The processing method of waste gas in a kind of peony extract production
Technical field
The present invention relates to technical field of waste gas treatment, particularly relate to the processing method of waste gas in the production of a kind of peony extract.
Background technology
Exhaust-gas treatment, also referred to as waste gas purification (Flue gas purification) the mainly pointer work of administering industrial waste gas such as dust granules thing, flue gas flue dust, gas with foreign flavor, toxic and harmful that industrial site produces.Common waste gas purification has factory's fume and exhaust gas purifying, workshop dust waste gas purification, organic waste-gas purification, the purification of waste gas peculiar smell, acid-base waste gas purifying, purification of chemical waste gas etc.
Exhaust-gas treatment, mainly comprises following methods:
1) diffusion method is diluted: principle: frowziness ground gas is drained into air by chimney, or uses odorless Dilution air, reduce odorant concentration to reduce stink.The scope of application: in being applicable to process, the foul gas discharged in a organized way of low concentration.Advantage: expense is low, equipment is simple.Shortcoming: be subject to meteorological condition restriction, odorant still exists.
2) water absorption method: principle: utilize the characteristic that Cucumber in foul smell is soluble in water, makes foul smell composition directly contact with water, thus is dissolved in water and reaches deodorization object.The scope of application: foul gas that is water-soluble, emission source in a organized way.Advantage: technique is simple, and convenient management, the low generation secondary pollution of equipment operation expense, need process cleaning solution.Shortcoming: purification efficiency is low, should with other technologies conbined usage, to mercaptan, the poor processing effect such as aliphatic acid.
3) aeration type activated sludge deodorization method: principle: odorant is distributed in the mixed liquid containing activated sludge with aeration form, applied widely by the microbial degradation odorant of suspension growth.The scope of application: Japan is for the Odor control of night soil plant, sewage treatment plant.Advantage: activated sludge is after domestication, and to the odor pollutant being no more than limit load amount, clearance can reach more than 99.5%.Shortcoming: the restriction being subject to aeration intensity, the application of this method also has certain limitation.
4) multimedium catalytic oxidation technique: principle: the solid fillers that in reaction tower, filling is special, the inner composite multimedium catalyst of filler.When under the effect of foul gas at air-introduced machine through packing layer, fully contact at solid phase filling surface in the liquid phase compound oxidant dispersing vaporific ejection with by special nozzle, and under the catalytic action of multimedium catalyst, the pollution factor in foul gas is adequately broken.
The extraction of Chinese herbaceous peony, main production process comprises extraction (alcohol extracting, concentrated, organic solvent are reclaimed), refining (extract and separate, concentrated, vacuum drying), essence dry (vacuum drying, spraying dry), general employing ethanol is as Extraction medium, and waste gas mainly produces in operations such as raw material extraction, spraying oven dry, dregs of a decoction oven dry.The waste gas of general plant extract just absorbs through simple water or directly discharges now, can produce serious pollution.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, in providing a kind of peony extract to produce, the processing method of waste gas, can effectively purify the waste gas produced in Chinese herbaceous peony leaching process, and successful.
The present invention is achieved through the following technical solutions, and specifically comprises the steps:
1) sub-cooled: send into low-temperature condenser after in the exhaust gas centralized produced in production and carry out sub-cooled, chilling temperature is 0-4 DEG C, and realize the initial gross separation of essential oil in waste gas, essential oil enters low-temperature storage tank;
2) spray column absorbs: step 1) waste gas out enters spray column process;
3) high altitude discharge: the gas processed by Cemented filling to factory's inner chimney high altitude discharge.
Described spray column is the level Four of series connection; liquid phase substance in level Four spray column is respectively the lower alkali lye of the concentration that with the addition of xanthans, with the addition of the higher alkali lye of the concentration of xanthans, with the addition of the higher alkali lye of the concentration of xanthans and water; wherein; the alkali lye that the first order with the addition of the concentration of xanthans lower is waste gas absorption main reaction tower; secondary, three-level protective; level Four water is to connect with subsequent technique process, and reduces alkali concn, is convenient to pipeline maintenance and repair.
The preferred 0.5-1.0% mass concentration of described xanthans addition.
Described alkali lye preferred NaOH, NaHCO
3, Na
2cO
3, described concentration is with reference to prior art.
The present invention with the addition of xanthans in the liquid phase substance of spray column, mainly consider that xanthans integrates thickening, suspension, emulsification in the world at present, is stable at, the biogum that best performance is got over, the molecular side chain end of xanthans contains the number of pyruvic acid group, its performance is had a significant impact, xanthans has the general performance of long chain macromolecule, but it contains more functional group than general macromolecule.Xanthans has good suspension effect to insoluble solid and oil droplet.Xanthans colloidal sol molecular energy forms the spiral EVA of superjunction crossed belt shape, forms the network structure of fragile similar glue, so can support the form of solid particle, drop and bubble, demonstrates very strong stable emulsifying effect and higher suspension ability.Xanthans is energy rapid solution in water, has well water-soluble.Also can dissolve in cold water especially, numerous and diverse process can be saved, easy to use.Xanthan gum solution has high viscosity under static or low shear action.The viscosity of xanthan gum solution can not variation with temperature and changing a lot, can viscosity B coefficent be there is because of heating in general polysaccharide, but the aqueous solution of xanthans viscosity between 10-80 DEG C has almost no change, even if the aqueous solution of low concentration still demonstrates stable high viscosity in wide temperature range.Xanthan gum solution is very stable to soda acid, is make its viscosity unaffected between 5-10 at pH, pH be less than 4 and be greater than 11 time viscosity have slight change.Xanthan gum solution can and many salting liquids (sylvite, sodium salt, calcium salt, magnesium salts etc.) miscible, viscosity is unaffected.Under higher salt concentrations condition, even in saturated salt solution, still keep its dissolubility and precipitation and flocculation do not occur, its viscosity is influenced hardly.
Compared with prior art, the present invention has the following advantages:
In the leaching process of 1, Chinese herbaceous peony, waste gas mainly produce extract at raw material, the operation such as spraying oven dry, dregs of a decoction oven dry.Abstraction process generally adopts water extraction or alcohol extracting, steam can be produced in water extraction process, and the flower of Chinese herbaceous peony, stem, Ye Zhong, containing a large amount of plants essential oils, Chinese herbaceous peony is soaked in hot water or water vapour, the essential oil discharged upwards volatilizees along with water vapour, if directly discharged, strong smell can be produced, the present invention passes through waste gas sub-cooled, the water vapour carrying essential oil condenses in low-temperature condenser, liquid is converted to again from gaseous state, essential oil proportion is lighter than water, and it is water insoluble, side waterborne can be swum in be removed again, below is containing micro-essential oil, with the liquid state of all water-soluble volatile substances, be called hydrosol, Chinese herbaceous peony value-added content of product can be increased after essential oil is separated with hydrosol.
2, in other operations that Chinese herbaceous peony is extracted, the pollution factor in waste gas is mainly NMHC, SS, SO
2, NO
xdeng, inorganization volatilization waste gas is mainly the ethanol volatile matter etc. of extraction or extraction process generation, and these pollution factors, at the alkali lye spray column by with the addition of xanthans, being compared and directly being used alkali lye, xanthans can form network structure in alkali lye, and pollution factor is more easily absorbed.
Detailed description of the invention
With embodiment, the invention will be further described below, but the present invention is not limited to these embodiments.
Embodiment 1:
In peony extract production, a processing method for waste gas, specifically comprises the steps:
1) sub-cooled: send into low-temperature condenser after in the exhaust gas centralized produced in production and carry out sub-cooled, chilling temperature is 0-4 DEG C, and realize the initial gross separation of essential oil in waste gas, essential oil enters low-temperature storage tank;
2) spray column absorbs: step 1) waste gas out enters spray column process;
Described spray column is the level Four of series connection, and the liquid phase substance in level Four spray column is respectively the lower alkali lye of the concentration that with the addition of xanthans, with the addition of the higher alkali lye of the concentration of xanthans, with the addition of the higher alkali lye of the concentration of xanthans and water; Described xanthans addition is 0.5% mass concentration;
3) high altitude discharge: the gas processed by Cemented filling to factory's inner chimney high altitude discharge.
Embodiment 2:
In peony extract production, a processing method for waste gas, specifically comprises the steps:
1) sub-cooled: send into low-temperature condenser after in the exhaust gas centralized produced in production and carry out sub-cooled, chilling temperature is 0-4 DEG C, and realize the initial gross separation of essential oil in waste gas, essential oil enters low-temperature storage tank;
2) spray column absorbs: step 1) waste gas out enters spray column process;
Described spray column is the level Four of series connection, and the liquid phase substance in level Four spray column is respectively the lower alkali lye of the concentration that with the addition of xanthans, with the addition of the higher alkali lye of the concentration of xanthans, with the addition of the higher alkali lye of the concentration of xanthans and water; Described xanthans addition is 1.0% mass concentration;
3) high altitude discharge: the gas processed by Cemented filling to factory's inner chimney high altitude discharge.
Result:
Discharge capacity (t/a) |
Dust (flue dust) |
SO
2 |
NO
X |
NMHC |
Embodiment 1 |
0.14 |
0.03 |
0.05 |
0.05 |
Embodiment 2 |
0.12 |
0.02 |
0.06 |
0.04 |
Prior art uncontrollable discharge |
|
|
|
7.90 |