CN104403522A - Coating composition for weather-resistant steel plate - Google Patents
Coating composition for weather-resistant steel plate Download PDFInfo
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- CN104403522A CN104403522A CN201410739883.8A CN201410739883A CN104403522A CN 104403522 A CN104403522 A CN 104403522A CN 201410739883 A CN201410739883 A CN 201410739883A CN 104403522 A CN104403522 A CN 104403522A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/40—Glass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2251—Oxides; Hydroxides of metals of chromium
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
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Abstract
The invention discloses a coating composition for a weather-resistant steel plate. The coating composition is prepared from the following components in percentage by weight: 30-50% of organosilicone modified polyester resin, 20-46% of filler, 1-2% of a siloxane coupling agent, 0.5-1% of phthalic ester and 1-48.5% of a xylene solvent; the coating composition is prepared from organosilicone modified polyester resin which is use as a base material of the coating composition and other auxiliaries. In actual use, as the organosilicone modified polyester resin has a relatively excellent high-temperature resisting performance, the formed coating composition further has good properties, can be sprayed on metal surfaces such as iron materials, aluminum products and stainless steel, and can be widely applied to heat-resisting materials, such as a petroleum refining furnace, an aluminum refining furnace, an engine exhaust system and an engine silencer, which are in a high-temperature working condition for a long time.
Description
Technical field
The invention belongs to the field of coating of metallic substance, specifically, a kind of coating composition of anti weathering steel.
Background technology
Coating on metal not only can play protection and beautify the effect of metal appearance, as antirust and painted etc., sometimes, coating also can be utilized to realize some special functions, as improved lubrication, improving deep drawability etc.In actual application, effect and the coating of coating have close relationship.For heat resisting coating, heat resisting coating refers to that its film can maintain high temperature (being generally more than 150 DEG C) not cracking for a long time, yellowish appearance degree is little, do not come off, suitable physicals and protection function can also be kept, existing patent documentation CN1583912 (coiled material priming paint coating and method for making thereof, 2005.02.23) disclose one by linear polyester resin or epoxy resin, aminoresin, rust-stabilising pigment, the professional coating of auxiliary agent and solvent composition, when reality uses, because the heat resisting temperature of vibrin or epoxy resin is at 130 ~ 155 DEG C, therefore, be applicable to heat zinc coating plate, electrolytic galvanized sheet, the best results such as alloying plate and cold rolled plate material.
Along with the progress of technology, it is found that silicone resin also has preferably thermotolerance, the basic framework of silicone resin is the main chain of Si-O, higher than the bond energy of the C-C key of common high molecular polymer, it is heat-resisting and antioxygenation is also stronger, under normal circumstances, the heat resisting temperature of silicone resin is 300 DEG C, be proven, silicone resin is except thermotolerance, also show excellent weathering resistance, pollution resistance, pull out water-based, the performance such as winter hardiness and resistance to chemical attack, but when reality uses, but also there are the following problems, such as: need hot setting (more than 250 DEG C) and set time long, not easily large-area construction, to the poor adhesive force of metal, poor solvent resistance and cost of manufacture high, for this reason, we certainly will need to find a kind of high performance material that can substitute silicone resin, simultaneously, more existing vibrin or epoxy resin is also needed to have higher thermotolerance.
Summary of the invention
The object of the present invention is to provide a kind of coating composition of anti weathering steel, the present invention adopts silicone modified polyester resin as the base-material of coating composition, and be aided with other auxiliary agents and be prepared from, when reality uses, because silicone modified polyester resin has more excellent resistance to elevated temperatures, therefore, consisting of coating composition have more good character, iron material can be sprayed on, the metallic surface such as aluminium or stainless steel, and be widely used in petroleum refinement stove, aluminium refines stove, engine exhaust system, silencer for motor vehicles etc. are on the heat-stable material under hot operation state for a long time.
The present invention is achieved through the following technical solutions: a kind of coating composition of anti weathering steel, and by weight percentage, described coating composition comprises following component:
Silicone modified polyester resin: 30 ~ 50%; Filler: 20 ~ 46%;
Silicone coupling agents: 1 ~ 2%; Phthalate: 0.5 ~ 1%;
Xylene solvent: 1 ~ 48.5%.
The present invention is the base-material using silicone modified polyester resin as coating composition, and be aided with other auxiliary combinations, in the present invention, silicone modified polyester resin is due to its excellent heat resisting temperature, to the excellent adhesion of metal material and processibility, excellent solvent resistance and good high hot hardness etc., can be used for being sprayed on the metallic surfaces such as iron material, aluminium or stainless steel, and be widely used in petroleum refinement stove, aluminium refines stove, engine exhaust system, silencer for motor vehicle etc. are on the heat-stable material under hot operation state for a long time.
Described silicone modified polyester resin is as properties-correcting agent by silicone resin, obtain through polycondensation with saturated polyester resin, in the present invention, silicone modified polyester resin has the advantage of silicone resin and saturated polyester resin concurrently, there is good resistance toheat, under normal circumstances, the high temperature resistant temperature of silicone modified polyester resin is 180 ~ 250 DEG C, when reality uses, the tack that the number of silicone resin content represents when decide coating composition film, shock-resistance and thermotolerance, for better solving described problem, the mass ratio of described silicone resin and saturated polyester resin is: 1:(0.1 ~ 0.4).
To better implement the present invention, the solid content of described silicone modified polyester resin is 55 ~ 65%, and proportion is 1.08 ~ 1.14, and acid number is 2 ~ 10mgKOH/g.
Described filler comprises glass powder, chromium sesquioxide and china clay, by weight percentage, described glass powder is 15 ~ 35%, chromium sesquioxide is 2 ~ 5%, china clay is 3 ~ 6%, the glass powder that the present invention relates to, chromium sesquioxide and china clay are technical grade, have the characteristic increasing hardness, improve component wear resistance.
To better implement the present invention, described filler also comprises aluminium powder and talcum powder, and by weight percentage, described filler comprises: the glass powder of 30%, the chromium sesquioxide of 3%, the china clay of 4%, the aluminium powder of 8% and 1% talcum powder.
The filler that the present invention relates to also comprises following situation: described filler also comprises aluminium powder and talcum powder, and by weight percentage, described filler comprises: the glass powder of 29%, the chromium sesquioxide of 2%, the china clay of 3%, the aluminium powder of 10% and 2% talcum powder.
The glass powder that the present invention relates to is glass powder with low melting point, and described glass powder is lead glass powder, boron glass powder or phosphate glass powder.
The present invention compared with prior art, has the following advantages and beneficial effect:
(1) the present invention is the base-material using silicone modified polyester resin as coating composition, and be aided with other auxiliary agents and be prepared from, in the present invention, silicone modified polyester resin is due to its excellent heat resisting temperature, to the excellent adhesion of metal material and processibility, excellent solvent resistance and good high hot hardness etc., can be used for being sprayed on the metallic surfaces such as iron material, aluminium or stainless steel, and be widely used in petroleum refinement stove, aluminium refines stove, engine exhaust system, silencer for motor vehicle etc. are on the heat-stable material under hot operation state for a long time.
(2) silicone modified polyester resin that the present invention relates to is as properties-correcting agent by silicone resin, obtain through polycondensation with saturated polyester resin, in the present invention, silicone modified polyester resin has the advantage of silicone resin and saturated polyester resin concurrently, there is good resistance toheat, under normal circumstances, the high temperature resistant temperature of silicone modified polyester resin is 180 ~ 250 DEG C.
(3) in the present invention, silicone resin and saturated polyester resin adopt 1:(0.1 ~ 0.4) mass ratio react obtained silicone modified polyester resin, silicone resin content is more, assessment is carried out to its film thing known, by this coating composition spray obtain its thermotolerance of class coating material and hot hardness better, therefore, be applicable to petroleum refinement stove, aluminium refine stove, product that engine exhaust system, silencer for motor vehicle etc. are under hot operation state for a long time time best results.
(4) filler that the present invention selects has glass powder, talcum powder, aluminium powder etc. can strengthen the composition of the resistance to elevated temperatures of coating, anti crack performance and corrosion resistance nature, and prepare by suitable proportion, fully taken into account the overlay film situation of various filler to coating composition, practical effect is good.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited thereto.
Embodiment 1:
The coating composition that the present embodiment relates to, by weight percentage, comprises following component:
Silicone modified polyester resin: 30%; Filler: 20%;
Silicone coupling agents: 1%; Phthalate: 0.5%;
Xylene solvent: 48.5%.
Below further describing above-mentioned component:
Silicone modified polyester resin: by silicone resin as properties-correcting agent, obtains through polycondensation with saturated polyester resin, and the mass ratio of described silicone resin and saturated polyester resin is: 1:0.1.
Filler: comprise lead glass powder, chromium sesquioxide and china clay, by weight percentage, lead glass powder is 15%, chromium sesquioxide is 2%, china clay is 3%.
Embodiment 2:
The coating composition that the present embodiment relates to, by weight percentage, comprises following component:
Silicone modified polyester resin: 50%; Filler: 46%;
Silicone coupling agents: 2%; Phthalate: 1%;
Xylene solvent: 1%.
Below further describing above-mentioned component:
Silicone modified polyester resin: by silicone resin as properties-correcting agent, obtains through polycondensation with saturated polyester resin, and the mass ratio of described silicone resin and saturated polyester resin is: 1:0.4.
Filler: comprise boron glass powder, chromium sesquioxide, china clay, aluminium powder and talcum powder, by weight percentage, boron glass powder is 30%, chromium sesquioxide is 3%, china clay is 4%, aluminium powder is 8%, talcum powder is 1%.
Embodiment 3:
The coating composition that the present embodiment relates to, by weight percentage, comprises following component:
Silicone modified polyester resin: 45%; Filler: 46%;
Silicone coupling agents: 1.5%; Phthalate: 0.5%;
Xylene solvent: 7%.
Below further describing above-mentioned component:
Silicone modified polyester resin: by silicone resin as properties-correcting agent, obtains through polycondensation with saturated polyester resin, and the mass ratio of described silicone resin and saturated polyester resin is: 1:0.3.
Filler: comprise phosphate glass powder, chromium sesquioxide, china clay, aluminium powder and talcum powder, by weight percentage, phosphate glass powder is 29%, chromium sesquioxide is 2%, china clay is 3%, aluminium powder is 10%, talcum powder is 2%.
Embodiment 4:
The coating composition that the present embodiment relates to, by weight percentage, comprises following component:
Silicone modified polyester resin: 40%; Filler: 30%;
Silicone coupling agents: 1.5%; Phthalate: 1%;
Xylene solvent: 27.5%.
Below further describing above-mentioned component:
Silicone modified polyester resin: solid content is 55%, proportion is 1.08, and acid number is 2mgKOH/g.
Filler: comprise boron glass powder, chromium sesquioxide and china clay, by weight percentage, boron glass powder is 19%, chromium sesquioxide is 5%, china clay is 6%.
Embodiment 5:
The coating composition that the present embodiment relates to, by weight percentage, comprises following component:
Silicone modified polyester resin: 50%; Filler: 46%;
Silicone coupling agents: 1%; Phthalate: 0.5%;
Xylene solvent: 2.5%.
Below further describing above-mentioned component:
Silicone modified polyester resin: solid content is 65%, proportion is 1.14, and acid number is 10mgKOH/g.
Filler: comprise lead glass powder, chromium sesquioxide, china clay, aluminium powder and talcum powder, by weight percentage, lead glass powder is 30%, chromium sesquioxide is 3%, china clay is 4%, aluminium powder is 8%, talcum powder is 1%.
Embodiment 6:
The coating composition that the present embodiment relates to, by weight percentage, comprises following component:
Silicone modified polyester resin: 35%; Filler: 46%;
Silicone coupling agents: 1.2%; Phthalate: 0.8%;
Xylene solvent: 17%.
Below further describing above-mentioned component:
Silicone modified polyester resin: solid content is 60%, proportion is 1.11, and acid number is 6mgKOH/g.
Filler: comprise phosphate glass powder, chromium sesquioxide, china clay, aluminium powder and talcum powder, by weight percentage, phosphate glass powder is 9%, chromium sesquioxide is 2%, china clay is 3%, aluminium powder is 10%, talcum powder is 2%.
Embodiment 7:
The coating composition that the present embodiment relates to, by weight percentage, comprises following component:
Silicone modified polyester resin: 45%; Filler: 46%;
Silicone coupling agents: 1.5%; Phthalate: 0.8%;
Xylene solvent: 6.7%.
Below further describing above-mentioned component:
Silicone modified polyester resin: by silicone resin as properties-correcting agent, obtain through polycondensation with saturated polyester resin, the mass ratio of described silicone resin and saturated polyester resin is: 1:0.3, the solid content of obtained silicone modified polyester resin is 60%, proportion is 1.12, and acid number is 8mgKOH/g.
Filler: comprise lead glass powder, chromium sesquioxide, china clay, aluminium powder and talcum powder, by weight percentage, lead glass powder is 30%, chromium sesquioxide is 3%, china clay is 4%, aluminium powder is 8%, talcum powder is 1%.
Embodiment 8:
The coating composition that the present embodiment relates to, by weight percentage, comprises following component:
Silicone modified polyester resin: 40%; Filler: 46%;
Silicone coupling agents: 1.2%; Phthalate: 0.6%;
Xylene solvent: 12.2%.
Below further describing above-mentioned component:
Silicone modified polyester resin: by silicone resin as properties-correcting agent, obtain through polycondensation with saturated polyester resin, the mass ratio of described silicone resin and saturated polyester resin is: 1:0.2, the solid content of obtained silicone modified polyester resin is 58%, proportion is 1.12, and acid number is 7mgKOH/g.
Filler: comprise boron glass powder, chromium sesquioxide, china clay, aluminium powder and talcum powder, by weight percentage, boron glass powder is 9%, chromium sesquioxide is 2%, china clay is 3%, aluminium powder is 10%, talcum powder is 2%.
The coating composition that above-described embodiment 1 ~ 8 prepares is sprayed on steel plate or tinplate, be placed in cabinet-type electric furnace, adopt heating schedule to be warming up to 250 DEG C, to take out and after being cooled to room temperature, carry out hardness, resistance to elevated temperatures, coating performance, film adhesive test, test result is in table 1.
Table 1
The above is only preferred embodiment of the present invention, and not do any pro forma restriction to the present invention, every any simple modification, equivalent variations done above embodiment according to technical spirit of the present invention, all falls within protection scope of the present invention.
Claims (7)
1. a coating composition for anti weathering steel, is characterized in that: by weight percentage, and described coating composition comprises following component:
Silicone modified polyester resin: 30 ~ 50%; Filler: 20 ~ 46%;
Silicone coupling agents: 1 ~ 2%; Phthalate: 0.5 ~ 1%;
Xylene solvent: 1 ~ 48.5%.
2. the coating composition of a kind of anti weathering steel according to claim 1, it is characterized in that: described silicone modified polyester resin is as properties-correcting agent by silicone resin, obtain through polycondensation with saturated polyester resin, the mass ratio of described silicone resin and saturated polyester resin is: 1:(0.1 ~ 0.4).
3. the coating composition of a kind of anti weathering steel according to claim 1, is characterized in that: the solid content of described silicone modified polyester resin is 55 ~ 65%, and proportion is 1.08 ~ 1.14, and acid number is 2 ~ 10mgKOH/g.
4. the coating composition of a kind of anti weathering steel according to claim 1, it is characterized in that: described filler comprises glass powder, chromium sesquioxide and china clay, by weight percentage, described glass powder is 15 ~ 35%, chromium sesquioxide is 2 ~ 5%, china clay is 3 ~ 6%.
5. the coating composition of a kind of anti weathering steel according to claim 3, it is characterized in that: described filler also comprises aluminium powder and talcum powder, by weight percentage, described filler comprises: the glass powder of 30%, the chromium sesquioxide of 3%, the china clay of 4%, the aluminium powder of 8% and 1% talcum powder.
6. the coating composition of a kind of anti weathering steel according to claim 3, it is characterized in that: described filler also comprises aluminium powder and talcum powder, by weight percentage, described filler comprises: the glass powder of 29%, the chromium sesquioxide of 2%, the china clay of 3%, the aluminium powder of 10% and 2% talcum powder.
7. the coating composition of a kind of anti weathering steel according to any one of claim 4 ~ 6, is characterized in that: described glass powder is lead glass powder, boron glass powder or phosphate glass powder.
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CN201410739883.8A CN104403522A (en) | 2014-12-08 | 2014-12-08 | Coating composition for weather-resistant steel plate |
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CN201410739883.8A CN104403522A (en) | 2014-12-08 | 2014-12-08 | Coating composition for weather-resistant steel plate |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104449367A (en) * | 2014-12-08 | 2015-03-25 | 成都锦汇科技有限公司 | Coating composition used for steel plates with weatherability and preparation method thereof |
CN106590416A (en) * | 2016-11-18 | 2017-04-26 | 成都锦汇科技有限公司 | Coating composition for colorized weather-resistant steel plate |
CN106590415A (en) * | 2016-11-18 | 2017-04-26 | 成都锦汇科技有限公司 | Preparation process of weather-resisting colored steel plate |
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CN1834177A (en) * | 2005-03-16 | 2006-09-20 | 嘉善维克托塑化有限公司 | High temp resistant electrostatic powdered paint and prodn. technique |
CN102618166A (en) * | 2012-03-27 | 2012-08-01 | 山东大学 | Electric arc sprayed aluminum coating sealant resistant to high-temperature alkali steam corrosion and usage method thereof |
CN103881104A (en) * | 2014-01-22 | 2014-06-25 | 杭州吉华高分子材料有限公司 | Preparation method and applications of modified polyester resin |
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2014
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CN1834177A (en) * | 2005-03-16 | 2006-09-20 | 嘉善维克托塑化有限公司 | High temp resistant electrostatic powdered paint and prodn. technique |
CN102618166A (en) * | 2012-03-27 | 2012-08-01 | 山东大学 | Electric arc sprayed aluminum coating sealant resistant to high-temperature alkali steam corrosion and usage method thereof |
CN103881104A (en) * | 2014-01-22 | 2014-06-25 | 杭州吉华高分子材料有限公司 | Preparation method and applications of modified polyester resin |
Non-Patent Citations (2)
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陈平等: "《高分子合成材料学》", 31 January 2005, 化学工业出版社 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104449367A (en) * | 2014-12-08 | 2015-03-25 | 成都锦汇科技有限公司 | Coating composition used for steel plates with weatherability and preparation method thereof |
CN106590416A (en) * | 2016-11-18 | 2017-04-26 | 成都锦汇科技有限公司 | Coating composition for colorized weather-resistant steel plate |
CN106590415A (en) * | 2016-11-18 | 2017-04-26 | 成都锦汇科技有限公司 | Preparation process of weather-resisting colored steel plate |
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