CN104479254A - Preparation process of electric ammeter shell material - Google Patents

Preparation process of electric ammeter shell material Download PDF

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Publication number
CN104479254A
CN104479254A CN201410842012.9A CN201410842012A CN104479254A CN 104479254 A CN104479254 A CN 104479254A CN 201410842012 A CN201410842012 A CN 201410842012A CN 104479254 A CN104479254 A CN 104479254A
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China
Prior art keywords
powder
preparation process
parts
mould
mold
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CN201410842012.9A
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Chinese (zh)
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CN104479254B (en
Inventor
邵晓东
管莉
张永超
黄倩
相京霞
王英山
吴学进
顾恩光
郑大伟
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Qidong Green Green Engineering Co Ltd
Original Assignee
JUNAN POWER SUPPLY CO Ltd
State Grid Corp of China SGCC
Linyi Power Supply Co of State Grid Shandong Electric Power Co Ltd
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Priority to CN201410842012.9A priority Critical patent/CN104479254B/en
Publication of CN104479254A publication Critical patent/CN104479254A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention belongs to the field of electric material processing, and discloses a preparation process of an electric ammeter shell material. The preparation process comprises the following steps: adding raw materials into a centrifuge in sequence, centrifugally stirring to uniformly mix the raw materials, feeding into a double-screw extruder to extrude to be in a molten state., rapidly injecting the molten body into a mold by using an ejection machine, performing mold closing and cooling molding, opening the mold, feeding a finished product into a secondary mold, and trimming inside the secondary mold by using a cutting machine, thereby obtaining the electric ammeter shell material. The preparation process is simple and feasible and applicable to large-scale production.

Description

A kind of preparation technology of power electric meter sheating material
Technical field
The invention belongs to electric power material processing field, specifically disclose a kind of preparation technology of power electric meter sheating material.
Background technology
Ammeter is the abbreviation of electric energy meter, is used to the instrument measuring electric energy, and also known as watt-hour meter, energy meter, electric energy meter, kilowatt-hour table, refers to the instrument measuring various electrical quantities.Meter case mainly plays the function of protection ammeter internals, needs good mechanical property, good thermostability and flame retardant properties.Domestic current meter case material many employings flame-proof ABS.Although flame-proof ABS is cheap, rigidity is not fine.Adopt reinforced polycarbonate (PC) at present abroad, along with China's expanding economy, domestic also will employing in a large number strengthens PC as meter case material more.Polycarbonate is a kind of water white indefiniteness thermoplastic material, and its chemical property is weak acid resistant, resistance to weak base, resistance to neutral oil, not ultraviolet resistance and not resistance to highly basic, and its physical properties is linear expansivity: 38 × 10cm/cm 2, thermal change type temperature 135 DEG C, has poor stability, has that stress is easy to split, power of hitting notched Izod impact is low, wears no resistance, low on metalwork bounding force, viscosity large, the shortcoming such as poor fluidity and impact processing injection moulding.
The more of at present both at home and abroad research is polycarbonate modified meter case material, and its main component is polycarbonate, adds other fire retardant materials, and it often exists insufficient strength or the poor defect of thermostability, and various performance cannot have both; And a large amount of polycarbonate cost that uses is higher, reduces the profit margin of enterprise.Chinese invention patent CN101469118A discloses a kind of polymer material for ammeter case, and this macromolecular material physical strength is inadequate, and cost is higher, does not utilize and promotes the use of.Chinese invention patent CN103740078A is applicant's patent of invention formerly, and disclosed sheating material possesses good physical strength and flame retardant properties, but heat-drawn wire is lower, is easily out of shape, under being not suitable for hot environment.
Summary of the invention
The object of the invention is the many defects solving meter case material in prior art, through lot of experiments and exploration, change existing raw material composition and preparation method, a kind of preparation technology of power electric meter sheating material is provided.
To achieve these goals, technical scheme of the present invention realizes in the following way:
A preparation technology for power electric meter sheating material, it comprises the steps:
Following each raw material is taken according to weight part, wherein, polyvinyl chloride 90-100 part, polyethylene 60-70 part, methyl methacrylate 40-50 part, glass fibre 38-42 part, polycarbonate 30-36 part, poly(lactic acid) 25-28 part, TDE 20-22 part, polydimethylsiloxane 18-20 part, chitin 12-15 part, silicon nitride powder 10-12 part, carborundum powder 7-8 part, sodium succinate 4-5 part, talcum powder 2-4 part, barium sulfate 2-3 part, Graphite Powder 99 1-2 part;
Each raw material is added in whizzer successively, 1000 turns/min centrifugal mixer 3 minutes, after mixing, enter twin screw extruder and be squeezed into molten state, then by injector, molten mass is injected mould fast, mould matched moulds cooling and shaping; After die sinking, finished product enters secondary mould, by cutting machine trimming and get final product in secondary mould.
Preferably, the length of glass fibre is preferably 1-5mm; The particle diameter of silicon nitride powder, carborundum powder, sodium succinate, talcum powder, barium sulfate and Graphite Powder 99 all controls more than 200 orders.
The beneficial effect that the present invention obtains is as follows:
Possess good synergy between each material component of meter case prepared by the present invention, higher mechanical property can be reached, and possess excellent thermostability and flame retardant properties, under being suitable for hot environment; The each low raw-material cost of the present invention, lower than the cost of the polycarbonate resin meter case that market is commonly used, is conducive to reducing enterprise's raw materials cost, promotes suitability for industrialized production; Preparation technology's simple possible of the present invention, is applicable to large-scale production.
Embodiment
Below employing specific embodiment is made further explanation to the present invention, but it is not as the restriction to initiative spirit of the present invention.
Embodiment 1
A preparation technology for power electric meter sheating material, it comprises the steps:
Following each raw material is taken according to weight part, wherein, polyvinyl chloride 90 parts, polyethylene 60 parts, methyl methacrylate 40 parts, 38 parts, glass fibre, polycarbonate 30 parts, poly(lactic acid) 25 parts, TDE 20 parts, polydimethylsiloxane 18 parts, chitin 12 parts, silicon nitride powder 10 parts, carborundum powder 7 parts, sodium succinate 4 parts, talcum powder 2 parts, 2 parts, barium sulfate, Graphite Powder 99 1 part.The length of glass fibre is 1mm; The size controlling of silicon nitride powder, carborundum powder, sodium succinate, talcum powder, barium sulfate and Graphite Powder 99 is at 200 orders; Each raw material is added in whizzer successively, 1000 turns/min centrifugal mixer 3 minutes, after mixing, enter twin screw extruder and be squeezed into molten state, then by injector, molten mass is injected mould fast, mould matched moulds cooling and shaping; After die sinking, finished product enters secondary mould, by cutting machine trimming and get final product in secondary mould.
Embodiment 2
A preparation technology for power electric meter sheating material, it comprises the steps:
Following each raw material is taken according to weight part, wherein, polyvinyl chloride 100 parts, polyethylene 70 parts, methyl methacrylate 50 parts, 42 parts, glass fibre, polycarbonate 36 parts, poly(lactic acid) 28 parts, TDE 22 parts, polydimethylsiloxane 20 parts, chitin 15 parts, silicon nitride powder 12 parts, carborundum powder 8 parts, sodium succinate 5 parts, talcum powder 4 parts, 3 parts, barium sulfate, Graphite Powder 99 2 parts; The length of glass fibre is 5mm; The size controlling of silicon nitride powder, carborundum powder, sodium succinate, talcum powder, barium sulfate and Graphite Powder 99 is at 300 orders;
Each raw material is added in whizzer successively, 1000 turns/min centrifugal mixer 3 minutes, after mixing, enter twin screw extruder and be squeezed into molten state, then by injector, molten mass is injected mould fast, mould matched moulds cooling and shaping; After die sinking, finished product enters secondary mould, by cutting machine trimming and get final product in secondary mould.
Embodiment 3
The performance test of meter case material prepared by the present invention:
The meter case material prepared for the embodiment of the present invention 1 and 2 carries out performance test; Wherein mould shrinks and presses ASTM D955 and test; Flexural strength is pressed ASTM D790 and is tested; Tensile strength is tested according to ASTM D638; Notched Izod impact strength is pressed ASTM D256 and is tested; Heat-drawn wire is pressed ASTM D648 and is tested.The test result of resulting materials is in table 1:
Table 1
Performance perameter Embodiment 1 Embodiment 2
Mould shrinks (%) 0.24 0.25
Flexural strength (Kgf/cm 2) normal temperature 1390 1386
Tensile strength (Kgf/cm 2) normal temperature 893 907
Notched Izod impact strength (KJ/m 2) 13.2 13.1
Heat-drawn wire DEG C 135 137
Conclusion: possess good synergy, better mechanical property between each material component of meter case prepared by the present invention, and possess excellent thermostability and flame retardant properties (flame retardant resistance UL94 is V0 level); Meter case prepared by the present invention under the high temperature conditions, still can keep good mechanical property, and not volatility; Low raw-material cost, lower than the cost of the polycarbonate resin meter case that market is commonly used, is conducive to suitability for industrialized production; Preparation technology's simple possible of the present invention, is applicable to large-scale production.
Finally, it is also to be noted that what enumerate above is only several specific embodiments of the present invention.Obviously, the invention is not restricted to above embodiment, many distortion can also be had.All distortion that those of ordinary skill in the art can directly derive from content disclosed by the invention or associate, all should think protection scope of the present invention.

Claims (3)

1. a preparation technology for power electric meter sheating material, is characterized in that, described technique comprises the steps:
1) following each raw material for standby is taken according to weight part: wherein, polyvinyl chloride 90-100 part, polyethylene 60-70 part, methyl methacrylate 40-50 part, glass fibre 38-42 part, polycarbonate 30-36 part, poly(lactic acid) 25-28 part, TDE 20-22 part, polydimethylsiloxane 18-20 part, chitin 12-15 part, silicon nitride powder 10-12 part, carborundum powder 7-8 part, sodium succinate 4-5 part, talcum powder 2-4 part, barium sulfate 2-3 part, Graphite Powder 99 1-2 part;
2) each raw material is added in whizzer successively, 1000 turns/min centrifugal mixer 3 minutes, after mixing, enter twin screw extruder and be squeezed into molten state, then by injector, molten mass is injected mould fast, mould matched moulds cooling and shaping; After die sinking, finished product enters secondary mould, by cutting machine trimming and get final product in secondary mould.
2. technique according to claim 1, is characterized in that, the length of described glass fibre is preferably 1-5mm.
3. technique according to claim 1, is characterized in that, the particle diameter of described silicon nitride powder, carborundum powder, sodium succinate, talcum powder, barium sulfate and Graphite Powder 99 all controls more than 200 orders.
CN201410842012.9A 2014-12-30 2014-12-30 A kind of preparation technology of power electric meter sheathing material Active CN104479254B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105542382A (en) * 2016-01-22 2016-05-04 杭州富阳高博信息技术服务有限公司 Plastic shell of electricity meter and application of plastic shell
CN105924845A (en) * 2016-06-13 2016-09-07 深圳市红岩电控设备有限公司 Efficient and energy-saving environment-friendly graphene power distribution cabinet
CN107057241A (en) * 2017-06-22 2017-08-18 合肥励仙电力工程有限公司 A kind of power electric meter erosion resisting insulation sheathing material and preparation method thereof
CN107189272A (en) * 2017-07-04 2017-09-22 合肥市大卓电力有限责任公司 A kind of power electric meter sheathing material and preparation method thereof
CN107286531A (en) * 2017-08-02 2017-10-24 合肥尚涵装饰工程有限公司 A kind of meter case material and preparation method thereof
CN107418119A (en) * 2017-08-01 2017-12-01 合肥市大卓电力有限责任公司 A kind of fire-retardant power electric meter sheathing material and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103665688A (en) * 2013-12-17 2014-03-26 国家电网公司 Electricity meter casing and preparation method thereof
CN103724900A (en) * 2013-12-31 2014-04-16 国家电网公司 Electric insulation material and application thereof
CN104151745A (en) * 2014-08-12 2014-11-19 山东梦奇电器有限公司 High and low voltage power distribution cabinet housing material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103665688A (en) * 2013-12-17 2014-03-26 国家电网公司 Electricity meter casing and preparation method thereof
CN103724900A (en) * 2013-12-31 2014-04-16 国家电网公司 Electric insulation material and application thereof
CN104151745A (en) * 2014-08-12 2014-11-19 山东梦奇电器有限公司 High and low voltage power distribution cabinet housing material and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105542382A (en) * 2016-01-22 2016-05-04 杭州富阳高博信息技术服务有限公司 Plastic shell of electricity meter and application of plastic shell
CN105924845A (en) * 2016-06-13 2016-09-07 深圳市红岩电控设备有限公司 Efficient and energy-saving environment-friendly graphene power distribution cabinet
CN107057241A (en) * 2017-06-22 2017-08-18 合肥励仙电力工程有限公司 A kind of power electric meter erosion resisting insulation sheathing material and preparation method thereof
CN107189272A (en) * 2017-07-04 2017-09-22 合肥市大卓电力有限责任公司 A kind of power electric meter sheathing material and preparation method thereof
CN107418119A (en) * 2017-08-01 2017-12-01 合肥市大卓电力有限责任公司 A kind of fire-retardant power electric meter sheathing material and preparation method thereof
CN107286531A (en) * 2017-08-02 2017-10-24 合肥尚涵装饰工程有限公司 A kind of meter case material and preparation method thereof

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Effective date of registration: 20170613

Address after: 226200 Nantong City, Qidong Province Economic Development Zone, No. triumph Road, No. 1

Patentee after: Qidong Green Green Engineering Co., Ltd.

Address before: 100761 West Chang'an Avenue, Beijing, No. 86, No.

Co-patentee before: Linyi Electric Power Company of Guo Wang Shandong Province Utilities Electric Co.

Patentee before: State Grid Corporation of China

Co-patentee before: Junan Power Supply Co.,Ltd.

TR01 Transfer of patent right