CN104449168B - A kind of preparation method of the antifouling water paint of sea water - Google Patents
A kind of preparation method of the antifouling water paint of sea water Download PDFInfo
- Publication number
- CN104449168B CN104449168B CN201410810810.3A CN201410810810A CN104449168B CN 104449168 B CN104449168 B CN 104449168B CN 201410810810 A CN201410810810 A CN 201410810810A CN 104449168 B CN104449168 B CN 104449168B
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- kilograms
- water
- antifouling
- weigh
- sea water
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
nullThe present invention relates to the preparation method of the antifouling water paint of a kind of sea water，The method can comprise the following steps: to weigh acrylic acid ester emulsion 15 kilograms、7 (4 benzyl chloride epoxides) 4，5 dihydro 2H [1，2，4] triazole [4，3 a] and quinoline 1 ketone 0.2 kilogram、Iron oxide red 2 kilograms、EFKA 67453 kilograms、BD 3,032 2 kilograms、Pulvis Talci 2 kilograms、Hydroxyethyl cellulose 2 kilograms and 80 kilograms of water，30 minutes it are thoroughly mixed under 250r/min，Pour in cone mill and be ground，Obtain graining paste，Weigh DOW CORNING DC 65 additive 1.5 kilograms and alcohol ester 12 3 kilograms，It is slowly added in graining paste under stirring at low speed 200r/min，Stirring 30min，Filter，Discharging，Obtain.The antifouling water paint of sea water of the present invention has preferable anti-fouling effect, has broad prospects in commercial Application.
Description
Technical field
The present invention relates to paint field, specifically, the present invention relates to a kind of antifouling aqueous of sea water
The preparation method of coating.
Background technology
Along with the development of human industry, the application of anti-soil technology becomes increasingly extensive.Make the mankind
In used all anti-soil technologies, it is the most ripe, most economical, most widely used for using antifouling paint
A kind of general method.The organotin self polishing copolymer antifouling paint that 20 century 70s are developed is efficient because of it
It is applied widely with light spectrality.But research subsequently show organotin can endanger ecology and
The health of the mankind.Traditional coating is all using organic solvent as solvent, can discharge organic waving
The property sent out gas (VOC), pollutes environment and injures the healthy of workman.Therefore, exploitation is efficiently
Low toxicity, antifouling paint nontoxic, Water-borne modification have just become the developing direction that following antifouling paint is inevitable.
Summary of the invention
It is an object of the invention to provide the preparation method of the antifouling water paint of a kind of sea water.
In order to realize the purpose of the present invention, the present invention provides the system of the antifouling water paint of a kind of sea water
Preparation Method, the method can comprise the following steps: to weigh acrylic acid ester emulsion 15 kilograms, 7-(4-
Chloro-benzyloxy)-4,5-dihydro-2H-[1,2,4]-triazole [4,3-a] quinoline-1-ketone 0.2 kilogram, ferrum
Red 2 kilograms, EFKA 6,745 3 kilograms, BD-3032 2 kilograms, Pulvis Talci 2 kilograms, ethoxy
Cellulose 2 kilograms and 80 kilograms of water, be thoroughly mixed under 250r/min 30 minutes, pour into
Cone mill is ground, obtains graining paste, weigh DOW CORNING DC-65 additive 1.5 kilograms and
Alcohol ester-12 3 kilograms, is slowly added in graining paste under stirring at low speed 200r/min, stirring
30min, filters, discharging, to obtain final product.
In the present invention:
It is highly preferred that described anti-fouling agent is 7-(the chloro-benzyloxy of 4-)-4,5-dihydro-2H-[1,2,4]-
Triazole [4,3-a] quinoline-1-ketone.
It is highly preferred that described pigment is iron oxide red.
It is highly preferred that described dispersant is EFKA 6745.
It is highly preferred that described wetting agent is BD-3032.
It is highly preferred that described defoamer is DOW CORNING DC-65 additive.
It is highly preferred that described thickening agent is hydroxyethyl cellulose.
It is highly preferred that described coalescents is alcohol ester-12.
The antifouling water paint of sea water of the present invention has preferable anti-fouling effect, should in industry
Use and have broad prospects.
Detailed description of the invention
Below by way of the description of detailed description of the invention, the invention will be further described, but this is not
Being limitation of the present invention, those skilled in the art, according to the basic thought of the present invention, can do
Go out various amendment or improvement, but without departing from the basic thought of the present invention, all in the present invention
Within the scope of.
Embodiment 1
(model DC-W10, purchased from the great achievement architectural engineering of Dechang, Beijing to weigh acrylic acid ester emulsion
Technology Co., Ltd.) 15 kilograms, 7-(the chloro-benzyloxy of 4-)-4,5-dihydro-2H-[1,2,4]-triazole [4,
3-a] and quinoline-1-ketone 0.2 kilogram, iron oxide red 2 kilograms, EFKA 6,745 3 kilograms, BD-3032 2
Kilogram, Pulvis Talci 2 kilograms, hydroxyethyl cellulose 2 kilograms and 80 kilograms of water, under 250r/min
It is thoroughly mixed 30 minutes, pours in cone mill and be ground, obtain graining paste, weigh
Healthy and free from worry DC-65 additive 1.5 kilograms and alcohol ester-12 3 kilograms, slow under stirring at low speed 200r/min
Slowly join in graining paste, stir 30min, filter, discharging, to obtain final product.
Embodiment 2
Preparing the antifouling water paint of sea water according to the same manner as in Example 1, difference exists
In not using 7-(the chloro-benzyloxy of 4-)-4,5-dihydro-2H-[1,2,4]-triazole [4,3-a] quinoline-1-
Ketone.
Experimental example
The low carbon steel plate of 150 × 70 × 2mm is as sample base plate, after polishing and processing of rust removing,
Acetone oil removing.By the coating application prepared in embodiment to above, it is allowed to form nonpolluting coating.
Use the SL200D type contact angle tester of Solon (Shanghai) Information Technology Co., Ltd., use outstanding
Dripping method (sea water) has carried out the test of contact angle to described nonpolluting coating.Result shows, implements
The contact angle of the antifouling paint of example 1 can reach 172 °, and the connecing of the antifouling paint of embodiment 2
Feeler is only 105 °, and both compare has significant difference (P ＜ 0.05).Contact angle is the biggest,
Soil resistance is the strongest, it can be seen that, the coating of the present invention has stronger soil resistance.
Claims (1)
1. the preparation method of the antifouling water paint of sea water, it is characterised in that the method bag
Include the following step: weigh acrylic acid ester emulsion 15 kilograms, 7-(the chloro-benzyloxy of 4-)-4,5-dihydro
-2H-[1,2,4]-triazole [4,3-a] quinoline-1-ketone 0.2 kilogram, iron oxide red 2 kilograms, EFKA
6745 3 kilograms, BD-3032 2 kilograms, Pulvis Talci 2 kilograms, hydroxyethyl cellulose 2
Kilogram and 80 kilograms of water, be thoroughly mixed under 250r/min 30 minutes, pour taper into
Mill is ground, obtains graining paste, weigh DOW CORNING DC-65 additive 1.5 kilograms and alcohol
Ester-12 3 kilograms, is slowly added in graining paste under stirring at low speed 200r/min, stirring
30min, filters, discharging, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410810810.3A CN104449168B (en) | 2014-12-23 | 2014-12-23 | A kind of preparation method of the antifouling water paint of sea water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410810810.3A CN104449168B (en) | 2014-12-23 | 2014-12-23 | A kind of preparation method of the antifouling water paint of sea water |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104449168A CN104449168A (en) | 2015-03-25 |
| CN104449168B true CN104449168B (en) | 2016-08-17 |
Family
ID=52895948
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410810810.3A Active CN104449168B (en) | 2014-12-23 | 2014-12-23 | A kind of preparation method of the antifouling water paint of sea water |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104449168B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1511909A (en) * | 2000-06-28 | 2004-07-14 | 三菱丽阳株式会社 | Mono soluble mixture containing metal, composition containing metal resin and dirt-proof paint |
| CN1606602A (en) * | 2002-10-23 | 2005-04-13 | 中国涂料株式会社 | Antifouling paint composition, antifouling paint films, and, ships, underwater structures, fishing gear and fishing nets covered with the films |
| CN102234251A (en) * | 2010-04-20 | 2011-11-09 | 中国科学院烟台海岸带研究所 | Benzisothiazolinone compound and application thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2538414A1 (en) * | 2005-03-02 | 2006-09-02 | Kansai Paint Co., Ltd. | Red-colored metallic paint formulations |
-
2014
- 2014-12-23 CN CN201410810810.3A patent/CN104449168B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1511909A (en) * | 2000-06-28 | 2004-07-14 | 三菱丽阳株式会社 | Mono soluble mixture containing metal, composition containing metal resin and dirt-proof paint |
| CN1606602A (en) * | 2002-10-23 | 2005-04-13 | 中国涂料株式会社 | Antifouling paint composition, antifouling paint films, and, ships, underwater structures, fishing gear and fishing nets covered with the films |
| CN102234251A (en) * | 2010-04-20 | 2011-11-09 | 中国科学院烟台海岸带研究所 | Benzisothiazolinone compound and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 1,2,4-三唑并[4,3-a]喹啉衍生物的合成及其抗惊厥活性;李元春等;《中国药物化学杂志》;20110228;第21卷(第1期);第12-18页 * |
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| Publication number | Publication date |
|---|---|
| CN104449168A (en) | 2015-03-25 |
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