CN104529112B - Sludge organism drying method for treating - Google Patents
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/02—Biological treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
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- Organic Chemistry (AREA)
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- Treatment Of Sludge (AREA)
Abstract
本发明是一种利用微生物发酵干化的污泥生物干化处理方法,解决现有污泥干化耗电高以及对环境污染较严重等技术问题。它是经浓缩处理后的含水率为76%~84%的新鲜污泥进行干化处理过程,它包括有以下步骤:a、调配新鲜污泥含水率;b、添加菌剂;c、污泥的发酵、干化。该干化处理后的干化污泥可用于补充土地等多方面。本发明是利用微生物好氧发酵产热来蒸发水分的生物干化工艺,充分利用了污泥自身的生物能,是一种经济、节能、环保的干化技术;提高了干化效率、缩短了干化周期。
The invention is a sludge biological drying treatment method utilizing microbial fermentation and drying, which solves the technical problems of high power consumption and serious environmental pollution in existing sludge drying. It is a drying treatment process for fresh sludge with a water content of 76% to 84% after concentration treatment. It includes the following steps: a. Adjusting the water content of fresh sludge; b. Adding bacterial agents; c. Sludge fermentation and drying. The dried sludge after drying treatment can be used in various aspects such as supplementing land. The present invention is a biological drying process that utilizes microbial aerobic fermentation to produce heat to evaporate water, fully utilizes the bioenergy of the sludge itself, and is an economical, energy-saving, and environmentally friendly drying technology; it improves the drying efficiency, shortens the drying cycle.
Description
技术领域technical field
本发明涉及污水处理产物即污泥的处理技术,尤其是污泥生物干化处理方法。The invention relates to a treatment technology of sludge, which is a sewage treatment product, in particular to a sludge biological drying treatment method.
背景技术Background technique
城镇生活污水处理时经初次沉淀池、二次沉淀池等工艺环节产生大量的污泥。一般情况下每万吨污水经处理后的污泥产生量(按含水率80%计)约为6~8吨。该污泥产生恶臭味,并含有大量的重金属元素(如Cd、Hg、As、Pb、Ni、Cr、Cu等)、有害的有机物质(如苯并芘、多氯联苯)和粪大肠菌和蛔虫卵等有害菌体,对城镇环境污染构成了严重威胁。During the treatment of urban domestic sewage, a large amount of sludge is generated through the process links such as primary sedimentation tank and secondary sedimentation tank. Under normal circumstances, the amount of sludge produced per 10,000 tons of sewage after treatment (based on a moisture content of 80%) is about 6 to 8 tons. The sludge produces a foul smell and contains a large amount of heavy metal elements (such as Cd, Hg, As, Pb, Ni, Cr, Cu, etc.), harmful organic substances (such as benzopyrene, polychlorinated biphenyls) and fecal colon Harmful bacteria such as bacteria and roundworm eggs pose a serious threat to urban environmental pollution.
目前污泥处置大致可分为:卫生填埋、堆肥土地利用、石灰固化填埋、厌氧制沼气和干化焚烧等。由于城市污泥含水率较高,经浓缩脱水后仍高达80%左右,具有体积大、不利于运输、性质不稳定等特点。“填埋”将会占用大量土地,同时还会产生渗滤液而污染地下水;“土地利用”则因运输量大、分散困难、容易污染地下水而受到限制;“堆肥土地利用”因污泥的重金属不稳定性难以合理施用;“焚烧”因含固率低而导致热值太低,无法维持有效自燃而耗费大量辅助燃料,使处置成本明显增加。因此污泥的干化处理是污泥资源处置的重要环节。At present, sludge disposal can be roughly divided into: sanitary landfill, composting land use, lime solidification landfill, anaerobic biogas production and dry incineration. Due to the high water content of municipal sludge, it is still as high as about 80% after concentration and dehydration. It has the characteristics of large volume, unfavorable transportation, and unstable properties. "Landfill" will occupy a large amount of land, and will also produce leachate to pollute groundwater; Instability is difficult to use reasonably; "incineration" has too low calorific value due to low solid content to maintain effective spontaneous combustion and consume a large amount of auxiliary fuel, which significantly increases the disposal cost. Therefore, the drying treatment of sludge is an important part of sludge resource disposal.
传统的污泥干化在污泥干化场的进行,将污泥堆积在室外的干化场,通过自然通风和重力作用对污泥进行干化。目前的干化工艺主要为热干化和机械干化,即通过外加热源、电源及相关的机械设备将污泥中的水分蒸发和挤压。前者占地面积大、效率低;后者投资和运行费用高、设备运行能耗高。虽然现阶段的国内外对热干化进行污泥干化的工艺在不断地改进,如优化热源、减少工艺步骤、优化运处参数,但其工艺本身的特性(利用外加热源)决定其干化过程能耗较高。The traditional sludge drying is carried out in the sludge drying field, and the sludge is piled up in the outdoor drying field, and the sludge is dried by natural ventilation and gravity. The current drying process is mainly thermal drying and mechanical drying, that is, the water in the sludge is evaporated and squeezed through an external heat source, power supply and related mechanical equipment. The former occupies a large area and has low efficiency; the latter has high investment and operating costs and high energy consumption for equipment operation. Although the domestic and foreign thermal drying sludge drying processes are constantly improving at this stage, such as optimizing heat sources, reducing process steps, and optimizing operating parameters, the characteristics of the process itself (using external heat sources) determine its drying process. Process energy consumption is high.
发明内容Contents of the invention
本发明是解决现有污泥干化(热干化)耗电高、成本高、占地广、干化过程中对环境污染较严重等技术问题,进而提供一种利用微生物发酵干化的污泥生物干化处理技术。The present invention solves the technical problems of the existing sludge drying (thermal drying) such as high power consumption, high cost, large land occupation, and serious environmental pollution during the drying process, and further provides a sludge drying method using microbial fermentation. Mud biological drying treatment technology.
本发明的污泥生物干化处理方法,是经浓缩处理后的含水率为76%~84%的新鲜污泥进行干化处理过程,它包括有以下步骤:The sludge biological drying treatment method of the present invention is a drying treatment process of fresh sludge with a moisture content of 76% to 84% after concentration treatment, and it includes the following steps:
a、调配新鲜污泥含水率:将新鲜污泥与含水率为28%~32%的基料按1∶1.4~1.6重量比进行搅拌混合,得混合料;a, deployment of fresh sludge water content: the fresh sludge and the base material with a water content of 28% to 32% are stirred and mixed in a weight ratio of 1:1.4 to 1.6 to obtain a mixture;
b、添加菌剂:向步骤a所得的混合料中加入混合料重量的2.0‰~2.5‰的复合型菌剂并拌匀,得待干化料;b. Add bacterial agent: add 2.0‰~2.5‰ of compound bacterial agent to the mixture obtained in step a and mix well to obtain dry material;
c、污泥的发酵、干化:将步骤b所得的待干化料堆成发酵干化泥堆进行发酵、干化,得干化污泥;c. Fermentation and drying of sludge: pile the material to be dried obtained in step b into a fermented and dried sludge pile for fermentation and drying to obtain dried sludge;
其中,该菌剂为复合型菌剂,由嗜热芽孢杆菌、高温放线菌、耐高温酵母菌、除臭菌按6:6:5:3的重量比进行混合而成的。Among them, the microbial agent is a composite bacterial agent, which is formed by mixing thermophilic bacillus, high-temperature actinomycetes, high-temperature-resistant yeast, and deodorant bacteria in a weight ratio of 6:6:5:3.
进一步,该混合料中的碳氮质量比为24~26∶1。Further, the mass ratio of carbon and nitrogen in the mixture is 24-26:1.
进一步,该碳氮质量比是在步骤a中通过添加辅料并搅拌均匀来实现的;该辅料为含碳量高的秸秆、稻草或草类植物。Further, the carbon-to-nitrogen mass ratio is achieved in step a by adding auxiliary materials and stirring uniformly; the auxiliary materials are straw, straw or grass plants with high carbon content.
进一步,该干化污泥的含水率为28%~32%。Furthermore, the moisture content of the dried sludge is 28%-32%.
进一步,该发酵干化泥堆每天推翻一次,其发酵、干化时间为10~12天。Furthermore, the pile of fermented and dried mud is overturned once a day, and the fermentation and drying time is 10-12 days.
进一步,该基料选用干化污泥。Further, the base material is dried sludge.
再进一步,上述步骤a中的搅拌混合是在密闭负压空间内进行的;该密闭负压空间设有除臭系统;该除臭系统用于将密闭负压空间内所产生的臭气进行处理并排放。Still further, the stirring and mixing in the above step a is carried out in a closed negative pressure space; the closed negative pressure space is provided with a deodorization system; the deodorization system is used to treat the odor generated in the closed negative pressure space side by side.
更进一步,上述步骤b、c是在污泥生物干化槽内进行的;该污泥生物干化槽设置在好氧发酵车间内;其槽底铺设有曝气系统,槽尾设有除臭抽风装置;该曝气系统用于对生物干化槽进行间断式强制通风,以使复合型菌剂中的好氧发酵菌种得到更好的发酵。Furthermore, the above steps b and c are carried out in a sludge biological drying tank; the sludge biological drying tank is set in an aerobic fermentation workshop; an aeration system is laid on the bottom of the tank, and a deodorization system is installed at the end of the tank. Air extraction device; the aeration system is used for intermittent forced ventilation of the biological drying tank, so that the aerobic fermentation bacteria in the compound bacterial agent can be better fermented.
本发明的一种由污泥生物干化处理方法处理后的干化污泥,用于补充土地、或用于制作砖体原料、或用于能量产生的能源。The dried sludge treated by the sludge biological drying treatment method of the present invention is used to replenish land, or to make brick raw materials, or to generate energy for energy.
本发明中加入基料以调整待干化处理污泥的含水率至46%~54%,有利于菌种的生长和污泥发酵干化。In the invention, the base material is added to adjust the water content of the sludge to be dried to 46%-54%, which is beneficial to the growth of bacteria and the fermentation and drying of the sludge.
本发明的基料采用已干化处理后的干化污泥,就地取材,减少了因开挖、运输带来的人工费、成本费,提高了设备的利用率,并同时避免了因开挖黄土等基料所带来的环境污染。The base material of the present invention adopts the dried sludge after drying treatment, and the materials are obtained locally, which reduces labor costs and costs caused by excavation and transportation, improves the utilization rate of equipment, and avoids Environmental pollution caused by digging loess and other base materials.
本发明采用合理的新鲜污泥与基料之间的配比,有利于缩短污泥干化时间,提高污泥处理效率。The invention adopts a reasonable ratio between the fresh sludge and the base material, which is beneficial to shorten the sludge drying time and improve the sludge treatment efficiency.
本发明中通过添加含纤维素高的物质来调整污泥中的碳氮比,有利于微生物对有机物的分解,去除有害物质,并产生热能,促使污泥的快速干化。经理论分析后的碳氮比与要求值相当(碳氮比例一般为25:1)。其原因是当微生物分解有机物时,同化5份碳时约需要同化1份氮来构成它自身细胞体,因为微生物自身的碳氮比大约是5:1。而在同化(吸收利用)1份碳时需要消耗4份有机碳来取得能量,所以微生物吸收利用1份氮时需要消耗利用25份有机碳。也就是说,微生物对有机质的正当分解的碳氮比的25:1。当低于其要求值,并进一步选用含纤维素较高的辅料以补充碳源。因此,通过添加辅料有利复合型菌剂发挥更好地作用,同时加快污泥的干化。In the present invention, the carbon-to-nitrogen ratio in the sludge is adjusted by adding substances with high cellulose content, which is beneficial to the decomposition of organic matter by microorganisms, removal of harmful substances, and generation of heat energy to promote rapid drying of the sludge. The carbon-nitrogen ratio after theoretical analysis is equivalent to the required value (the carbon-nitrogen ratio is generally 25:1). The reason is that when microorganisms decompose organic matter, they need to assimilate about 1 part of nitrogen when assimilating 5 parts of carbon to form their own cell body, because the carbon-nitrogen ratio of microorganisms is about 5:1. When assimilating (absorbing and utilizing) 1 part of carbon, it needs to consume 4 parts of organic carbon to obtain energy, so when microorganisms absorb and utilize 1 part of nitrogen, they need to consume and utilize 25 parts of organic carbon. That is to say, the carbon-to-nitrogen ratio of microorganisms to the proper decomposition of organic matter is 25:1. When it is lower than its required value, further select auxiliary materials with higher cellulose content to supplement the carbon source. Therefore, the addition of auxiliary materials is beneficial to the composite bacterial agent to play a better role, and at the same time accelerate the drying of sludge.
本发明与现有污泥干化工艺相比还具有以下优点:由于本发明利用微生物好氧发酵产热来蒸发水分的生物干化工艺,充分利用了污泥自身的生物能,除通风曝气所需的电耗外,不用外加热源,因此是一种经济、节能、环保的干化技术。通过对待干化料进行强制鼓风。提高了干化效率、缩短了干化周期。具体比较请参阅下表1。Compared with the existing sludge drying process, the present invention also has the following advantages: Since the biological drying process of the present invention utilizes microbial aerobic fermentation to generate heat to evaporate water, the biological energy of the sludge itself is fully utilized, and ventilation and aeration are eliminated. In addition to the required power consumption, no external heating source is required, so it is an economical, energy-saving and environmentally friendly drying technology. By forced air blowing of the material to be dried. Improve the drying efficiency and shorten the drying cycle. Please refer to Table 1 below for a specific comparison.
表1.热干化、自然干化与生物干化比较Table 1. Comparison of thermal drying, natural drying and biological drying
图面说明Illustration
图1是针对表2中所列不同配方的混合料干化温度变化曲线图;Fig. 1 is the variation curve diagram of the mixture drying temperature for the different formulations listed in Table 2;
图2是菌体对污泥干化的影响曲线图。Figure 2 is a graph showing the effect of bacteria on sludge drying.
实验分析experiment analysis
1、基料及其配比1. Base material and its ratio
加入基料主要是用于调整新鲜污泥(污水处理厂直接产生的并经浓缩处理后的污泥)含水率。一般情况下从污水处理厂产生的并经浓缩处理后的新鲜污泥的含水率为76%~84%(即80%左右),为了方便作业,并保证生物菌剂的生长,通过加入基料以调整其含水率。Adding the base material is mainly used to adjust the moisture content of the fresh sludge (the sludge directly produced by the sewage treatment plant and after concentrated treatment). Generally speaking, the water content of fresh sludge produced from sewage treatment plants and concentrated treatment is 76% to 84% (about 80%). In order to facilitate the operation and ensure the growth of biological bacteria, by adding base to adjust its moisture content.
原料:新鲜污泥:使用污水处理厂污泥,含水率为80%。Raw materials: fresh sludge: use sewage treatment plant sludge with a water content of 80%.
基料:选用干化污泥(注:首次采用含水率相当替代物,Base material: use dried sludge (note: for the first time, a substitute with a comparable moisture content is used,
如黄土等),为污泥生物干化后产物,含水率30%。Such as loess, etc.), which is the product of sludge biological drying, with a moisture content of 30%.
将上述两种原料在不加入生物菌剂的情况下按表2要求进行调配,每一“项目”的混合料经搅拌均匀后分别堆至四个干化槽中,检测不同时期混合料的温度变化并进行比较。The above two raw materials are prepared according to the requirements of Table 2 without adding biological agents. The mixture of each "item" is stirred evenly and then stacked into four drying tanks, and the temperature of the mixture in different periods is detected. change and compare.
表2.新鲜污泥与基料配比Table 2. Ratio of fresh sludge and base material
从表2并结合图1可见,配方A因为水分含量较高,其温度随时间推移变化最小,配方D温度变化最大。配方C、D适合作为生物干化配方,配方D效果最好。从实际应用角度考虑,由于配方D中基料使用量是新鲜污泥的2倍,混合后体积翻倍,增加了生物干化槽的负担,使得新鲜污泥处理率降低;从温度变化和基料使用量两个方面综合考虑,配方C是最合理的配比,有利于污泥的干化。It can be seen from Table 2 combined with Figure 1 that the temperature of formula A has the smallest change over time because of its high moisture content, and the temperature of formula D has the largest change. Formulas C and D are suitable as biological drying formulas, and formula D has the best effect. From the perspective of practical application, since the amount of base material used in formula D is twice that of fresh sludge, the volume after mixing doubles, which increases the burden on the biological drying tank and reduces the treatment rate of fresh sludge; from the temperature change and base Considering the two aspects of material usage, formula C is the most reasonable ratio, which is conducive to the drying of sludge.
按上表2将同量污泥与不同量基料混合,分别放入同一条件下的污泥干化槽,并进行自然干化,以研究不同配方在同一时期的生物干化水分含量变化情况。参见表3,表3所列数据为不同比例配方的混合料在干化第11天时取样测定的水分含量。从表3可见,配方C和配方D的水分蒸发量最多,配方C在干化第11天时的水分含量为31%,配方D为29%。Mix the same amount of sludge with different amounts of base material according to Table 2 above, put them into sludge drying tanks under the same conditions, and carry out natural drying to study the changes in the moisture content of different formulas in the same period of biological drying . See Table 3, the data listed in Table 3 is the moisture content of the mixed materials with different proportions of formulations sampled and measured on the 11th day of drying. It can be seen from Table 3 that formula C and formula D have the largest amount of water evaporation, formula C has a moisture content of 31% on the 11th day of drying, and formula D is 29%.
表3:不同配方物料生物干化水分含量变化比较Table 3: Comparison of moisture content changes in biological drying of different formula materials
由此可见:1、新鲜污泥干化后作为基料再次与新鲜污泥混合进行生物干化是可行的;2、新鲜污泥与基料最优配方为重量比1:1.4~1.6;3、由于生物干化是一个生物活动的过程,因此需要合适的碳氮比,若污泥干化后的作为基料多次循环使用,可能导致碳源流失,应考虑在每次混合过程中添加一些高纤维素含量的辅料,用于补充碳源,辅料的添加量在5%-8%之间。It can be seen from this: 1. It is feasible to mix fresh sludge with fresh sludge as a base material for biological drying after drying; 2. The optimal formula of fresh sludge and base material is a weight ratio of 1:1.4 to 1.6; 3. . Since biological drying is a process of biological activity, an appropriate carbon-to-nitrogen ratio is required. If the dried sludge is used as a base material for multiple cycles, it may lead to the loss of carbon sources. It should be considered to add it during each mixing process. Some auxiliary materials with high cellulose content are used to supplement carbon sources, and the amount of auxiliary materials added is between 5% and 8%.
2、菌剂的选择及配比2. Selection and ratio of bacterial agents
①、微生物菌剂的筛选试验。① Screening test of microbial agents.
菌剂:选用由中国农业大学农用生物制剂中试基地提供的多种菌株培养的复合型菌剂,该复合型菌剂包括有嗜热芽孢杆菌、高温放线菌、耐高温酵母菌、除臭菌四种菌。其中嗜热芽孢杆菌的最低生长温度为28℃,最高生长温度70~77℃,最适宜生长繁殖温度为56~65℃。高温放线菌的生长合适温度为57℃~60℃;生孢子的合适温度为55℃,37℃。耐高温酵母菌最适宜生长温度一般在20℃~40℃之间,其在生物干化初期大量繁殖,起到升温和调节pH值的作用。该除臭菌是由2株好气性除臭菌复合而成。采用上述四种菌按不同的比例进行配制的复合型菌剂,即菌剂Ⅰ、菌剂Ⅱ、菌剂Ⅲ和菌剂Ⅳ,具体配比参见表4。Bacteria: a compound bacterial agent cultivated by a variety of strains provided by the pilot test base of agricultural biological preparations of China Agricultural University. The composite bacterial agent includes thermophilic bacillus, high temperature actinomycetes, high temperature resistant yeast, Bacteria four kinds of bacteria. Among them, the minimum growth temperature of thermophilic Bacillus is 28°C, the maximum growth temperature is 70-77°C, and the optimum growth and reproduction temperature is 56-65°C. The suitable temperature for the growth of hyperthermic actinomycetes is 57°C to 60°C; the suitable temperature for sporulation is 55°C and 37°C. The most suitable growth temperature for thermostable yeasts is generally between 20°C and 40°C, and they multiply in large numbers in the initial stage of biological drying, which plays a role in heating up and adjusting the pH value. The deodorant bacteria is compounded by two strains of aerobic deodorant bacteria. The above four kinds of bacteria were used to prepare the composite bacterial agents in different proportions, namely bacterial agents I, bacterial agents II, bacterial agents III and bacterial agents IV. See Table 4 for the specific proportions.
表4:复合型菌剂的配比(重量比)Table 4: Proportioning (weight ratio) of composite bacterial agents
污泥:生活污水处理厂经浓缩处理后的新鲜污泥,含水量为80%左右。Sludge: fresh sludge after concentrated treatment in domestic sewage treatment plants, with a water content of about 80%.
试验方法:将新鲜污泥与基料以重量比为1:1.5的比例进行搅拌混合后,建成4个大小、形状、重量一致的四个堆体,每个堆体10吨。然后将四种生物菌剂按2‰的比例(重量比,以新鲜污泥和基料总量计)均匀搅拌到对应的四个堆体中。每天观察温度变化,同时检测堆体水分含量的变化,绘制变化曲线图,如图2所示。Test method: After stirring and mixing fresh sludge and base material at a weight ratio of 1:1.5, four piles of the same size, shape, and weight were built, each pile was 10 tons. Then the four kinds of biological bacteria agents are evenly stirred into the corresponding four heaps at a ratio of 2‰ (weight ratio, based on the total amount of fresh sludge and base material). Observe the temperature change every day, and at the same time detect the change of the moisture content of the pile, and draw the change curve, as shown in Figure 2.
从图2中可以看出,对加入不同菌剂处理的四个堆体,连续11天进行温度测量,处理1和处理4的堆体升温快,温度变化较大,而处理1和处理2的堆体温度升高到52℃时几乎不在上升。处理3和处理4进行比较,处理4最好,相同时间温度升高最快,能快速蒸化堆体中水分,对于生物干化来讲,是最佳的生物菌剂。It can be seen from Figure 2 that for the four piles treated with different bacterial agents, the temperature was measured for 11 consecutive days. When the temperature of the pile rises to 52°C, it hardly increases. Comparing treatment 3 and treatment 4, treatment 4 is the best, the temperature rises the fastest at the same time, and can quickly evaporate the water in the pile, and it is the best biological agent for biological drying.
上述实验中经生物干化11天时,取每个堆体的物料分别进行水分检测,其不同菌剂产生热量蒸化水分的情况如表4。In the above experiment, after 11 days of biological drying, the materials of each pile were taken for moisture detection respectively.
表5:不同菌剂对堆体水分蒸发量的比较Table 5: Comparison of different bacterial agents on the water evaporation of the heap
从表5中可以看出,菌剂Ⅳ蒸发水分量最高,11天生物干化时间内可将50%的含水量降低到29%,脱水率达到了40%左右,去水效果比较明显。因此,本发明的菌剂采用由嗜热芽孢杆菌、高温放线菌、耐高温酵母菌、除臭菌混合而成的复合菌剂,它们之间的重量比如下:嗜热芽孢杆菌:高温放线菌:耐高温酵母菌:除臭菌为6:6:5:3。It can be seen from Table 5 that bacterial agent IV has the highest evaporation water content, and the water content of 50% can be reduced to 29% within 11 days of biological drying, and the dehydration rate has reached about 40%, and the dehydration effect is relatively obvious. Therefore, the microbial agent of the present invention adopts a composite microbial agent mixed by thermophilic bacillus, high-temperature actinomycetes, high-temperature-resistant yeast, and deodorant bacteria, and the weight ratio between them is as follows: thermophilic bacillus: high-temperature actinomycetes Nematodes: high temperature resistant yeasts: deodorizing bacteria is 6:6:5:3.
②、菌剂Ⅳ添加量的对比试验②. Contrast test of the addition amount of bacterial agent Ⅳ
在实际生产过程中,菌剂的使用量关系到处置成本的高低,为了研究菌剂使用量对污泥干化水分蒸发量的效果,我们对上述所选的菌剂Ⅳ进行了不同使用量蒸发水分效果的试验,干化周期为11天,其结果如表6所示。In the actual production process, the amount of bacterial agent used is related to the cost of disposal. In order to study the effect of the amount of bacterial agent used on the evaporation of sludge drying water, we evaporated the above-mentioned selected bacterial agent IV in different amounts. In the test of moisture effect, the drying cycle was 11 days, and the results are shown in Table 6.
从表6中可以看出,当菌剂使用量在2‰以上时,水分蒸发量无明显差异。在考虑处理成本的前提下,菌剂Ⅳ的合理使用量在2‰~2.5‰(重量比)之间为最佳。It can be seen from Table 6 that when the amount of bacterial agent used is above 2‰, there is no significant difference in water evaporation. Under the premise of considering the treatment cost, the reasonable usage amount of bacterial agent IV is the best between 2‰~2.5‰ (weight ratio).
表6:菌剂Ⅳ不同使用量对水分蒸发的比较Table 6: Comparison of different dosages of bacterial agent Ⅳ on water evaporation
从上述各实验可见,⑴污泥生物干化技术是利用微生物高温好氧发酵过程中有机物降解所产生的生物能,配合强制通风促进水分的蒸发去除,从而实现污泥快速干化。试验所筛选的菌剂Ⅳ是集中温菌、高温菌等四种菌株培养的复合型菌剂。⑵当菌剂使用量在2‰以上时,水分蒸发量无明显差异。在考虑处理成本的前提下,菌剂Ⅳ的合理使用量在2‰~2.5‰(重量比)之间为最佳。⑶由于污泥生物干化是利用微生物高温好氧发酵过程中有机物降解所产生的生物能达到蒸发水分的目的,因此在整个干化过程中要根据堆体中温度变化情况适时进行通风补氧,让生物菌体的活动维持在较高的水平。It can be seen from the above experiments that (1) sludge biological drying technology uses the bioenergy produced by the degradation of organic matter in the high-temperature aerobic fermentation process of microorganisms, and cooperates with forced ventilation to promote the evaporation and removal of water, so as to achieve rapid sludge drying. The bacterial agent IV screened in the test is a composite microbial agent cultivated by four strains of concentrated thermophilic bacteria and thermophilic bacteria. (2) When the amount of bacterial agent used is above 2‰, there is no significant difference in water evaporation. Under the premise of considering the treatment cost, the reasonable usage amount of bacterial agent IV is the best between 2‰~2.5‰ (weight ratio). (3) Since sludge biological drying uses the biological energy produced by the degradation of organic matter in the high-temperature aerobic fermentation process of microorganisms to achieve the purpose of evaporating water, it is necessary to timely ventilate and supplement oxygen during the entire drying process according to the temperature changes in the pile. Keep the activity of biological bacteria at a high level.
具体实施方式Detailed ways
实施例一Embodiment one
本发明的污泥生物干化处理方法,是经浓缩处理后的含水率为76%~84%的新鲜污泥进行干化处理过程。本实施例中直接从生活污水处理厂取经浓缩处理后的新鲜污泥3000kg,经检测其含水率为80%。该新鲜污泥的各项指标请参见表7;除此之外,其中还含有大量地有机物质和大肠菌、虫卵等。The sludge biological drying treatment method of the present invention is a drying treatment process of fresh sludge with a water content of 76% to 84% after concentration treatment. In this embodiment, 3000 kg of concentrated fresh sludge is taken directly from the domestic sewage treatment plant, and its water content is 80% after testing. For the indicators of the fresh sludge, please refer to Table 7; in addition, it also contains a large amount of organic matter, coliform bacteria, insect eggs, etc.
表7:新鲜污泥中主要有害物质含量。Table 7: Contents of main harmful substances in fresh sludge.
本发明污泥的生物干化处理方法包括有以下步骤:The biological drying treatment method of sludge of the present invention comprises the following steps:
a、调配新鲜污泥含水率:将上述含水率为80%的新鲜污泥与含水率为30%的基料按1∶1.5重量比进行搅拌混合,得含水率为50%的混合料。同时选用含水率为30%的基料4500kg。该基料优先选用污泥干化处理后的干化污泥。在第一次使用时,可选择含水量相当的物质(如黄土或灰渣等)代替污泥干化处理后的干化污泥。本实施例中基料选用黄土和灰渣的混合基料代替干化污泥,该混合基料重4500kg,含水率为30%。经理论分析,新鲜污泥与基料两者混合后的含水率为50%。并同时检测混合料中的碳氮质量比,并控制其碳氮质量比在24~26:1之间,在该碳氮质量比范围内有利于微生物分解有机物,如果碳氮比过大,微生物的分解作用变慢,不利于干化。经检测其碳氮质量比约为25:1,满足上述条件。a, deploy fresh sludge water content: the above-mentioned fresh sludge with a water content of 80% and the base material with a water content of 30% are stirred and mixed in a weight ratio of 1:1.5 to obtain a mixture with a water content of 50%. Select the base material 4500kg that moisture content is 30% for use simultaneously. The base material is preferably dried sludge after sludge drying treatment. When using for the first time, materials with equivalent water content (such as loess or ash) can be selected to replace the dried sludge after sludge drying treatment. In this embodiment, the mixed base material of loess and ash is selected as the base material instead of dried sludge. The mixed base material weighs 4500 kg and has a moisture content of 30%. According to theoretical analysis, the moisture content of fresh sludge and base material after mixing is 50%. At the same time, the carbon-nitrogen mass ratio in the mixture is detected, and the carbon-nitrogen mass ratio is controlled between 24 and 26:1. In this range of carbon-nitrogen mass ratio, it is beneficial for microorganisms to decompose organic matter. If the carbon-nitrogen ratio is too large, microorganisms will The decomposition of the product slows down, which is not conducive to drying. It has been detected that the mass ratio of carbon to nitrogen is about 25:1, which meets the above conditions.
将上述的含水率为80%的新鲜污泥3000kg与含水率为30%的基料4500kg进行搅拌混合,得混合料7500kg;该混合料含水率为50%;其物质含量中的碳氮质量比为25:1。3000kg of fresh sludge with a water content of 80% and 4500 kg of base material with a water content of 30% are stirred and mixed to obtain a mixture of 7500 kg; the water content of the mixture is 50%; the mass ratio of carbon and nitrogen in its substance content is 25:1.
该新鲜污泥与基料的搅拌混合是在密闭负压空间(密闭负压空间一般根据搅拌机的大小规格进行设计)内由搅拌机进行混合搅拌过程。本实施例中新鲜污泥和基料分别由螺旋输送机定量输送至设在密闭负压空间内的搅拌站;该密闭负压空间设有除臭系统,该除臭系统用于将密闭负压空间内所产生的臭气进行处理,达标后排放。该密闭负压空间中所产生的臭气等由除臭系统处理后达标排放。由搅拌站中的搅拌机将新鲜污泥和基料充分搅拌完成其搅拌混合工艺,该搅拌机的搅拌时间根据搅拌机容量及转速而定,一般地,对于转速为100转/分搅拌机,其搅拌时间可为60~90s。上述新鲜污泥和基料经搅拌机搅拌均匀后,得混合料。The stirring and mixing of the fresh sludge and the base material is carried out by the mixer in the closed negative pressure space (the closed negative pressure space is generally designed according to the size and specification of the mixer). In this embodiment, the fresh sludge and the base material are quantitatively transported to the mixing station in the closed negative pressure space by the screw conveyor respectively; The odor generated in the space is treated and discharged after reaching the standard. The odor generated in the closed negative pressure space is treated by the deodorization system and then discharged up to standard. The mixer in the mixing station fully mixes the fresh sludge and the base material to complete the mixing process. The mixing time of the mixer depends on the capacity and speed of the mixer. Generally, for a mixer with a speed of 100 rpm, the mixing time can be 60-90s. The above-mentioned fresh sludge and base material are uniformly stirred by a mixer to obtain a mixture.
b、添加菌剂:向步骤a所得的混合料中加入混合料重量的2.0‰~2.5‰的复合型菌剂并拌匀,得待干化料。上述的混合料经布料机输送至污泥生物干化槽。该污泥生物干化槽(或干化池)可采用以下规格:长×宽×高为72m×4.28m×2.4m,其日处理污泥量200t/d。该污泥生物干化槽设置在好氧发酵车间内。其槽底铺设有曝气系统,槽头设有翻堆机和换轨台车通道(用于翻堆机转槽作业),槽尾设有除臭抽风装置,一般情况下,可根据生物干化槽布设条数的进行配制相关设备。如设置10条生物干化槽时,可匹配2台翻堆机、2台换轨台车,4台曝气风机,10台除臭风机。向由布料机输送至污泥生物干化槽中的混合料中按2.0‰(以混合料的总量计)的比值加入复合型菌剂15kg,该复合型菌剂均匀喷撒至混合料的表面,再由翻堆机进行翻动,以便复合型菌剂均匀掺入混合料中。经上述过程得待干化料约7500kg。b. Add bacterial agent: add 2.0‰~2.5‰ of compound bacterial agent to the mixed material obtained in step a and mix well to obtain dry chemical material. The above-mentioned mixture is transported to the sludge biological drying tank through the distributor. The sludge biological drying tank (or drying tank) can adopt the following specifications: length x width x height is 72m x 4.28m x 2.4m, and its daily sludge treatment volume is 200t/d. The sludge biological drying tank is set in the aerobic fermentation workshop. The bottom of the tank is equipped with an aeration system, the head of the tank is equipped with a compost turning machine and a track-changing trolley channel (for the compost turning machine to transfer to the tank), and the tail of the tank is equipped with a deodorizing ventilation device. Prepare the relevant equipment according to the number of chemical tanks. If 10 biological drying tanks are set up, it can be matched with 2 compost turning machines, 2 track changing trolleys, 4 aeration fans and 10 deodorizing fans. Add 15kg of composite bacterial agent at a ratio of 2.0‰ (based on the total amount of the mixture) to the mixture that is transported to the sludge biological drying tank by the distributor, and the composite bacterial agent is evenly sprayed to the mixture. The surface is then turned by a compost turner so that the compound bacterial agent can be evenly mixed into the mixture. Through the above process, about 7500kg of chemical material to be dried is obtained.
c、污泥的发酵、干化:将步骤b所得的待干化料堆成发酵干化泥堆进行发酵、干化,得干化污泥。上述待干化料再由堆翻机在污泥生物干化槽内堆成泥堆进行发酵干化。所堆成的发酵干化泥堆的高不大于2m,宽不大于4m。然后每天由堆翻机将该泥堆翻抛一次并堆成堆,每次翻抛移动距离不少于6m,该翻抛过程即是堆动混合料移动的过程。该曝气系统用于在污泥发酵、干化过程中对生物干化槽内的污泥进行间断式强制通风,以使复合型菌剂中的好氧发酵菌种得到更好的发酵。上述堆成的发酵干化泥堆在发酵、干化的同时,由曝气系统进行间隔3小时,通风1小时的强制通风(一般通风时间和间隔与泥堆的高度有关,在堆高2m的情况下,可采用间隔3小时,通风1小时),以使好氧发酵的菌种得至更好的发酵。该曝气系统包括有风机、管路、阀门及控制系统,其管路铺设在槽底和槽壁上。上述待发酵干化料经11天的发酵、干化后,检测其含水率降至30%,得干污泥约5340kg。该干污泥实现了污泥的减量化。该干污泥经皮带输送系统自动输送至成品库中,以做它用,如循环利用。所得干污泥经检测达到了相关质量标准。具体数据请参见表8。c. Fermentation and drying of sludge: Pile the material to be dried obtained in step b into a fermented and dried sludge pile for fermentation and drying to obtain dried sludge. The above-mentioned materials to be dried are then piled up into mud piles by a stacker in the sludge biological drying tank for fermentation and drying. The height of the pile of fermented and dried sludge is not more than 2m, and the width is not more than 4m. Then the pile of mud is turned over once a day by the stacker and piled up into piles, and the moving distance of each turning is not less than 6m. The turning process is the process of moving the piled mixture. The aeration system is used for intermittent forced ventilation of the sludge in the biological drying tank during the sludge fermentation and drying process, so that the aerobic fermentation bacteria in the compound bacterial agent can be better fermented. The above-mentioned fermented and dried mud heap piled up is fermented and dried, and the aeration system is carried out with an interval of 3 hours and forced ventilation of ventilation for 1 hour (the general ventilation time and interval are related to the height of the mud heap, and when the height of the heap is 2m In some cases, an interval of 3 hours and ventilation for 1 hour) can be used to allow better fermentation of the aerobic fermentation strains. The aeration system includes a fan, pipelines, valves and a control system, and the pipelines are laid on the tank bottom and the tank wall. After 11 days of fermentation and drying, the moisture content of the material to be fermented and dried was reduced to 30%, and about 5340 kg of dry sludge was obtained. This dried sludge achieves sludge reduction. The dried sludge is automatically transported to the finished product warehouse through the belt conveyor system for other uses, such as recycling. The obtained dry sludge has reached relevant quality standards after testing. Please refer to Table 8 for specific data.
表8:干化污泥的检测结果。Table 8: Test results of dried sludge.
上述所得的干化污泥中含有各种有机物质、各种营养元素和能量。可广泛用于以下方面:一是土地利用,将污泥中的有机质和营养元素补充到土地;二是通过厌氧消化或焚烧等技术回收污泥中的能量;三是通过利用干化污泥焚烧后的灰渣制砖来实现污泥资源化。The dried sludge obtained above contains various organic substances, various nutrients and energy. It can be widely used in the following aspects: first, land utilization, to supplement the organic matter and nutrients in the sludge to the land; second, to recover the energy in the sludge through anaerobic digestion or incineration; third, through the use of dried sludge The incinerated ash is used to make bricks to realize sludge recycling.
实施例二Embodiment two
本发明的污泥生物干化处理方法,是经浓缩处理后的含水率为76%~84%的新鲜污泥进行干化处理过程。本实施例中直接从生活污水处理厂取经浓缩处理后的新鲜污泥5000kg,经检测其含水率为82%。该新鲜污泥的各项指标与上表7大致相同。本发明污泥的生物干化处理方法包括有以下步骤:The sludge biological drying treatment method of the present invention is a drying treatment process of fresh sludge with a water content of 76% to 84% after concentration treatment. In this embodiment, 5000 kg of concentrated fresh sludge is taken directly from the domestic sewage treatment plant, and its water content is 82% after testing. The indicators of the fresh sludge are roughly the same as in Table 7 above. The biological drying treatment method of sludge of the present invention comprises the following steps:
a、调配新鲜污泥含水率:将上述含水率为82%的新鲜污泥3000kg与含水率为30%的基料按1∶1.6重量比进行搅拌混合,得含水率为50%的混合料。本实施例中所选用的基料为实施例一中的干化污泥,含水率为30%,重量为4800kg,经理论分析,新鲜污泥与基料两者混合后的含水率为50%。并同时检测混合料中的碳氮比,经检测其碳氮质量比22:1,该碳氮质量比不利于微生物分解有机物。通过向混合料中添加辅料后,使其碳氮比符合标准。本实施例中所添加的辅料为稻草和草料的混合料。根据就地取材原则,也可选用秸秆。所添加辅料粒度不大于3mm,含水率在10%~25%。辅料的添加量可根据混合料的重量、所测定的碳氮质量比以及辅料的性质来确定。a, allotment fresh sludge water content: 3000kg of the above-mentioned fresh sludge with a water content of 82% and the base material with a water content of 30% are stirred and mixed in a weight ratio of 1: 1.6 to obtain a mixture with a water content of 50%. The base material used in this example is the dried sludge in Example 1, with a moisture content of 30% and a weight of 4800kg. According to theoretical analysis, the moisture content of fresh sludge and base material after mixing is 50%. . At the same time, the carbon-to-nitrogen ratio in the mixture was detected, and the carbon-to-nitrogen mass ratio was detected to be 22:1, which is not conducive to microbial decomposition of organic matter. After adding auxiliary materials to the mixture, its carbon-nitrogen ratio meets the standard. The auxiliary material added in the present embodiment is the mixture of straw and forage. According to the principle of local materials, straw can also be used. The particle size of the added auxiliary materials is not greater than 3mm, and the moisture content is between 10% and 25%. The amount of auxiliary materials added can be determined according to the weight of the mixture, the measured carbon-nitrogen mass ratio and the properties of auxiliary materials.
将上述的含水率为82%的新鲜污泥3000kg与含水率为30%的干污泥4800kg进行搅拌,同时加入一定量的稻草和草料的辅料进行搅拌混合,得混合料约7800kg;该混合料含水率为50%;其物质含量中的碳氮质量比处于24~26:1。3000kg of fresh sludge with a moisture content of 82% and 4800kg of dry sludge with a moisture content of 30% are stirred, and a certain amount of straw and forage auxiliary materials are added to mix and mix to obtain a mixture of about 7800kg; The water content is 50%; the mass ratio of carbon and nitrogen in the material content is 24-26:1.
该新鲜污泥与基料的搅拌混合是在密闭负压空间内由搅拌机进行混合搅拌过程。该密闭负压空间设有除臭系统,该密闭负压空间中所产生的臭气等由除臭系统处理后达标排放。上述新鲜污泥和干污泥及辅料经搅拌机搅拌均匀后,得混合料约7800kg。The stirring and mixing of the fresh sludge and the base material is carried out by a mixer in a closed negative pressure space. The closed negative pressure space is equipped with a deodorization system, and the odor generated in the closed negative pressure space is treated by the deodorization system and then discharged up to standard. The above-mentioned fresh sludge, dry sludge and auxiliary materials are uniformly stirred by a mixer to obtain about 7800 kg of mixed materials.
b、添加菌剂:向步骤a所得的混合料中加入混合料重量的2.5‰的复合型菌剂并拌匀,得待干化料。向由布料机输送至污泥生物干化槽中的混合料中按2.5‰(以混合料的总量计)的比值加入复合型菌剂19.5kg,该复合型菌剂均匀喷撒至混合料的表面,再由翻堆机进行翻动,以便复合型菌剂均匀掺入混合料中。经上述过程得待干化料约7800kg。B, add bacterial agent: add the compound bacterial agent of 2.5‰ of the weight of mixture to the compound material obtained in step a and mix well, get the material to be dried. Add 19.5kg of compound bacteria agent to the mixture transported by the distribution machine to the sludge biological drying tank at a ratio of 2.5‰ (in terms of the total amount of the mixture), and the compound bacteria agent is evenly sprayed onto the mixture surface, and then turned by the turner so that the compound bacterial agent can be evenly mixed into the mixture. Through the above process, about 7800kg of chemical material to be dried is obtained.
c、污泥的发酵、干化:将步骤b所得的待干化料堆成发酵干化泥堆进行发酵、干化,得干化污泥。上述待干化料再由堆翻机在污泥生物干化槽内堆成泥堆进行发酵干化。每天由堆翻机将该泥堆翻抛一次并堆成堆。上述堆成的发酵干化泥堆在发酵、干化的同时,由曝气系统进行间隔3小时,通风1小时的强制通风以使好氧发酵的菌种得至更好的发酵。该曝气系统包括有风机、管路、阀门及控制系统,其管路铺设在槽底和槽壁上。上述待发酵干化料经12天的发酵、干化后,检测其含水率降至28%,得干污泥约5400kg。该干污泥实现了污泥的减量化。该干污泥经皮带输送系统自动输送至成品库中,以做它用,如循环利用。所得干污泥经检测达到了相关质量标准。具体数据与表8数据相接近。c. Fermentation and drying of sludge: Pile the material to be dried obtained in step b into a fermented and dried sludge pile for fermentation and drying to obtain dried sludge. The above-mentioned materials to be dried are then piled up into mud piles by a stacker in the sludge biological drying tank for fermentation and drying. The mud heap is turned and thrown once a day by a stacker and piled into piles. The above-mentioned fermented and dried mud heap piled up is fermented and dried, and the aeration system is forced to ventilate for 3 hours at an interval of 1 hour so that the aerobic fermentation bacteria can be better fermented. The aeration system includes a fan, pipelines, valves and a control system, and the pipelines are laid on the tank bottom and the tank wall. After 12 days of fermentation and drying, the water content of the material to be fermented and dried was reduced to 28%, and about 5400 kg of dry sludge was obtained. This dried sludge achieves sludge reduction. The dried sludge is automatically transported to the finished product warehouse through the belt conveyor system for other uses, such as recycling. The obtained dry sludge has reached relevant quality standards after testing. The specific data is close to the data in Table 8.
上述所得的干污泥中含有各种有机物质、各种营养元素和能量。可广泛用于以下方面:一是土地利用,将污泥中的有机质和营养元素补充到土地;二是通过厌氧消化或焚烧等技术回收污泥中的能量;三是通过利用干化污泥焚烧后的灰渣制砖来实现污泥资源化。The dry sludge obtained above contains various organic substances, various nutrients and energy. It can be widely used in the following aspects: first, land utilization, to supplement the organic matter and nutrients in the sludge to the land; second, to recover the energy in the sludge through anaerobic digestion or incineration; third, through the use of dried sludge The incinerated ash is used to make bricks to realize sludge recycling.
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