CN104451694B - High-quality metal rust inhibitor for transformer and preparation method of high-quality metal rust inhibitor - Google Patents
High-quality metal rust inhibitor for transformer and preparation method of high-quality metal rust inhibitor Download PDFInfo
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- CN104451694B CN104451694B CN201410639709.6A CN201410639709A CN104451694B CN 104451694 B CN104451694 B CN 104451694B CN 201410639709 A CN201410639709 A CN 201410639709A CN 104451694 B CN104451694 B CN 104451694B
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Abstract
The invention discloses a high-quality metal rust inhibitor for a transformer and a preparation method of the high-quality metal rust inhibitor. The high-quality metal rust inhibitor comprises the following raw material components in percentage by weight: 4-8% of zinc naphthenate, 3-8% of zinc sulfate, 5-9% of amino trimethylene phosphonic acid, 4-10% of sodium gluconate, 2-10% of phenylethyl phenol polyoxyethylene ether, 2-12% of alkanolamide and the balance of water or machine oil. Compared with the prior art, the high-quality metal rust inhibitor has the beneficial effects that the high-quality metal rust inhibitor is prepared by compounding a rust inhibitor, a corrosion inhibitor, an emulsifying agent, a wetting agent and the like according to a formula and has favorable rust prevention and removal effects; no energy consumption can be generated; demoulding is not needed in the subsequent processes, and water environment destruction caused by sewage generation can be avoided; in addition, the production process is simple, and the production cost is low.
Description
Technical field
The present invention relates to a kind of high-test metal antirust agent for transformator and preparation method thereof.
Background technology
Metal in an atmosphere, can occur chemical action or electrochemical action with oxygen, water and other impurities under certain condition
And produce metal erosion.Especially be at the metal material between metalworking procedures, because surface activity is high, workpiece processing,
Carrying, check that air, hand perspiration and contact with the harmful gass in air through moisture makes the workpiece be easy to generation corrosion,
Oneself is caused processing workpiece to scrap or do over again.In order to prevent metal works during storing corrosion it is necessary to carry out antirust treatment.Tradition
Antirust treatment have antirust oil processing and water-based antirust agent to process.
Antirust oil is made up of mineral oil, oil-soluble inhibitor and other additives, by antirust oil in metal surface shape
Become protective oil film, isolation in the air steam is to corrosion of metal, thus it is antirust to reach the long period, be characterized in operating
Simply, there is certain rust-proof effect.But oiliness antirust agent also has high volatile, inflammability, easy-clear not to be to need simultaneously
Consume substantial amounts of oil plant raw material, exacerbate the shortcomings of energy resource consumption, waste of resource, simultaneously the work to surrounding using oiliness antirust agent
Will also result in pollution as environment, and in following process：Such as welding, paint, plating, assembling and unpacking, are required to cleaning and remove
Oil, not only produce a large amount of clean oily waste liquors discharge, cause the pollution to environment, and it be time-consuming to clean oil removing, also can increase
Addition is originally.
Traditional waterborne anti-rust processes and mainly uses sodium nitrite, bichromate and sodium carbonate, sodium silicate etc. to compound,
Be dissolved in the water under higher concentration composition waterborne anti-rust liquid, be characterized in simple to operate it is adaptable between metalworking procedures
Short-term rust prevention, but this rust-proofing method to there is also rust-proof life short, wherein main component sodium nitrite, bichromate are all violents in toxicity
Matter, causes huge harm to environment, operator.
Although also have developed several new water-based antirust agents both at home and abroad in recent years, with antirust industry at present, aqueouss are prevented
The requirement of rust agent is compared and there is a big difference, and existing water-based antirust agent can not meet the needs in market.Antirust time, antirust solution
Stability be all par water-based antirust agent performance leading indicator.
Rust preventing emulsion disclosed in Chinese patent CN1035522, by less than 10% polyvinyl alcohol, 1-20% Oleic acid, 2-18%'s
Barium mahogany sulfonate, the triethanolamine of 1-35%, less than 10% paraffin, remaining forms for distilled water.Though having preferable rust-proof effect,
But paraffin is the film former of most original, but because film forming is thicker, one is to enter necessary membrane removal before lower one technique, and two is that Parafilm removes
Film is difficult, time-consuming.Therefore still there is worth improved place.
A kind of composite membrane water-based antirust agent disclosed in Chinese patent CN201110119486, by the organic zinc sequestration thing of synthesis
(5-15wt%), amide surfactants (5-10wt%) are compounded with rust inhibitor (0. 1-2wt%) and are obtained.Its preparation procedure
As follows：(1) organic zinc and intercalating agent, stirring at normal temperature 30 minutes are added after adding suitable quantity of water in a kettle.；(2) in a kettle.
Add the derivant of the desired amount of acid amide or acid amide, stirring at normal temperature 20 minutes；(3) add the desired amount of antirust add in a kettle.
Plus agent, stirring at normal temperature 20 minutes；(4) add water to setting volume, continue stirring 20 minutes；(5) 10 to 30 minutes are stood, exclusion fills
Dress.Its using method is as follows：Described novel aqueous antirust agent is pressed 1 with tap water:10-1:After 50 dilutions, spray or dipping make
With；Described novel aqueous antirust agent is pressed 1:10-1:20 part by weight are added to metalworking fluid, grinding fluid, abluent gold
Belong to working fluid.
Although the composite membrane water-based antirust agent of this formula has advantages below：Antirust oil, fat is replaced to be used in intermetallic composite coating
Metal rust prevention during manufacture and its finished product seal up for safekeeping antirust；As metal working fluids such as metalworking fluid, grinding fluid, abluents
Rust-inhibiting additive；Antirust cost in reduction intermetallic composite coating, storage and transport process；In the no any residuals in metal surface, keep gold
Belong to true qualities, exempt cleaning process；Need not dry after water operation being carried, use using metal during antirust agent, easy to use；For metal
Working fluid provides stablizes basicity, suppresses the corrupt, rotten of metal working fluid；It is applied to the anti-of cast iron, steel and multiple steel alloy
Rust；Without poisonous and harmful substances such as nitrite, chromium, phosphorus, silicon, safe and environment-friendly.But its preparation process is loaded down with trivial details, increased life
Produce cost.
Water soluble anti-rust agent disclosed in Chinese patent CN200910008115, consisting of：2-10wt% barium mahogany sulfonate
And/or two nonyl certain herbaceous plants with big flowers base barium sulfonates, 1-6wt% sodium platinate and/or platinic acid amine, 0-10wt% SA,
2-10wt % polyacrylate, the 3-20wt% oil liquor-saturated amine soap of triethylenetetraminehexaacetic acid and/or 2-6wt% sorbitan mono-oleic acid ester,
0-15wt% petroleum sodium sulfonate, 0-8wt% glycerol, balance of water or machinery oil.Although the water soluble anti-rust agent of this formula has anti-
The advantage of rust time length, but there is one layer of antirust film through the metal surface of the method antirust treatment, in subsequent operation
Needs carry out moving back film process, and moving back film process needs more than 50 degree of hot water, increased thermal energy consumption, and moves back in membrane process and can produce
Waste water, can be to environment.
Improvement to the high-test metal antirust agent for transformator need to be improved.
Content of the invention
It is for above-mentioned the deficiencies in the prior art that the present invention needs the problems referred to above solving, and provides one kind to be used for transformator
High-test metal antirust agent.
For solving above-mentioned technical problem, the technical solution used in the present invention is：
A kind of high-test metal antirust agent for transformator, its raw material constituent and weight percentage ranges are respectively：
Zinc naphthenate 4%-8%；
Zinc sulfate 3%-8%；
ATMP 5%-9%；
Sodium gluconate 4%-10%；
Phenethyl phenol polyethenoxy ether 2%-10%；
Alkanolamide 2%-12%；
Balance of water or machinery oil.
As the preferred technical solution of the present invention, the described high-test metal antirust agent for transformator, its raw material forms
Composition and weight percentage ranges are respectively：
Zinc naphthenate 4.5%-7%；
Zinc sulfate 3.5%-7%；
ATMP 5.5%-8%；
Sodium gluconate 4.5%-9%；
Phenethyl phenol polyethenoxy ether 3%-9%；
Alkanolamide 3%-11%；
Balance of water or machinery oil.
As the preferred technical solution of the present invention, the described high-test metal antirust agent for transformator, its raw material forms
Composition and weight percentage ranges are respectively：
Zinc naphthenate 5%-6.5%；
Zinc sulfate 4%-6%；
ATMP 6%-7%；
Sodium gluconate 5%-8%；
Phenethyl phenol polyethenoxy ether 4%-8%；
Alkanolamide 4%-6%；
Balance of water or machinery oil.
As the preferred technical solution of the present invention, the described high-test metal antirust agent for transformator, its raw material forms
Composition and weight percentage ranges are respectively：
Zinc naphthenate 5.5%-6%；
Zinc sulfate 4.5%-5.5%；
ATMP 6.5%-7%；
Sodium gluconate 6%-7%；
Phenethyl phenol polyethenoxy ether 5%-7%；
Alkanolamide 5%-5.5%；
Balance of water or machinery oil.
As the preferred technical solution of the present invention, described solvent is machinery oil.
The preparation method of the described high-test metal antirust agent for transformator, weighs raw material by described percentage by weight,
The zinc naphthenate being weighed；Zinc sulfate；ATMP；Sodium gluconate；Phenethyl phenol polyethenoxy ether；Alkanol acyl
Amine adds in water or machinery oil, stirs and is completely dissolved to all the components.
Compared with prior art, the invention has the beneficial effects as follows：This formula is by antirust agent, corrosion inhibiter, emulsifying agent and profit
Humectant etc. is compounding to be formed, and has good derusting rust-proofing effect；Energy consumption will not be produced；Demoulding is not needed during subsequent technique,
Sewage will not be produced and destroy water environment, and production process is simple, low production cost.
Specific embodiment
Embodiment 1
A kind of high-test metal antirust agent for transformator, its raw material constituent and weight percentage ranges are respectively：
Zinc naphthenate 4%；
Zinc sulfate 3%；
ATMP 5%；
Sodium gluconate 4%；
Phenethyl phenol polyethenoxy ether 2%；
Alkanolamide 2%；
Balance of machinery oil.
The preparation method of the above-mentioned high-test metal antirust agent for transformator, weighs raw material by described percentage by weight,
The zinc naphthenate being weighed；Zinc sulfate；ATMP；Sodium gluconate；Phenethyl phenol polyethenoxy ether；Alkanol acyl
Amine adds in machinery oil, stirs and is completely dissolved to all the components.
For the high-test metal antirust agent of transformator, metal bar is carried out after antirust treatment using this formula, in high/low temperature
Under all stable, damp and hot antirust experiment is lower to be up to 8 days, and indoor lacing film is up to 4 months, seal up for safekeeping antirust be up to 7 months, rust-proof effect is excellent
Good.
Embodiment 2
The described high-test metal antirust agent for transformator, its raw material constituent and weight percentage ranges are respectively
For：
Zinc naphthenate 7%；
Zinc sulfate 7%；
ATMP 8%；
Sodium gluconate 9%；
Phenethyl phenol polyethenoxy ether 9%；
Alkanolamide 11%；
Balance of machinery oil.
The preparation method of the above-mentioned high-test metal antirust agent for transformator, weighs raw material by described percentage by weight,
The zinc naphthenate being weighed；Zinc sulfate；ATMP；Sodium gluconate；Phenethyl phenol polyethenoxy ether；Alkanol acyl
Amine adds in machinery oil, stirs and is completely dissolved to all the components.
For the high-test metal antirust agent of transformator, metal bar is carried out after antirust treatment using this formula, in high/low temperature
Under all stable, damp and hot antirust experiment is lower to be up to 9.5 days, and indoor lacing film is up to 6 months, seal up for safekeeping antirust be up to 8 months, rust-proof effect
Excellent.
Embodiment 3
The described high-test metal antirust agent for transformator, its raw material constituent and weight percentage ranges are respectively
For：
Zinc naphthenate 5%；
Zinc sulfate 4%；
ATMP 6%；
Sodium gluconate 5%；
Phenethyl phenol polyethenoxy ether 4%；
Alkanolamide 4%；
Balance of machinery oil.
The preparation method of the above-mentioned high-test metal antirust agent for transformator, weighs raw material by described percentage by weight,
The zinc naphthenate being weighed；Zinc sulfate；ATMP；Sodium gluconate；Phenethyl phenol polyethenoxy ether；Alkanol acyl
Amine adds in machinery oil, stirs and is completely dissolved to all the components.
For the high-test metal antirust agent of transformator, metal bar is carried out after antirust treatment using this formula, in high/low temperature
Under all stable, damp and hot antirust experiment is lower to be up to 11 days, and indoor lacing film is up to 7 months, seal up for safekeeping antirust be up to 12 months, rust-proof effect
Excellent.
Embodiment 4
The described high-test metal antirust agent for transformator, its raw material constituent and weight percentage ranges are respectively
For：
Zinc naphthenate 6%；
Zinc sulfate 5.5%；
ATMP 7%；
Sodium gluconate 7%；
Phenethyl phenol polyethenoxy ether 7%；
Alkanolamide 5.5%；
Balance of machinery oil.
The preparation method of the above-mentioned high-test metal antirust agent for transformator, weighs raw material by described percentage by weight,
The zinc naphthenate being weighed；Zinc sulfate；ATMP；Sodium gluconate；Phenethyl phenol polyethenoxy ether；Alkanol acyl
Amine adds in machinery oil, stirs and is completely dissolved to all the components.
For the high-test metal antirust agent of transformator, metal bar is carried out after antirust treatment using this formula, in high/low temperature
Under all stable, damp and hot antirust experiment is lower to be up to 12 days, and indoor lacing film is up to 8 months, seal up for safekeeping antirust be up to 14 months, rust-proof effect
Excellent.
With the above-mentioned desirable embodiment according to the present invention for enlightenment, by above-mentioned description, relevant staff is complete
Entirely various change and modification can be carried out in the range of without departing from this invention technological thought.The technology of this invention
The content that property scope is not limited in description it is necessary to determine its technical scope according to right.
Claims (5)
1. a kind of metal antirusting agent for transformator it is characterised in that：Its raw material constituent and weight percentage ranges are divided
It is not：
Zinc naphthenate 4%-8%；
Zinc sulfate 3%-8%；
ATMP 5%-9%；
Sodium gluconate 4%-10%；
Phenethyl phenol polyethenoxy ether 2%-10%；
Alkanolamide 2%-12%；
Balance of water or machinery oil.
2. the metal antirusting agent for transformator according to claim 1 it is characterised in that：Its raw material constituent and weight
Amount percentage range is respectively：
Zinc naphthenate 4.5%-7%；
Zinc sulfate 3.5%-7%；
ATMP 5.5%-8%；
Sodium gluconate 4.5%-9%；
Phenethyl phenol polyethenoxy ether 3%-9%；
Alkanolamide 3%-11%；
Balance of water or machinery oil.
3. the metal antirusting agent for transformator according to claim 1 it is characterised in that：Its raw material constituent and weight
Amount percentage range is respectively：
Zinc naphthenate 5%-6.5%；
Zinc sulfate 4%-6%；
ATMP 6%-7%；
Sodium gluconate 5%-8%；
Phenethyl phenol polyethenoxy ether 4%-8%；
Alkanolamide 4%-6%；
Balance of water or machinery oil.
4. the metal antirusting agent for transformator according to claim 1 it is characterised in that：Its raw material constituent and weight
Amount percentage range is respectively：
Zinc naphthenate 5.5%-6%；
Zinc sulfate 4.5%-5.5%；
ATMP 6.5%-7%；
Sodium gluconate 6%-7%；
Phenethyl phenol polyethenoxy ether 5%-7%；
Alkanolamide 5%-5.5%；
Balance of water or machinery oil.
5. the metal antirusting agent for transformator according to claim 1 preparation method it is characterised in that：By described heavy
Amount percentage ratio weighs raw material, the zinc naphthenate being weighed；Zinc sulfate；ATMP；Sodium gluconate；Phenethyl phenol
Polyoxyethylene ether；Alkanolamide adds in water or machinery oil, stirs and is completely dissolved to all the components.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410639709.6A CN104451694B (en) | 2014-11-14 | 2014-11-14 | High-quality metal rust inhibitor for transformer and preparation method of high-quality metal rust inhibitor |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410639709.6A CN104451694B (en) | 2014-11-14 | 2014-11-14 | High-quality metal rust inhibitor for transformer and preparation method of high-quality metal rust inhibitor |
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| CN104451694A CN104451694A (en) | 2015-03-25 |
| CN104451694B true CN104451694B (en) | 2017-02-15 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1043952A (en) * | 1988-12-30 | 1990-07-18 | 杨延松 | Silicon sheet sheared edge rust preventive and method for making thereof |
| CN102296295A (en) * | 2011-05-04 | 2011-12-28 | 南通飞拓界面工程科技有限公司 | Novel water-based rust inhibitor |
| CN103184456A (en) * | 2013-03-01 | 2013-07-03 | 上海金兆节能科技有限公司 | Environment-friendly long-life emulsified antirust agent and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5922794B2 (en) * | 1978-12-23 | 1984-05-29 | 株式会社片山化学工業研究所 | Metal corrosion prevention method in dehumidification equipment |
-
2014
- 2014-11-14 CN CN201410639709.6A patent/CN104451694B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1043952A (en) * | 1988-12-30 | 1990-07-18 | 杨延松 | Silicon sheet sheared edge rust preventive and method for making thereof |
| CN102296295A (en) * | 2011-05-04 | 2011-12-28 | 南通飞拓界面工程科技有限公司 | Novel water-based rust inhibitor |
| CN103184456A (en) * | 2013-03-01 | 2013-07-03 | 上海金兆节能科技有限公司 | Environment-friendly long-life emulsified antirust agent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 水基防锈剂的研究进展;李志林等;《表面技术》;20061031;第35卷(第5期);第51-53页 * |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
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Inventor after: Yan Hongbing Inventor before: Yu Shenglin |
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| TR01 | Transfer of patent right |
Effective date of registration: 20180129 Address after: No. 23, painter Lake Road, Yangcheng Lake Town, Xiangcheng District, Suzhou, Jiangsu Patentee after: Suzhou Yangxin materials Polytron Technologies Inc Address before: 214135 Jiangsu city of Wuxi province innovation building No. 97 Linghu Wuxi national hi tech Industrial Development Zone, road two South Building Room 101 Patentee before: Wuxi NUIST Weather Sensor Network Technology Co., Ltd. |
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