CN104531368A - Detergent for balsam pears - Google Patents
Detergent for balsam pears Download PDFInfo
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- CN104531368A CN104531368A CN201510005484.3A CN201510005484A CN104531368A CN 104531368 A CN104531368 A CN 104531368A CN 201510005484 A CN201510005484 A CN 201510005484A CN 104531368 A CN104531368 A CN 104531368A
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Abstract
The invention relates to a detergent, in particular to a detergent for balsam pears. The detergent for the balsam pears is prepared from tris(2,3-dichloropropyl) phosphate, 3,7,11,15-tetramethyl-1-hexadecene-3-alcohol, isopropylmalonic acid, 2-amino-3-(2-oxo-1,2-dihydro quinoline-4-base) propionic acid hydrochloride, (E)-3,7-dimethylocta-2,6-dien-1-alcohol, diethyl ethoxymethylenemalonate, 3,6-dimethylocta-1,4-dioxane-2,5-diketone and poly(oxy-1,2-ethanediyl), alpha-sulfo-omega-hydroxy-, C14-18-alkyl ethers, sodium salts. By means of the detergent for the balsam pears, high detergency is achieved, strumae on the surface of the balsam pears can be adapted, hazardous substances such as organophosphorus pesticide, pyrethrin pesticide, heavy metal lead, and cadmium which are attached to the root portion of the strumae can be effectively cleared away, and the whole cleaning effect after the balsam pears are cleaned is guaranteed.
Description
Technical field
The present invention relates to a kind of washing composition, be specifically related to a kind of balsam pear washing composition.
Background technology
Balsam pear has another name called balsam pear, is cucurbitaceous plant, is annual climbing herb, and its fruit oblong, surface has most irregular strumae.Balsam pear extracts flavonoid substances and is combined with Folium Mori extract S-GI and forms a kind of novel substance---and wash pancreas sugared clearly plain, having the effects such as hypoglycemic, blood fat, anti-inflammatory, is a kind of vegetables that people like.
And due to the singularity of its fruit surface projection, the residual lipophilic agrochemicals pole of its appearance is not easily cleaned out, produce pesticide residue.Residual toxicity can work the mischief to eater is healthy, can cause time serious uncomfortable, vomiting, diarrhoea even cause death.Pesticide residue exceed standard the neural system and the vitals such as liver, kidney that directly can jeopardize human body.The simultaneously accumulation of remains of pesticide in human body, exceed a certain amount of after can cause some chronic diseases, as numb in muscle etc., even can bring out vascular disease and cancer etc.
Summary of the invention
The object of the invention is to the balsam pear remained on surface agricultural chemicals solving the existence of above-mentioned prior art, clean insufficient defect, the balsam pear washing composition that a kind of cleaning efficiency is high is provided.
The present invention is achieved by the following technical solutions:
A kind of balsam pear washing composition, special character is to be prepared from by the raw material of following weight: tricresyl phosphate (2, 3-bis-chloropropyl) ester 28-32 part, 3, 7, 11, phytanetriol-cetene-3-alcohol 24-26 part, isopropyl-malonic acid 33-37 part, 2-amino-3-(2-oxo-1, 2-dihydroquinoline-4-base) propionic salt hydrochlorate 20-25 part, (E)-3, 7-dimethyl-2, 6-octadiene-1-alcohol 18-22 part, diethyl ethoxymethylenemalonate 16-19 part, 3, 6-dimethyl-1, 4-dioxane-2, 5-diketone 12-15 part, alpha-sulfo-ω-hydroxyl gathers (oxygen-1, 2-ethylidene) C14-18 alkyl oxide sodium salt 17-23 part.
Preferably, a kind of balsam pear washing composition is prepared from by the raw material of following weight: tricresyl phosphate (2, 3-bis-chloropropyl) ester 28 parts, 3, 7, 11, phytanetriol-cetene-3-alcohol 26 parts, isopropyl-malonic acid 33 parts, 2-amino-3-(2-oxo-1, 2-dihydroquinoline-4-base) propionic salt hydrochlorate 23 parts, (E)-3, 7-dimethyl-2, 6-octadiene-1-alcohol 20 parts, diethyl ethoxymethylenemalonate 16 parts, 3, 6-dimethyl-1, 4-dioxane-2, 5-diketone 15 parts, alpha-sulfo-ω-hydroxyl gathers (oxygen-1, 2-ethylidene) C14-18 alkyl oxide sodium salt 17 parts.
Further, in order to obtain the higher balsam pear washing composition of cleaning efficiency, described balsam pear washing composition also comprises the raw material of following weight: N-ethoxycarbonylpiperazine 6-8 part, cyclopentanone-2-carboxylates 8-10 part, 4,4-bis-(tert-butyl hydroperoxide) n-butyl pentanoate 7-12 part.
Preferably, balsam pear detergent raw material weight is: N-ethoxycarbonylpiperazine 7 parts, cyclopentanone-2-carboxylates 9 parts, 4,4-bis-(tert-butyl hydroperoxide) n-butyl pentanoate 10 parts.
Preparation method of the present invention: by deionized water, tricresyl phosphate (2, 3-bis-chloropropyl) ester, 3, 7, 11, phytanetriol-cetene-3-alcohol, isopropyl-malonic acid, 2-amino-3-(2-oxo-1, 2-dihydroquinoline-4-base) propionic salt hydrochlorate to add in reactor 1 stirring and dissolving at 40-50 DEG C, by (E)-3, 7-dimethyl-2, 6-octadiene-1-alcohol, diethyl ethoxymethylenemalonate, 3, 6-dimethyl-1, 4-dioxane-2, 5-diketone, alpha-sulfo-ω-hydroxyl gathers (oxygen-1, 2-ethylidene) C14-18 alkyl oxide sodium salt stirring and dissolving at 50-60 DEG C in reactor 2, mixture in reactor 2 is joined gradually in reactor 1, fully 25-40 minute is stirred in 40 DEG C of waters bath with thermostatic control, leave standstill 1.5-2 hour, namely required balsam pear washing composition is obtained.
This balsam pear washing composition, not only there is high cleaning force, and the strumae feature on balsam pear surface can be complied with, the objectionable impurities such as organophosphorus pesticide, cinerins agricultural chemicals, heavy metal lead, cadmium of effective removing balsam pear protrusion of surface root attachment, ensure the overall cleaning effect after balsam pear cleaning, edible more relieved.
Embodiment
Below provide the specific embodiment of the present invention, be used for being further described the present invention.In the present invention, if no special instructions, each raw material all in working substance content for 100%.
In following examples and comparative example, raw material introduction:
Tricresyl phosphate (2,3-bis-chloropropyl) ester, CAS accession number is: 78-43-3;
3,7,11, phytanetriol-cetene-3-alcohol, CAS accession number is: 505-32-8;
Isopropyl-malonic acid, CAS accession number is: 601-79-6;
2-amino-3-(2-oxo-1,2-dihydroquinoline-4-base) propionic salt hydrochlorate, CAS accession number is: 4876-14-6;
(E)-3,7-dimethyl-2,6-octadiene-1-alcohol, CAS accession number is: 106-24-1;
Diethyl ethoxymethylenemalonate, CAS accession number is: 87-13-8;
3,6-dimethyl-Isosorbide-5-Nitrae-dioxane-2,5-diketone, CAS accession number is: 95-96-5;
Alpha-sulfo-ω-hydroxyl gathers (oxygen-ethylene) C14-18 alkyl oxide sodium salt, and CAS accession number is: 68187-52-0;
N-ethoxycarbonylpiperazine, CAS accession number is: 120-43-4;
Cyclopentanone-2-carboxylates, CAS accession number is: 613-03-6;
4,4-bis-(tert-butyl hydroperoxide) n-butyl pentanoate, CAS accession number is: 995-33-5.
Embodiment 1
Weigh the raw material of following weight:
Tricresyl phosphate (2,3-bis-chloropropyl) ester 28kg, 3,7,11, phytanetriol-cetene-3-alcohol 26kg, isopropyl-malonic acid 33kg, 2-amino-3-(2-oxo-1,2-dihydroquinoline-4-base) propionic salt hydrochlorate 23kg, (E)-3,7-dimethyl-2,6-octadiene-1-alcohol 20kg, diethyl ethoxymethylenemalonate 16kg, 3,6-dimethyl-Isosorbide-5-Nitrae-dioxane-2,5-diketone 15kg, alpha-sulfo-ω-hydroxyl gathers (oxygen-ethylene) C14-18 alkyl oxide sodium salt 17kg.
The preparation method of the present embodiment balsam pear washing composition: by deionized water, tricresyl phosphate (2, 3-bis-chloropropyl) ester, 3, 7, 11, phytanetriol-cetene-3-alcohol, isopropyl-malonic acid, 2-amino-3-(2-oxo-1, 2-dihydroquinoline-4-base) propionic salt hydrochlorate to add in reactor 1 stirring and dissolving at 40-50 DEG C, by (E)-3, 7-dimethyl-2, 6-octadiene-1-alcohol, diethyl ethoxymethylenemalonate, 3, 6-dimethyl-1, 4-dioxane-2, 5-diketone, alpha-sulfo-ω-hydroxyl gathers (oxygen-1, 2-ethylidene) C14-18 alkyl oxide sodium salt stirring and dissolving at 50-60 DEG C in reactor 2, mixture in reactor 2 is joined gradually in reactor 1, fully 25-40 minute is stirred in 40 DEG C of waters bath with thermostatic control, leave standstill 1.5-2 hour, namely required balsam pear washing composition is obtained.
Embodiment 2
Weigh the raw material of following weight:
Tricresyl phosphate (2, 3-bis-chloropropyl) ester 30kg, 3, 7, 11, phytanetriol-cetene-3-alcohol 25kg, isopropyl-malonic acid 35kg, 2-amino-3-(2-oxo-1, 2-dihydroquinoline-4-base) propionic salt hydrochlorate 25kg, (E)-3, 7-dimethyl-2, 6-octadiene-1-alcohol 22kg, diethyl ethoxymethylenemalonate 19kg, 3, 6-dimethyl-1, 4-dioxane-2, 5-diketone 13kg, alpha-sulfo-ω-hydroxyl gathers (oxygen-1, 2-ethylidene) C14-18 alkyl oxide sodium salt 23kg, N-ethoxycarbonylpiperazine 6 parts, cyclopentanone-2-carboxylates 10 parts, 4, 4-bis-(tert-butyl hydroperoxide) n-butyl pentanoate 7 parts.
The preparation method of this embodiment balsam pear washing composition is with embodiment 1.
Embodiment 3
Weigh the raw material of following weight:
Tricresyl phosphate (2, 3-bis-chloropropyl) ester 32kg, 3, 7, 11, phytanetriol-cetene-3-alcohol 24kg, isopropyl-malonic acid 37kg, 2-amino-3-(2-oxo-1, 2-dihydroquinoline-4-base) propionic salt hydrochlorate 20kg, (E)-3, 7-dimethyl-2, 6-octadiene-1-alcohol 18kg, diethyl ethoxymethylenemalonate 17kg, 3, 6-dimethyl-1, 4-dioxane-2, 5-diketone 12kg, alpha-sulfo-ω-hydroxyl gathers (oxygen-1, 2-ethylidene) C14-18 alkyl oxide sodium salt 20kg, N-ethoxycarbonylpiperazine 8 parts, cyclopentanone-2-carboxylates 8 parts, 4, 4-bis-(tert-butyl hydroperoxide) n-butyl pentanoate 12 parts.
The preparation method of this embodiment balsam pear washing composition is with embodiment 1.
Embodiment 4
Tricresyl phosphate (2, 3-bis-chloropropyl) ester 28kg, 3, 7, 11, phytanetriol-cetene-3-alcohol 26kg, isopropyl-malonic acid 33kg, 2-amino-3-(2-oxo-1, 2-dihydroquinoline-4-base) propionic salt hydrochlorate 23kg, (E)-3, 7-dimethyl-2, 6-octadiene-1-alcohol 20kg, diethyl ethoxymethylenemalonate 16kg, 3, 6-dimethyl-1, 4-dioxane-2, 5-diketone 15kg, alpha-sulfo-ω-hydroxyl gathers (oxygen-1, 2-ethylidene) C14-18 alkyl oxide sodium salt 17kg, N-ethoxycarbonylpiperazine 7 parts, cyclopentanone-2-carboxylates 9 parts, 4, 4-bis-(tert-butyl hydroperoxide) n-butyl pentanoate 10 parts.
The preparation method of this embodiment balsam pear washing composition is with embodiment 1.
(1), wetting property test is carried out with embodiment 1-4 gained finished product
With commercial detergent as a control group
Getting four pieces of diameters is that the circular glass fiber of 5cm is placed on platform respectively, above-mentioned 4 kinds of samples of isodose are measured respectively with liquid meter, per sample (p.s.) drips in a glass fibre surrounding simultaneously respectively, there is the blank annulus being spaced apart 3cm between sample and glass fibre.The moment that sample drips to platform starts timing, starts sized glass fibres stop timing to sample.
Sample sized glass fibres required time is as shown in the table:
| Time, s | |
| Embodiment 1 | 1.4 |
| Embodiment 2 | 1.3 |
| Embodiment 3 | 1.3 |
| Embodiment 4 | 1.2 |
| Control group | 2.1 |
(2), the test of pesticide residue clearance is carried out with embodiment 1-4 gained finished product
(1) pollute balsam pear to prepare
Choose the Chlorpyrifos 94 of sigmar company production, SD-1750, Cypermethrin, Fenvalerate standard substance, the lead of 1000mg/L, cadmium heavy metal reference liquid.
Pesticide preparation is watered dilution by recommendation dosage, gets balsam pear and to be immersed in agricultural chemicals diluent 60 minutes, take out nature and dry and carried out washing test at 3 days, 10 days respectively afterwards.
By plumbous, that cadmium storage liquid is diluted to 10mg/L soak solution, get balsam pear and to be immersed in heavy metal diluent 60 minutes, take out nature and dry and carried out washing test at 3 days, 10 days respectively afterwards.
(2) residue removal rate test
Agricultural chemicals: get above-mentioned balsam pear after pesticide-treated and make background determination, clean is as follows, taking from water 2000ml inserts in basin, add embodiment product, commercial detergent and tap water respectively, mixing, balsam pear is put into basin to soak by taking-up after normal way cleaning after 8 minutes, then with tap water.
Heavy metal: get above-mentioned balsam pear after heavy metal process and make background determination, the same pesticide-treated of clean.
(3) sample preparation, instrument detect
Agricultural chemicals: with reference to NY/T 761-2004.
Heavy metal: with reference to GB/T 5009.12-2003 and GB/T 5009.15-2003.
(4) calculating of clearance
Pesticides removal rate %=
(5) interpretation of result
The balsam pear clean-out system of different embodiment and commercially available fruits and vegetables washing composition, the cleaning performance of tap water to agricultural chemicals, heavy metal see the following form.
As can be seen from the table, balsam pear washing composition of the present invention all has good cleaning performance to agricultural chemicals, heavy metal, reaches 89.8%, 88.7%, 95.7%, more than 93.8% respectively to the clearance of organophosphorus pesticide, cinerins agricultural chemicals, heavy metal lead, cadmium.To the washing effect of the pesticide residue washing effect apparently higher than commercial detergent, and be significantly higher than the washing effect of tap water; The washing effect of heavy metal, compared with commercial detergent, also has certain synergism.
From agricultural chemicals and the washing effect of balsam pear duration of contact, along with the increase of time, pesticide residue washing effect declines to some extent, and this may with agricultural chemicals owing to contacting with balsam pear for a long time, have part agricultural chemicals by the space of balsam pear or stratum corneum penetration to inner, cause washing effect to decline.
In sum, the cleaning performance of balsam pear clean-out system of the present invention to agricultural chemicals and heavy metal is obviously better than commercially available fruits and vegetables washing composition and tap water, has high application and popularization value.
Claims (4)
1. a balsam pear washing composition, it is characterized in that being prepared from by the raw material of following weight: tricresyl phosphate (2, 3-bis-chloropropyl) ester 28-32 part, 3, 7, 11, phytanetriol-cetene-3-alcohol 24-26 part, isopropyl-malonic acid 33-37 part, 2-amino-3-(2-oxo-1, 2-dihydroquinoline-4-base) propionic salt hydrochlorate 20-25 part, (E)-3, 7-dimethyl-2, 6-octadiene-1-alcohol 18-22 part, diethyl ethoxymethylenemalonate 16-19 part, 3, 6-dimethyl-1, 4-dioxane-2, 5-diketone 12-15 part, alpha-sulfo-ω-hydroxyl gathers (oxygen-1, 2-ethylidene) C14-18 alkyl oxide sodium salt 17-23 part.
2. balsam pear washing composition as claimed in claim 1, it is characterized in that being prepared from by the raw material of following weight: tricresyl phosphate (2, 3-bis-chloropropyl) ester 28 parts, 3, 7, 11, phytanetriol-cetene-3-alcohol 26 parts, isopropyl-malonic acid 33 parts, 2-amino-3-(2-oxo-1, 2-dihydroquinoline-4-base) propionic salt hydrochlorate 23 parts, (E)-3, 7-dimethyl-2, 6-octadiene-1-alcohol 20 parts, diethyl ethoxymethylenemalonate 16 parts, 3, 6-dimethyl-1, 4-dioxane-2, 5-diketone 15 parts, alpha-sulfo-ω-hydroxyl gathers (oxygen-1, 2-ethylidene) C14-18 alkyl oxide sodium salt 17 parts.
3. balsam pear washing composition as claimed in claim 1 or 2, characterized by further comprising the raw material of following weight: N-ethoxycarbonylpiperazine 6-8 part, cyclopentanone-2-carboxylates 8-10 part, 4,4-bis-(tert-butyl hydroperoxide) n-butyl pentanoate 7-12 part.
4. balsam pear washing composition as claimed in claim 3, is characterized in that parts by weight of raw materials proportioning is: N-ethoxycarbonylpiperazine 7 parts, cyclopentanone-2-carboxylates 9 parts, 4,4-bis-(tert-butyl hydroperoxide) n-butyl pentanoate 10 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510005484.3A CN104531368A (en) | 2015-01-07 | 2015-01-07 | Detergent for balsam pears |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510005484.3A CN104531368A (en) | 2015-01-07 | 2015-01-07 | Detergent for balsam pears |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104531368A true CN104531368A (en) | 2015-04-22 |
Family
ID=52847004
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510005484.3A Pending CN104531368A (en) | 2015-01-07 | 2015-01-07 | Detergent for balsam pears |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104531368A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105532688A (en) * | 2016-01-14 | 2016-05-04 | 烟台顺隆化工科技有限公司 | Herbicide for apple orchard |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0268033A1 (en) * | 1986-10-22 | 1988-05-25 | Joh. A. Benckiser GmbH | Agent for cleaning food |
| CN1059931A (en) * | 1991-09-21 | 1992-04-01 | 广州白云科技开发中心 | Vegetables, fruit cleaning agent of remanent pesticide |
| CN1139699A (en) * | 1995-10-24 | 1997-01-08 | 贾宏山 | Detergent for removing farm chemical remained on vegetable and fruit |
-
2015
- 2015-01-07 CN CN201510005484.3A patent/CN104531368A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0268033A1 (en) * | 1986-10-22 | 1988-05-25 | Joh. A. Benckiser GmbH | Agent for cleaning food |
| CN1059931A (en) * | 1991-09-21 | 1992-04-01 | 广州白云科技开发中心 | Vegetables, fruit cleaning agent of remanent pesticide |
| CN1139699A (en) * | 1995-10-24 | 1997-01-08 | 贾宏山 | Detergent for removing farm chemical remained on vegetable and fruit |
Non-Patent Citations (5)
| Title |
|---|
| 何月光主编: "《全科医生用药指南》", 30 November 2010 * |
| 刘树文主编: "《合成香料技术手册》", 31 January 2009 * |
| 刘益军主编: "《聚氨酯原料及助剂手册 第2版》", 31 January 2013 * |
| 欧阳平凯主编: "《化工产品手册 生物化工产品》", 30 April 2008 * |
| 王武钰主编: "《文物养护工作手册》", 31 October 2008 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105532688A (en) * | 2016-01-14 | 2016-05-04 | 烟台顺隆化工科技有限公司 | Herbicide for apple orchard |
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