CN104449378A - Hard film rust preventive and preparation method thereof - Google Patents
Hard film rust preventive and preparation method thereof Download PDFInfo
- Publication number
- CN104449378A CN104449378A CN201410566481.2A CN201410566481A CN104449378A CN 104449378 A CN104449378 A CN 104449378A CN 201410566481 A CN201410566481 A CN 201410566481A CN 104449378 A CN104449378 A CN 104449378A
- Authority
- CN
- China
- Prior art keywords
- parts
- hard film
- rust
- preventive agent
- rust preventive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
- C09D193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses a hard film rust preventive comprising the following components in parts by weight: 5-10 parts of rosin ester resin, 1-6 parts of petroleum resin, 65-85 parts of a dearomatization aliphatic solvent, 3-8 parts of a rust preventive, 2-10 parts of machine oil and 0.1-0.3 part of an organic dye. The hard film rust preventive uses the dearomatization aliphatic solvent, so that the irritation of the hard film rust preventive is extremely low, the hard film rust preventive can be accepted by consumers easily, and meanwhile, the hard film rust preventive uses the rosin ester resin and the petroleum resin as film forming matters and a dearomatization petroleum solvent as a carrier, and the rust preventive and the machine oil are added to enhance the rust prevention performance; and moreover, a yellow organic dye is added to facilitate judgment of film forming, and a transparent film layer is formed on the surface of a workpiece, so that the hard film rust preventive has good adhesive force and glossiness and cannot be stripped easily.
Description
Technical field
The present invention relates to rust-preventive agent, particularly relate to a kind of hard film rust preventives.
Background technology
Hard film rust preventives of the prior art mainly uses rosin and maleic anhydride 80-100 DEG C of reaction, add rust-preventive agent again to stir synthetic intermediate, intermediate add stir in Tianna solution after add alkylphenol polyoxyethylene and dimethyl silicone oil stir filter filling, obtained finished product.But, owing to using the pungencys such as Tianna solution, aromatic hydrocarbons, butylacetate, ethyl acetate, solvent that toxicity is larger in prior art, thus be difficult to be accepted, simultaneously, dried dura mater is more crisp, easy stripping, in addition, existing hard film rust preventives also needs to rely on numerous and diverse manufacture craft and is achieved.
Summary of the invention
The technical problem to be solved in the present invention is, for the deficiencies in the prior art, provide that a kind of pungency is little, toxicity is little, dried dura mater is not easily peeled off, and simple hard film rust preventives of complete processing and preparation method thereof.
For solving the problems of the technologies described above, the present invention adopts following technical scheme.
A kind of hard film rust preventives, by weight, described hard film rust preventives the ratio of each component is: rosin ester resin 5 parts ~ 10 parts; Petroleum resin 1 part ~ 6 parts; Porous deproteinized bone aliphatic solvent 65 parts ~ 85 parts; Rust-preventive agent 3 parts ~ 8 parts; 2 parts ~ 10 parts, machinery oil; Organic dye 0.1 part ~ 0.3 part.
Preferably, described petroleum resin are any one or a few the mixing in C5 petroleum resin, C9 petroleum resin and terpine resin.
Preferably, described Porous deproteinized bone aliphatic solvent be straight-chain paraffin, isoparaffin one or more.
Preferably, described rust-preventive agent is any one or a few the mixing in T701 rust-preventive agent, T702 rust-preventive agent, T746 rust-preventive agent, T705 rust-preventive agent, calcium mahogany sulfonate and dinonylnaphthalene sulfonic acid calcium.
Preferably, described organic dye is yellow organic dye.
A preparation method for hard film rust preventives, the method comprises the steps: step S1: pulverized by rosin ester resin; Step S2: Porous deproteinized bone aliphatic solvent is dropped in reactor, adds the rosin ester resin and petroleum resin that have crushed while stirring, be stirred to and dissolve completely; Step S3: rust-preventive agent, machinery oil, organic dye are added reactor and stir, filters filling.
Preferably, in described step S2, reactor is heated to 50 DEG C with accelerate dissolution rosin ester resin and petroleum resin.
In hard film rust preventives disclosed by the invention, owing to it using Porous deproteinized bone aliphatic solvent, thus its pungency is extremely low, easily accept by human consumer, meanwhile, this hard film rust preventives with rosin ester resin and petroleum resin for film forming matter, with Porous deproteinized bone petroleum solvent for carrier, add rust-preventive agent, machinery oil again to strengthen rustless property, in addition, add organic dye and conveniently judge film forming situation, after using, transparent film layer can be formed at workpiece surface, there is good sticking power and glossiness, not easily peel off.
Embodiment
Below in conjunction with embodiment, the present invention is described in more detail.
The invention discloses a kind of hard film rust preventives, by weight, described hard film rust preventives the ratio of each component is:
Rosin ester resin 5 parts ~ 10 parts;
Petroleum resin 1 part ~ 6 parts;
Porous deproteinized bone aliphatic solvent 65 parts ~ 85 parts;
Rust-preventive agent 3 parts ~ 8 parts;
2 parts ~ 10 parts, machinery oil;
Organic dye 0.1 part ~ 0.3 part, described organic dye is yellow organic dye.
In above-mentioned hard film rust preventives, owing to it using Porous deproteinized bone aliphatic solvent, thus its pungency is extremely low, easily accept by human consumer, meanwhile, this hard film rust preventives with rosin ester resin and petroleum resin for film forming matter, with Porous deproteinized bone petroleum solvent for carrier, add rust-preventive agent, machinery oil again to strengthen rustless property, in addition, add organic dye and conveniently judge film forming situation, after using, glassy yellow film can be formed at workpiece surface, there is good sticking power and glossiness, not easily peel off.
By the hard film rust preventives of said ratio, can learn after tested: its outward appearance is yellow transparent/translucent liquid, be applied to 45# steel, the >24 hour not corrosion of salt fog time.
As a kind of preferred implementation, described petroleum resin are any one or a few the mixing in C5 petroleum resin, C9 petroleum resin and terpine resin.Described Porous deproteinized bone aliphatic solvent be straight-chain paraffin, isoparaffin one or more.Described rust-preventive agent is any one or a few the mixing in T701 rust-preventive agent, T702 rust-preventive agent, T746 rust-preventive agent, T705 rust-preventive agent, calcium mahogany sulfonate and dinonylnaphthalene sulfonic acid calcium.
In order to obtain this hard film rust preventives better, the present invention also discloses a kind of preparation method of hard film rust preventives, and the method comprises the steps:
Step S1: rosin ester resin is pulverized;
Step S2: Porous deproteinized bone aliphatic solvent is dropped in reactor, adds the rosin ester resin and petroleum resin that have crushed while stirring, be stirred to and dissolve completely, in this step, reactor is heated to 50 DEG C with accelerate dissolution rosin ester resin and petroleum resin;
Step S3: rust-preventive agent, machinery oil, organic dye are added reactor and stir, filters filling.
This preparation method above-mentioned not only technique is simple, and without the need to pyroreaction, thus greatly can reduce energy consumption.The hard film rust preventives prepared as stated above, can form glassy yellow film at workpiece surface, have good sticking power and glossiness.
About the preparation method of hard film rust preventives, please refer to following embodiment.
Embodiment 1:
In the present embodiment, the preparation method of hard film rust preventives is: step S1: pulverized by 5 parts of rosin ester resins; Step S2: 65 parts of Porous deproteinized bone aliphatic solvents are dropped in reactor, adds the rosin ester resin and 1 part of petroleum resin that have crushed while stirring, be stirred to and dissolve completely; Step S3: 3 parts of rust-preventive agent, 2 parts of machinery oil, 0.1 part of organic dye are added reactor and stir, filters filling.
Embodiment 2:
In the present embodiment, the preparation method of hard film rust preventives is: step S1: pulverized by 7 parts of rosin ester resins; Step S2: 75 parts of Porous deproteinized bone aliphatic solvents are dropped in reactor, adds the rosin ester resin and 4 parts of petroleum resin that have crushed while stirring, be stirred to and dissolve completely; Step S3: 6 parts of rust-preventive agent, 6 parts of machinery oil, 0.2 part of organic dye are added reactor and stir, filters filling.
Embodiment 3:
In the present embodiment, the preparation method of hard film rust preventives is: step S1: pulverized by 10 parts of rosin ester resins; Step S2: 85 parts of Porous deproteinized bone aliphatic solvents are dropped in reactor, adds the rosin ester resin and 6 parts of petroleum resin that have crushed while stirring, be stirred to and dissolve completely; Step S3: 8 parts of rust-preventive agent, 10 parts of machinery oil, 0.3 part of organic dye are added reactor and stir, filters filling.
The above is preferred embodiment of the present invention, is not limited to the present invention, all make in technical scope of the present invention amendment, equivalent to replace or improvement etc., all should be included in scope that the present invention protects.
Claims (7)
1. a hard film rust preventives, is characterized in that, by weight, described hard film rust preventives the ratio of each component is:
Rosin ester resin 5 parts ~ 10 parts;
Petroleum resin 1 part ~ 6 parts;
Porous deproteinized bone aliphatic solvent 65 parts ~ 85 parts;
Rust-preventive agent 3 parts ~ 8 parts;
2 parts ~ 10 parts, machinery oil;
Organic dye 0.1 part ~ 0.3 part.
2. hard film rust preventives as claimed in claim 1, it is characterized in that, described petroleum resin are any one or a few the mixing in C5 petroleum resin, C9 petroleum resin and terpine resin.
3. hard film rust preventives as claimed in claim 1, is characterized in that, described Porous deproteinized bone aliphatic solvent be straight-chain paraffin, isoparaffin one or more.
4. hard film rust preventives as claimed in claim 1, it is characterized in that, described rust-preventive agent is any one or a few the mixing in T701 rust-preventive agent, T702 rust-preventive agent, T746 rust-preventive agent, T705 rust-preventive agent, calcium mahogany sulfonate and dinonylnaphthalene sulfonic acid calcium.
5. hard film rust preventives as claimed in claim 1, it is characterized in that, described organic dye is yellow organic dye.
6. a preparation method for hard film rust preventives, is characterized in that, the method comprises the steps:
Step S1: rosin ester resin is pulverized;
Step S2: Porous deproteinized bone aliphatic solvent is dropped in reactor, adds the rosin ester resin and petroleum resin that have crushed while stirring, be stirred to and dissolve completely;
Step S3: rust-preventive agent, machinery oil, organic dye are added reactor and stir, filters filling.
7. the preparation method of hard film rust preventives as claimed in claim 6, is characterized in that, in described step S2, reactor is heated to 50 DEG C with accelerate dissolution rosin ester resin and petroleum resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566481.2A CN104449378A (en) | 2014-10-22 | 2014-10-22 | Hard film rust preventive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566481.2A CN104449378A (en) | 2014-10-22 | 2014-10-22 | Hard film rust preventive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104449378A true CN104449378A (en) | 2015-03-25 |
Family
ID=52896154
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410566481.2A Pending CN104449378A (en) | 2014-10-22 | 2014-10-22 | Hard film rust preventive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104449378A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893791A (en) * | 2015-05-11 | 2015-09-09 | 江西瑞思博化工有限公司 | Hard film rust preventive oil and preparation method thereof |
| CN107699319A (en) * | 2017-10-09 | 2018-02-16 | 东莞市德虏克新材料科技有限公司 | A kind of hard film rust preventives |
| CN108546434A (en) * | 2018-05-25 | 2018-09-18 | 上海巨石化工有限公司 | A kind of environment-friendly type hard film rust preventives and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52133472A (en) * | 1976-04-30 | 1977-11-08 | Nippon Grease Kk | Lubricating composition and method of the same |
| CN101812359A (en) * | 2010-03-19 | 2010-08-25 | 北京天一精人石化科技有限公司 | Antirust oil for high-speed railway track switch and production method thereof |
| CN102153935A (en) * | 2011-01-27 | 2011-08-17 | 衡阳艳利化学工业有限公司 | Interpenetrating network hard coat antirust oil and preparation method thereof |
| CN103087808A (en) * | 2012-10-12 | 2013-05-08 | 布兰诺工业包装材料(上海)有限公司 | Fast-drying hard film rust preventive oil and preparation method thereof |
-
2014
- 2014-10-22 CN CN201410566481.2A patent/CN104449378A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52133472A (en) * | 1976-04-30 | 1977-11-08 | Nippon Grease Kk | Lubricating composition and method of the same |
| CN101812359A (en) * | 2010-03-19 | 2010-08-25 | 北京天一精人石化科技有限公司 | Antirust oil for high-speed railway track switch and production method thereof |
| CN102153935A (en) * | 2011-01-27 | 2011-08-17 | 衡阳艳利化学工业有限公司 | Interpenetrating network hard coat antirust oil and preparation method thereof |
| CN103087808A (en) * | 2012-10-12 | 2013-05-08 | 布兰诺工业包装材料(上海)有限公司 | Fast-drying hard film rust preventive oil and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893791A (en) * | 2015-05-11 | 2015-09-09 | 江西瑞思博化工有限公司 | Hard film rust preventive oil and preparation method thereof |
| CN107699319A (en) * | 2017-10-09 | 2018-02-16 | 东莞市德虏克新材料科技有限公司 | A kind of hard film rust preventives |
| CN108546434A (en) * | 2018-05-25 | 2018-09-18 | 上海巨石化工有限公司 | A kind of environment-friendly type hard film rust preventives and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103012634B (en) | Phosphate modified origoester acrylate of a kind of ultraviolet light polymerization and preparation method thereof | |
| CN104449378A (en) | Hard film rust preventive and preparation method thereof | |
| CN105038588B (en) | A kind of environment protecting wood wax oil and preparation method thereof | |
| CN104212329B (en) | A kind of anti-rust metal coating and its preparation method | |
| CN102010602A (en) | Water-based tackifier resin emulsion and preparation method thereof | |
| CN102585701A (en) | Vegetable oil paint | |
| CN104610892B (en) | A kind of formula of environmental protection granule thermotropic pressure sensitive glue and preparation method thereof | |
| CN103805028A (en) | Preparation method of solvent-free antifouling paint for underwater construction | |
| CN102786898A (en) | Hot melt adhesive composition for carpet skid resistance and preparation method of hot melt adhesive composition | |
| RU2663171C2 (en) | Aqueous coating compositions including reaction product of maleic anhydride with unsaturated compound and amine | |
| CN104497873A (en) | High-gloss environment-friendly natural wood oil and preparation method thereof | |
| CN104046143A (en) | Sustained-release fly and mosquito repellent emulsion paint | |
| CN102604516A (en) | Anti-greening PE (Polyethylene) transparent primer and preparation method thereof | |
| CN104497813A (en) | Nitrocellulose-modified low-temperature quick-drying unsaturated polyester primer and preparation method thereof | |
| CN102888177A (en) | Environment-friendly antirust paint | |
| CN104744678A (en) | Alkyd resin and preparation method thereof | |
| CN104231695A (en) | Green antibacterial coating for interior wall | |
| CN105038343A (en) | Antiskid paint for wood floor | |
| CN108641468A (en) | A kind of formula of alcohol aqueous composite ink | |
| CN101260276A (en) | Water-soluble vacuum coating paint | |
| CN104109408A (en) | Building roof waterproof coating | |
| CN102796419A (en) | Offset ink for improving polyester film binding fastness | |
| CN104673102A (en) | Environment-friendly high-adhesiveness organic glass adhesive | |
| CN104017461A (en) | Metal mold surface protective agent | |
| CN104072739A (en) | Hydrolysis resisting aqueous alkyd resin and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150325 |