CN104531289A - Lubricating oil having long service life and specially used for dual-fuel engines - Google Patents

Lubricating oil having long service life and specially used for dual-fuel engines Download PDF

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Publication number
CN104531289A
CN104531289A CN201410731339.9A CN201410731339A CN104531289A CN 104531289 A CN104531289 A CN 104531289A CN 201410731339 A CN201410731339 A CN 201410731339A CN 104531289 A CN104531289 A CN 104531289A
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CN
China
Prior art keywords
parts
dual
service life
lubricating oil
poly
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Pending
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CN201410731339.9A
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Chinese (zh)
Inventor
唐仕川
宋世远
张龙
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CHONGQING JIAZHOU LUBRICATING OIL Co Ltd
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CHONGQING JIAZHOU LUBRICATING OIL Co Ltd
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Priority to CN201410731339.9A priority Critical patent/CN104531289A/en
Publication of CN104531289A publication Critical patent/CN104531289A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a lubricating oil having long service life and specially used for dual-fuel engines. The lubricating oil comprises 40-50 parts of poly-alpha-olefin synthetic base oil PAO6, 25-40 parts of PAO8, 10-15 parts of naphthenic oil, 1-5 parts of polyol ester TMTC synthetic base oil, 1.5-3.8 parts of nonylphenol polyoxyethylene, 1-7 parts of polyvinyl ether, 11-18 parts of poly-alpha-olefin, 10-20 parts of overbased synthetic calcium sulfonate, 1-3 parts of calcium alkylbenzene sulfonate, 1-3 parts of zinc butyl octyl dithiophosphate, 2-5 parts of salicylate, 1-3 parts of succinimide, 2-3.5 parts of zinc dialkyl dithiophosphate, 1.5-2.5 parts of organic amine, 3-5 parts of an ashless dispersant, 25-35 parts of a complexing agent, 5-10 parts of a viscosity index improver, 0.1-0.6 parts of a pour-point depressant and 10-15 parts of citric acid mono-methyl ester. The lubricating oil has excellent oxidation and abrasion resistance.

Description

A kind of dual-fuel engine special lube of long service life
Technical field
The present invention relates to a kind of lubricating oil, be specifically related to a kind of dual-fuel engine special lube of long service life.
Background technology
Dual-fuel engine uses Sweet natural gas or liquefied petroleum gas (LPG) to be fuel, its calorific value is very high, exhaust emissions temperatures as high 480 DEG C, exceed 180 DEG C-200 DEG C than the temperature of common I. C. engine oil, engine combustion temperatures is high, causes lubricating oil evaporation loss large, NOx too high levels, I. C. engine oil very easily makes NOx that oxidation or nitration occur, and increases greasy filth and carbon deposit, thus boost engine weares and teares, deterioration of lubricant is aging; Further, compressed natural gas or the unlubricated effect of liquefied petroleum gas (LPG) self, therefore, require that the ash content of I. C. engine oil is moderate, make the ash content lubricate be deposited on valve and valve seating, ash content is too low, do not have lubrication, easily cause intake valve, vent valve and the prooving of valve seat, ash content is too high, engine can be caused to light a fire in early days and sparking plug pollution, affect engine power, generate hard settling in engine surface, carbon deposit is too much, valve melting loss.
Summary of the invention
For the problems referred to above that prior art exists, the object of this invention is to provide a kind of dual-fuel engine special lube of long service life.
For achieving the above object, the present invention adopts following technical scheme: a kind of dual-fuel engine special lube of long service life, it is characterized in that: the component comprising following mass fraction: poly-@alkene synthetic base oil PAO6 is 40-50 part, PAO8 is 25-40 part, naphthene base crude oil is 10-15 part, polyol resin TMTC synthetic base oil is 1-5 part polyoxyethylene nonylphenol ether is 1.5-3.8 part, polyvinyl ether is 1-7 part, poly-alpha olefins is 11-18 part, high base number calcium alkylbenzenesulfonate is 10-20 part, alkyl benzene calcium sulfonate is 1-3 part, sulphur phosphorus fourth octyl group zinc salt is 1-3 part, the salicylate that base number is greater than 300mgKOH/g is 2-5 part, fourth two phthalimide is 1-3 part, zinc dialkyl dithiophosphate is 2-3.5 part, organic amine is 1.5-2.5 part, ashless dispersant polyisobutene succinimide is 3-5 part, recombiner P6040 is 25-35 part, viscosity index improver SV261 is 5-10 part, pour point depressant 1-248 is 0.1-0.6 part, citric acid mono-methyl is 10-15 part.
As optimization, described organic amine is alkyl diphenylamine or N-phenyl-a-Cai amine.
Relative to prior art, tool of the present invention has the following advantages: the raw material that lubricating oil provided by the invention is selected has extremely strong compatibility reasonableness, make dual-fuel engine lubricating oil ash moderate, there is excellent resistance of oxidation, high base number acid-proof voltinism, abrasion resistance, effectively reduce the evaporation loss of lubricating oil, improve the wearing and tearing that lubricating oil in the past causes engine, thus add the work-ing life of engine, solve the aging fast problem of deterioration of lubricant, extend the drain period of lubricating oil, improve the power of engine.
Embodiment
Below the present invention is described in further detail.
A kind of dual-fuel engine special lube of long service life, comprise the component of following mass fraction: poly-@alkene synthetic base oil PAO6 is 40-50 part, PAO8 is 25-40 part, naphthene base crude oil is 10-15 part, polyol resin TMTC synthetic base oil is 1-5 part polyoxyethylene nonylphenol ether is 1.5-3.8 part, polyvinyl ether is 1-7 part, poly-alpha olefins is 11-18 part, high base number calcium alkylbenzenesulfonate 10-20 part, alkyl benzene calcium sulfonate is 1-3 part, sulphur phosphorus fourth octyl group zinc salt is 1-3 part, the salicylate that base number is greater than 300mgKOH/g is 2-5 part, fourth two phthalimide is 1-3 part, zinc dialkyl dithiophosphate is 2-3.5 part, organic amine is 1.5-2.5 part, ashless dispersant polyisobutene succinimide is 3-5 part, recombiner P6040 is 25-35 part, recombiner P6040 is the engine oil composite additive of a high-performance multipurpose, its main component is calcium, molybdenum, nitrogen, zinc, it applies novel ashless dispersant and full calcium base purification agent, there is excellent detergent-dispersant performance energy, there is excellent oxidation and corrosion inhibition and thermal stability, viscosity index improver SV261 is 5-10 part, viscosity index improver SV261 is a kind of viscosity index improver of poly-hydrogenated styrene isoprene type, may be used for allocating the multi-grade oil meeting modern gasoline machine, diesel engine performance requirement, there is good permanent shear stability (25 SSI can meet European shear stability and require), excellent low temperature flowability and desirable high temperature high shear performance, pour point depressant 1-248 is 0.1-0.6 part, the main component of pour point depressant 1-248 is poly-methyl acrylate, can improve low temperature flowability and the condensation point of lubricating oil, makes vehicle ensure when pole low temperature to start smoothly, reduces the service life reduction of the spare and accessory parts that dry wear causes, citric acid mono-methyl is 10-15 part.
Embodiment 1: a kind of dual-fuel engine special lube of long service life, poly-@alkene synthetic base oil PAO6 is 40 parts, PAO8 is 25 parts, naphthene base crude oil is 10 parts, polyol resin TMTC synthetic base oil is 1 part of polyoxyethylene nonylphenol ether is 1.5 parts, polyvinyl ether is 1 part, poly-alpha olefins is 11 parts, high base number calcium alkylbenzenesulfonate 10 parts, alkyl benzene calcium sulfonate is 1 part, sulphur phosphorus fourth octyl group zinc salt is 1 part, the salicylate that base number is greater than 300mgKOH/g is 2 parts, fourth two phthalimide is 1 part, zinc dialkyl dithiophosphate is 2 parts, alkyl diphenylamine is 1.5 parts, ashless dispersant polyisobutene succinimide is 3 parts, recombiner P6040 is 25 parts, viscosity index improver SV261 is 5 parts, pour point depressant 1-248 is 0.1 part, citric acid mono-methyl is 10 parts.
Embodiment 2: a kind of dual-fuel engine special lube of long service life, poly-@alkene synthetic base oil PAO6 is 45 parts, PAO8 35 parts, naphthene base crude oil is 12 parts, polyol resin TMTC synthetic base oil is 2.5 parts of polyoxyethylene nonylphenol ethers is 2.5 parts, polyvinyl ether is 5 parts, poly-alpha olefins is 15 parts, high base number calcium alkylbenzenesulfonate 15 parts, alkyl benzene calcium sulfonate is 2 parts, sulphur phosphorus fourth octyl group zinc salt is 2 parts, the salicylate that base number is greater than 300mgKOH/g is 3 parts, fourth two phthalimide is 2 parts, zinc dialkyl dithiophosphate is 3 parts, alkyl diphenylamine is 2 parts, ashless dispersant polyisobutene succinimide is 4 parts, recombiner P6040 is 30 parts, viscosity index improver SV261 is 15 parts, pour point depressant 1-248 is 0.4 part, citric acid mono-methyl is 13 parts.
Embodiment 3: a kind of dual-fuel engine special lube of long service life, poly-@alkene synthetic base oil PAO6 is 50 parts, PAO8 40 parts, naphthene base crude oil is 15 parts, polyol resin TMTC synthetic base oil is 5 parts of polyoxyethylene nonylphenol ethers is 3.8 parts, polyvinyl ether is 7 parts, poly-alpha olefins is 18 parts, high base number calcium alkylbenzenesulfonate 20 parts, alkyl benzene calcium sulfonate is 3 parts, sulphur phosphorus fourth octyl group zinc salt is 3 parts, the salicylate that base number is greater than 300mgKOH/g is 5 parts, fourth two phthalimide is 3 parts, zinc dialkyl dithiophosphate is 3.5 parts, N-phenyl-a-Cai amine is 2.5 parts, ashless dispersant polyisobutene succinimide is 5 parts, recombiner P6040 is 35 parts, viscosity index improver SV261 is 10 parts, pour point depressant 1-248 is 0.6 part, citric acid mono-methyl is 15 parts.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to technical scheme of the present invention or equivalent replacement, and not departing from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of right of the present invention.

Claims (2)

1. the dual-fuel engine special lube of a long service life, it is characterized in that: the component comprising following mass fraction: poly-@alkene synthetic base oil PAO6 is 40-50 part, PAO8 is 25-40 part, naphthene base crude oil is 10-15 part, polyol resin TMTC synthetic base oil is 1-5 part polyoxyethylene nonylphenol ether is 1.5-3.8 part, polyvinyl ether is 1-7 part, poly-alpha olefins is 11-18 part, high base number calcium alkylbenzenesulfonate is 10-20 part, alkyl benzene calcium sulfonate is 1-3 part, sulphur phosphorus fourth octyl group zinc salt is 1-3 part, the salicylate that base number is greater than 300mgKOH/g is 2-5 part, fourth two phthalimide is 1-3 part, zinc dialkyl dithiophosphate is 2-3.5 part, organic amine is 1.5-2.5 part, ashless dispersant polyisobutene succinimide is 3-5 part, recombiner P6040 is 25-35 part, viscosity index improver SV261 is 5-10 part, pour point depressant 1-248 is 0.1-0.6 part, citric acid mono-methyl is 10-15 part.
2. the dual-fuel engine special lube of long service life as claimed in claim 1, is characterized in that: described organic amine is alkyl diphenylamine or N-phenyl-a-Cai amine.
CN201410731339.9A 2014-12-05 2014-12-05 Lubricating oil having long service life and specially used for dual-fuel engines Pending CN104531289A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105733773B (en) * 2016-03-14 2019-04-26 张继德 Oil gas general purpose engine oil
CN110300796A (en) * 2017-02-22 2019-10-01 株式会社Sonoda The manufacturing method of lube oil additive and lube oil additive
CN111918955A (en) * 2018-03-30 2020-11-10 出光兴产株式会社 Lubricating oil composition and method for using lubricating oil composition
CN113502184A (en) * 2021-08-09 2021-10-15 圣保路石油化工(天津)股份有限公司 Engine cleaning agent and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012071185A2 (en) * 2010-11-24 2012-05-31 Chevron Oronite Company Llc Lubricating composition containing friction modifier blend
CN103666654A (en) * 2013-12-05 2014-03-26 青岛汇而通商贸有限公司 Engine lubricating oil
CN103695109A (en) * 2013-12-05 2014-04-02 青岛汇而通商贸有限公司 Energy-efficient engine lubricating oil
CN104109573A (en) * 2014-07-01 2014-10-22 山东力牌石油化学有限公司 Formula and production process for special lubricating oil for turbosupercharged engine

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012071185A2 (en) * 2010-11-24 2012-05-31 Chevron Oronite Company Llc Lubricating composition containing friction modifier blend
CN103666654A (en) * 2013-12-05 2014-03-26 青岛汇而通商贸有限公司 Engine lubricating oil
CN103695109A (en) * 2013-12-05 2014-04-02 青岛汇而通商贸有限公司 Energy-efficient engine lubricating oil
CN104109573A (en) * 2014-07-01 2014-10-22 山东力牌石油化学有限公司 Formula and production process for special lubricating oil for turbosupercharged engine

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105733773B (en) * 2016-03-14 2019-04-26 张继德 Oil gas general purpose engine oil
CN110300796A (en) * 2017-02-22 2019-10-01 株式会社Sonoda The manufacturing method of lube oil additive and lube oil additive
CN111918955A (en) * 2018-03-30 2020-11-10 出光兴产株式会社 Lubricating oil composition and method for using lubricating oil composition
US11274262B2 (en) 2018-03-30 2022-03-15 Idemitsu Kosan Co., Ltd. Lubricating oil composition and use method therefor
CN113502184A (en) * 2021-08-09 2021-10-15 圣保路石油化工(天津)股份有限公司 Engine cleaning agent and preparation method thereof

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Application publication date: 20150422

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