CN104446277A - Electro-ceramic cement adhesive composite material prescription - Google Patents
Electro-ceramic cement adhesive composite material prescription Download PDFInfo
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- CN104446277A CN104446277A CN201410767234.9A CN201410767234A CN104446277A CN 104446277 A CN104446277 A CN 104446277A CN 201410767234 A CN201410767234 A CN 201410767234A CN 104446277 A CN104446277 A CN 104446277A
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Abstract
The invention relates to a material for production of an electro-ceramic insulator, and particularly relates to an electro-ceramic cement adhesive composite material prescription. The electro-ceramic cement adhesive composite material prescription comprises the following mixed components in parts by mass: 100 parts of sulphate aluminium cement, 45-55 parts of cemented quartz sand, 27 parts of water, 0.4-0.5 part of an additive, 2-3 parts of silica powder and 0.08-0.11 part of glass fiber, wherein the fineness of the sulphate aluminium cement particles is smaller than or equal to 0.09mm; more than 80% of the cemented quartz sand is particles of which the particle size is 0.3mm to 1mm; the pH value of the water is 7.0 to 7.2; the water temperature is lower than 35 DEG C. By adopting the electro-ceramic cement adhesive composite material prescription disclosed by the invention, the early strength of an electro-ceramic cement adhesive can be greatly enhanced.
Description
Technical field
The present invention relates to a kind of electric porcelain insulator and produce materials, be specifically related to a kind of electroceramics cement glue composite material type formula.
Background technology
Along with the development of China's power construction, ultra-high voltage, large span, long distance power transmission obtain universal rapidly, and the electrotechnical porcelain product played an important role in project of transmitting and converting electricity is widely used.Electroceramics cement glue is the important component part of electrotechnical porcelain product, be mainly used in the electric porcelain insulator such as suspension type, line pole type, it plays forms holistic effect by porcelain piece and metal-ware, run because electric porcelain insulator hangs on high-tension bus-bar, electric porcelain insulator go wrong then whole circuit by power-off, huge numbers of families are by instantaneous power failure, very large on the life impact of people.In prior art, electrotechnical porcelain product also exists following problem in mucilage binding: after product mucilage binding, cementing agent early strength is less, has had a strong impact on production efficiency; In addition in order to ensure the intensity of mucilage binding, in traditional cement glue, the consumption of cement is very large, causes cement glue cost higher.
Summary of the invention
The technical problem to be solved in the present invention is to provide one can improve cementing agent early strength.
To achieve these goals, the invention provides a kind of electroceramics cement glue composite material type formula, mixed by the component of following mass parts and form: aluminosulfate cement: 100, mucilage binding quartz sand: 45 ~ 55, water: 27, admixture: 0.4 ~ 0.5, silicon powder: 2 ~ 3, glass fibre: 0.08 ~ 0.11;
Wherein, the fineness≤0.09mm of aluminosulfate cement 100% particle; The particle of mucilage binding quartz sand 0.3 ~ 1mm is greater than 80%; The pH value of water is 7.0 ~ 7.2, water temperature < 35 DEG C.
Wherein, mucilage binding quartz sand is a kind of quartz sand raw material through processing, and its chemical composition is Fe
2o
3be 0.4%, SiO
2be 95.8%, wherein mechanical iron level about 0.015%.
Nearly 30 batches of formula Physicochemical test have successively been carried out in application, and test method is undertaken by Xian Electrical Ceramics Research Institute " the electroceramics inspection of raw and process materials and technology controlling and process test method ".By Integrated comparative, have selected the electroceramics cement glue formula that cost performance is relatively best.Proportioning and the physicochemical property of formula are as follows:
(1) electroceramics cement glue composite material type formulation ratio:
Aluminosulfate cement | Mucilage binding quartz sand | Water | Admixture | Silicon powder | Glass fibre |
100 | 50 | 27 | 0.4 | 2.6 | 0.09 |
(2) electroceramics cement glue composite material type formula moulding process:
Test pilot scale cement mixer and cement mortar shaking platform carry out.
(3) test block of electroceramics cement glue in the early strength performance of maintenance after seven days as following table:
Test event | Test result | Tradition performance |
Folding strength | 17.44MPa | 12.32MPa |
Ultimate compression strength | 105.21MPa | 59.42MPa |
Can be drawn by upper table adopts the electroceramics cement glue composite material type of technique scheme formula tool to have the following advantages: 1) electroceramics cement glue early strength exceeds very many compared to traditional cementing agent; 2) interpolation of silicon powder and glass fibre, improves the resistance to compression of electroceramics cement glue, cracking resistance, freeze proof, anticorrosion and physical strength etc. aspect performance.
Embodiment
Embodiment
The invention provides a kind of electroceramics cement glue composite material type formula, mixed by the component of following mass parts and form: aluminosulfate cement: 100, mucilage binding quartz sand: 45 ~ 55, water: 27, admixture: 0.4 ~ 0.5, silicon powder: 2 ~ 3, glass fibre: 0.08 ~ 0.11; Preferred proportioning is, aluminosulfate cement: 100, mucilage binding quartz sand: 50, water: 27, admixture: 0.4, silicon powder: 2.6, glass fibre: 0.09.
Wherein, the fineness≤0.09mm of aluminosulfate cement 100% particle;
The particle of mucilage binding quartz sand 0.3 ~ 1mm is greater than 80%;
The pH value of water is 7.0 ~ 7.2, water temperature < 35 DEG C.
Admixture is naphthalene series high-efficiency water-reducing agent, it is the non-research work of air entrained type high efficiency water reducing agent through chemical industry synthesis, chemical name is naphthalenesulfonate formaldehyde condensation compound, originate in Shandong Zibo, outward appearance is yellow powder, the mobility of cement glue can be improved, reduce water consumption, highly beneficial to raising electroceramics cement glue intensity.
Silicon powder originates in Xi'an silicon powder manufactory, has and improves cementing agent resistance to compression, anti-folding, impervious, anticorrosion, shock resistance and wear resisting property.
Glass fibre originates in Tai'an Jia Cheng fiber company limited, selects model to be K6 beta glass fibre silk, glass fibre can make that the electrical insulating property of cement glue is good, thermotolerance is strong, cracking resistance, freeze proof, erosion resistance, good water-retaining property, physical strength is high.
From 26 days April in 2014, start to carry out above-mentioned electroceramics cement glue small serial production trial-production, the product type of trial-production was U70BP/146D, wherein U represents disc insulator, and 70 represent that dynamo-electric load 70KN, BP represent resistant dish type, 146 represent height, and D represents deep bid footpath, and quantity is 60.From product batch test, all can reach standard with these products of above-mentioned electroceramics cement glue formula trial-production, test of products the results are shown in following table:
U70BP/146D batch test is reported
In order to investigate the use properties of cement glue, this batch of trial product is placed in the test carrying out exposing to the sun and rain in roof, workshop by contriver, and timing sampling observation.Selective examination test is carried out on August 2nd, 2014:
U70BP/146D batch test is reported
Known by detecting, expose to the sun and rain through closely trimestral, cementing agent product performance are still up to standard, and without the phenomenon that steel pin loosens.
For other consumption of mucilage binding quartz sand, admixture, silicon powder and glass fibre, those of ordinary skill in the art can adjust in the scope limited in conjunction with material quality, without the need to paying performing creative labour, repeat no more.
Above-described is only certain preferred embodiments of the present invention, it should be pointed out that for a person skilled in the art, and under the prerequisite not departing from instant component proportioning, can also make some improvement, these also should be considered as protection scope of the present invention.
Claims (2)
1. electroceramics cement glue composite material type formula, it is characterized in that: mixed by the component of following mass parts and form: aluminosulfate cement: 100, mucilage binding quartz sand: 45 ~ 55, water: 27, admixture: 0.4 ~ 0.5, silicon powder: 2 ~ 3, glass fibre: 0.08 ~ 0.11;
Wherein, the fineness≤0.09mm of aluminosulfate cement particle;
The particle of mucilage binding quartz sand 0.3 ~ 1mm is greater than 80%;
The pH value of water is 7.0 ~ 7.2, water temperature < 35 DEG C.
2. electroceramics cement glue composite material type formula as claimed in claim 1, it is characterized in that: mixed by the component of following mass parts and form: aluminosulfate cement: 100, mucilage binding quartz sand: 50, water: 27, admixture: 0.4, silicon powder: 2.6, glass fibre: 0.09, described admixture is naphthalenesulfonate formaldehyde condensation compound.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106699063A (en) * | 2016-12-30 | 2017-05-24 | 重庆鸽牌电瓷有限公司 | Special adhesive for electrotechnical porcelain with low cement-sand ratio |
CN109534747A (en) * | 2018-12-19 | 2019-03-29 | 唐山高压电瓷有限公司 | A kind of high strength electroceramice ductility cement glue and preparation method thereof |
CN110877969A (en) * | 2019-12-11 | 2020-03-13 | 芦溪县鸿泰工业瓷厂 | Composite cementing material for high-voltage electric porcelain gluing and preparation method thereof |
CN112374842A (en) * | 2020-12-14 | 2021-02-19 | 南京电气绝缘子有限公司 | High-strength aluminate cement adhesive for insulator |
CN113061004A (en) * | 2021-05-13 | 2021-07-02 | 重庆鸽牌电瓷有限公司 | Electroceramic cement adhesive composite material type formula |
CN115180901A (en) * | 2022-07-26 | 2022-10-14 | 重庆鸽牌电瓷有限公司 | Special adhesive between electric porcelain insulator and metal accessory |
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CA2851757A1 (en) * | 2011-12-15 | 2013-06-20 | Dow Global Technologies Llc | Dry mix formulations containing carboxylated styrene-butadiene redispersible polymer powders and alumina rich containing cements |
CN103342512A (en) * | 2013-07-05 | 2013-10-09 | 三瑞科技(江西)有限公司 | Cement adhesive and preparation method |
CN103496924A (en) * | 2013-09-18 | 2014-01-08 | 重庆鸽牌电瓷有限公司 | Cement adhesive for porcelain insulator and metal accessory |
CN104072197A (en) * | 2014-06-30 | 2014-10-01 | 江苏南瓷绝缘子股份有限公司 | Method for curing insulator cement adhesive |
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CN101844896A (en) * | 2009-03-26 | 2010-09-29 | 大连电瓷集团股份有限公司 | Silicate cement adhesive for high-voltage electrical appliance bushing |
CA2851757A1 (en) * | 2011-12-15 | 2013-06-20 | Dow Global Technologies Llc | Dry mix formulations containing carboxylated styrene-butadiene redispersible polymer powders and alumina rich containing cements |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106699063A (en) * | 2016-12-30 | 2017-05-24 | 重庆鸽牌电瓷有限公司 | Special adhesive for electrotechnical porcelain with low cement-sand ratio |
CN109534747A (en) * | 2018-12-19 | 2019-03-29 | 唐山高压电瓷有限公司 | A kind of high strength electroceramice ductility cement glue and preparation method thereof |
CN110877969A (en) * | 2019-12-11 | 2020-03-13 | 芦溪县鸿泰工业瓷厂 | Composite cementing material for high-voltage electric porcelain gluing and preparation method thereof |
CN110877969B (en) * | 2019-12-11 | 2022-01-18 | 芦溪县鸿泰工业瓷厂 | Composite cementing material for high-voltage electric porcelain gluing and preparation method thereof |
CN112374842A (en) * | 2020-12-14 | 2021-02-19 | 南京电气绝缘子有限公司 | High-strength aluminate cement adhesive for insulator |
CN113061004A (en) * | 2021-05-13 | 2021-07-02 | 重庆鸽牌电瓷有限公司 | Electroceramic cement adhesive composite material type formula |
CN115180901A (en) * | 2022-07-26 | 2022-10-14 | 重庆鸽牌电瓷有限公司 | Special adhesive between electric porcelain insulator and metal accessory |
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