CN104529022B - A kind of closed treatment method of printing and dying wastewater - Google Patents

A kind of closed treatment method of printing and dying wastewater Download PDF

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Publication number
CN104529022B
CN104529022B CN201510011144.1A CN201510011144A CN104529022B CN 104529022 B CN104529022 B CN 104529022B CN 201510011144 A CN201510011144 A CN 201510011144A CN 104529022 B CN104529022 B CN 104529022B
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filter tank
tank
active carbon
water
backwash
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CN104529022A (en
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张华军
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Chongqing Tuwei Environmental Protection Technology Co.,Ltd.
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项敬来
张华军
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/308Dyes; Colorants; Fluorescent agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/30Nature of the water, waste water, sewage or sludge to be treated from the textile industry

Abstract

The invention discloses a kind of closed treatment method of printing and dying wastewater, waste water passes through between filter, cistern, regulating reservoir, reaction tank, quartz sand filter tank, active carbon filter tank, floating stuffing filter tank, backwash successively, external automatic medicament feeding machine, air blast, backwashing pump, clear water reserviors. Quartz sand filter tank, active carbon filter tank and floating stuffing filter tank are detachable filter tank, can manually carry out replacing and the cleaning of filler. In sanitary wastewater by this method processing, the clearance of COD reaches 97.8%; The clearance of total nitrogen reaches 96.9%, and the clearance of five-day BOD reaches 96.4%, and the clearance of suspension reaches 95.9%, chroma removal rate 94.8%, turbidity removal rate 98.2%.

Description

A kind of closed treatment method of printing and dying wastewater
Technical field
The present invention relates to a kind of processing method of closed dyeing waste water, belong to the water treatment field in environmental protection.
Background technology
It is environmental protection and energy saving (low-carbon (LC)) problems that Development of Textile Industry one of mainly hinders, and the subject matter of environmental protection is waste water, and approximately 80% textile waste comes from dyeing. Statistics demonstration, 2,300,000,000 tons of textile waste discharge capacitys in 2008, occupy the 3rd of each industrial trade, account for 10.60% of national discharged volume of industrial waste water. 31.4 ten thousand tons of COD in textile industry waste discharge (CODCr) discharge capacitys, occupy the 4th of each industrial trade, account for 7.76% of national industrial wastewater CODCr. These data are the statistics to the above enterprise of scale, and real data is much larger possibly. In fact dyeing is that medium-sized and small enterprises proportion accounts for 99.6% taking medium-sized and small enterprises as main competitive industry, and non-public enterprises account for 95%, and a large amount of small enterprises data are also not included in. If need carry out dyeing and printing process in 70% of fiber process amount, year waste discharge is about 3,000,000,000 tons of left and right.
The successful example of printing and dyeing mill's wastewater treatment is more, but not good quite a few of effect, its reason roughly has following several situation: (1) printing and dyeing mill does not analyze self waste water speciality (water quality, the water yield), indiscriminately imitates his factory's experience, and result is often undesirable. (2) by the design specification of municipal sewage treatment, for treatment of dyeing wastewater, only change some parameters, cause very large loss. Particularly in early days, large-scale printing and dyeing mill Wastewater Concentrated, be all responsible for by large-scale designing institute, and it is understood in depth not to dyeing waste water character, causes very large loss. (3) new technology, new technology, new medicament, without pilot scale, are directly used in engineering, cause a lot of failures. New technology is many should pass through lab scale, pilot scale, could be used for engineering, and generally examination scale is 3% ~ 5% of the engineering water yield, at most about magnify 20. Laboratory research achievement is directly used in engineering, and difficulty has successful case. Engineering should adopt ripe, the safest technology. (4) the close waste water of production technology, can adopt similar treatment process, but also will, according to water quality, the suitable adjustment technology parameter of the water yield, ensure processing horizontal. (5) actual motion technology and administrative skill are improper, and do not change and appropriately adjust according to waste water, be also the reason of fluctuation of service.
The progress of the rise of Silk and finishing process in printing and dye-ing technology, make the bio-refractory organic matters such as PVA slurry, artificial silk alkaline hydrolysis thing (being mainly O-phthalic acids material), New-type adjuvant enter in a large number dyeing waste water, its COD concentration also rises to 2000~3000mg/L by original hundreds of mg/L, thereby make original biological treatment system COD clearance drop to 50% left and right from 70%, even lower. Traditional biological treatment has been subject to serious challenge; Traditional chemical precipitation and By Bubble-floating Method are only also 30% left and right to the COD clearance of this class dyeing waste water. Therefore the effective techniques of Dyeing Wastewater Treatment of exploiting economy becomes the problem that current environmental protection industry (epi) is paid close attention to day by day.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of closed treatment method of printing and dying wastewater, dyeing waste water enters the water inlet of filter by pipeline, after filtration removal particle, enter the water inlet of cistern by the delivery port of filter, when the water level of cistern arrives after preset value, waste water flows out from the delivery port of cistern the water inlet that enters regulating reservoir, and pH meter is set in regulating reservoir, adjusting pH is 3-5, and external automatic medicament feeding machine adds FeSO by the first medicine-pouring port of regulating reservoir4Amount be 1g/L, external automatic medicament feeding machine adds H by the second medicine-pouring port of regulating reservoir2O2Amount be 2.67mL/L, waste water stops after 1h in regulating reservoir, enters the water inlet of reaction tank from delivery port, reaction tank outer wall is provided with insulating protective layer, is provided with irony electrode pair in pond, interval 10cm between electrode, adds flocculant FeCl3When reaction, between irony electrode, be 1A by electric current, after reaction, water enters the water inlet of quartz sand filter tank from the delivery port of reaction tank, the delivery port of quartz sand filter tank connects the water inlet of active carbon filter tank by pipeline, in active carbon filter tank, be provided with dissolved oxygen instrument, dissolved oxygen is controlled at 4mg/L, at the bottom of tank, be provided with the cobble supporting layer of high 20cm, on cobble supporting layer, be filled with the active carbon layer that thickness is 200cm, height of water level is 250cm, and active carbon is selected coal mass active carbon, coal mass active carbon size 0.4mm, porosity 50%-60%, bulk density 400kg/m3,After stopping 1h in active carbon filter tank, water enters the water inlet of floating stuffing filter tank from the delivery port of active carbon filter tank, in floating stuffing filter tank, be provided with dissolved oxygen instrument, dissolved oxygen is controlled at 4mg/L, at the bottom of tank, be provided with the cobble supporting layer of high 20cm, on cobble supporting layer, loading thickness is the hollow modified plastics floating stuffing layer of 230cm, porosity 98%, bulk density 60kg/m3, height of water level is 250cm, waterpower, and current stop 2h from the delivery port at the bottom of tank and enter drainage pipeline in tank deck enters tank; Between backwash, be provided with air blast, backwashing pump and clear water reserviors, the first backwash outlet between backwash connects the backwash entrance of quartz sand filter tank by pipeline, the second backwash outlet between backwash connects the backwash entrance of active carbon filter tank by pipeline, the 3rd backwash outlet between backwash connects the backwash entrance of floating stuffing filter tank by pipeline, backwash adopts gas punching, air water to combine the mode of flushing, water rinse combination, first gas rushes 30min, air water is combined flushing 30min, the mode of last water rinse 15min again.
Quartz sand filter tank, active carbon filter tank and floating stuffing filter tank are detachable filter tank, can manually carry out replacing and the cleaning of filler.
On quartz sand filter tank, active carbon filter tank and floating stuffing filter tank, leave water intaking and detect mouth, tank body adopts transparent material manufacture to form simultaneously.
The invention has the advantages that:
(1) stable equipment operation, floor space is little, and hydraulic detention time is short.
(2) in the sanitary wastewater by this method processing, the clearance of COD reaches 97.8%; The clearance of total nitrogen reaches 96.9%, and the clearance of five-day BOD reaches 96.4%, and the clearance of suspension reaches 95.9%, chroma removal rate 94.8%, turbidity removal rate 98.2%.
(3) the material dirt-removing power of selecting is strong, and surface hydrophilic power is strong, and investment operating cost is low.
(4) safeguard that easily operating automation degree is high, does and makes high efficient and reliable, the construction period is short, has mobility.
Brief description of the drawings
Fig. 1 is a kind of equipment schematic diagram of the closed Waste Water Treatment that ignites.
Between 1-filter, 2-cistern, 3-regulating reservoir, 4-reaction tank, 5-quartz sand filter tank, 6-active carbon filter tank, 7-floating stuffing filter tank, 8-backwash, the external automatic medicament feeding machine of 22-, 23-clear water reserviors, 24-backwashing pump, 25-air blast.
Detailed description of the invention
A kind of closed treatment method of printing and dying wastewater, dyeing waste water enters the water inlet of filter 1 by pipeline, after filtration removal particle, enter the water inlet of cistern 2 by the delivery port of filter, when the water level of cistern 2 arrives after preset value, waste water flows out from the delivery port of cistern 2 water inlet that enters regulating reservoir 3, in regulating reservoir 3, pH meter is set, adjusting pH is 3-5, and external automatic medicament feeding machine 22 adds FeSO by the first medicine-pouring port of regulating reservoir4Amount be 1g/L, external automatic medicament feeding machine 22 adds H by the second medicine-pouring port of regulating reservoir2O2Amount be 2.67mL/L, waste water stops after 1h in regulating reservoir 3, enters the water inlet of reaction tank 4 from delivery port, reaction tank 4 outer walls are provided with insulating protective layer, are provided with irony electrode pair in pond, interval 10cm between electrode, adds flocculant FeCl3When reaction, between irony electrode, be 1A by electric current, after reaction, water enters the water inlet of quartz sand filter tank from the delivery port of reaction tank, the delivery port of quartz sand filter tank connects the water inlet of active carbon filter tank by pipeline, in active carbon filter tank, be provided with dissolved oxygen instrument, dissolved oxygen is controlled at 4mg/L, at the bottom of tank, be provided with the cobble supporting layer of high 20cm, on cobble supporting layer, be filled with the active carbon layer that thickness is 200cm, height of water level is 250cm, and active carbon is selected coal mass active carbon, coal mass active carbon size 0.4mm, porosity 50%-60%, bulk density 400kg/m3,After stopping 1h in active carbon filter tank, water enters the water inlet of floating stuffing filter tank 7 from the delivery port of active carbon filter tank 6, in floating stuffing filter tank 7, be provided with dissolved oxygen instrument, dissolved oxygen is controlled at 4mg/L, at the bottom of tank, be provided with the cobble supporting layer of high 20cm, on cobble supporting layer, loading thickness is the hollow modified plastics floating stuffing layer of 230cm, porosity 98%, bulk density 60kg/m3, height of water level is 250cm, waterpower, and current stop 2h from the delivery port at the bottom of tank and enter drainage pipeline in tank deck enters tank; Between backwash, 8 are provided with air blast 25, backwashing pump and clear water reserviors, between backwash, the first backwash outlet of 8 connects the backwash entrance of quartz sand filter tank 5 by pipeline, between backwash, the second backwash outlet of 8 connects the backwash entrance of active carbon filter tank 6 by pipeline, between backwash, 8 the 3rd backwash outlet connects the backwash entrance of floating stuffing filter tank 7 by pipeline, backwash adopts gas punching, air water to combine the mode of flushing, water rinse combination, first gas rushes 30min, air water is combined flushing 30min, the mode of last water rinse 15min again. Quartz sand filter tank, active carbon filter tank and floating stuffing filter tank are detachable filter tank, can manually carry out replacing and the cleaning of filler. On quartz sand filter tank, active carbon filter tank and floating stuffing filter tank, leave water intaking and detect mouth, tank body adopts transparent material manufacture to form simultaneously.

Claims (3)

1. a closed treatment method of printing and dying wastewater, it is characterized in that: dyeing waste water enters the water inlet of filter by pipeline, after filtration removal particle, enter the water inlet of cistern by the delivery port of filter, when the water level of cistern arrives after preset value, waste water flows out from the delivery port of cistern the water inlet that enters regulating reservoir, pH meter is set in regulating reservoir, and regulating pH value is 3-5, and external automatic medicament feeding machine adds FeSO by the first medicine-pouring port of regulating reservoir4Amount be 1g/L, external automatic medicament feeding machine adds H by the second medicine-pouring port of regulating reservoir2O2Amount be 2.67mL/L, waste water stops after 1h in regulating reservoir, enters the water inlet of reaction tank from delivery port, reaction tank outer wall is provided with insulating protective layer, is provided with irony electrode pair in pond, interval 10cm between electrode, adds flocculant FeCl3When reaction, between irony electrode, be 1A by electric current, after reaction, water enters the water inlet of quartz sand filter tank from the delivery port of reaction tank, the delivery port of quartz sand filter tank connects the water inlet of active carbon filter tank by pipeline, in active carbon filter tank, be provided with dissolved oxygen instrument, dissolved oxygen is controlled at 4mg/L, at the bottom of tank, be provided with the cobble supporting layer of high 20cm, on cobble supporting layer, be filled with the active carbon layer that thickness is 200cm, height of water level is 250cm, and active carbon is selected coal mass active carbon, coal mass active carbon size 0.4mm, porosity is 50%-60%, bulk density 400kg/m3,After stopping 1h in active carbon filter tank, water enters the water inlet of floating stuffing filter tank from the delivery port of active carbon filter tank, in floating stuffing filter tank, be provided with dissolved oxygen instrument, dissolved oxygen is controlled at 4mg/L, at the bottom of tank, be provided with the cobble supporting layer of high 20cm, on cobble supporting layer, loading thickness is the hollow modified plastics floating stuffing layer of 230cm, porosity 98%, bulk density 60kg/m3, height of water level is 250cm, waterpower, current stop 2h from the delivery port at the bottom of tank and enter drainage pipeline in tank deck enters tank; Between backwash, be provided with air blast, backwashing pump and clear water reserviors, the first backwash outlet between backwash connects the backwash entrance of quartz sand filter tank by pipeline, the second backwash outlet between backwash connects the backwash entrance of active carbon filter tank by pipeline, the 3rd backwash outlet between backwash connects the backwash entrance of floating stuffing filter tank by pipeline, backwash adopts gas punching, air water to combine the mode of flushing and water rinse combination, first gas rushes 30min, air water is combined flushing 30min, the mode of last water rinse 15min again.
2. the closed treatment method of printing and dying wastewater of one according to claim 1, is characterized in that, quartz sand filter tank, active carbon filter tank and floating stuffing filter tank are detachable filter tank, can manually carry out replacing and the cleaning of filler.
3. the closed treatment method of printing and dying wastewater of one according to claim 1, is characterized in that, leaves water intaking and detect mouth on quartz sand filter tank, active carbon filter tank and floating stuffing filter tank, and tank body adopts transparent material manufacture to form simultaneously.
CN201510011144.1A 2015-01-11 2015-01-11 A kind of closed treatment method of printing and dying wastewater Active CN104529022B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105060562A (en) * 2015-08-13 2015-11-18 山东省环科院环境工程有限公司 Deep treatment method of tannery wastewater

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101723548A (en) * 2009-12-10 2010-06-09 上海宝钢化工有限公司 System for recycling and treating coking wastewater
CN102701500A (en) * 2012-06-25 2012-10-03 龙岩市康琦环保科技有限公司 Printing and dyeing wastewater zero-discharge reuse treatment method
CN103539296A (en) * 2013-10-31 2014-01-29 四川凯沃环保科技有限公司 Method and device for treating high-concentration nonbiodegradable organic wastewater
CN103755093A (en) * 2013-12-13 2014-04-30 盐城工学院 Fenton fluidized bed-IBAC combined method used for advanced treatment of textile dyeing and finishing waste water
CN104478139A (en) * 2015-01-11 2015-04-01 叶澄 Closed type printing and dyeing waste water processing system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101723548A (en) * 2009-12-10 2010-06-09 上海宝钢化工有限公司 System for recycling and treating coking wastewater
CN102701500A (en) * 2012-06-25 2012-10-03 龙岩市康琦环保科技有限公司 Printing and dyeing wastewater zero-discharge reuse treatment method
CN103539296A (en) * 2013-10-31 2014-01-29 四川凯沃环保科技有限公司 Method and device for treating high-concentration nonbiodegradable organic wastewater
CN103755093A (en) * 2013-12-13 2014-04-30 盐城工学院 Fenton fluidized bed-IBAC combined method used for advanced treatment of textile dyeing and finishing waste water
CN104478139A (en) * 2015-01-11 2015-04-01 叶澄 Closed type printing and dyeing waste water processing system

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