CN104403482A - Preparation technology of insulation wear-resistant polyurethane paint - Google Patents

Preparation technology of insulation wear-resistant polyurethane paint Download PDF

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Publication number
CN104403482A
CN104403482A CN201410630684.3A CN201410630684A CN104403482A CN 104403482 A CN104403482 A CN 104403482A CN 201410630684 A CN201410630684 A CN 201410630684A CN 104403482 A CN104403482 A CN 104403482A
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CN
China
Prior art keywords
paint
component
pitch
insulation
resistant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410630684.3A
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Chinese (zh)
Inventor
黄勇
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Individual
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Individual
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Publication date
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Priority to CN201410630684.3A priority Critical patent/CN104403482A/en
Publication of CN104403482A publication Critical patent/CN104403482A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a preparation method of an insulation wear-resistant polyurethane paint. The paint comprises a component A composed of unsaturated polyester (70-90%) and 2,4-dichlorobenzoyl peroxide (10-30%) and a component B composed of styrene (80-90%), tobulene-2,4-di[N,N-dimethylaminopropylurea] (5-10%) and asphalt (5-10%). The prepared paint has the advantages of good curing performance, rapid drying, strong adhesive force, high dielectric coefficient, dampness resistance, heat resistance, and wide application prospect.

Description

The preparation technology of a kind of insulation, resistant polyester paint
Technical field
The present invention relates to a kind of paint, the preparation method of particularly a kind of insulation, resistant polyester paint, belongs to chemical field.
Background technology
Painting large is in early days main raw material mainly with vegetables oil, therefore is called " paint ".Paint plays very important effect to the progress of human lives.Enter 21 century, on the one hand, the development of social productive forces and growth in the living standard, new requirement is constantly proposed to the kind of painting and quality, on the other hand, the progress of science and technology, particularly vitochemical development, the continuous appearance of novel resin, for the large production of coating provides possibility, many new oil paint materials are come out one after another.Occur that clinging power is larger, the paint of higher, fire-retardant, the anticorrosive shades of colour high with thermostability of glossiness.
Current paint has more than several thousand kinds.By whitewashing position classification, be mainly divided into wall paint, metallic paint, wood lacquer.Wall paint comprises exterior wall paint, interior wall paint and end face paint, mainly emulsion paint; Metallic paint is enamel paint mainly; Wood lacquer mainly contains pyroxylin(e)finish, Polyester Paint etc.
Polyester Paint is the one of conventional paint, and it is a kind of polycomponent paint, is be the thick matter paint of one that main film forming matter is made with vibrin.The nineties in 20th century, after Polyester Paint imports China into, just instead of varnish very soon, become a kind of main paint.Polyester Paint is by adding a certain amount of pitch, insulation, wear-resisting paint can be prepared, be widely used in motor, electrical equipment coil and insulation component, and fill its gap and micropore, to dry or after heating, drying, a closely knit entirety is formed in solidification, thus improves its disruptive strength, mechanical property.Paint curing performance prepared by present method is good, quick-drying, adhesive power strong, have thermo-elasticity; Corrosive nature is not played to copper and coil or other materials; There is higher dielectric, moisture resistance, thermotolerance, be with a wide range of applications.
Summary of the invention
The object of this invention is to provide the preparation method of a kind of insulation, resistant polyester paint.
This paint comprises A and B two component, and component A is unsaturated polyester and 2.4-dichlorobenzoperoxide, and B component is vinylbenzene, Toluene-2,4-diisocyanate, 4-bis-[N, N-dimethylamino third urea] and pitch, and each component formula content is as follows:
Component A
Unsaturated polyester: 70%-90%
2.4-dichlorobenzoperoxide: 10%-30%;
B component
Vinylbenzene: 80%-90%
Toluene-2,4-diisocyanate, 4-bis-[N, N-dimethylamino third urea]: 5 %-10%
Pitch: 5%-10%;
The preparation method of a kind of oil resistant, corrosion-resistant paint carries out as follows:
(1) first the component A material containing main paint is heated to 40-50 DEG C;
(2) slowly added in B component by component A material after heating, do not stop to stir, make it mix, the ratio control added is between A:B=2:1 and 3:1 again;
(3) when modulation has certain viscosity, just can be brushed to body surface or be filled in electric elements gap, the unsaturated double-bond in the main chain of polyester under the effect of 2.4-dichlorobenzoperoxide solidifying agent with carry out radical copolyreaction and film-forming as strong solvent vinylbenzene.
The present invention has following advantages and characteristic:
(1) good, the quick-drying of the paint curing performance prepared of present method;
(2) paint has higher dielectricity, does not play corrosive nature to copper and coil or other materials;
(3) the preparation technology of this paint is less demanding, and flow process is simple, is with a wide range of applications.
Embodiment
Embodiment one:
The preparation method of a kind of insulation, resistant polyester paint.This paint comprises A and B two component composition, and component A is unsaturated polyester and 2.4-dichlorobenzoperoxide, and B component is vinylbenzene, Toluene-2,4-diisocyanate, 4-bis-[N, N-dimethylamino third urea] and pitch, and each component concentration is as follows:
Component A,
Unsaturated polyester: 70%
2.4-dichlorobenzoperoxide: 30%;
B component,
Vinylbenzene: 80%
Toluene-2,4-diisocyanate, 4-bis-[N, N-dimethylamino third urea]: 10%
Pitch: 10%;
During use, paint is prepared as follows:
(1) first the component A material containing main paint is heated to 40 DEG C,
(2) slowly added in B component by component A material after heating, do not stop to stir, the ratio added is A:B=2:1, makes it mix again,
(3) when modulation has certain viscosity, just can be brushed to body surface or be filled in electric elements gap, unsaturated polyester and vinylbenzene and bituminization film forming.
Embodiment two:
The preparation method of a kind of insulation, resistant polyester paint.This paint comprises A and B two component composition, and component A is unsaturated polyester and 2.4-dichlorobenzoperoxide, and B component is vinylbenzene, Toluene-2,4-diisocyanate, 4-bis-[N, N-dimethylamino third urea] and pitch, and each component concentration is as follows:
Component A,
Unsaturated polyester: 90%
2.4-dichlorobenzoperoxide: 10%;
B component,
Vinylbenzene: 90%
Toluene-2,4-diisocyanate, 4-bis-[N, N-dimethylamino third urea]: 5%
Pitch: 5%;
During use, paint is prepared as follows:
(1) first the component A material containing main paint is heated to 50 DEG C,
(2) slowly added in B component by component A material after heating, do not stop to stir, the ratio added is A:B=3:1, makes it mix again,
(3) when modulation has certain viscosity, just can be brushed to body surface or be filled in electric elements gap, unsaturated polyester and vinylbenzene and bituminization film forming.

Claims (3)

1. insulation, a resistant polyester paint, its feature comprises A and B two component, and component A is unsaturated polyester and 2.4-dichlorobenzoperoxide, B component is vinylbenzene and Toluene-2,4-diisocyanate, 4-bis-[N, N-dimethylamino third urea] and pitch.
2. one insulation according to claim 1, resistant polyester paint, is characterized in that each component concentration of described A, B is as follows:
Component A
Unsaturated polyester: 70%-90%
2.4-dichlorobenzoperoxide: 10%-30%;
B component
Vinylbenzene: 80%-90%
Toluene-2,4-diisocyanate, 4-bis-[N, N-dimethylamino third urea]: 10%-20%
Pitch: 5%-10%.
3. a kind of oil resistant according to claim 1 and 2, corrosion-resistant paint, is characterized in that added pitch is petroleum refinement pitch.
CN201410630684.3A 2014-11-11 2014-11-11 Preparation technology of insulation wear-resistant polyurethane paint Pending CN104403482A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410630684.3A CN104403482A (en) 2014-11-11 2014-11-11 Preparation technology of insulation wear-resistant polyurethane paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410630684.3A CN104403482A (en) 2014-11-11 2014-11-11 Preparation technology of insulation wear-resistant polyurethane paint

Publications (1)

Publication Number Publication Date
CN104403482A true CN104403482A (en) 2015-03-11

Family

ID=52641156

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410630684.3A Pending CN104403482A (en) 2014-11-11 2014-11-11 Preparation technology of insulation wear-resistant polyurethane paint

Country Status (1)

Country Link
CN (1) CN104403482A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61115966A (en) * 1984-11-12 1986-06-03 Toshiba Chem Corp Electrical insulating varnish
CN101768404A (en) * 2009-12-25 2010-07-07 艾伦塔斯电气绝缘材料(珠海)有限公司 Impregnated insulating paint and preparation method thereof
CN102321425A (en) * 2011-08-10 2012-01-18 中国西电集团公司 Formula for solvent-free impregnating varnish
CN103540244A (en) * 2013-09-29 2014-01-29 安徽墙煌彩铝科技有限公司 Polyester finishing coat for colourful stainless steel plate of mobile phone shielding case and preparation method of polyester finishing coat

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61115966A (en) * 1984-11-12 1986-06-03 Toshiba Chem Corp Electrical insulating varnish
CN101768404A (en) * 2009-12-25 2010-07-07 艾伦塔斯电气绝缘材料(珠海)有限公司 Impregnated insulating paint and preparation method thereof
CN102321425A (en) * 2011-08-10 2012-01-18 中国西电集团公司 Formula for solvent-free impregnating varnish
CN103540244A (en) * 2013-09-29 2014-01-29 安徽墙煌彩铝科技有限公司 Polyester finishing coat for colourful stainless steel plate of mobile phone shielding case and preparation method of polyester finishing coat

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
苑芳友等: "《建筑材料与检测技术(第2版)》", 31 January 2014, 北京理工大学出版社 *

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Application publication date: 20150311

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