CN104497518A - Anti-parasitic plastic for seabed optical cable conjunction boxes - Google Patents
Anti-parasitic plastic for seabed optical cable conjunction boxes Download PDFInfo
- Publication number
- CN104497518A CN104497518A CN201410688745.1A CN201410688745A CN104497518A CN 104497518 A CN104497518 A CN 104497518A CN 201410688745 A CN201410688745 A CN 201410688745A CN 104497518 A CN104497518 A CN 104497518A
- Authority
- CN
- China
- Prior art keywords
- parts
- maleic anhydride
- optical fiber
- terminal box
- fiber cable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004033 plastic Substances 0.000 title claims abstract description 28
- 229920003023 plastic Polymers 0.000 title claims abstract description 28
- 230000002141 anti-parasite Effects 0.000 title abstract description 4
- 239000003096 antiparasitic agent Substances 0.000 title abstract description 4
- 230000003287 optical effect Effects 0.000 title abstract 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 29
- 238000007906 compression Methods 0.000 claims abstract description 18
- 239000003365 glass fiber Substances 0.000 claims abstract description 10
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 8
- 229920002943 EPDM rubber Polymers 0.000 claims abstract description 5
- 239000013307 optical fiber Substances 0.000 claims description 35
- 230000003071 parasitic effect Effects 0.000 claims description 16
- 230000006835 compression Effects 0.000 claims description 15
- 239000003112 inhibitor Substances 0.000 claims description 14
- 230000003647 oxidation Effects 0.000 claims description 14
- 238000007254 oxidation reaction Methods 0.000 claims description 14
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 claims description 8
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 7
- 239000004760 aramid Substances 0.000 claims description 5
- 229920003235 aromatic polyamide Polymers 0.000 claims description 5
- XJQPQKLURWNAAH-UHFFFAOYSA-N dihydrocapsaicin Chemical compound COC1=CC(CNC(=O)CCCCCCC(C)C)=CC=C1O XJQPQKLURWNAAH-UHFFFAOYSA-N 0.000 claims description 3
- RBCYRZPENADQGZ-UHFFFAOYSA-N dihydrocapsaicin Natural products COC1=CC(COC(=O)CCCCCCC(C)C)=CC=C1O RBCYRZPENADQGZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003513 alkali Substances 0.000 abstract description 2
- 239000003963 antioxidant agent Substances 0.000 abstract 2
- 230000003078 antioxidant effect Effects 0.000 abstract 2
- 235000006708 antioxidants Nutrition 0.000 abstract 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 abstract 1
- 238000009395 breeding Methods 0.000 abstract 1
- 230000001488 breeding effect Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 9
- 239000004417 polycarbonate Substances 0.000 description 9
- 230000003245 working effect Effects 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 230000035939 shock Effects 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- -1 polybutylene terephthalate Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Light Guides In General And Applications Therefor (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Disclosed anti-parasitic plastic for seabed optical cable conjunction boxes is composed of the following compositions in parts by weight: 50-100 parts of PC, 15-60 parts of PBT, 30-70 parts of glass fiber, 10-30 parts of an anti-compression agent, 3-7 parts of a flexibilizer, 1-5 parts of a toner, 0.2-2 parts of an anti-oxidant, and 3-10 parts of a marine-benthos-parasitism resistant agent. The flexibilizer comprises a maleic anhydride grafted compatilizer, and the maleic anhydride grafted compatilizer comprises maleic anhydride grafted POE, maleic anhydride grafted EVA, maleic anhydride grafted SBS, maleic anhydride grafted EPDM, maleic anhydride grafted PE or maleic anhydride grafted ABS; the anti-oxidant comprises an anti-oxidant 168; the specification of the toner comprises black color mater; and the anti-compression agent comprises aramid fiber or aramid fiber pulp. The provided anti-parasitic plastic for seabed optical cable conjunction boxes has the advantages of relatively strong anti-compression property, mechanical strength, acid-alkali resistance, marine-benthos breeding resistance and the like.
Description
Technical field
The present invention relates to a kind of submarine optical fiber cable terminal box plastics of anti-parasitism, particularly relate to a kind of submarine optical fiber cable terminal box plastic formula of anti-parasitism.
Background technology
One of important technology index of submarine optical fiber cable terminal box to bear hundreds of to one thousand atmospheric hydraulic pressure, and current submarine optical fiber cable terminal box poor voltage withstand capability, work-ing life is short, need frequently change.
In addition, the not anti-parasitic function of existing submarine optical fiber cable terminal box, epibiota is easily attached thereto grows growth, easily hinders the function of submarine optical fiber cable terminal box.
Summary of the invention
Technical problem to be solved by this invention is, provides a kind of submarine optical fiber cable terminal box plastics with the parasitic function of anti-epibiota; Further, the invention provides a kind of good pressure-resistant performance, the submarine optical fiber cable terminal box plastics that physical strength is large; Further, the present invention also has the corrosion resistant feature of acid and alkali-resistance.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
Submarine optical fiber cable terminal box plastics for anti-parasitism, are made up of the component of following weight part: PC:50 ~ 100 part; PBT:15 ~ 60 part; Glass fibre: 30 ~ 70 parts; Resistance to compression agent: 10 ~ 30 parts; Toughner: 3 ~ 7 parts; Toner: 1 ~ 5 part; Oxidation inhibitor: 0.2 ~ 2 part; The parasitic agent of anti-epibiota: 3 ~ 10 parts.
Described toughner comprises maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer comprises maleic anhydride and meets POE, EVA, SBS, EPDM, PE or ABS.
Described oxidation inhibitor comprises irgasfos 168.
The specification of described toner comprises black masterbatch.
Described resistance to compression agent comprises aramid fiber or aramid pulp.
The parasitic agent of described anti-epibiota comprises capsicine, Dihydrocapsaicin or Capsaicinoids.
The submarine optical fiber cable terminal box plastics of a kind of anti-parasitism provided by the invention, the introducing of the parasitic agent of anti-epibiota, can effectively suppress epibiota to grow in terminal box, the work-ing life of the submarine optical fiber cable terminal box effectively extended; The introducing of resistance to compression agent, greatly strengthen withstand voltage properties of the present invention, aramid fiber or aramid pulp have superstrength, high-modulus and high temperature resistant, acid-fast alkali-proof, the premium properties such as lightweight, its intensity is 5 ~ 6 times of steel wire, and modulus is 2 ~ 3 times of steel wire or glass fibre, and toughness is 2 times of steel wire, and weight is only about 1/5 of steel wire, at the temperature of 560 degree, do not decompose, do not melt.It has good insulativity and ageing resistance, has very long life cycle; PBT(polybutylene terephthalate, English name Polybutylene terephthalate) be thermoplastic polyester, have that intensity is high, resistance to fatigue, dimensional stabilizing, creep are little, the characteristic such as heat-resistant aging and solvent resistance (unstressed cracking); PC(polycarbonate, English name Polycarbonate) water white transparency, have excellent shock resistance and thermal diffusivity, spread heat is relatively more even and product appearance is smooth; Glass fibre is a kind of ceramic of excellent performance, of a great variety, and advantage is good insulating, thermotolerance is strong, erosion resistance good, and physical strength is high; Formula in the present invention, after combination, makes submarine optical fiber cable terminal box plastics have stronger resistance to pressure, physical strength, acid-alkali-resistant degree and the advantage such as prevent that epibiota from growing.
Embodiment
Embodiment 1: a kind of submarine optical fiber cable terminal box plastics of anti-parasitism, are made up of the component of following weight part: PC:50 part; PBT:15 part; Glass fibre: 30 parts; Resistance to compression agent: 10 parts; Toughner: 3 parts; Toner: 1 part; Oxidation inhibitor: 0.2 part; The parasitic agent of anti-epibiota: 3 parts.
Described toughner is maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer is that maleic anhydride meets POE.
Described oxidation inhibitor is irgasfos 168.
The specification of described toner is black masterbatch.
Described resistance to compression agent is aramid fiber.
The parasitic agent of described anti-epibiota is for drawing together capsicine.
The submarine optical fiber cable terminal box plastics of a kind of anti-parasitism of the present embodiment, surface gloss 50%, resistance to impact shock 96MPa, tensile strength 78 MPa, and acid and alkali-resistance is anticorrosive and the function that prevents epibiota from growing, at least extend submarine optical fiber cable terminal box work-ing life of 3 years thereon.
Embodiment 2: a kind of submarine optical fiber cable terminal box plastics of anti-parasitism, are made up of the component of following weight part: PC:60 part; PBT:20 part; Glass fibre: 40 parts; Resistance to compression agent: 15 parts; Toughner: 4 parts; Toner: 2 parts; Oxidation inhibitor: 0.5 part; The parasitic agent of anti-epibiota: 4 parts.
Described toughner is maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer is that maleic anhydride meets EVA.
Described oxidation inhibitor is irgasfos 168.
The specification of described toner is black masterbatch.
Described resistance to compression agent is aramid pulp.
The parasitic agent of described anti-epibiota is Dihydrocapsaicin.
The submarine optical fiber cable terminal box plastics of a kind of anti-parasitism of the present embodiment, surface gloss 55%, resistance to impact shock 112MPa, stretch strong 85 MPa, and acid and alkali-resistance is anticorrosive and the function that prevents epibiota from growing, at least extend submarine optical fiber cable terminal box work-ing life of 3.5 years thereon.
Embodiment 3: a kind of submarine optical fiber cable terminal box plastics of anti-parasitism, are made up of the component of following weight part: PC:70 part; PBT:30 part; Glass fibre: 50 parts; Resistance to compression agent: 25 parts; Toughner: 5 parts; Toner: 3 parts; Oxidation inhibitor: 1 part; The parasitic agent of anti-epibiota: 6 parts.
Described toughner is maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer is that maleic anhydride meets SBS.
Described oxidation inhibitor is irgasfos 168.
The specification of described toner is black masterbatch.
Described resistance to compression agent is aramid fiber.
The parasitic agent of described anti-epibiota is Capsaicinoids.
The submarine optical fiber cable terminal box plastics of a kind of anti-parasitism of the present embodiment, surface gloss 58%, resistance to impact shock 120MPa, tensile strength 89 MPa, and acid and alkali-resistance is anticorrosive and the function that prevents epibiota from growing, at least extend submarine optical fiber cable terminal box work-ing life of 4 years thereon.
Embodiment 4: a kind of submarine optical fiber cable terminal box plastics of anti-parasitism, are made up of the component of following weight part: PC:80 part; PBT:40 part; Glass fibre: 60 parts; Resistance to compression agent: 28 parts; Toughner: 6 parts; Toner: 4 parts; Oxidation inhibitor: 1.5 parts; The parasitic agent of anti-epibiota: 8 parts.
Described toughner is maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer is that maleic anhydride meets EPDM.
Described oxidation inhibitor is irgasfos 168.
The specification of described toner is black masterbatch.
Described resistance to compression agent is aramid fiber.
The parasitic agent of described anti-epibiota is capsicine.
The submarine optical fiber cable terminal box plastics of a kind of anti-parasitism of the present embodiment, surface gloss 63%, resistance to impact shock 133MPa, tensile strength 95 MPa, and acid and alkali-resistance is anticorrosive and the function that prevents epibiota from growing, at least extend submarine optical fiber cable terminal box work-ing life of 5 years thereon.
Embodiment 5: a kind of submarine optical fiber cable terminal box plastics of anti-parasitism, are made up of the component of following weight part: PC:100 part; PBT:60 part; Glass fibre: 70 parts; Resistance to compression agent: 30 parts; Toughner: 7 parts; Toner: 5 parts; Oxidation inhibitor: 2 parts; The parasitic agent of anti-epibiota: 10 parts.
Described toughner is maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer is that maleic anhydride meets EPDM.
Described oxidation inhibitor is irgasfos 168.
The specification of described toner is black masterbatch.
Described resistance to compression agent is aramid pulp.
The parasitic agent of described anti-epibiota is Capsaicinoids.
The submarine optical fiber cable terminal box plastics of a kind of anti-parasitism of the present embodiment, surface gloss 69%, resistance to impact shock 149MPa, tensile strength 105 MPa, and acid and alkali-resistance is anticorrosive and the function that prevents epibiota from growing, at least extend submarine optical fiber cable terminal box work-ing life of 6 years thereon.
The above is only the preferred embodiment of the present invention; be noted that for those skilled in the art; under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (7)
1. submarine optical fiber cable terminal box plastics for anti-parasitism, are made up of the component of following weight part: PC:50 ~ 100 part; PBT:15 ~ 60 part; Glass fibre: 30 ~ 70 parts; Resistance to compression agent: 10 ~ 30 parts; Toughner: 3 ~ 7 parts; Toner: 1 ~ 5 part; Oxidation inhibitor: 0.2 ~ 2 part; The parasitic agent of anti-epibiota: 3 ~ 10 parts.
2. the submarine optical fiber cable terminal box plastics of a kind of anti-parasitism according to claim 1, is characterized in that: described toughner comprises maleic anhydride graft compatilizer.
3. the submarine optical fiber cable terminal box plastics of a kind of anti-parasitism according to claim 2, is characterized in that: described maleic anhydride graft compatilizer comprises maleic anhydride and meets POE, EVA, SBS, EPDM, PE or ABS.
4. the submarine optical fiber cable terminal box plastics of a kind of anti-parasitism according to claim 1, is characterized in that: described oxidation inhibitor comprises irgasfos 168.
5. the submarine optical fiber cable terminal box plastics of a kind of anti-parasitism according to claim 1, is characterized in that: the specification of described toner comprises black masterbatch.
6. the submarine optical fiber cable terminal box plastics of a kind of anti-parasitism according to claim 1, is characterized in that: described resistance to compression agent comprises aramid fiber or aramid pulp.
7. the submarine optical fiber cable terminal box plastics of a kind of anti-parasitism according to claim 1, is characterized in that: the parasitic agent of described anti-epibiota comprises capsicine, Dihydrocapsaicin or Capsaicinoids.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410688745.1A CN104497518B (en) | 2014-11-26 | 2014-11-26 | A kind of submarine optical fiber cable terminal box plastics of anti-parasitism |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410688745.1A CN104497518B (en) | 2014-11-26 | 2014-11-26 | A kind of submarine optical fiber cable terminal box plastics of anti-parasitism |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104497518A true CN104497518A (en) | 2015-04-08 |
| CN104497518B CN104497518B (en) | 2016-08-31 |
Family
ID=52938981
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410688745.1A Expired - Fee Related CN104497518B (en) | 2014-11-26 | 2014-11-26 | A kind of submarine optical fiber cable terminal box plastics of anti-parasitism |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104497518B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1123608C (en) * | 1999-11-12 | 2003-10-08 | 陈光宇 | Low surface energy repelling type dirt-proof paint and use method thereof |
| CN1569931A (en) * | 2004-04-26 | 2005-01-26 | 东莞市正昱塑胶五金有限公司 | Fiber reinforced thermolplastic plastic preparation method |
-
2014
- 2014-11-26 CN CN201410688745.1A patent/CN104497518B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1123608C (en) * | 1999-11-12 | 2003-10-08 | 陈光宇 | Low surface energy repelling type dirt-proof paint and use method thereof |
| CN1569931A (en) * | 2004-04-26 | 2005-01-26 | 东莞市正昱塑胶五金有限公司 | Fiber reinforced thermolplastic plastic preparation method |
Non-Patent Citations (2)
| Title |
|---|
| 彤彤: ""彤彤的博客"", 《HTTP://BLOG.SINA.COM.CN/S/BLOG_626F83860100FAPQ.HTML》, 6 October 2009 (2009-10-06), pages 1 - 2 * |
| 秦大同等: "《常用机械工程材料》", 31 March 2013, article ""玻璃纤维增强聚碳酸酯复合材料"", pages: 524-525 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104497518B (en) | 2016-08-31 |
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Effective date of registration: 20180105 Address after: 215002 754 room, No. 379, No. 1, Tower Park Road, Suzhou high tech Zone, Jiangsu Patentee after: SUZHOU NIUMAITIAN NEW MATERIAL TECHNOLOGY CO.,LTD. Address before: 215129, Huashan Road, Suzhou high tech Zone, Jiangsu, China, No. Patentee before: SUZHOU NEW DISTRICT JIAHE PLASTIC Co.,Ltd. |
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Effective date of registration: 20210308 Address after: 211111 p556, building 1, 12 mozhou East Road, Jiangning District, Nanjing City, Jiangsu Province Patentee after: NANJING YOUGU INTELLECTUAL PROPERTY SERVICE Co.,Ltd. Address before: Room 754, Building 379, Tayuan Road, Suzhou High-tech Zone, Jiangsu Province Patentee before: SUZHOU NIUMAITIAN NEW MATERIAL TECHNOLOGY Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160831 |
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| CF01 | Termination of patent right due to non-payment of annual fee |