CN104530528B - Non-slip antistatic IXPE sheet and preparation method thereof - Google Patents
Non-slip antistatic IXPE sheet and preparation method thereof Download PDFInfo
- Publication number
- CN104530528B CN104530528B CN201410817705.2A CN201410817705A CN104530528B CN 104530528 B CN104530528 B CN 104530528B CN 201410817705 A CN201410817705 A CN 201410817705A CN 104530528 B CN104530528 B CN 104530528B
- Authority
- CN
- China
- Prior art keywords
- ixpe
- antistatic
- slip
- thin slice
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/101—Agents modifying the decomposition temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a non-slip antistatic IXPE sheet and a preparation method thereof. The non-slip antistatic IXPE sheet comprises the following components in percentage by weight: 5-20% of POE, 5-20% of EPDM, 3-10% of EVA, 1-10% of an antistatic agent, 5-9% of a foaming agent, 40-86% of LDPE, 0.2-3% of ZnO, 0.5-5% of ZnSt and 0.2-3% of 1010 and DSTP. The non-slip antistatic IXPE sheet provided by the invention has the beneficial effects that the preparation method is simple and the obtained product is thin and wide to apply.
Description
Technical field
The present invention relates to a kind of on-slip antistatic IXPE thin slice and preparation method thereof.
Background technology
The coming five years is the fast-developing period of the industry such as electronic information, medicine, plans according to " 12 " related industry,
China's electronic information manufacturing industry income from sales average annual growth rate will remain in about 10%, and the average annual growth expectations of industrial added value exceedes
15%, the whole nation medical industry gross output value increases every year and is up to about 20%, and additionally the industry such as Aero-Space, food, chemical industry exists
" 12 " period also will be rapidly progressed.Therefore downstream industry will significantly to the demand of Anti-static ultra-clean woven technical products
Promote.Chinese Institute of Electronics's anticipated China antistatic in " China's Anti-static ultra-clean woven technical products industry market research report " surpasses
The market scale of clean technical products will be increased to 763.92 hundred million yuan in 2015 by 428.83 hundred million yuan of 2010.
Especially electronic circuit and the miniaturization of element, lightweight, integrated and digitized, cause electronics used in everyday
Product is vulnerable to Electromagnetic Interference and more sensitive to electrostatic.In particular with liquid crystal panel, panel computer, smart mobile phone fast
Speed development, the requirement for conductive package material is the highest, and the thickness requirement for foam is more and more thinner, causes polyethylene to be prevented
The demand of the slim foam of electrostatic increases rapidly.Polyethylene antistatic foam can be automatically releasable electrostatic, shields the interference of electromagnetism, with
Time easy post-forming process, nontoxic, obtained market and more and more approved.
In prior art, liquid crystal panel is due to miniaturization, integrated circuit so that it is be easily subject to during transport, transfer
To electrostatic, the damage of transport shake, prior art uses PE Foam (EPE) two-layer bonding antistatic film to avoid it to damage mostly
Evil, EPE plays shockproof effect, and antistatic film plays the effect of antistatic.PE Foam (EPE) is by Low Density Polyethylene
And nucleator is blended uniformly in high-speed mixer (LDPE), put in foam extrusion machine, material through screw rod shearing, extruding and
Barrel heat jointly act on plastifying fusion.Fused materials uniformly mixes, after molding die with the butane foaming agent of addition
Decompression discharges and becomes foaming product.Then by processing methods such as laminating, curtain coatings, on its surface, laminating white carbon black type antistatic is thin
Film, reaches anti-static effect.
But, the shortcoming of prior art is:
1, EPE easily comes off with antistatic film, causes the infringement of counter plate；
2, antistatic film is in overturning Folding Process, easily forms a rule vestige, and the response rate is the lowest；
3, more smooth due to antistatic film surface, panel easily slides in transportation, reciprocating collision, easily damages；
4, the slim foam less than 1mm, this type of product cost is higher；
5, being black product due to antistatic film, and flat board is Lycoperdon polymorphum Vitt product, light identification system is easily made mistakes, thus raw
Suspend during product, it is impossible to continuous and automatic.
Summary of the invention
In order to solve above technical problem, the present invention provides a kind of on-slip antistatic IXPE thin slice, by weight percentage, bag
Include: the antistatic agent of EVA, 1-10% of the EPDM of POE, 5-20 of 5-20%, 3-10%, the foaming agent of 5-9%, 40-86%
LDPE, 0.2-3% ZnO, 0.5-5% ZnSt, 0.2-3% 1010 with DSTP, wherein 1010 and the mass ratio of DSTP
Between 0.5-1.
Preferably, the PE melt index of LDPE is 1.5-2.5g/10min.
Wherein, foaming agent uses azodicarbonamide.
Described antistatic agent uses the one in hydroxy ester calcification amine, weight sulfamic acid sodium and glycerol monosterate.
The present invention uses above technical scheme, has an advantage in that, by document and related data academic report, according to squeezing
Go out processing conditions and select suitable Low Density Polyethylene (LDPE) major ingredient kind, important indicator melt index (MI) (the melted finger passed through
Number is at 1.5-2.5g/10min)；Determine Low Density Polyethylene kind, in order to improve the non-skid property of foam, improve its friction system
Number so that it is will not slidably reciprocate in transportation, add a certain proportion of EVA, EPDM, POE, reach anti-slip effect；In order to anti-
The only frictional static infringement to liquid crystal flat-panel, adds antistatic agent in using, also reach humidity under the conditions of 60 ± 5%, surface
Resistance is less than 5 × 109, use interpolation antioxidant 1010 and DSTP to improve the heat stability of IXPE foam product；In order to drop
Low ratio foamed temperature, improves IXPE coiled material mechanical property in foaming furnace, uses and adds ZnSt, ZnO.
The present invention also provides for a kind of method preparing this on-slip antistatic IXPE thin slice, including following step:
Step A: first by EPDM, EVA, POE mix homogeneously, is then carried out its master batch and antistatic agent, foaming agent altogether
Mixed, under 100-120 DEG C of temperature conditions, be blended 7-15 minute, add 1010, DSTP, ZnO and ZnSt close with Low Density Polyethylene
Refining pelletize.
Step B: the Low Density Polyethylene banburying pelletize that will obtain, adds extruding pelletization in extruder, simultaneously at extruder
Die heater is installed at three rollers, makes at three rollers coolant water temperature at 20-40 DEG C.
Step C: using electron accelerator to produce high-velocity electrons, the high-velocity electrons section of beating C-H is good for, and forms free radical, then enters
Row coupled reaction, forms cancellated IXPE sheet material.
Step D: IXPE sheet material is put in vertical foaming stove and foam, obtain on-slip antistatic IXPE thin slice, wherein, temperature
Between 200-230 DEG C, speed is at 10-20m/min.
The principle of this method is: by banbury, major ingredient, adjuvant, AC foaming agent, antistatic agent is blended pelletize, then adopts
Extruding coiled material molding with single screw extrusion machine, High-speed Electric subfield carries out continuous radiation crosslinking to extrusion coiled material, then radiation is handed over
Sheet material after connection is put in vertical foaming stove, decomposes generation gas at vertical foaming stove foaming agent (azodicarbonamide) thus leads
Cause the foaming of plastic cement master slice, generate IXPE foam；Carry out the Formula Development of on-slip antistatic IXPE material sheet on this basis, really
Determine major ingredient, foaming agent, antistatic agent, special auxiliary agent etc..
The present invention uses above method, has an advantage in that, applicant use on-slip antistatic IXPE thin slice formula and
Processing technique, its production procedure is: feed proportioning → mixing granulator → extrusion molding → crosslinking with radiation → vertical foaming stove foaming.
Wherein, the mixing granulator technique impact on foamed products performance: the dispersion effect of antistatic master batch directly determines
The uniformity of antistatic index of product, antistatic index, LDPE, POE, EPDM, EVA, the direct shadow of dispersity of foaming agent
Ring foamed products uniform foam cell, fine and closely woven degree.In order to realize the homogeneous blend of various major ingredient, adjuvant, it is necessary to material is mixed
Refining is blended for twice respectively.First by EPDM, EVA, PE mix homogeneously, then its master batch is blended with antistatic agent.One
Under fixed temperature, certain time is blended, adds different proportion 1010 with DSTP with Low Density Polyethylene banburying pelletize, addition the most on year-on-year basis
ZnO and ZnSt of example and Low Density Polyethylene banburying pelletize.It addition, in master slice extruding-out process, foaming coiled (master slice)
Physical dimension, superficial appearance substantially determine the width of final foamed products, thickness, apparent mass, and technological condition is
Temperature, rotating speed, head pressure, mouth die gap, the selection of various technological parameters not decomposed or differential solution at material foaming agent
Ensure under premise that master slice plasticizing is uniform, thickness is uniform, smooth surface, internal stress are uniform.Theoretically, master slice thickness d0With product
1 corresponding relation of product thickness d is(n is coefficient of foaming), wide association is also similar to.But in actual production by
There is internal stress in master slice, master slice width, thickness to carry out suitable correctionRevise；Because of female in foaming process
After sheet is heated in the horizontal foaming furnace of combustion type, under internal stress effect, master slice width, thickness increase, contraction in length, shadow after foaming
Ring product specification size；So the existence of internal stress is the biggest on product size Changing Pattern impact in foaming process；Additionally planted agent
The existence of power, can cause the product in foaming process to crimp, adhesion, so the internal stress in master slice must be eliminated as far as possible.For disappearing
Except internal stress, extrusion is installed at extruder three roller die heater, makes coolant water temperature at three rollers constant in a temperature, so
Master slice is at extruding machine mold die orifice after discharging, and biography is guided to will not acute cold generation internal stress in three roller cooling procedures；
Furthermore, in irradiation technique, crosslinking with radiation refers exclusively to utilize between various radiation-initiated polymerization thing high polymer long chain
The technological means of cross-linking reaction.Here " radiation " refers exclusively to various radioprotective such as electron beam, gamma-rays, neutron beam, particle beam etc.
Photochemistry field is then belonged to, it is possible to utilize ultraviolet light to cause cross-linking reaction, referred to as light to hand over Deng the application of, light radiation such as ultraviolet light etc.
Connection.We use electron accelerator to produce high-velocity electrons, and high-velocity electrons penetrate PE sheet material and become IXPE sheet material, are its molecule links
Structure, from linearly becoming network structure, improves the intensity of polythene PE sheet material, could pass through foaming furnace foaming.
In foam process, foamed by the product of frothing test all size, determine in products of different specifications formula
Required foaming agent and the content of blowing promotor.
The invention has the beneficial effects as follows: method is simple, and the product obtained is thinner, applies more extensive.
Detailed description of the invention
Below the preferably embodiment of the present invention is described in further detail:
Embodiment 1
A kind of on-slip antistatic IXPE thin slice, by weight percentage, including: the POE of 5%, the EPDM of 12%, 8% send out
Infusion, the EVA of 3%, the hydroxy ester calcification amine of 10%, the LDPE of 51%, the ZnO of 3%, the ZnSt of 5%, 3% 1010 with
DSTP.The mass ratio of 1010 and DSTP is 0.5, and the PE melt index of LDPE is 1.5g/10min.
Preparation method includes following step:
Step A: first by EPDM, EVA, POE mix homogeneously, is then carried out its master batch and antistatic agent, foaming agent altogether
Mixed, at 100 DEG C, it is blended 7 minutes, adds 1010, DSTP, ZnO and ZnSt and Low Density Polyethylene banburying pelletize.
Step B: the Low Density Polyethylene banburying pelletize that will obtain, adds extruding pelletization in extruder, simultaneously at extruder
Die heater is installed at three rollers, makes coolant water temperature constant temperature 20 DEG C at three rollers.
Step C: using electron accelerator to produce high-velocity electrons, high-velocity electrons penetrate PE sheet material and become IXPE sheet material.
Step D: foamed by IXPE sheet material, obtains on-slip antistatic IXPE thin slice.
Embodiment 2
A kind of on-slip antistatic IXPE thin slice, by weight percentage, including: the POE of 12%, the EPDM of 5%, 8% send out
Infusion, the EVA of 8%, the weight sulfamic acid sodium of 5%, the LDPE of 61%, the ZnO of 0.2%, the ZnSt of 0.5%, the 1010 of 0.3%
With DSTP, the mass ratio of 1010 and DSTP is 0.8, and wherein, the PE melt index of LDPE is 2.5g/10min.
Preparation method includes following step:
Step A: first by EPDM, EVA, POE mix homogeneously, is then carried out its master batch and antistatic agent, foaming agent altogether
Mixed, at 120 DEG C, it is blended 15 minutes, adds 1010, DSTP, ZnO and ZnSt and Low Density Polyethylene banburying pelletize.
Step B: the Low Density Polyethylene banburying pelletize that will obtain, adds extruding pelletization in extruder, simultaneously at extruder
Die heater is installed at three rollers, makes coolant water temperature constant temperature 30 DEG C at three rollers.
Step C: using electron accelerator to produce high-velocity electrons, high-velocity electrons penetrate PE sheet material and become IXPE sheet material.
Step D: foamed by IXPE sheet material, obtains on-slip antistatic IXPE thin slice.
Embodiment 3
A kind of on-slip antistatic IXPE thin slice, by weight percentage, including: the POE of 5%, the EPDM of 12%, 8% send out
Infusion, the EVA of 8%, the glycerol monosterate of 4%, the LDPE of 59%, the ZnO of 1%, the ZnSt of 2%, 1% 1010 with
DSTP, the mass ratio of 1010 and DSTP is 1, and wherein, the PE melt index of LDPE is 2g/10min.
Preparation method includes following step:
Step A: first by EPDM, EVA, POE mix homogeneously, is then carried out its master batch and antistatic agent, foaming agent altogether
Mixed, at 110 DEG C, it is blended 12 minutes, adds 1010, DSTP, ZnO and ZnSt and Low Density Polyethylene banburying pelletize.
Step B: the Low Density Polyethylene banburying pelletize that will obtain, adds extruding pelletization in extruder, simultaneously at extruder
Die heater is installed at three rollers, makes coolant water temperature constant temperature 40 DEG C at three rollers.
Step C: using electron accelerator to produce high-velocity electrons, high-velocity electrons penetrate PE sheet material and become IXPE sheet material.
Step D: foamed by IXPE sheet material, obtains on-slip antistatic IXPE thin slice.
Performance test:
1. using finger gauge to carry out thickness measuring the product obtained by embodiment 1-3, result is as shown in table 1:
Table 1
| Thickness (mm) | |
| Conventional composite product | 1 |
| The product of embodiment 1 | 1 |
| The product of embodiment 2 | 0.9 |
| The product of embodiment 3 | 0.8 |
2. by adding EPDM and EVA, improve the pliability of foam, thus improve the coefficient of friction of foam, improve on-slip
Performance, according to ISTA testing standard (5-200Hz；1.0Grms X, Y, Z three axes (30min/axis), in specified maximum
In excursion, adding up its rebuffed number of times, data are as shown in table 2:
Table 2
| Max (X.Y)=10cm | Max (X.Y)=15cm | Max (X.Y)=20cm |
| Conventional composite product (secondary/min) | 45 | 30 | 21 |
| The product (secondary/min) of embodiment 1 | 15 | 9 | 4 |
| The product (secondary/min) of embodiment 2 | 14 | 8 | 3 |
| The product (secondary/min) of embodiment 3 | 13 | 7 | 2 |
3. after the extruding of conventional composite product is agglomerating once, detailed fold seen from surface, and layering, and embodiment 1-3 only
Sliding product extrudes agglomerating more than 10 times repeatedly, replys prototype equally.
4. the recovery experiment situation of pair product carries out laboratory simulation, is put in panel by product, employing high/low temperature baking oven,
Mechanical movement is simulated, the breakage rate of statistical product, and data are as shown in table 3:
Table 3
| Conventional composite product | The product of embodiment 1 | The product of embodiment 2 | The product of embodiment 3 | |
| Breakage rate (%) | 33 | 95 | 97 | 99 |
5. all use robotic to operate due to flat board, therefore the identification to product is the most crucial, and we are to difference
Product has carried out online experiment, adds up its error rate, and data are as shown in table 4:
Table 4
| Conventional composite product | Embodiment 1 product | Embodiment 2 product | Embodiment 3 product | |
| Error rate (%) | 3.2 | 0.5 | 0.4 | 0.3 |
6. more and more thinner along with liquid crystal panel, more and more big to slim foam demand, its 1mm also under product cost be less than
Traditional product.
7. sheet resistance is when humidity is 60 ± 10%, and sheet resistance value is less than or equal to 5 × 109Ω, as shown in table 5:
Table 5
Above content is to combine concrete preferred implementation further description made for the present invention, it is impossible to assert
Being embodied as of the present invention is confined to these explanations.For general technical staff of the technical field of the invention,
On the premise of present inventive concept, it is also possible to make some simple deduction or replace, all should be considered as belonging to the present invention's
Protection domain.
Claims (5)
1. an on-slip antistatic IXPE thin slice, it is characterised in that by weight percentage, including: POE, 5-20% of 5-20%
The antistatic agent of EVA, 1-10% of EPDM, 3-10%, the foaming agent of 5-9%, the ZnO of the LDPE of 51-61%, 0.2-3%,
The 1010 and DSTP of ZnSt, 0.2-3% of 0.5-5%；Foaming agent uses azodicarbonamide；Described antistatic agent uses ammonia
One in base sodium sulfonate and glycerol monosterate.
2. the method for the on-slip antistatic IXPE thin slice that a kind is prepared as described in claim 1, it is characterised in that include following
Several steps:
Step A: first by EPDM, EVA, POE mix homogeneously, is then mixed thing and carries out altogether with antistatic agent, foaming agent
Mixed, add 1010, DSTP, ZnO and ZnSt and Low Density Polyethylene banburying pelletize；
Step B: the Low Density Polyethylene banburying pelletize that will obtain, adds extruding pelletization in extruder, simultaneously at extruder three roller
Die heater is installed at place, makes coolant water temperature constant temperature at three rollers；
Step C: using electron accelerator to produce high-velocity electrons, high-velocity electrons penetrate PE sheet material and become IXPE sheet material；
Step D: IXPE sheet material is put in vertical foaming stove and foam, obtain on-slip antistatic IXPE thin slice.
3. the method preparing on-slip antistatic IXPE thin slice as claimed in claim 2, it is characterised in that described step A
In, temperature is 100-120 DEG C, and the blended time is 7-15 minute.
4. the method preparing on-slip antistatic IXPE thin slice as claimed in claim 2, it is characterised in that described step B
In, the temperature of constant temperature is 20-40 DEG C.
5. the method preparing on-slip antistatic IXPE thin slice as claimed in claim 2, it is characterised in that described step D
In, temperature is between 200-230 DEG C, and speed is at 10-20m/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410817705.2A CN104530528B (en) | 2014-12-24 | 2014-12-24 | Non-slip antistatic IXPE sheet and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410817705.2A CN104530528B (en) | 2014-12-24 | 2014-12-24 | Non-slip antistatic IXPE sheet and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104530528A CN104530528A (en) | 2015-04-22 |
| CN104530528B true CN104530528B (en) | 2017-01-11 |
Family
ID=52846177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410817705.2A Active CN104530528B (en) | 2014-12-24 | 2014-12-24 | Non-slip antistatic IXPE sheet and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104530528B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107090113A (en) * | 2017-05-04 | 2017-08-25 | 湖州长园特发科技有限公司 | A kind of slim foam of novel radiation crosslinked polyethylene and preparation method thereof |
| CN107141548A (en) * | 2017-06-02 | 2017-09-08 | 东莞市楚成橡塑复合材料有限公司 | A kind of foamed shoe-pad preparation method |
| CN107163334A (en) * | 2017-06-02 | 2017-09-15 | 东莞市楚成橡塑复合材料有限公司 | A kind of foam-in-mould moulding material |
| CN107266765A (en) * | 2017-06-07 | 2017-10-20 | 深圳市长园特发科技有限公司 | A kind of inorganic foamed IXPE foams and preparation method thereof |
| CN107652500A (en) * | 2017-09-14 | 2018-02-02 | 浙江润阳新材料科技股份有限公司 | A kind of antistatic foaming material and preparation method thereof |
| CN107936321A (en) * | 2017-11-03 | 2018-04-20 | 中国科学院宁波材料技术与工程研究所 | A kind of shooting foaming elastomeric material and preparation method thereof |
| CN107868294A (en) * | 2017-11-03 | 2018-04-03 | 中国科学院宁波材料技术与工程研究所 | A kind of high durometer rubber expanded material and preparation method thereof |
| CN108485086A (en) * | 2018-04-11 | 2018-09-04 | 东莞市福斯特橡塑科技有限公司 | A kind of isobutyl group and the compound rubber sole on-slip agent prescription and preparation method thereof of halobutyl |
| CN110343317A (en) * | 2019-07-12 | 2019-10-18 | 余修军 | A kind of IXPE foam and preparation method |
| CN111518328A (en) * | 2020-04-24 | 2020-08-11 | 浙江润阳新材料科技股份有限公司 | One-step formed antistatic IXPE and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101358004B (en) * | 2007-07-31 | 2011-01-26 | 深圳市长园特发科技有限公司 | IXPE electron radiation on crosslinking polyethylene conductive foam and preparation method thereof |
| CN103387705B (en) * | 2013-08-09 | 2015-08-26 | 深圳市长园特发科技有限公司 | A kind of preparation method without methane amide IXPE foam |
| CN103694542B (en) * | 2013-12-30 | 2015-02-25 | 广州石头造环保科技有限公司 | High-fill high-resilience soft expanded polyethylene material and preparation method thereof |
-
2014
- 2014-12-24 CN CN201410817705.2A patent/CN104530528B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104530528A (en) | 2015-04-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104530528B (en) | Non-slip antistatic IXPE sheet and preparation method thereof | |
| CN101358004B (en) | IXPE electron radiation on crosslinking polyethylene conductive foam and preparation method thereof | |
| CN104002523B (en) | Flame retardant carbon fiber prepreg and preparation method thereof | |
| CN104610631A (en) | Ultra-thin resin foamed sheet as well as production method and application thereof | |
| CN107266765A (en) | A kind of inorganic foamed IXPE foams and preparation method thereof | |
| CN103387705B (en) | A kind of preparation method without methane amide IXPE foam | |
| CN102199322B (en) | Irradiation cross-linked heat resistant flame-retardant rubber-plastic compound conductive foam and manufacturing method thereof | |
| US10392481B2 (en) | High strength polyethylene products and a process for preparation thereof | |
| CN107674228A (en) | The preparation method of graphene heat conducting film | |
| CN107090113A (en) | A kind of slim foam of novel radiation crosslinked polyethylene and preparation method thereof | |
| CN105882094A (en) | Solar panel high-temperature-resistant anti-ultraviolet self-adhesive film | |
| CN107057276A (en) | A kind of glass-fiber reinforced antistatic polyether-ether-ketone composite material and preparation method | |
| CN107857978A (en) | Antistatic biodegradable foam material and preparation method thereof | |
| CN111454670A (en) | High-low temperature-resistant high-brightness PET functional film | |
| CN114561056A (en) | Low-thermal conductivity XPE foam and preparation method thereof | |
| CN105419173A (en) | Low-cost antistatic plastic floor material and preparation method thereof | |
| CN115093798A (en) | Antibacterial and antistatic high-transparency polyethylene protective film and preparation method thereof | |
| CN105348810A (en) | Environmentally friendly porous silicone rubber sponge and preparation method thereof | |
| CN104119594A (en) | Scratch-resistant PE (polyethylene) film packaging material and preparation method thereof | |
| CN107325214A (en) | A kind of TPO vector resin, Masterbatch and preparation method thereof | |
| CN106380812A (en) | Flame-retardant master batch for transparent PC (polycarbonate) materials, and preparation method and application thereof | |
| CN109280273B (en) | High melt strength polypropylene film compositions and films and uses thereof | |
| CN110540747A (en) | Ultrahigh-friction master batch and preparation method thereof, ultrahigh-friction polyamide film and preparation method thereof | |
| CN110343333A (en) | A kind of expanded polypropylene composite material having antistatic property and its preparation process | |
| CN113504592B (en) | Diffusion film for printing display and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |