CN104448415B - Ventilation property medical gloves matrix material and preparation method thereof - Google Patents
Ventilation property medical gloves matrix material and preparation method thereof Download PDFInfo
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- CN104448415B CN104448415B CN201410697050.XA CN201410697050A CN104448415B CN 104448415 B CN104448415 B CN 104448415B CN 201410697050 A CN201410697050 A CN 201410697050A CN 104448415 B CN104448415 B CN 104448415B
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- 239000011159 matrix material Substances 0.000 title claims abstract description 53
- 238000009423 ventilation Methods 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 62
- 229920001971 elastomer Polymers 0.000 claims abstract description 38
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims abstract description 33
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 33
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 33
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 33
- VIMXTGUGWLAOFZ-UHFFFAOYSA-N ethyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CCOC(=O)C1C(C=C(C)C)C1(C)C VIMXTGUGWLAOFZ-UHFFFAOYSA-N 0.000 claims abstract description 33
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 33
- 229920001194 natural rubber Polymers 0.000 claims abstract description 33
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 33
- 229920001897 terpolymer Polymers 0.000 claims abstract description 33
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 claims abstract description 31
- 241000276489 Merlangius merlangus Species 0.000 claims abstract description 29
- 238000002156 mixing Methods 0.000 claims description 10
- 238000005453 pelletization Methods 0.000 claims description 10
- 238000010792 warming Methods 0.000 claims description 10
- 230000032683 aging Effects 0.000 abstract description 5
- 239000002131 composite material Substances 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 210000004243 sweat Anatomy 0.000 abstract description 2
- 208000025865 Ulcer Diseases 0.000 description 3
- 230000036269 ulceration Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 208000004210 Pressure Ulcer Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Gloves (AREA)
Abstract
The present invention relates to a kind of ventilation property medical gloves matrix material and preparation method thereof, belong to medical composite material field.This ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 15-25 part, maleic anhydride graft terpolymer EP rubber 5-10 part, oyster shell whiting 10-15 part, nano-calcium carbonate 8-16 part, coconut monoethanolamide 5-12 part, ethyl chrysanthemate 2-7 part, γ-methacryloxypropyl trimethoxy silane 2-6 part, polycarbodiimide 0.5-3 part, polyvinyl alcohol 4-8 part.Matrix material of the present invention has good elasticity and ageing resistance, and effectively can absorb sweat, keeps gloves inner drying to clean; Matrix material of the present invention also has good ventilation property; Preparation method of the present invention is simple, is suitable for applying on a large scale.
Description
Technical field
The invention belongs to medical composite material technical field, be specifically related to a kind of ventilation property medical gloves matrix material and preparation method thereof.
Background technology
Rubber gloves, is the class gloves made with rubber sheet or film, can be divided into acid and alkali-resistance gloves, electrical isolation gloves, radiation-resistant gloves and medical gloves by purposes; Latex glove and mold pressing gloves can be divided into by rubber raw materials or manufacturing process.
Medical gloves is using the most extensive in internal medicine clinical nursing activity, and the general state of an illness is heavier, the patient of health many places ulceration, is generally to use air-fluidized bed, air ring etc. to prevent patient's ulceration place to fester generation bedsore after being admitted to hospital.And air ring can only be fixed on certain point in Clinical practice, and it to bear pressure also limited, and use according to being padded on ulceration place after disposable rubber gloves water filling, clinical effectiveness can be better.Disposable rubber gloves is after injection warm water, and can bear the pressure at four limbs position, along with the Different of patient, in bag, liquid can regulate the laminating degree with skin thereupon, thus makes patient feel suitable, without constriction.
And more talcum powder in general a lot of medical gloves, can be disperseed, wet and slippery sticky with what prevent from causing because gloves are airtight.Therefore the ventilation property of medical gloves just seems particularly important.
In sum, the deficiency solving prior art existence has become this area technical problem urgently to be resolved hurrily.
Summary of the invention
The present invention is in order to solve the deficiencies in the prior art, and provide a kind of ventilation property medical gloves matrix material and preparation method thereof, this matrix material has good ageing resistance and elasticity, and good air permeability.
The technical solution used in the present invention is as follows:
Ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 15-25 part, maleic anhydride graft terpolymer EP rubber 5-10 part, oyster shell whiting 10-15 part, nano-calcium carbonate 8-16 part, coconut monoethanolamide 5-12 part, ethyl chrysanthemate 2-7 part, γ-methacryloxypropyl trimethoxy silane 2-6 part, polycarbodiimide 0.5-3 part, polyvinyl alcohol 4-8 part.
Described ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 17-24 part, maleic anhydride graft terpolymer EP rubber 6-8 part, oyster shell whiting 11-14 part, nano-calcium carbonate 9-15 part, coconut monoethanolamide 6-11 part, ethyl chrysanthemate 3-6 part, γ-methacryloxypropyl trimethoxy silane 3-5 part, polycarbodiimide 1-2.5 part, polyvinyl alcohol 5-7 part.
Described ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 19-22 part, maleic anhydride graft terpolymer EP rubber 6-7 part, oyster shell whiting 12-13 part, nano-calcium carbonate 10-13 part, coconut monoethanolamide 7-10 part, ethyl chrysanthemate 4-5 part, γ-methacryloxypropyl trimethoxy silane 3-4 part, polycarbodiimide 1-2 part, polyvinyl alcohol 5-6 part.
Described ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 17 parts, maleic anhydride graft terpolymer EP rubber 6 parts, oyster shell whiting 11 parts, nano-calcium carbonate 9 parts, coconut monoethanolamide 6 parts, ethyl chrysanthemate 3 parts, γ-methacryloxypropyl trimethoxy silane 3 parts, polycarbodiimide 1 part, polyvinyl alcohol 5 parts.
Described ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 24 parts, maleic anhydride graft terpolymer EP rubber 8 parts, oyster shell whiting 14 parts, nano-calcium carbonate 15 parts, coconut monoethanolamide 11 parts, ethyl chrysanthemate 6 parts, γ-methacryloxypropyl trimethoxy silane 5 parts, polycarbodiimide 2.5 parts, polyvinyl alcohol 7 parts.
Described ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 19 parts, maleic anhydride graft terpolymer EP rubber 6 parts, oyster shell whiting 12 parts, nano-calcium carbonate 10 parts, coconut monoethanolamide 7 parts, ethyl chrysanthemate 4 parts, γ-methacryloxypropyl trimethoxy silane 3 parts, polycarbodiimide 1 part, polyvinyl alcohol 5 parts.
Described ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 22 parts, maleic anhydride graft terpolymer EP rubber 7 parts, oyster shell whiting 13 parts, nano-calcium carbonate 13 parts, coconut monoethanolamide 10 parts, ethyl chrysanthemate 5 parts, γ-methacryloxypropyl trimethoxy silane 4 parts, polycarbodiimide 2 parts, polyvinyl alcohol 6 parts.
The preparation method of described ventilation property medical gloves matrix material, comprise the steps: according to weight proportion, by the mixing of natural rubber, maleic anhydride graft terpolymer EP rubber, γ-methacryloxypropyl trimethoxy silane and polyvinyl alcohol evenly, successively coconut monoethanolamide, ethyl chrysanthemate and polycarbodiimide are being added wherein, be warming up to 140-148 DEG C, again oyster shell whiting, nano-calcium carbonate are added wherein, after at 165-170 DEG C extruding pelletization, obtain described ventilation property medical gloves matrix material.
compared with prior art, its beneficial effect is in the present invention:the first, matrix material of the present invention has good elasticity and ageing resistance, and effectively can absorb sweat, keeps gloves inner drying to clean; The second, matrix material of the present invention also has good ventilation property; 3rd, preparation method of the present invention is simple, is suitable for applying on a large scale.
Embodiment
Below in conjunction with embodiment, set forth the present invention further.
embodiment 1
Ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 15 parts, maleic anhydride graft terpolymer EP rubber 5 parts, oyster shell whiting 10 parts, nano-calcium carbonate 8-16 part, coconut monoethanolamide 5 parts, ethyl chrysanthemate 2 parts, γ-methacryloxypropyl trimethoxy silane 2 parts, polycarbodiimide 0.5 part, polyvinyl alcohol 4 parts.
The preparation method of described ventilation property medical gloves matrix material, comprise the steps: according to weight proportion, by the mixing of natural rubber, maleic anhydride graft terpolymer EP rubber, γ-methacryloxypropyl trimethoxy silane and polyvinyl alcohol evenly, successively coconut monoethanolamide, ethyl chrysanthemate and polycarbodiimide are being added wherein, be warming up to 140 DEG C, again oyster shell whiting, nano-calcium carbonate are added wherein, after at 165 DEG C extruding pelletization, obtain described ventilation property medical gloves matrix material.
embodiment 2
Ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 15-25 part, maleic anhydride graft terpolymer EP rubber 10 parts, oyster shell whiting 15 parts, nano-calcium carbonate 16 parts, coconut monoethanolamide 12 parts, ethyl chrysanthemate 7 parts, γ-methacryloxypropyl trimethoxy silane 6 parts, polycarbodiimide 3 parts, polyvinyl alcohol 8 parts.
The preparation method of described ventilation property medical gloves matrix material, comprise the steps: according to weight proportion, by the mixing of natural rubber, maleic anhydride graft terpolymer EP rubber, γ-methacryloxypropyl trimethoxy silane and polyvinyl alcohol evenly, successively coconut monoethanolamide, ethyl chrysanthemate and polycarbodiimide are being added wherein, be warming up to 148 DEG C, again oyster shell whiting, nano-calcium carbonate are added wherein, after at 170 DEG C extruding pelletization, obtain described ventilation property medical gloves matrix material.
embodiment 3
Ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 17 parts, maleic anhydride graft terpolymer EP rubber 6 parts, oyster shell whiting 11 parts, nano-calcium carbonate 9 parts, coconut monoethanolamide 6 parts, ethyl chrysanthemate 3 parts, γ-methacryloxypropyl trimethoxy silane 3 parts, polycarbodiimide 1 part, polyvinyl alcohol 5 parts.
The preparation method of described ventilation property medical gloves matrix material, comprise the steps: according to weight proportion, by the mixing of natural rubber, maleic anhydride graft terpolymer EP rubber, γ-methacryloxypropyl trimethoxy silane and polyvinyl alcohol evenly, successively coconut monoethanolamide, ethyl chrysanthemate and polycarbodiimide are being added wherein, be warming up to 142 DEG C, again oyster shell whiting, nano-calcium carbonate are added wherein, after at 166 DEG C extruding pelletization, obtain described ventilation property medical gloves matrix material.
embodiment 4
Ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 24 parts, maleic anhydride graft terpolymer EP rubber 8 parts, oyster shell whiting 14 parts, nano-calcium carbonate 15 parts, coconut monoethanolamide 11 parts, ethyl chrysanthemate 6 parts, γ-methacryloxypropyl trimethoxy silane 5 parts, polycarbodiimide 2.5 parts, polyvinyl alcohol 7 parts.
The preparation method of described ventilation property medical gloves matrix material, comprise the steps: according to weight proportion, by the mixing of natural rubber, maleic anhydride graft terpolymer EP rubber, γ-methacryloxypropyl trimethoxy silane and polyvinyl alcohol evenly, successively coconut monoethanolamide, ethyl chrysanthemate and polycarbodiimide are being added wherein, be warming up to 144 DEG C, again oyster shell whiting, nano-calcium carbonate are added wherein, after at 167 DEG C extruding pelletization, obtain described ventilation property medical gloves matrix material.
embodiment 5
Ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 19 parts, maleic anhydride graft terpolymer EP rubber 6 parts, oyster shell whiting 12 parts, nano-calcium carbonate 10 parts, coconut monoethanolamide 7 parts, ethyl chrysanthemate 4 parts, γ-methacryloxypropyl trimethoxy silane 3 parts, polycarbodiimide 1 part, polyvinyl alcohol 5 parts.
The preparation method of described ventilation property medical gloves matrix material, comprise the steps: according to weight proportion, by the mixing of natural rubber, maleic anhydride graft terpolymer EP rubber, γ-methacryloxypropyl trimethoxy silane and polyvinyl alcohol evenly, successively coconut monoethanolamide, ethyl chrysanthemate and polycarbodiimide are being added wherein, be warming up to 146 DEG C, again oyster shell whiting, nano-calcium carbonate are added wherein, after at 168 DEG C extruding pelletization, obtain described ventilation property medical gloves matrix material.
embodiment 6
Ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 22 parts, maleic anhydride graft terpolymer EP rubber 7 parts, oyster shell whiting 13 parts, nano-calcium carbonate 13 parts, coconut monoethanolamide 10 parts, ethyl chrysanthemate 5 parts, γ-methacryloxypropyl trimethoxy silane 4 parts, polycarbodiimide 2 parts, polyvinyl alcohol 6 parts.
The preparation method of described ventilation property medical gloves matrix material, comprise the steps: according to weight proportion, by the mixing of natural rubber, maleic anhydride graft terpolymer EP rubber, γ-methacryloxypropyl trimethoxy silane and polyvinyl alcohol evenly, successively coconut monoethanolamide, ethyl chrysanthemate and polycarbodiimide are being added wherein, be warming up to 147 DEG C, again oyster shell whiting, nano-calcium carbonate are added wherein, after at 169 DEG C extruding pelletization, obtain described ventilation property medical gloves matrix material.
reference examples 1
Ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 17 parts, maleic anhydride graft terpolymer EP rubber 6 parts, nano-calcium carbonate 9 parts, coconut monoethanolamide 6 parts, ethyl chrysanthemate 3 parts, γ-methacryloxypropyl trimethoxy silane 3 parts, polycarbodiimide 1 part, polyvinyl alcohol 5 parts.
The preparation method of described ventilation property medical gloves matrix material, comprise the steps: according to weight proportion, by the mixing of natural rubber, maleic anhydride graft terpolymer EP rubber, γ-methacryloxypropyl trimethoxy silane and polyvinyl alcohol evenly, successively coconut monoethanolamide, ethyl chrysanthemate and polycarbodiimide are being added wherein, be warming up to 142 DEG C, again nano-calcium carbonate is added wherein, after at 166 DEG C extruding pelletization, obtain described ventilation property medical gloves matrix material.
reference examples 2
Ventilation property medical gloves matrix material, comprises the following component according to weight parts: natural rubber 17 parts, maleic anhydride graft terpolymer EP rubber 6 parts, nano-calcium carbonate 9 parts, ethyl chrysanthemate 3 parts, γ-methacryloxypropyl trimethoxy silane 3 parts, polycarbodiimide 1 part, polyvinyl alcohol 5 parts.
The preparation method of described ventilation property medical gloves matrix material, comprise the steps: according to weight proportion, by the mixing of natural rubber, maleic anhydride graft terpolymer EP rubber, γ-methacryloxypropyl trimethoxy silane and polyvinyl alcohol evenly, successively ethyl chrysanthemate and polycarbodiimide are being added wherein, be warming up to 142 DEG C, again nano-calcium carbonate is added wherein, after at 166 DEG C extruding pelletization, obtain described ventilation property medical gloves matrix material.
performance Detection:
The embodiment of the present invention 1 to 6 gained finished product, reference examples 1 to 2 gained finished product are carried out performance test, and result is as follows:
Table 1 performance test data
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Reference examples 1 | Reference examples 2 | |
| Heat resisting temperature, DEG C | 170 | 172 | 175 | 179 | 170 | 172 | 50 | 68 |
| Water vapor transmittance, % | 90 | 92 | 94 | 91 | 94 | 93 | 56 | 67 |
| Ageing resistance, xenon lamp aging, 3000h | Unchanged | Unchanged | Unchanged | Unchanged | Unchanged | Unchanged | Turn yellow and have crackle | Turn yellow and have crackle |
As can be seen from the table, the present invention has excellent performance, and wherein the performance of embodiment 3 is best.In addition gained finished product safety and environmental protection of the present invention, to human body and environmental friendliness.
Claims (8)
1. ventilation property medical gloves matrix material, it is characterized in that, comprise the following component according to weight parts: natural rubber 15-25 part, maleic anhydride graft terpolymer EP rubber 5-10 part, oyster shell whiting 10-15 part, nano-calcium carbonate 8-16 part, coconut monoethanolamide 5-12 part, ethyl chrysanthemate 2-7 part, γ-methacryloxypropyl trimethoxy silane 2-6 part, polycarbodiimide 0.5-3 part, polyvinyl alcohol 4-8 part.
2. ventilation property medical gloves matrix material according to claim 1, it is characterized in that, comprise the following component according to weight parts: natural rubber 17-24 part, maleic anhydride graft terpolymer EP rubber 6-8 part, oyster shell whiting 11-14 part, nano-calcium carbonate 9-15 part, coconut monoethanolamide 6-11 part, ethyl chrysanthemate 3-6 part, γ-methacryloxypropyl trimethoxy silane 3-5 part, polycarbodiimide 1-2.5 part, polyvinyl alcohol 5-7 part.
3. ventilation property medical gloves matrix material according to claim 1, it is characterized in that, comprise the following component according to weight parts: natural rubber 19-22 part, maleic anhydride graft terpolymer EP rubber 6-7 part, oyster shell whiting 12-13 part, nano-calcium carbonate 10-13 part, coconut monoethanolamide 7-10 part, ethyl chrysanthemate 4-5 part, γ-methacryloxypropyl trimethoxy silane 3-4 part, polycarbodiimide 1-2 part, polyvinyl alcohol 5-6 part.
4. ventilation property medical gloves matrix material according to claim 1, it is characterized in that, comprise the following component according to weight parts: natural rubber 17 parts, maleic anhydride graft terpolymer EP rubber 6 parts, oyster shell whiting 11 parts, nano-calcium carbonate 9 parts, coconut monoethanolamide 6 parts, ethyl chrysanthemate 3 parts, γ-methacryloxypropyl trimethoxy silane 3 parts, polycarbodiimide 1 part, polyvinyl alcohol 5 parts.
5. ventilation property medical gloves matrix material according to claim 1, it is characterized in that, comprise the following component according to weight parts: natural rubber 24 parts, maleic anhydride graft terpolymer EP rubber 8 parts, oyster shell whiting 14 parts, nano-calcium carbonate 15 parts, coconut monoethanolamide 11 parts, ethyl chrysanthemate 6 parts, γ-methacryloxypropyl trimethoxy silane 5 parts, polycarbodiimide 2.5 parts, polyvinyl alcohol 7 parts.
6. ventilation property medical gloves matrix material according to claim 1, it is characterized in that, comprise the following component according to weight parts: natural rubber 19 parts, maleic anhydride graft terpolymer EP rubber 6 parts, oyster shell whiting 12 parts, nano-calcium carbonate 10 parts, coconut monoethanolamide 7 parts, ethyl chrysanthemate 4 parts, γ-methacryloxypropyl trimethoxy silane 3 parts, polycarbodiimide 1 part, polyvinyl alcohol 5 parts.
7. ventilation property medical gloves matrix material according to claim 1, it is characterized in that, comprise the following component according to weight parts: natural rubber 22 parts, maleic anhydride graft terpolymer EP rubber 7 parts, oyster shell whiting 13 parts, nano-calcium carbonate 13 parts, coconut monoethanolamide 10 parts, ethyl chrysanthemate 5 parts, γ-methacryloxypropyl trimethoxy silane 4 parts, polycarbodiimide 2 parts, polyvinyl alcohol 6 parts.
8. the preparation method of ventilation property medical gloves matrix material according to claim 1, it is characterized in that, comprise the steps: according to weight proportion, by natural rubber, maleic anhydride graft terpolymer EP rubber, γ-methacryloxypropyl trimethoxy silane and polyvinyl alcohol mixing are evenly, successively by coconut monoethanolamide, ethyl chrysanthemate and polycarbodiimide add wherein, be warming up to 140-148 DEG C, again by oyster shell whiting, nano-calcium carbonate adds wherein, after at 165-170 DEG C extruding pelletization, obtain described ventilation property medical gloves matrix material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410697050.XA CN104448415B (en) | 2014-11-27 | 2014-11-27 | Ventilation property medical gloves matrix material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410697050.XA CN104448415B (en) | 2014-11-27 | 2014-11-27 | Ventilation property medical gloves matrix material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN104448415A CN104448415A (en) | 2015-03-25 |
| CN104448415B true CN104448415B (en) | 2016-04-27 |
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| CN201410697050.XA Expired - Fee Related CN104448415B (en) | 2014-11-27 | 2014-11-27 | Ventilation property medical gloves matrix material and preparation method thereof |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107471755A (en) * | 2017-08-21 | 2017-12-15 | 苏州井村服饰有限公司 | A kind of ventilative work clothes fabric of wear-resisting comfortable |
| CN107521165A (en) * | 2017-08-21 | 2017-12-29 | 苏州井村服饰有限公司 | A kind of lightweight antibacterial breathable fabric |
| CN107521190A (en) * | 2017-08-21 | 2017-12-29 | 苏州井村服饰有限公司 | A kind of high-strength light anti-static ventilation plus material |
| CN107351467A (en) * | 2017-08-21 | 2017-11-17 | 苏州井村服饰有限公司 | A kind of lightweight comfort air-permeable anti-bacterial fabric |
| CN107379704A (en) * | 2017-08-21 | 2017-11-24 | 苏州井村服饰有限公司 | A kind of lightweight breathable wear-resistant fabric |
| CN107336479A (en) * | 2017-08-21 | 2017-11-10 | 苏州井村服饰有限公司 | A kind of antibacterial breathable fabric |
| CN107373810A (en) * | 2017-08-21 | 2017-11-24 | 苏州井村服饰有限公司 | A kind of ventilation wear-resistance type raincoat special fabric of pants |
| CN107512048A (en) * | 2017-08-21 | 2017-12-26 | 苏州井村服饰有限公司 | A kind of anti-static ventilation plus material |
| CN107400265A (en) * | 2017-08-25 | 2017-11-28 | 江苏菲勒电气有限公司 | A kind of insulating glove elastomeric material |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| ATE178912T1 (en) * | 1993-08-05 | 1999-04-15 | Ansell Perry Inc | PRODUCTION OF RUBBER ARTICLES |
| AU2004319695B2 (en) * | 2004-04-16 | 2010-01-28 | Ansell Healthcare Products Llc | On-line making of powder-free rubber gloves |
| CN101456961B (en) * | 2009-01-07 | 2011-01-19 | 中国热带农业科学院农产品加工研究所 | Method for preparing reactive nano calcium carbonate-native rubber composite material |
| CN102838788B (en) * | 2012-09-26 | 2015-06-24 | 中国热带农业科学院农产品加工研究所 | Shell powder-natural rubber composite material and preparation method thereof |
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