CN104498772A - Solid-state antimony-mercury alloy for fluorescent lamps - Google Patents
Solid-state antimony-mercury alloy for fluorescent lamps Download PDFInfo
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- CN104498772A CN104498772A CN201410615868.2A CN201410615868A CN104498772A CN 104498772 A CN104498772 A CN 104498772A CN 201410615868 A CN201410615868 A CN 201410615868A CN 104498772 A CN104498772 A CN 104498772A
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- Prior art keywords
- mercury
- solid
- fluorescent lamps
- antimony
- state antimony
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- 229910000645 Hg alloy Inorganic materials 0.000 title abstract 5
- ZVTBWAYGRKISJK-UHFFFAOYSA-N [Sb].[Hg] Chemical compound [Sb].[Hg] ZVTBWAYGRKISJK-UHFFFAOYSA-N 0.000 title abstract 5
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 29
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 8
- 229910052718 tin Inorganic materials 0.000 claims abstract description 8
- 229910052787 antimony Inorganic materials 0.000 claims description 21
- 229910000497 Amalgam Inorganic materials 0.000 claims description 15
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 15
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract description 26
- 239000007788 liquid Substances 0.000 abstract description 14
- 230000009194 climbing Effects 0.000 abstract description 5
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 2
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- FAWGZAFXDJGWBB-UHFFFAOYSA-N antimony(3+) Chemical compound [Sb+3] FAWGZAFXDJGWBB-UHFFFAOYSA-N 0.000 description 2
- 230000005281 excited state Effects 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 230000005283 ground state Effects 0.000 description 2
- DAEJUPKPHRBQHZ-UHFFFAOYSA-N [Sn].[Hg] Chemical compound [Sn].[Hg] DAEJUPKPHRBQHZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
Landscapes
- Vessels And Coating Films For Discharge Lamps (AREA)
Abstract
Description
技术领域 technical field
本发明属于固汞技术领域,具体涉及一种荧光灯用固态锑汞合金。 The invention belongs to the technical field of solid mercury, in particular to a solid antimony amalgam for fluorescent lamps.
背景技术 Background technique
荧光灯中的汞原子在电场的作用下,不断地从基态激发成激发态,同时又由激发态返回到基态,并辐射出253.7nm的紫外线,涂覆在玻管内壁上的荧光粉吸收253.7nm紫外线把它转化为可见光。荧光灯使用液汞,存在的明显缺点是在荧光灯生产使用过程中,液汞极易流失,从而造成环境污染。同时由于液汞特性,每只灯管的注汞量不易准确控制。 Mercury atoms in the fluorescent lamp are continuously excited from the ground state to the excited state under the action of the electric field, and at the same time return from the excited state to the ground state, and radiate 253.7nm ultraviolet rays, and the fluorescent powder coated on the inner wall of the glass tube absorbs 253.7nm Ultraviolet light converts it into visible light. Fluorescent lamps use liquid mercury, and the obvious disadvantage is that liquid mercury is easily lost during the production and use of fluorescent lamps, resulting in environmental pollution. At the same time, due to the characteristics of liquid mercury, it is difficult to accurately control the amount of mercury injected into each lamp tube.
发明内容 Contents of the invention
发明目的:针对现有技术中存在的不足,本发明的目的在于提供一种荧光灯用固态锑汞合金,在常温下能提供与液汞相媲美的爬升速度。 Purpose of the invention: In view of the deficiencies in the prior art, the purpose of the invention is to provide a solid antimony amalgam for fluorescent lamps, which can provide a climbing speed comparable to that of liquid mercury at room temperature.
技术方案:为了实现上述发明目的,本发明采用的技术方案为: Technical solution: In order to realize the above-mentioned purpose of the invention, the technical solution adopted in the present invention is:
一种荧光灯用固态锑汞合金,由以下重量百分含量各成分组成:10-30%Sb,18-53%Hg,20-52%Zn、Sn和Bi中的一种或两种,各成分重量百分含量之和为100%。 A solid antimony amalgam for fluorescent lamps, which is composed of the following components in weight percent: 10-30% Sb, 18-53% Hg, 20-52% Zn, one or two of Sn and Bi, each component The sum of weight percentages is 100%.
所述的荧光灯用固态锑汞合金,优选由以下重量百分含量各成分组成:20-30%Sb,28-53%Hg,20-45%Sn和Bi中的一种或两种,各成分重量百分含量之和为100%。 The solid-state antimony amalgam for fluorescent lamps is preferably composed of the following components in weight percent: 20-30% Sb, 28-53% Hg, 20-45% Sn and Bi or one or both, each component The sum of weight percentages is 100%.
所述的荧光灯用固态锑汞合金,优选由以下重量百分含量各成分组成:20-28%Sb,30-50%Hg,25-40%Sn或Bi,各成分重量百分含量之和为100%。 The solid antimony amalgam for fluorescent lamps is preferably composed of the following components in weight percent: 20-28% Sb, 30-50% Hg, 25-40% Sn or Bi, and the sum of the weight percent of each component is 100%.
本发明荧光灯用固态锑汞合金中,大大缩短了从阴极辉光放电到热电子发射的时间差,从而加快了灯管的爬升速度。 In the solid antimony amalgam for fluorescent lamps of the present invention, the time difference from cathode glow discharge to thermal electron emission is greatly shortened, thereby accelerating the climbing speed of the lamp tube.
有益效果:与现有技术相比,本发明的荧光灯用固态锑汞合金,克服了现有荧光灯因采用液汞存在的生产使用过程中液汞极易流失以及注汞量不易准确控制的不足,在室温下能提供类似液汞的汞蒸气压,同时具有类似以液汞的爬升特性。在荧光灯中既能够准确控制每只灯管的用汞量,又明显减少环境污染,具有很好的实用和推广价值。 Beneficial effects: Compared with the prior art, the solid antimony amalgam for fluorescent lamps of the present invention overcomes the disadvantages of the existing fluorescent lamps that the liquid mercury is easily lost and the amount of mercury injected is difficult to accurately control during production and use due to the presence of liquid mercury. It can provide a mercury vapor pressure similar to liquid mercury at room temperature, and has a climb characteristic similar to liquid mercury. In fluorescent lamps, the amount of mercury used by each lamp tube can be accurately controlled, and environmental pollution can be significantly reduced, so it has very good practical and popularization value.
具体实施方式 Detailed ways
下面结合具体实施例对本发明作进一步的说明。 The present invention will be further described below in conjunction with specific examples.
一种荧光灯用固态锑汞合金,各成分组成如表1所示。 A solid antimony amalgam for fluorescent lamps, the composition of which is shown in Table 1.
表1 荧光灯用固态锑汞合金成分 Table 1 Composition of solid antimony amalgam for fluorescent lamps
在本发明的产品中,添加高含量的锑元素,使得固态锑汞合金的抗压能力获得大幅提高,由普通的抗压0.3公斤/平方厘米提高至0.8公斤/平方厘米;同时也提高了合同的熔点,可使其熔点达到500℃以上;同时,高含量的锑元素的加入,也不影响汞的释放,获得很好的爬升时间和光通量。 In the product of the present invention, the high content of antimony element is added, so that the compressive capacity of the solid antimony amalgam is greatly improved, from the ordinary compressive capacity of 0.3 kg/cm2 to 0.8 kg/cm2; The melting point can reach above 500°C; at the same time, the addition of high content of antimony element does not affect the release of mercury, and obtains good climbing time and luminous flux.
以现有的传统固汞(锡汞)、液汞为对照,测试本发明荧光灯用固态锑汞合金的爬升时间与光通量,具体数据如表2所示,可见,本发明的固态锑汞合金,克服了已有固汞爬升慢的缺点,提供了可以与液汞相比美的爬升速度。具有很好的实用和推广价值。 Taking existing traditional solid mercury (tin mercury) and liquid mercury as contrast, test the climbing time and luminous flux of the solid antimony amalgam for fluorescent lamps of the present invention, the specific data are as shown in table 2, as can be seen, the solid antimony amalgam of the present invention, It overcomes the disadvantage of slow climb of the existing solid mercury, and provides a climb speed comparable to that of liquid mercury. It has very good practical and promotional value.
表2 测试结果 Table 2 Test results
Claims (3)
Priority Applications (1)
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CN201410615868.2A CN104498772B (en) | 2014-11-05 | 2014-11-05 | A kind of fluorescent-lamp-use solid-state antimony mercury alloy |
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CN201410615868.2A CN104498772B (en) | 2014-11-05 | 2014-11-05 | A kind of fluorescent-lamp-use solid-state antimony mercury alloy |
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CN104498772A true CN104498772A (en) | 2015-04-08 |
CN104498772B CN104498772B (en) | 2017-12-08 |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5834555A (en) * | 1981-08-25 | 1983-03-01 | Toshiba Corp | Low pressure mercury vapor discharge lamp |
CN1916212A (en) * | 2006-09-06 | 2007-02-21 | 朱斌 | Low temperature amalgam suitable to round arranged machine |
WO2007146196A2 (en) * | 2006-06-09 | 2007-12-21 | Advanced Lighting Technologies, Inc. | Bismuth-zinc-mercury amalgam, fluorescent lamps, and related methods |
CN101093779A (en) * | 2007-06-29 | 2007-12-26 | 程亚军 | Amalgam in use for fluorescent lamp, and preparation method |
CN102329979A (en) * | 2011-08-13 | 2012-01-25 | 何志明 | Hg-rich type Sb-Sn-Hg alloy |
CN103730328A (en) * | 2013-12-31 | 2014-04-16 | 高邮高和光电器材有限公司 | Solid mercury for manufacturing lamp |
-
2014
- 2014-11-05 CN CN201410615868.2A patent/CN104498772B/en not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5834555A (en) * | 1981-08-25 | 1983-03-01 | Toshiba Corp | Low pressure mercury vapor discharge lamp |
WO2007146196A2 (en) * | 2006-06-09 | 2007-12-21 | Advanced Lighting Technologies, Inc. | Bismuth-zinc-mercury amalgam, fluorescent lamps, and related methods |
US20080001519A1 (en) * | 2006-06-09 | 2008-01-03 | Hansen Steven C | Bismuth-zinc-mercury amalgam, fluorescent lamps, and related methods |
CN1916212A (en) * | 2006-09-06 | 2007-02-21 | 朱斌 | Low temperature amalgam suitable to round arranged machine |
CN101093779A (en) * | 2007-06-29 | 2007-12-26 | 程亚军 | Amalgam in use for fluorescent lamp, and preparation method |
CN102329979A (en) * | 2011-08-13 | 2012-01-25 | 何志明 | Hg-rich type Sb-Sn-Hg alloy |
CN103730328A (en) * | 2013-12-31 | 2014-04-16 | 高邮高和光电器材有限公司 | Solid mercury for manufacturing lamp |
Non-Patent Citations (1)
Title |
---|
中国照明电器协会组织: "《低汞荧光灯技术》", 31 January 2014, 中国轻工业出版社 * |
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Effective date of registration: 20191118 Address after: 225000 in high tech entrepreneurship service center, Hanjiang Economic Development Zone, Yangzhou City, Jiangsu Province Patentee after: YANGZHOU HANJIANG SHENZHU ELECTRONIC EQUIPMENT FACTORY Address before: 225000 No. 217 West Development Road, Hanjiang District, Jiangsu, Yangzhou Patentee before: YANGZHOU HANJIANG SHENGZHU PHOTOELECTRICITY Co.,Ltd. |
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