A kind of preparation technology of power electric meter sheating material
Technical field
The invention belongs to electric power material processing field, specifically disclose a kind of preparation technology of power electric meter sheating material.
Background technology
Ammeter is the abbreviation of electric energy meter, is used to the instrument measuring electric energy, and also known as watt-hour meter, energy meter, electric energy meter, kilowatt-hour table, refers to the instrument measuring various electrical quantities.Meter case mainly plays the function of protection ammeter internals, needs good mechanical property, good thermostability and flame retardant properties.Domestic current meter case material many employings flame-proof ABS.Although flame-proof ABS is cheap, rigidity is not fine.Adopt reinforced polycarbonate (PC) at present abroad, along with China's expanding economy, domestic also will employing in a large number strengthens PC as meter case material more.Polycarbonate is a kind of water white indefiniteness thermoplastic material, and its chemical property is weak acid resistant, resistance to weak base, resistance to neutral oil, not ultraviolet resistance and not resistance to highly basic, and its physical properties is linear expansivity: 38 × 10cm/cm
2, thermal change type temperature 135 DEG C, has poor stability, has that stress is easy to split, power of hitting notched Izod impact is low, wears no resistance, low on metalwork bounding force, viscosity large, the shortcoming such as poor fluidity and impact processing injection moulding.
The more of at present both at home and abroad research is polycarbonate modified meter case material, and its main component is polycarbonate, adds other fire retardant materials, and it often exists insufficient strength or the poor defect of thermostability, and various performance cannot have both; And a large amount of polycarbonate cost that uses is higher, reduces the profit margin of enterprise.Chinese invention patent CN101469118A discloses a kind of polymer material for ammeter case, and this macromolecular material physical strength is inadequate, and cost is higher, does not utilize and promotes the use of.Chinese invention patent CN103740078A is applicant's patent of invention formerly, and disclosed sheating material possesses good physical strength and flame retardant properties, but heat-drawn wire is lower, is easily out of shape, under being not suitable for hot environment.
Summary of the invention
The object of the invention is the many defects solving meter case material in prior art, through lot of experiments and exploration, change existing raw material composition and preparation method, a kind of preparation technology of power electric meter sheating material is provided.
To achieve these goals, technical scheme of the present invention realizes in the following way:
A preparation technology for power electric meter sheating material, it comprises the steps:
Following each raw material is taken according to weight part, wherein, polyvinyl chloride 90-100 part, polyethylene 60-70 part, methyl methacrylate 40-50 part, glass fibre 38-42 part, polycarbonate 30-36 part, poly(lactic acid) 25-28 part, TDE 20-22 part, polydimethylsiloxane 18-20 part, chitin 12-15 part, silicon nitride powder 10-12 part, carborundum powder 7-8 part, sodium succinate 4-5 part, talcum powder 2-4 part, barium sulfate 2-3 part, Graphite Powder 99 1-2 part;
Each raw material is added in whizzer successively, 1000 turns/min centrifugal mixer 3 minutes, after mixing, enter twin screw extruder and be squeezed into molten state, then by injector, molten mass is injected mould fast, mould matched moulds cooling and shaping; After die sinking, finished product enters secondary mould, by cutting machine trimming and get final product in secondary mould.
Preferably, the length of glass fibre is preferably 1-5mm; The particle diameter of silicon nitride powder, carborundum powder, sodium succinate, talcum powder, barium sulfate and Graphite Powder 99 all controls more than 200 orders.
The beneficial effect that the present invention obtains is as follows:
Possess good synergy between each material component of meter case prepared by the present invention, higher mechanical property can be reached, and possess excellent thermostability and flame retardant properties, under being suitable for hot environment; The each low raw-material cost of the present invention, lower than the cost of the polycarbonate resin meter case that market is commonly used, is conducive to reducing enterprise's raw materials cost, promotes suitability for industrialized production; Preparation technology's simple possible of the present invention, is applicable to large-scale production.
Embodiment
Below employing specific embodiment is made further explanation to the present invention, but it is not as the restriction to initiative spirit of the present invention.
Embodiment 1
A preparation technology for power electric meter sheating material, it comprises the steps:
Following each raw material is taken according to weight part, wherein, polyvinyl chloride 90 parts, polyethylene 60 parts, methyl methacrylate 40 parts, 38 parts, glass fibre, polycarbonate 30 parts, poly(lactic acid) 25 parts, TDE 20 parts, polydimethylsiloxane 18 parts, chitin 12 parts, silicon nitride powder 10 parts, carborundum powder 7 parts, sodium succinate 4 parts, talcum powder 2 parts, 2 parts, barium sulfate, Graphite Powder 99 1 part.The length of glass fibre is 1mm; The size controlling of silicon nitride powder, carborundum powder, sodium succinate, talcum powder, barium sulfate and Graphite Powder 99 is at 200 orders; Each raw material is added in whizzer successively, 1000 turns/min centrifugal mixer 3 minutes, after mixing, enter twin screw extruder and be squeezed into molten state, then by injector, molten mass is injected mould fast, mould matched moulds cooling and shaping; After die sinking, finished product enters secondary mould, by cutting machine trimming and get final product in secondary mould.
Embodiment 2
A preparation technology for power electric meter sheating material, it comprises the steps:
Following each raw material is taken according to weight part, wherein, polyvinyl chloride 100 parts, polyethylene 70 parts, methyl methacrylate 50 parts, 42 parts, glass fibre, polycarbonate 36 parts, poly(lactic acid) 28 parts, TDE 22 parts, polydimethylsiloxane 20 parts, chitin 15 parts, silicon nitride powder 12 parts, carborundum powder 8 parts, sodium succinate 5 parts, talcum powder 4 parts, 3 parts, barium sulfate, Graphite Powder 99 2 parts; The length of glass fibre is 5mm; The size controlling of silicon nitride powder, carborundum powder, sodium succinate, talcum powder, barium sulfate and Graphite Powder 99 is at 300 orders;
Each raw material is added in whizzer successively, 1000 turns/min centrifugal mixer 3 minutes, after mixing, enter twin screw extruder and be squeezed into molten state, then by injector, molten mass is injected mould fast, mould matched moulds cooling and shaping; After die sinking, finished product enters secondary mould, by cutting machine trimming and get final product in secondary mould.
Embodiment 3
The performance test of meter case material prepared by the present invention:
The meter case material prepared for the embodiment of the present invention 1 and 2 carries out performance test; Wherein mould shrinks and presses ASTM D955 and test; Flexural strength is pressed ASTM D790 and is tested; Tensile strength is tested according to ASTM D638; Notched Izod impact strength is pressed ASTM D256 and is tested; Heat-drawn wire is pressed ASTM D648 and is tested.The test result of resulting materials is in table 1:
Table 1
Performance perameter |
Embodiment 1 |
Embodiment 2 |
Mould shrinks (%) |
0.24 |
0.25 |
Flexural strength (Kgf/cm
2) normal temperature
|
1390 |
1386 |
Tensile strength (Kgf/cm
2) normal temperature
|
893 |
907 |
Notched Izod impact strength (KJ/m
2)
|
13.2 |
13.1 |
Heat-drawn wire DEG C |
135 |
137 |
Conclusion: possess good synergy, better mechanical property between each material component of meter case prepared by the present invention, and possess excellent thermostability and flame retardant properties (flame retardant resistance UL94 is V0 level); Meter case prepared by the present invention under the high temperature conditions, still can keep good mechanical property, and not volatility; Low raw-material cost, lower than the cost of the polycarbonate resin meter case that market is commonly used, is conducive to suitability for industrialized production; Preparation technology's simple possible of the present invention, is applicable to large-scale production.
Finally, it is also to be noted that what enumerate above is only several specific embodiments of the present invention.Obviously, the invention is not restricted to above embodiment, many distortion can also be had.All distortion that those of ordinary skill in the art can directly derive from content disclosed by the invention or associate, all should think protection scope of the present invention.