CN104448766A - High-performance chlorohydrin rubber material - Google Patents
High-performance chlorohydrin rubber material Download PDFInfo
- Publication number
- CN104448766A CN104448766A CN201410725244.6A CN201410725244A CN104448766A CN 104448766 A CN104448766 A CN 104448766A CN 201410725244 A CN201410725244 A CN 201410725244A CN 104448766 A CN104448766 A CN 104448766A
- Authority
- CN
- China
- Prior art keywords
- parts
- nano
- chlorohydrin rubber
- environment
- rubber material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an environment-friendly high-performance chlorohydrin rubber material. The material comprises the following raw materials in parts by weight: 30-70 parts of chlorohydrin rubber, 20-40 parts of chloroprene rubber, 4-6 parts of zinc oxide, 3-5 parts of magnesium oxide, 5-12 parts of lead-free vulcanizing agent XL-21S, 3-9 parts of antimonous oxide, 5-10 parts of decabromodiphenylethane, 5-8 parts of zinc borate, 8-12 parts of tricresyl phosphate, 2-5 parts of acetyl tributyl citrate, 3-6 parts of nano-nylon 6, 5-8 parts of nano-montmorillonite, 40-60 parts of fast extruding furnace black N550, 2-3 parts of paraffin, 2-5 parts of anti-aging agent RD and 1-3 parts of anti-aging agent 4010NA. The environment-friendly high-performance chlorohydrin rubber material is safe and environment-friendly, does not pollute the environment and has excellent heat and aging resistance.
Description
Technical field
The present invention relates to technical field of rubber material, particularly relate to a kind of High-property epichlorohydrin rubber material.
Background technology
Along with the enhancing of people's environmental consciousness, require more and more higher to the safety and environmental protection of used elastomeric material, mostly current domestic normally used chlorohydrin rubber material is to use leaded metal oxide, although use leaded metal oxide can have good crosslinking degree thus obtain good heat aging property, but plumbous quasi-metal oxides is evaporated for a long time in the environment of heat, also can the life security of serious harm people, and, the wear resistance of chlorohydrin rubber material is poor, therefore be badly in need of exploitation one and meet environmental requirement, and it is heat-resisting, wear-resisting elastomeric material is just very important.
Summary of the invention
The present invention proposes a kind of High-property epichlorohydrin rubber material, safety and environmental protection, wear-resisting, heat-resisting, ageing-resistant performance is excellent.
A kind of High-property epichlorohydrin rubber material that the present invention proposes, its raw material comprises by weight:
Chlorohydrin rubber 50-60 part,
Paracril 30-40 part,
3-aminopropyl trimethoxysilane 1-4 part,
Zinic stearas 2-3 part,
Magnesium oxide 1-2 part,
Linking agent TAC 2-4 part,
Zinc borate 2-5 part,
Tritolyl Phosphate 5-10 part,
Tributyl acetylcitrate 3-6 part,
Nano-nylon 6 4-8 part,
Nano imvite 10-15 part,
Fast extrusion carbon black N660 30-40 part,
Nanoclay 30-40 part,
Paraffin 1-3 part,
Antioxidant NBC 1-2 part,
Antioxidant 4010NA 2-4 part.
Preferably, in above-mentioned High-property epichlorohydrin rubber material, the weight ratio of chlorohydrin rubber, paracril is 50-55:35-40.
Preferably, in above-mentioned High-property epichlorohydrin rubber material, the weight ratio 2-4:6-8 of zinc borate, Tritolyl Phosphate.
Preferably, in above-mentioned High-property epichlorohydrin rubber material, the weight ratio of Tritolyl Phosphate, tributyl acetylcitrate is 6-8:4-6.
Preferably, in above-mentioned High-property epichlorohydrin rubber material, the weight ratio of nano-nylon, nano imvite is 6-8:10-12.
Preferably, High-property epichlorohydrin rubber material described above, its raw material comprises by weight:
Chlorohydrin rubber 50-55 part,
Paracril 35-40 part,
3-aminopropyl trimethoxysilane 1-4 part,
Zinic stearas 2-3 part,
Magnesium oxide 1-1.5 part,
Linking agent TAC 2-3 part,
Zinc borate 2-4 part,
Tritolyl Phosphate 6-8 part,
Tributyl acetylcitrate 4-6 part,
Nano-nylon 6 6-8 part,
Nano imvite 10-12 part,
Fast extrusion carbon black N660 35-38 part,
Nanoclay 36-38 part,
Paraffin 1-2 part,
Antioxidant NBC 1.4-1.8 part,
Antioxidant 4010NA 2-3 part.
Preferably, High-property epichlorohydrin rubber material described above, its raw material comprises by weight:
Chlorohydrin rubber 52 parts,
Paracril 38 parts,
3-aminopropyl trimethoxysilane 2 parts,
Zinic stearas 2.5 parts,
1.2 parts, magnesium oxide,
Linking agent TAC 2.6 parts,
Zinc borate 3 parts,
Tritolyl Phosphate 7 parts,
Tributyl acetylcitrate 5 parts,
Nano-nylon 67 parts,
Nano imvite 11 parts,
Fast extrusion carbon black N660 36 parts,
Nanoclay 37 parts,
1.5 parts, paraffin,
Antioxidant NBC 1.6 parts,
Antioxidant 4010NA 2.4 parts.
High-property epichlorohydrin rubber material of the present invention can play flame retardant effect, there is environment protecting simultaneously, meet many-sided environmental requirement, it adopts chlorohydrin rubber and paracril to be major ingredient, linking agent TAC is adopted to be cross-linked, and add Tritolyl Phosphate, zinc borate, nano-nylon 6, nano imvite is as fire retardant, Tritolyl Phosphate wherein and tributyl acetylcitrate have plasticization effect, finally make the heat-resisting of product, ageing-resistant, wear resisting property is excellent, and permanent compression set is little, asepsis environment-protecting, nano-nylon 6 and nano imvite acting in conjunction, heat-resisting effect is good, excellent in mechanical performance, permanent compression set is little, nano-nylon 6 and nano imvite and chlorohydrin rubber, paracril has very strong avidity, and with 3-aminopropyl trimethoxysilane, fast extrusion carbon black N660, nanoclay one works, product wear-resisting, heat-resisting, ageing-resistant performance can strengthen further, and safety and environmental protection.
Embodiment
Embodiment 1
A kind of High-property epichlorohydrin rubber material, its raw material comprises by weight:
Chlorohydrin rubber 50 parts,
Paracril 40 parts,
3-aminopropyl trimethoxysilane 1 part,
Zinic stearas 3 parts,
1 part, magnesium oxide,
Linking agent TAC 4 parts,
Zinc borate 2 parts,
Tritolyl Phosphate 10 parts,
Tributyl acetylcitrate 3 parts,
Nano-nylon 68 parts,
Nano imvite 10 parts,
Fast extrusion carbon black N660 40 parts,
Nanoclay 30 parts,
3 parts, paraffin,
Antioxidant NBC 1 part,
Antioxidant 4010NA 4 parts.
Embodiment 2
A kind of High-property epichlorohydrin rubber material, its raw material comprises by weight:
Chlorohydrin rubber 60 parts,
Paracril 30 parts,
3-aminopropyl trimethoxysilane 4 parts,
Zinic stearas 2 parts,
2 parts, magnesium oxide,
Linking agent TAC 2 parts,
Zinc borate 5 parts,
Tritolyl Phosphate 5 parts,
Tributyl acetylcitrate 6 parts,
Nano-nylon 64 parts,
Nano imvite 15 parts,
Fast extrusion carbon black N660 30 parts,
Nanoclay 40 parts,
1 part, paraffin,
Antioxidant NBC 2 parts,
Antioxidant 4010NA 2 parts.
Embodiment 3
A kind of High-property epichlorohydrin rubber material, its raw material comprises by weight:
Chlorohydrin rubber 50 parts,
Paracril 40 parts,
3-aminopropyl trimethoxysilane 1 part,
Zinic stearas 3 parts,
1 part, magnesium oxide,
Linking agent TAC 3 parts,
Zinc borate 2 parts,
Tritolyl Phosphate 8 parts,
Tributyl acetylcitrate 4 parts,
Nano-nylon 68 parts,
Nano imvite 10 parts,
Fast extrusion carbon black N660 38 parts,
Nanoclay 36 parts,
2 parts, paraffin,
Antioxidant NBC 1.4 parts,
Antioxidant 4010NA 3 parts.
Embodiment 4
A kind of High-property epichlorohydrin rubber material, its raw material comprises by weight:
Chlorohydrin rubber 55 parts,
Paracril 35 parts,
3-aminopropyl trimethoxysilane 4 parts,
Zinic stearas 2 parts,
1.5 parts, magnesium oxide,
Linking agent TAC 2 parts,
Zinc borate 4 parts,
Tritolyl Phosphate 6 parts,
Tributyl acetylcitrate 6 parts,
Nano-nylon 66 parts,
Nano imvite 12 parts,
Fast extrusion carbon black N660 35 parts,
Nanoclay 38 parts,
1 part, paraffin,
Antioxidant NBC 1.8 parts,
Antioxidant 4010NA 2 parts.
Embodiment 5
A kind of High-property epichlorohydrin rubber material, its raw material comprises by weight:
Chlorohydrin rubber 52 parts,
Paracril 38 parts,
3-aminopropyl trimethoxysilane 2 parts,
Zinic stearas 2.5 parts,
1.2 parts, magnesium oxide,
Linking agent TAC 2.6 parts,
Zinc borate 3 parts,
Tritolyl Phosphate 7 parts,
Tributyl acetylcitrate 5 parts,
Nano-nylon 67 parts,
Nano imvite 11 parts,
Fast extrusion carbon black N660 36 parts,
Nanoclay 37 parts,
1.5 parts, paraffin,
Antioxidant NBC 1.6 parts,
Antioxidant 4010NA 2.4 parts.
Carry out performance test to the High-property epichlorohydrin rubber material described in embodiment 1-5, test result is as follows:
Note: contrast test is the formula contained hazardous substance.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (7)
1. an environment-friendly and high-performance chlorohydrin rubber material, is characterized in that, its raw material comprises by weight:
Chlorohydrin rubber 30-70 part,
Chloroprene rubber 20-40 part,
Zinc oxide 4-6 part,
Magnesium oxide 3-5 part,
Unleaded vulcanizing agent XL-21S 5-12 part,
Antimonous oxide 3-9 part,
TDE 5-10 part,
Zinc borate 5-8 part,
Tritolyl Phosphate 8-12 part,
Tributyl acetylcitrate 2-5 part,
Nano-nylon 6 3-6 part,
Nano imvite 5-8 part,
Fast extrusion carbon black N550 40-60 part,
Paraffin 2-3 part,
Anti-aging agent RD 2-5 part,
Antioxidant 4010NA 1-3 part.
2. environment-friendly and high-performance chlorohydrin rubber material according to claim 1, is characterized in that, the weight ratio of chlorohydrin rubber, chloroprene rubber is 50-60:25-35.
3. environment-friendly and high-performance chlorohydrin rubber material according to claim 1, is characterized in that, the weight ratio 6-8:8-10:6-8:10-12 of antimonous oxide, TDE, zinc borate, Tritolyl Phosphate.
4. environment-friendly and high-performance chlorohydrin rubber material according to claim 1, is characterized in that, the weight ratio of Tritolyl Phosphate, tributyl acetylcitrate is 10-12:2-4.
5. environment-friendly and high-performance chlorohydrin rubber material according to claim 1, is characterized in that, the weight ratio of nano-nylon, nano imvite is 3-4:6-8.
6. the environment-friendly and high-performance chlorohydrin rubber material according to any one of claim 1-5, it is characterized in that, its raw material comprises by weight:
Chlorohydrin rubber 50-60 part,
Chloroprene rubber 25-35 part,
Zinc oxide 4-5 part,
Magnesium oxide 3-4 part,
Unleaded vulcanizing agent XL-21S 6-7 part,
Antimonous oxide 6-8 part,
TDE 8-10 part,
Zinc borate 6-8 part,
Tritolyl Phosphate 10-12 part,
Tributyl acetylcitrate 2-4 part,
Nano-nylon 6 3-4 part,
Nano imvite 6-8 part,
Fast extrusion carbon black N550 50-55 part,
Paraffin 2-3 part,
Anti-aging agent RD 2-4 part,
Antioxidant 4010NA 1-2 part.
7. environment-friendly and high-performance chlorohydrin rubber material according to claim 6, it is characterized in that, its raw material comprises by weight:
Chlorohydrin rubber 56 parts,
Chloroprene rubber 32 parts,
4 parts, zinc oxide,
3.6 parts, magnesium oxide,
Unleaded vulcanizing agent XL-21S 6 parts,
Antimonous oxide 7 parts,
TDE 9 parts,
Zinc borate 7 parts,
Tritolyl Phosphate 11 parts,
Tributyl acetylcitrate 3 parts,
Nano-nylon 63 parts,
Nano imvite 7 parts,
Fast extrusion carbon black N550 52 parts,
3 parts, paraffin,
Anti-aging agent RD 3 parts,
Antioxidant 4010NA 2 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410725244.6A CN104448766A (en) | 2014-12-04 | 2014-12-04 | High-performance chlorohydrin rubber material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410725244.6A CN104448766A (en) | 2014-12-04 | 2014-12-04 | High-performance chlorohydrin rubber material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104448766A true CN104448766A (en) | 2015-03-25 |
Family
ID=52895554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410725244.6A Pending CN104448766A (en) | 2014-12-04 | 2014-12-04 | High-performance chlorohydrin rubber material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104448766A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448769A (en) * | 2014-12-04 | 2015-03-25 | 侨健新能源科技（苏州）有限公司 | Environment-friendly high-performance chlorohydrin rubber material |
| CN109400993A (en) * | 2018-09-28 | 2019-03-01 | 芜湖集拓橡胶技术有限公司 | A kind of flame-retardant chloroprene rubber |
-
2014
- 2014-12-04 CN CN201410725244.6A patent/CN104448766A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448769A (en) * | 2014-12-04 | 2015-03-25 | 侨健新能源科技（苏州）有限公司 | Environment-friendly high-performance chlorohydrin rubber material |
| CN109400993A (en) * | 2018-09-28 | 2019-03-01 | 芜湖集拓橡胶技术有限公司 | A kind of flame-retardant chloroprene rubber |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104558714B (en) | A kind of flame-retardant thermoplastic elastomer of cold resisting type and preparation method thereof | |
| CN104448769A (en) | Environment-friendly high-performance chlorohydrin rubber material | |
| CN104558965B (en) | A kind of thermoplastic elastomer (TPE) of flame-retardant and anti-static and preparation method thereof | |
| CN102964696B (en) | A kind of ethylene propylene diene rubber fire-resistant cable material and preparation method thereof | |
| CN103804808B (en) | One is high-strength presses down cigarette Pyrotenax sheath material | |
| CN102875932A (en) | PVC (polyvinyl chloride) power pipeline material and preparation method thereof | |
| CN102757651A (en) | Silicone rubber insulating fluororubber cable material and preparation method thereof | |
| CN102746549A (en) | Polyethylene insulation power cable material for coal and method for preparing the same | |
| CN103073802B (en) | A kind of chlorosulfonated polyethylene rubber/chlorohydrin rubber gasket and preparation method thereof | |
| CN104403300A (en) | Environment-friendly heat-resistant aging-resistant rubber material | |
| CN104448766A (en) | High-performance chlorohydrin rubber material | |
| CN104448435A (en) | 120-DEG C aging-resistant nitrile/polyvinyl chloride rubber composition | |
| CN104311909A (en) | Fire-resistant and flame-retardant tire rubber composite | |
| CN104448770A (en) | Environment-friendly epichlorohydrin rubber material resistant to wear, heat and ageing | |
| CN106700277A (en) | Low-smoke and low-toxicity halogen-free flame retardant ethylene propylene diene methylene (EPDM) vibration isolating rubber material | |
| CN101759940A (en) | Formulation of environment-friendly chlorosulfonated polyethylene rubber | |
| CN102746564A (en) | Modified electric cable material with characteristics of high temperature resistance and corrosion resistance, and preparation method thereof | |
| CN103044768B (en) | Polypropylene pipe for underground coal mine | |
| CN101955601B (en) | Chloroprene rubber improved by employing ionomer | |
| CN103724792A (en) | Low-smoke zero-halogen environment-friendly EVA/LLDPE flame resistant composite material | |
| CN102977483A (en) | Chlorosulfonated polyethylene rubber/EPDM rubber gasket and preparation method thereof | |
| CN105754161A (en) | High-strength, wear-resisting and fire-resisting cable | |
| CN102977612B (en) | A kind of acrylate flame-proof environmental protection rubber cable material and preparation method thereof | |
| CN102719079B (en) | Environment-friendly flame-retardant type epichlorohydrin-rubber pipe formula | |
| CN103289416A (en) | Environment-friendly flame-retardant silicone rubber and butadiene rubber blending material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150325 |
|
| RJ01 | Rejection of invention patent application after publication |