), cartridge filter (8), ultrafiltration apparatus (9), nanofiltration equipment (10), ultraviolet sterilizer (11) and aseptic water tank (12), described former water tank (2) inside is provided with adverse current forming apparatus (25) and filter screen of water tank (26), and described adverse current forming apparatus (25) comprises on two, lower two funnel shaped parts, water stream channel is provided with in the middle of the bottom of described upper hopper shape parts, described lower funnel-shaped part sealed bottom, described filter screen of water tank (26) is positioned at the below of described adverse current forming apparatus (25), described former water tank (2) is divided into, lower two chambers, the bottom of described former water tank (2) is provided with water outlet (27), is provided with ultraviolet lamp (28) near described water outlet (27).
2. the tap water sterilization system based on membrane technique according to claim 1, is characterized in that: the ultra-filtration membrane that described ultrafiltration apparatus (9) adopts to be membrane pore size the be polysulfone hollow fibre ultra-filtration membrane of 0.02-0.1 μm.
3. the tap water sterilization system based on membrane technique according to claim 1, is characterized in that: the nanofiltration membrane that described nanofiltration equipment (10) adopts is the hollow fiber nanofiltration membrane of membrane pore size 1.2-2.0 μm.
4. the tap water sterilization system based on membrane technique according to claim 1, it is characterized in that: the water inlet of described active sand filter (4) is also connected with dosing tank, described dosing tank is built with water purification agent, and described water purification agent comprises following components by weight percent:
Deionized water: 100 parts;
Massfraction is the chitosan acetic acid solution of 5%: 4-6 part;
Massfraction is the cyclodextrin soln of 5%: 15-20 part;
Chitin: 0.5-0.7 part;
Citric acid: 0.5-0.7 part;
Calcium oxide: 3-5 part;
Carboxymethyl cellulose: 2-4 part;
Lalgine: 1.5-2.5 part.
5. the tap water sterilization system based on membrane technique according to claim 1, is characterized in that: the inner-wall material of described aseptic water tank (12) is PE resin, and the outside of described aseptic water tank (12) is provided with PEF thermal insulation layer.
6. the tap water sterilization system based on membrane technique according to claim 1, it is characterized in that: the top of described former water tank (2) is respectively equipped with water tank inlet (21), liquid level controller for water tank (22) and water tank inflation exhaust and filtration apparatus (23), inner tank water-in (21) below of described former water tank (2) is provided with the shower nozzle (24) of at least two levels installations, described shower nozzle (24) below is provided with described adverse current forming apparatus (25), the below of described adverse current forming apparatus (25) is provided with described filter screen of water tank (26), the bottom of described former water tank (2) is also provided with water tank sewage draining exit (29).
7. the tap water sterilization system based on membrane technique according to claim 1 or 6, it is characterized in that: the inwall of described former water tank (2) is provided with polytetrafluoroethylene floor, described polytetrafluoroethylene floor surface is also provided with light-catalyzed reaction rete, and the material of described light-catalyzed reaction rete comprises following components by weight percent:
Methyl acrylate: 100 parts;
Nano titanium oxide: 6-7 part;
Poly(lactic acid): 10-15 part;
Chitosan: 6-8 part;
Cellulose acetate: 5-7 part;
Epoxypropyltrimethylchloride chloride: 10-15 part;
Deionized water: 50-100 part.
CN201410815824.4A 2014-12-25 2014-12-25 A kind of running water sterilization system based on membrane technology Expired - Fee Related CN104556509B (en)

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CN107986538A (en) * 2018-01-19 2018-05-04 兰州交通大学 A kind of optoacoustic is electrically coupled can field multi-stage oxidizing-UF membrane collaboration water treatment system and technique

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JP2013043126A (en) * 2011-08-24 2013-03-04 Sharp Corp Water purifier
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CN202022812U (en) * 2011-03-04 2011-11-02 深圳市和科达水处理设备有限公司 Ultrapure water preparation system
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