CN104497376A - Flame-retardation rubber sole - Google Patents
Flame-retardation rubber sole Download PDFInfo
- Publication number
- CN104497376A CN104497376A CN201410689371.5A CN201410689371A CN104497376A CN 104497376 A CN104497376 A CN 104497376A CN 201410689371 A CN201410689371 A CN 201410689371A CN 104497376 A CN104497376 A CN 104497376A
- Authority
- CN
- China
- Prior art keywords
- parts
- rubber
- flame
- oxide
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A disclosed flame-retardation rubber sole is prepared from the following raw materials in parts by weight: 7-15 parts of natural rubber, 10-20 parts of styrene-butadiene rubber, 4-8 parts of ABS high glue powder, 7-11 parts of titanate coupling agent TMC-TTS, 5-10 parts of dioctyl terephthalate DOTP, 30-40 parts of white carbon black, 11-16 parts of diantimony trioxide, 8-16 parts of salicylic acid, 10-20 parts of zinc carbonate, 11-21 parts of stearic acid, 13-20 parts of sulphur, 12-24 parts of high styrene, 10-15 parts of nanometer zinc oxide, 5-15 parts of solid cumarone, 4-8 parts of PE wax, 6-10 parts of teflon micro powder, 7-12 parts of magnesium oxide, and 6-9 parts of polyvinyl alcohol. The provided flame-retardation rubber sole is simple in formula, low in production cost, good in flame-retardation effect, relatively good in heat resistance and strong in binding power.
Description
Technical field
The present invention relates to rubber processing techniques field, be specifically related to a kind of flame retardant rubber sole.
Background technology
Rubber overshoes rubber components has two kinds of outward appearance development trends, a kind of is take high glossiness as the beautiful type product of representative, another kind is then that color and luster is soft, the quiet elegance of outward appearance, give harmonious quiet style, people are felt safe, healthy comfortable frosted type product, this product has the special-effect of the sense organ vision that stimulates consumer, one of Major Epidemic trend becoming current product color.Frosted type rubber overshoes product has become the new lover of human consumer because of its soft, natural, graceful visual appearance.
Natural rubber as a kind of macromolecular material of excellent property, in widespread use already and various field.Most rubber item is all flammable or inflammable, and this is its major defect in application, and therefore their flame retardant properties is most important.When rubber uses as a kind of material for sole of shoe, its flame retardant properties is also most important, and such as at special dimensions such as fire-fightings, flame retardant rubber sole can well protect the personnel safety of firefighter.Therefore a kind of rubber soles with anti-flaming function is needed.
Summary of the invention
For the deficiencies in the prior art, technical problem to be solved by this invention is, provides a kind of flame retardant rubber sole simple, production cost is low, good flame retardation effect, thermotolerance are better, cohesive force is strong of filling a prescription.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of flame retardant rubber sole, be made up of the raw material of following parts by weight: natural rubber 7-15 part, styrene-butadiene rubber(SBR) 10-20 part, ABS high glue powder 4-8 part, titanate coupling agent TMC-TTS 7-11 part, dioctyl terephthalate DOTP 5-10 part, white carbon black 30-40 part, antimonous oxide 11-16 part, Whitfield's ointment 8-16 part, zinc carbonate 10-20 part, stearic acid 11-21 part, sulphur 13-20 part, high-phenylethylene 12-24 part, nano zine oxide 10-15 part, solid coumarone 5-15 part, PE wax 4-8 part, ptfe micropowder 6-10 part, magnesium oxide 7-12 part, polyvinyl alcohol 6-9 part.
Above-mentioned flame retardant rubber sole, be made up of the raw material of following parts by weight: natural rubber 12 parts; 15 parts, styrene-butadiene rubber(SBR), ABS high glue powder 6 parts, titanate coupling agent TMC-TTS 9 parts; dioctyl terephthalate DOTP 8 parts; white carbon black 35 parts, antimonous oxide 13 parts, Whitfield's ointment 13 parts; zinc carbonate 15 parts; stearic acid 18 parts, 16 parts, sulphur, high-phenylethylene 18 parts; nano zine oxide 13 parts; solid coumarone 10 parts, 6 parts, PE wax, ptfe micropowder 8 parts; 11 parts, magnesium oxide, polyvinyl alcohol 8 parts.
Flame retardant rubber sole advantage of the present invention is:
1, flame retardant rubber sole of the present invention, formula is simple, production cost is low, good flame retardation effect, thermotolerance are better, cohesive force is strong.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1, a kind of flame retardant rubber sole, is made up of the raw material of following parts by weight: natural rubber 7 parts, 10 parts, styrene-butadiene rubber(SBR), ABS high glue powder 4 parts, titanate coupling agent TMC-TTS 7 parts, dioctyl terephthalate DOTP 5 parts, white carbon black 30 parts, antimonous oxide 11 parts, Whitfield's ointment 8 parts, zinc carbonate 10 parts, stearic acid 11 parts, 13 parts, sulphur, high-phenylethylene 12 parts, nano zine oxide 10 parts, solid coumarone 5 parts, 4 parts, PE wax, ptfe micropowder 6 parts, 7 parts, magnesium oxide, polyvinyl alcohol 6 parts.
Embodiment 2, a kind of flame retardant rubber sole, is made up of the raw material of following parts by weight: natural rubber 12 parts, 15 parts, styrene-butadiene rubber(SBR), ABS high glue powder 6 parts, titanate coupling agent TMC-TTS 9 parts, dioctyl terephthalate DOTP 8 parts, white carbon black 35 parts, antimonous oxide 13 parts, Whitfield's ointment 13 parts, zinc carbonate 15 parts, stearic acid 18 parts, 16 parts, sulphur, high-phenylethylene 18 parts, nano zine oxide 13 parts, solid coumarone 10 parts, 6 parts, PE wax, ptfe micropowder 8 parts, 11 parts, magnesium oxide, polyvinyl alcohol 8 parts.
Embodiment 3, a kind of flame retardant rubber sole, is made up of the raw material of following parts by weight: natural rubber 15 parts, 20 parts, styrene-butadiene rubber(SBR), ABS high glue powder 8 parts, titanate coupling agent TMC-TTS 11 parts, dioctyl terephthalate DOTP 10 parts, white carbon black 40 parts, antimonous oxide 16 parts, Whitfield's ointment 16 parts, zinc carbonate 20 parts, stearic acid 21 parts, 20 parts, sulphur, high-phenylethylene 24 parts, nano zine oxide 15 parts, solid coumarone 15 parts, 8 parts, PE wax, ptfe micropowder 10 parts, 12 parts, magnesium oxide, polyvinyl alcohol 9 parts.
Certainly, above-mentioned explanation is not limitation of the present invention, and the present invention is also not limited to above-mentioned citing; those skilled in the art; in essential scope of the present invention, the change made, change, interpolation or replacement, all should belong to protection scope of the present invention.
Claims (2)
1. a flame retardant rubber sole, it is characterized in that: be made up of the raw material of following parts by weight: natural rubber 7-15 part, styrene-butadiene rubber(SBR) 10-20 part, ABS high glue powder 4-8 part, titanate coupling agent TMC-TTS 7-11 part, dioctyl terephthalate DOTP 5-10 part, white carbon black 30-40 part, antimonous oxide 11-16 part, Whitfield's ointment 8-16 part, zinc carbonate 10-20 part, stearic acid 11-21 part, sulphur 13-20 part, high-phenylethylene 12-24 part, nano zine oxide 10-15 part, solid coumarone 5-15 part, PE wax 4-8 part, ptfe micropowder 6-10 part, magnesium oxide 7-12 part, polyvinyl alcohol 6-9 part.
2. flame retardant rubber sole according to claim 1, it is characterized in that: be made up of the raw material of following parts by weight: natural rubber 12 parts; 15 parts, styrene-butadiene rubber(SBR), ABS high glue powder 6 parts, titanate coupling agent TMC-TTS 9 parts; dioctyl terephthalate DOTP 8 parts; white carbon black 35 parts, antimonous oxide 13 parts, Whitfield's ointment 13 parts; zinc carbonate 15 parts; stearic acid 18 parts, 16 parts, sulphur, high-phenylethylene 18 parts; nano zine oxide 13 parts; solid coumarone 10 parts, 6 parts, PE wax, ptfe micropowder 8 parts; 11 parts, magnesium oxide, polyvinyl alcohol 8 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410689371.5A CN104497376A (en) | 2014-11-26 | 2014-11-26 | Flame-retardation rubber sole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410689371.5A CN104497376A (en) | 2014-11-26 | 2014-11-26 | Flame-retardation rubber sole |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104497376A true CN104497376A (en) | 2015-04-08 |
Family
ID=52938839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410689371.5A Pending CN104497376A (en) | 2014-11-26 | 2014-11-26 | Flame-retardation rubber sole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104497376A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440335A (en) * | 2015-12-14 | 2016-03-30 | 桐乡市亿源鞋业有限公司 | Fireproof high temperature-resistant rubber sole material |
| CN105968463A (en) * | 2016-06-24 | 2016-09-28 | 广州恩熙鞋业有限公司 | High-elasticity sole rubber and preparation method thereof |
| CN106810732A (en) * | 2016-12-14 | 2017-06-09 | 安徽得尚电子科技有限公司 | A kind of anti-corrosion flame retardant rubber compounding |
| CN114921007A (en) * | 2022-06-29 | 2022-08-19 | 界首市玉丰塑业有限公司 | Preparation method of wear-resistant rain shoes |
| CN114957814A (en) * | 2022-06-14 | 2022-08-30 | 陈栋 | Wear-resistant rubber material for fire-fighting shoes and preparation method thereof |
-
2014
- 2014-11-26 CN CN201410689371.5A patent/CN104497376A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440335A (en) * | 2015-12-14 | 2016-03-30 | 桐乡市亿源鞋业有限公司 | Fireproof high temperature-resistant rubber sole material |
| CN105968463A (en) * | 2016-06-24 | 2016-09-28 | 广州恩熙鞋业有限公司 | High-elasticity sole rubber and preparation method thereof |
| CN106810732A (en) * | 2016-12-14 | 2017-06-09 | 安徽得尚电子科技有限公司 | A kind of anti-corrosion flame retardant rubber compounding |
| CN114957814A (en) * | 2022-06-14 | 2022-08-30 | 陈栋 | Wear-resistant rubber material for fire-fighting shoes and preparation method thereof |
| CN114921007A (en) * | 2022-06-29 | 2022-08-19 | 界首市玉丰塑业有限公司 | Preparation method of wear-resistant rain shoes |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150408 |