CN104479512A - Preparation method of carboxyl-terminated bromine-carbon polyester resin fireproof coating used in marine climate - Google Patents

Preparation method of carboxyl-terminated bromine-carbon polyester resin fireproof coating used in marine climate Download PDF

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Publication number
CN104479512A
CN104479512A CN201410741492.XA CN201410741492A CN104479512A CN 104479512 A CN104479512 A CN 104479512A CN 201410741492 A CN201410741492 A CN 201410741492A CN 104479512 A CN104479512 A CN 104479512A
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China
Prior art keywords
parts
polyester resin
carbon polyester
end carboxyl
preparation
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Pending
Application number
CN201410741492.XA
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Chinese (zh)
Inventor
张和庆
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TAIXING HEQING MACHINERY FITTINGS FACTORY
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TAIXING HEQING MACHINERY FITTINGS FACTORY
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Application filed by TAIXING HEQING MACHINERY FITTINGS FACTORY filed Critical TAIXING HEQING MACHINERY FITTINGS FACTORY
Priority to CN201410741492.XA priority Critical patent/CN104479512A/en
Publication of CN104479512A publication Critical patent/CN104479512A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a preparation method of a carboxyl-terminated bromine-carbon polyester resin fireproof coating used in the marine climate. The coating comprises the following raw materials in parts by weight: 80-90 parts of carboxyl-terminated bromine-carbon polyester resin, 3.5-4 parts of triethanolamine, 10-15 parts of melamine, 5-10 parts of titanium dioxide, 8-14 parts of expanded perlite, 8-12 parts of hydroxyethyl cellulose, 3-6 parts of sodium methylsilanolate and 4-7 parts of aluminium sulfate. The preparation method comprises the following steps: firstly mixing the carboxyl-terminated bromine-carbon polyester resin and triethanolamine, then adding melamine, titanium dioxide, expanded perlite and hydroxyethyl cellulose, mixing the materials to prepare primary slurry, mixing sodium methylsilanolate and aluminium sulfate, then adding the primary slurry and mixing the materials, finally melt-extruding the mixture with an extruder, and grinding the product in sequence, thus obtaining the coating.

Description

A kind of oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating preparation method
Technical field
The present invention relates to a kind of frie retardant coating, is a kind of oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating and preparation method thereof specifically.
Background technology
Polyester powder coating has good physical and mechanical properties; decoration and the protection of metallic surface can be widely used in; boats and ships require that coating is prevented fires, water-fast, corrosion resistance nature is higher under oceanic climate; polyester powder coating on existing market is excellent performance in fire prevention mostly only, but cannot meet the use of oceanic climate particular requirement.
Summary of the invention
For above-mentioned deficiency of the prior art, the invention provides a kind of easily manufactured, cost is low, fire prevention, water-fast, the good a kind of oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating of corrosion resistance nature and preparation method.
The technical solution used in the present invention is: a kind of oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating, is made up of in mass ratio following raw materials according: end carboxyl bromine carbon polyester resin 80-90 part, trolamine 3.5-4 part, trimeric cyanamide 10-15 part, titanium dioxide 5-10 part, pearlstone 8-14 part, Natvosol 8-12 part, methyl silicon sodium alcoholate 3-6 part, Tai-Ace S 150 4-7 part.
A kind of preparation method of oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating, comprise the following steps: first end carboxyl bromine carbon polyester resin is mixed with trolamine, add trimeric cyanamide again, titanium dioxide, pearlstone, Natvosol carry out being mixed into magma, mixing adding magma after methyl silicon sodium alcoholate, Tai-Ace S 150 mixing preparation, finally melt extruding through forcing machine successively, pulverize and obtain coating.
A kind of oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating, is made up of in mass ratio following raw materials according: end carboxyl bromine carbon polyester resin 80-85 part, trolamine 3.5-4 part, trimeric cyanamide 10-15 part, titanium dioxide 5-10 part, pearlstone 8-14 part, Natvosol 8-12 part, methyl silicon sodium alcoholate 3-6 part, Tai-Ace S 150 4-7 part.
A kind of oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating, is made up of in mass ratio following raw materials according: end carboxyl bromine carbon polyester resin 85 parts, trolamine 3.6 parts, trimeric cyanamide 12 parts, titanium dioxide 7 parts, pearlstone 11 parts, Natvosol 10 parts, methyl silicon sodium alcoholate 4 parts, 5 parts, Tai-Ace S 150.
The present invention adds trolamine, trimeric cyanamide, titanium dioxide, pearlstone, Natvosol in end carboxyl bromine carbon polyester resin, be equipped with methyl silicon sodium alcoholate and Tai-Ace S 150, fire prevention, water-fast, corrosion resistance nature can be taken into account, Special use requirement under applicable oceanic climate.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment one
A kind of oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating, is made up of in mass ratio following raw materials according: end carboxyl bromine carbon polyester resin 80 parts, trolamine 3.5 parts, trimeric cyanamide 10 parts, titanium dioxide 5 parts, pearlstone 8 parts, Natvosol 8 parts, methyl silicon sodium alcoholate 3 parts, 4 parts, Tai-Ace S 150.Preparation method comprises the following steps: first mixed with trolamine by end carboxyl bromine carbon polyester resin, add trimeric cyanamide again, titanium dioxide, pearlstone, Natvosol carry out being mixed into magma, mixing adding magma after methyl silicon sodium alcoholate, Tai-Ace S 150 mixing preparation, finally melt extruding through forcing machine successively, pulverize and obtain coating.
Embodiment two
A kind of oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating, is made up of in mass ratio following raw materials according: end carboxyl bromine carbon polyester resin 90 parts, trolamine 4 parts, trimeric cyanamide 15 parts, titanium dioxide 10 parts, pearlstone 14 parts, Natvosol 12 parts, methyl silicon sodium alcoholate 6 parts, 7 parts, Tai-Ace S 150.Preparation method comprises the following steps: first mixed with trolamine by end carboxyl bromine carbon polyester resin, add trimeric cyanamide again, titanium dioxide, pearlstone, Natvosol carry out being mixed into magma, mixing adding magma after methyl silicon sodium alcoholate, Tai-Ace S 150 mixing preparation, finally melt extruding through forcing machine successively, pulverize and obtain coating.
Embodiment three
A kind of oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating, is made up of in mass ratio following raw materials according: end carboxyl bromine carbon polyester resin 85 parts, trolamine 3.6 parts, trimeric cyanamide 12 parts, titanium dioxide 7 parts, pearlstone 11 parts, Natvosol 10 parts, methyl silicon sodium alcoholate 4 parts, 5 parts, Tai-Ace S 150.Preparation method comprises the following steps: first mixed with trolamine by end carboxyl bromine carbon polyester resin, add trimeric cyanamide again, titanium dioxide, pearlstone, Natvosol carry out being mixed into magma, mixing adding magma after methyl silicon sodium alcoholate, Tai-Ace S 150 mixing preparation, finally melt extruding through forcing machine successively, pulverize and obtain coating.

Claims (3)

1. an oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating preparation method, comprise the following steps: first end carboxyl bromine carbon polyester resin is mixed with trolamine, add trimeric cyanamide again, titanium dioxide, pearlstone, Natvosol carries out being mixed into magma, by methyl silicon sodium alcoholate, add magma after Tai-Ace S 150 mixing preparation to mix, finally melt extrude through forcing machine successively, pulverizing obtains coating, raw material forms in mass ratio: end carboxyl bromine carbon polyester resin 80-90 part, trolamine 3.5-4 part, trimeric cyanamide 10-15 part, titanium dioxide 5-10 part, pearlstone 8-14 part, Natvosol 8-12 part, methyl silicon sodium alcoholate 3-6 part, Tai-Ace S 150 4-7 part.
2. an oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating preparation method, is made up of in mass ratio following raw materials according: end carboxyl bromine carbon polyester resin 80-85 part, trolamine 3.5-4 part, trimeric cyanamide 10-15 part, titanium dioxide 5-10 part, pearlstone 8-14 part, Natvosol 8-12 part, methyl silicon sodium alcoholate 3-6 part, Tai-Ace S 150 4-7 part.
3. an oceanic climate end carboxyl bromine carbon polyester resin frie retardant coating preparation method, is made up of in mass ratio following raw materials according: end carboxyl bromine carbon polyester resin 85 parts, trolamine 3.6 parts, trimeric cyanamide 12 parts, titanium dioxide 7 parts, pearlstone 11 parts, Natvosol 10 parts, methyl silicon sodium alcoholate 4 parts, 5 parts, Tai-Ace S 150.
CN201410741492.XA 2014-12-09 2014-12-09 Preparation method of carboxyl-terminated bromine-carbon polyester resin fireproof coating used in marine climate Pending CN104479512A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410741492.XA CN104479512A (en) 2014-12-09 2014-12-09 Preparation method of carboxyl-terminated bromine-carbon polyester resin fireproof coating used in marine climate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410741492.XA CN104479512A (en) 2014-12-09 2014-12-09 Preparation method of carboxyl-terminated bromine-carbon polyester resin fireproof coating used in marine climate

Publications (1)

Publication Number Publication Date
CN104479512A true CN104479512A (en) 2015-04-01

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410741492.XA Pending CN104479512A (en) 2014-12-09 2014-12-09 Preparation method of carboxyl-terminated bromine-carbon polyester resin fireproof coating used in marine climate

Country Status (1)

Country Link
CN (1) CN104479512A (en)

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Application publication date: 20150401

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