CN104476852A - Glass fiber jet yarn with small temperature absorption performance - Google Patents
Glass fiber jet yarn with small temperature absorption performance Download PDFInfo
- Publication number
- CN104476852A CN104476852A CN201410726697.0A CN201410726697A CN104476852A CN 104476852 A CN104476852 A CN 104476852A CN 201410726697 A CN201410726697 A CN 201410726697A CN 104476852 A CN104476852 A CN 104476852A
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- CN
- China
- Prior art keywords
- yarn
- glass
- suction temperature
- little
- sprays
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Woven Fabrics (AREA)
Abstract
The invention discloses a glass fiber jet yarn with small temperature absorption performance. The glass fiber jet yarn with small temperature absorption performance is formed by combining a reinforced thermosetting resin layer positioned on an uppermost layer, a coupling agent positioned on a middle layer, and a glass fiber layer positioned on a lowermost layer, wherein the reinforced thermosetting resin layer is silicon ether resin, the glass fiber layer is a glass yarn, the silicon ether resin accounts for 34-40% of the overall weight of the glass fiber jet yarn with small temperature absorption performance, the coupling agent accounts for 2-7% of the overall weight of the glass fiber jet yarn with small temperature absorption performance, and the glass yarn accounts for 57-59% of the overall weight of the glass fiber jet yarn with small temperature absorption performance. The glass fiber jet yarn with small temperature absorption performance, disclosed by the invention, has the advantages of good wear resistance, less broken filament, stable fiber linear density, high single fiber strength, small temperature absorption performance and the like.
Description
Technical field
The present invention relates to the little glass of a kind of suction temperature and spray yarn.
Background technology
The glass cloth that glass cloth China produces, be divided into alkali-free and middle alkali two class, external great majority are E-GLASS alkali-free glass cloths.Glass cloth is mainly for the production of various electric insulation layer pressing plate, printed substrate, various carbody, basin, ships and light boats, mould etc.Middle alkali glass cloth mainly for the production of plastic-coated packing sheet, and for corrosion-resistant occasion.The characteristic of fabric determined by fibre property, thread count, yarn texture and weavy grain.Thread count is determined by knot structure and weavy grain again.Weft density adds knot structure, just determines the physical property of fabric, as weight, thickness and fracture strength etc.There is the weavy grain that five kinds basic: plain weave plan (similar woven roving), twill twill (general+-45 degree), satin weave statin (similar unidirectional cloth), rib-loop leno (the main weave of fiberglass gridding cloth) and basket matts (similar oxford).
Coupling agent is the material that a class has two heterogeneity functional groups, and the maximum feature of its molecular structure is two groups different containing chemical property in molecule, and one is the group of close inorganic matter, easily and mineral surfaces chemically reactive; Another is close organic group, or can generate hydrogen bond and is dissolved in wherein with synthetic resin or other polymer generation chemical reaction.Therefore coupling agent is referred to as " molecular bridge ", in order to improve the interface interaction between inorganic matter and organic matter, thus greatly improves the performance of composite, as physical property, electrical property, hot property, optical property etc.Coupling agent is used for, in rubber industry, can improving wearability and the ageing-resistant performance of the products such as tire, offset plate, sebific duct, rubber overshoes, and reducing NR consumption, thus reduce costs.Coupling agent effect be in the composite it can with some radical reaction on reinforcing material surface, can react with matrix resin again, a boundary layer is formed between reinforcing material and resin matrix, boundary layer can transmit stress, thus enhance bonding strength between reinforcing material and resin, improve the performance of composite, other medium can also be prevented to contacting permeation simultaneously, improve interface state, be conducive to ageing-resistant, proof stress and the electrical insulation capability of goods.
Summary of the invention
The glass injection yarn that the suction temperature of the advantages such as the invention provides and a kind ofly have good wearability, lousiness is few, fiber linear density is stablized, and the high and suction temperature of filament strength is little is little.
Technical scheme of the present invention is: the glass that a kind of suction temperature is little sprays yarn, the glass that described suction temperature is little sprays the enhancing thermoset resin layer that yarn comprises the superiors, coupling agent and the undermost glass layer in intermediate layer combine, described enhancing thermoset resin layer is silicon ether resin, described glass layer is organdy, described silicon ether resin accounts for the 34%-40% that the little glass of suction temperature sprays the overall component of yarn, described coupling agent accounts for the 2%-7% that the little glass of suction temperature sprays the overall component of yarn, described organdy accounts for the 57%-59% that the little glass of suction temperature sprays the overall component of yarn.
In a preferred embodiment of the present invention, described coupling agent comprises organochromium complexes, silanes, titanate ester and aluminated compound.
In a preferred embodiment of the present invention, described silicon ether resin accounts for the little glass of suction temperature and sprays 36% of the overall component of yarn, described coupling agent accounts for the little glass of suction temperature and sprays 6% of the overall component of yarn, and described organdy accounts for the little glass of suction temperature and sprays 58% of the overall component of yarn.
The little glass of a kind of suction temperature of the present invention sprays yarn, and have good wearability, lousiness is few, fiber linear density is stable, filament strength height and the advantage such as suction temperature is little.
Detailed description of the invention
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
Wherein, the glass that described suction temperature is little sprays the enhancing thermoset resin layer that yarn comprises the superiors, coupling agent and the undermost glass layer in intermediate layer combine, described enhancing thermoset resin layer is silicon ether resin, described glass layer is organdy, described silicon ether resin accounts for the 34%-40% that the little glass of suction temperature sprays the overall component of yarn, described coupling agent accounts for the 2%-7% that the little glass of suction temperature sprays the overall component of yarn, described organdy accounts for the 57%-59% that the little glass of suction temperature sprays the overall component of yarn, described coupling agent comprises organochromium complexes, silanes, titanate ester and aluminated compound.
Further illustrate, described silicon ether resin accounts for the little glass of suction temperature and sprays 36% of the overall component of yarn, and described coupling agent accounts for the little glass of suction temperature and sprays 6% of the overall component of yarn, and described organdy accounts for the little glass of suction temperature and sprays 58% of the overall component of yarn.
Further illustrating, organdy is also known as Bali voile/organdy, and organdy is the thin transparent fabric that a kind of plain weave knits system.The feature of organdy is: longitude and latitude all adopts thin special combing strong twisted yarn, and in fabric, thread count is smaller, due to " carefully ", " rare ", adds heavy twist, makes fabric thin transparent.The raw material of organdy has cotton textiles, polyester-cotton blend.Through weft yarn in fabric, or be single thread, or be strand.Organdy is different by processing, and organdy is divided into stained glass yarn, bleaching organdy, paint glass yarn, yarn-dyed jacquard organdy etc.The quality of organdy fabric is thin, and feel is very refreshing, and cloth hole is clear, transparent air-permeable.Organdy/Bali voile: the thin plain cloth knitting system with thin extra-heavy twist yarn.Density is sparse, and quality is thinner, and step hole is clear, and feel is very refreshing, high resilience, and good permeability is comfortable and easy to wear.Because transparency is good, be organdy again.For the base fabric of summer shirt skirt, pyjamas, scarf, veil and punchwork, desk lamp cover, curtain etc.
Further illustrating, after hardening, due to intermolecular cross-linking, form network structure, therefore rigidity is large, hardness is high, heatproof is high, nonflammable, product size good stability, but property is crisp for thermosetting resin.Thus most thermosetting resin is before being shaped to goods, all adds various reinforcing material, as wood powder, mineral powder, fiber or textile etc. make it strengthen, makes reinforced plastics.In thermosetting resin, add reinforcing material and other additives, as curing agent, colouring agent, lubricant etc., thermosetting plastics can be made, have in powdery, granular, what have is made bulk, sheet, is referred to as moulding compound.The processing method that thermosetting plastics is conventional has mold pressing, lamination, transfer modling, casting etc., and some kind also can be used for injection moulding.The invention provides the little glass of a kind of suction temperature and spray yarn, have good wearability, lousiness is few, fiber linear density is stable, filament strength height and the advantage such as suction temperature is little.
The specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention, and the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.
Claims (3)
1. the glass injection yarn that a suction temperature is little, it is characterized in that: the glass that described suction temperature is little sprays the enhancing thermoset resin layer that yarn comprises the superiors, coupling agent and the undermost glass layer in intermediate layer combine, described enhancing thermoset resin layer is silicon ether resin, described glass layer is organdy, described silicon ether resin accounts for the 34%-40% that the little glass of suction temperature sprays the overall component of yarn, described coupling agent accounts for the 2%-7% that the little glass of suction temperature sprays the overall component of yarn, described organdy accounts for the 57%-59% that the little glass of suction temperature sprays the overall component of yarn.
2. the glass that suction temperature according to claim 1 is little sprays yarn, it is characterized in that: described coupling agent comprises organochromium complexes, silanes, titanate ester and aluminated compound.
3. the glass that suction temperature according to claim 1 is little sprays yarn, it is characterized in that: described silicon ether resin accounts for the little glass of suction temperature and sprays 36% of the overall component of yarn, described coupling agent accounts for the little glass of suction temperature and sprays 6% of the overall component of yarn, and described organdy accounts for the little glass of suction temperature and sprays 58% of the overall component of yarn.
Priority Applications (1)
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CN201410726697.0A CN104476852A (en) | 2014-12-04 | 2014-12-04 | Glass fiber jet yarn with small temperature absorption performance |
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CN201410726697.0A CN104476852A (en) | 2014-12-04 | 2014-12-04 | Glass fiber jet yarn with small temperature absorption performance |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1127806A (en) * | 1994-09-06 | 1996-07-31 | 恩尼彻姆公司 | Process for the preparation of a flexible thermoplastic composite filament containing continuous fibres |
CN201043252Y (en) * | 2007-05-25 | 2008-04-02 | 常州市宏发纵横染整有限公司 | Multiaxial warp knitting reinforced sheet material |
CN101177817A (en) * | 2007-12-10 | 2008-05-14 | 盛虹集团有限公司 | Flame-proof wrap yarn |
CN101960060A (en) * | 2008-02-28 | 2011-01-26 | 贝尔直升机泰克斯特龙公司 | Uncured composite rope including a plurality of different fiber materials |
CN102391547A (en) * | 2010-06-18 | 2012-03-28 | 日信化学工业株式会社 | Glass fiber product and glass fiber reinforced plastic |
CN102575389A (en) * | 2009-09-21 | 2012-07-11 | 纱环劳仕工业公司 | Composite yarn, method for obtaining same and resulting textile structure |
US20130225721A1 (en) * | 2012-02-24 | 2013-08-29 | Ems-Patent Ag | Fiber structure, method for its manufacture and use as well as fiber-resin composite material |
-
2014
- 2014-12-04 CN CN201410726697.0A patent/CN104476852A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1127806A (en) * | 1994-09-06 | 1996-07-31 | 恩尼彻姆公司 | Process for the preparation of a flexible thermoplastic composite filament containing continuous fibres |
CN201043252Y (en) * | 2007-05-25 | 2008-04-02 | 常州市宏发纵横染整有限公司 | Multiaxial warp knitting reinforced sheet material |
CN101177817A (en) * | 2007-12-10 | 2008-05-14 | 盛虹集团有限公司 | Flame-proof wrap yarn |
CN101960060A (en) * | 2008-02-28 | 2011-01-26 | 贝尔直升机泰克斯特龙公司 | Uncured composite rope including a plurality of different fiber materials |
CN102575389A (en) * | 2009-09-21 | 2012-07-11 | 纱环劳仕工业公司 | Composite yarn, method for obtaining same and resulting textile structure |
CN102391547A (en) * | 2010-06-18 | 2012-03-28 | 日信化学工业株式会社 | Glass fiber product and glass fiber reinforced plastic |
US20130225721A1 (en) * | 2012-02-24 | 2013-08-29 | Ems-Patent Ag | Fiber structure, method for its manufacture and use as well as fiber-resin composite material |
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Application publication date: 20150401 |