CN104387947A - UV coating with mirror surface effect - Google Patents

UV coating with mirror surface effect Download PDF

Info

Publication number
CN104387947A
CN104387947A CN201410707134.7A CN201410707134A CN104387947A CN 104387947 A CN104387947 A CN 104387947A CN 201410707134 A CN201410707134 A CN 201410707134A CN 104387947 A CN104387947 A CN 104387947A
Authority
CN
China
Prior art keywords
mirror effect
coating
percent
coating according
effect
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410707134.7A
Other languages
Chinese (zh)
Inventor
刘国俊
刘辉煌
黄荣泰
刘东岳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI XIECHENGCHANG CHEMICAL CO Ltd
Original Assignee
SHANGHAI XIECHENGCHANG CHEMICAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI XIECHENGCHANG CHEMICAL CO Ltd filed Critical SHANGHAI XIECHENGCHANG CHEMICAL CO Ltd
Priority to CN201410707134.7A priority Critical patent/CN104387947A/en
Publication of CN104387947A publication Critical patent/CN104387947A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a UV coating with the mirror surface effect. The UV coating is prepared from the following components in percentage by weight: 4.74 percent of solid acrylic resin, 41.45 percent of light-cured resin, 50.1 percent of reactive diluent, 0.12 percent of defoamer, 0.20 percent of rheological additive, 0.13 percent of inhibitor, 2.67 percent of photoinitiator, 0.29 percent of flatting agent and 0.30 percent of scratch resistance additive. The UV coating with the mirror surface effect is good in leveling property and high light property (the mirror surface effect), is capable of enabling the surface of a plate after coating not to have poor leveling expressions of sagging, orange peels, shrinkage cavities and the like and forming the stoving varnish-like gorgeous effect as bright as a mirror, can satisfy the using and environment-friendly requirements of numerous consumers and has remarkable market application value.

Description

Mirror effect UV coating
Technical field
The present invention relates to coating, particularly a kind of mirror effect UV coating.
Background technology
Modern grows with each passing day to being naturally crazy about, and regress into nature, back to nature household agitation " surge forward ", and people yearn for more healthy, more natural domestic environment and mode of life.In life, the surface gloss of human consumer for the topcoating of building materials and the difference of levelling property meeting foundation purposes and individual aesthetic, and there is different demands; The solid wood texture commercially almost can looked genuine adds light type furniture and the building materials of gorgeous effect as bright as a sixpence as baking vanish, is rather subject to the welcome of some human consumers.But, the light type furniture of current commercial type and building materials mostly are solvent based coating or nitro paint, and the UV type coating of more environmental protection, because can there is the problem that good levelling property and highlighted photosensitiveness (mirror effect) cannot realize simultaneously, directly affects the promotion and application of UV type coating.
Summary of the invention
The problems referred to above existed for prior art and demand, object of the present invention, is to provide a kind of mirror effect UV coating, to solve the problem that the good levelling property of UV coating and highlighted photosensitiveness (mirror effect) realize simultaneously.
For achieving the above object, the technical solution used in the present invention is as follows: a kind of mirror effect UV coating, formulated by appended weight percent content by following material:
The preferred version of above-mentioned mirror effect UV coating is formulated by appended weight percent content by following material:
Above-mentioned mirror effect UV coating, wherein, described solid propenoic acid resin is selected from least one in acrylic acid esters co-polymer, Polymers.
Above-mentioned mirror effect UV coating, wherein, described light-cured resin is selected from least one in urethane acrylate, epoxy acrylate, polyester acrylate.
Above-mentioned mirror effect UV coating, wherein, described reactive thinner is selected from least one in hydroxyethyl methylacrylate, tripropylene glycol diacrylate, ethoxylated neopentylglycol diacrylate.
Above-mentioned mirror effect UV coating, wherein, described defoamer is selected from least one in modified siloxane solution, vinyl polymer.
Above-mentioned mirror effect UV coating, wherein, described auxiliary rheological agents is selected from least one in polyamide wax, aerosil.
Above-mentioned mirror effect UV coating, wherein, described inhibitor is selected from least one in MEHQ, three (N-nitroso-group-N-Phenylhydroxylamine) aluminium salt.
Above-mentioned mirror effect UV coating, wherein, described light trigger is selected from least one in 2-hydroxy-2-methyl-1-phenyl-1-acetone, methyl benzoylformate, benzophenone, 2,4,6-trimethylbenzoy-dipheny phosphine oxides.
Above-mentioned mirror effect UV coating, wherein, described flow agent is selected from least one in polyacrylate solution, modified organic silicon solution.
Above-mentioned mirror effect UV coating, wherein, described scratch resistant auxiliary agent is selected from least one in polyether-modified polydimethylsiloxane solution, polyester modification polydimethylsiloxane.
The all components of proportional quantity is uniformly mixed rear filtration by the preparation method of coating of the present invention.
The experiment proved that, mirror effect UV coating provided by the invention has good levelling property and highlighted photosensitiveness (mirror effect), the performance of the both levelling difference such as no sag, orange peel, shrinkage cavity of the plate surface after application can be made, plate surface can be made again to form gorgeous effect as bright as a sixpence as baking vanish, the use of consumers in general and the requirement of environmental protection can be met greatly, there is significant market using value.
Embodiment
Below in conjunction with embodiment and comparative example, technical scheme of the present invention is described further.
Embodiment 1
Fill a prescription as shown in table 1:
Table 1
Fill a prescription according to table 1, dropped into by the material of each component in Scattered Kettle, use high speed dispersor filters after being stirred to and being uniformly dispersed, packs, and namely obtains a kind of mirror effect UV coating of the present invention.
Embodiment 2
Fill a prescription as shown in table 2:
Table 2
Fill a prescription according to table 2, dropped into by the material of each component in Scattered Kettle, use high speed dispersor filters after being stirred to and being uniformly dispersed, packs, and namely obtains a kind of mirror effect UV coating of the present invention.
Embodiment 3
Fill a prescription as shown in table 3.
Table 3
Fill a prescription according to table 3, dropped into by the material of each component in Scattered Kettle, use high speed dispersor filters after being stirred to and being uniformly dispersed, packs, and namely obtains a kind of mirror effect UV coating of the present invention.
Comparative example
Fill a prescription as shown in table 4:
Table 4 (the optimum formulation for coating material that the embodiment 4 of CN201310270498.9 provides)
Component Name of material/model Proportioning (weight percentage)
Light-cured resin Two functional modified polyurethane acrylic resins 80
Defoamer Polyacrylic acid superpolymer 0.7
Dispersion agent High molecular weight block copolymer solution 0.7
Initiator Fragrance ketone 3.5
Flow agent BYK-371 0.5
Monomer Modification acrylate class 14.6
Effect contrasts:
Get a block length be 90cm, wide for 10cm, thickness be the medium density fibre board (MDF) (MDF) of 2cm, be equally divided into four pieces, above-described embodiment 1 ~ 3 and comparative example are prepared etc. after weight coating carries out application respectively in the following order: sanding → roller coating black UV priming paint → UV solidification → roller coating black UV priming paint → UV solidification → sanding → roller coating mirror effect UV coating → UV solidification, carry out application finished product effect comparison.
Result shows, mirror effect UV coating of the present invention has good levelling property, and building material surface can be made to form gorgeous effect as bright as a sixpence as baking vanish.And the levelling of comparative example is general, mirror effect is poor.Visible, mirror effect UV coating of the present invention can meet the use of consumers in general and the requirement of environmental protection greatly, has significant market using value.

Claims (11)

1. a mirror effect UV coating, is characterized in that, formulated by appended weight percent content by following material:
2. mirror effect UV coating as claimed in claim 1, is characterized in that: formulated by appended weight percent content by following material:
3. mirror effect UV coating according to claim 1 and 2, is characterized in that: described solid propenoic acid resin is selected from least one in acrylic acid esters co-polymer, Polymers.
4. mirror effect UV coating according to claim 1 and 2, is characterized in that: described light-cured resin is selected from least one in urethane acrylate, epoxy acrylate, polyester acrylate.
5. mirror effect UV coating according to claim 1 and 2, is characterized in that: described reactive thinner is selected from least one in hydroxyethyl methylacrylate, tripropylene glycol diacrylate, ethoxylated neopentylglycol diacrylate.
6. mirror effect UV coating according to claim 1 and 2, is characterized in that: described defoamer is selected from least one in modified siloxane solution, vinyl polymer.
7. mirror effect UV coating according to claim 1 and 2, is characterized in that: described auxiliary rheological agents is selected from least one in polyamide wax, aerosil.
8. mirror effect UV coating according to claim 1 and 2, is characterized in that: described inhibitor is selected from least one in MEHQ, three (N-nitroso-group-N-Phenylhydroxylamine) aluminium salt.
9. a kind of mirror effect UV coating according to claim 1 and 2; it is characterized in that: described light trigger is selected from 2-hydroxy-2-methyl-1-phenyl-1-acetone, methyl benzoylformate, benzophenone, 2; at least one in 4,6-trimethylbenzoy-dipheny phosphine oxide.
10. mirror effect UV coating according to claim 1 and 2, is characterized in that: described flow agent is selected from least one in polyacrylate solution, modified organic silicon solution.
11. mirror effect UV coating according to claim 1 and 2, is characterized in that: described scratch resistant auxiliary agent is selected from least one in polyether-modified polydimethylsiloxane solution, polyester modification polydimethylsiloxane.
CN201410707134.7A 2014-11-27 2014-11-27 UV coating with mirror surface effect Pending CN104387947A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410707134.7A CN104387947A (en) 2014-11-27 2014-11-27 UV coating with mirror surface effect

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410707134.7A CN104387947A (en) 2014-11-27 2014-11-27 UV coating with mirror surface effect

Publications (1)

Publication Number Publication Date
CN104387947A true CN104387947A (en) 2015-03-04

Family

ID=52605913

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410707134.7A Pending CN104387947A (en) 2014-11-27 2014-11-27 UV coating with mirror surface effect

Country Status (1)

Country Link
CN (1) CN104387947A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105838165A (en) * 2016-03-30 2016-08-10 田绍鸿 UV reflective paint, and preparation method and application thereof
CN106832063A (en) * 2015-12-03 2017-06-13 天津久日新材料股份有限公司 The compounding light trigger of low-yellowing high activity

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030198824A1 (en) * 2002-04-19 2003-10-23 Fong John W. Photocurable compositions containing reactive polysiloxane particles
CN101457058A (en) * 2007-12-12 2009-06-17 深圳市高域化学材料有限公司 Ultraviolet cured primer special for vacuum coating
CN101864204A (en) * 2010-06-09 2010-10-20 宜兴市宏泰化工有限公司 Dedicated high-performance primer of ultraviolet-curing vacuum coating for reflector of automobile lamps
CN101967338A (en) * 2010-11-03 2011-02-09 苏州凯康化工科技有限公司 High gloss high abrasion resistance ultra-violet curing overprinting varnish of mobile phone and preparation method thereof
CN102220070A (en) * 2011-05-10 2011-10-19 上海富臣化工有限公司 Ultraviolet solidified yellowing resistant and glossy woodenware paint and application technology thereof
CN103289457A (en) * 2012-03-02 2013-09-11 上海富臣化工有限公司 UV curtain coating flexible topcoat gloss paint

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030198824A1 (en) * 2002-04-19 2003-10-23 Fong John W. Photocurable compositions containing reactive polysiloxane particles
CN101457058A (en) * 2007-12-12 2009-06-17 深圳市高域化学材料有限公司 Ultraviolet cured primer special for vacuum coating
CN101864204A (en) * 2010-06-09 2010-10-20 宜兴市宏泰化工有限公司 Dedicated high-performance primer of ultraviolet-curing vacuum coating for reflector of automobile lamps
CN101967338A (en) * 2010-11-03 2011-02-09 苏州凯康化工科技有限公司 High gloss high abrasion resistance ultra-violet curing overprinting varnish of mobile phone and preparation method thereof
CN102220070A (en) * 2011-05-10 2011-10-19 上海富臣化工有限公司 Ultraviolet solidified yellowing resistant and glossy woodenware paint and application technology thereof
CN103289457A (en) * 2012-03-02 2013-09-11 上海富臣化工有限公司 UV curtain coating flexible topcoat gloss paint

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
刘益军: "《聚氨酯原料及助剂手册 第二版》", 31 January 2013, 化学工业出版社 *
寇杰等: "《油气集输技术数据手册》", 31 July 2013, 中国石化出版社 *
汪长春等: "《丙烯酸酯涂料》", 30 April 2005, 化学工业出版社 *
金养智: "《光固化材料性能及应用手册》", 31 July 2010, 化学工业出版社 *
钱逢麟: "《涂料助剂-品种和性能手册》", 30 November 1990, 化学工业出版社 *
闫福安等: "《涂料树脂合成及应用》", 30 September 2008, 化学工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832063A (en) * 2015-12-03 2017-06-13 天津久日新材料股份有限公司 The compounding light trigger of low-yellowing high activity
CN105838165A (en) * 2016-03-30 2016-08-10 田绍鸿 UV reflective paint, and preparation method and application thereof
CN105838165B (en) * 2016-03-30 2018-05-11 田绍鸿 A kind of UV reflecting coatings and its preparation method and application

Similar Documents

Publication Publication Date Title
CN103013325B (en) A kind of preparation method of scratch-resistant polyurethane matt black finish for woodware
CN104479436B (en) Peelable glue coating composition, peelable gel coating, the preparation method and application of peelable gel coating
CN111471375B (en) Anti-scratch photocuring odorless matte white finish
CN102206463A (en) Vacuum plating UV cured primer
CN102977748A (en) UV furniture spray-coating gloss topcoat without volatile organic solvent
CN102337704B (en) Temperature-resisting printing paper water base varnish and preparation method thereof
CN103555193A (en) Ultraviolet light cured elastic polyurethane acrylate flat lacquer and preparation method thereof
CN101935496A (en) UV (Ultraviolet)-scratch-resistant finish paint
CN104073040A (en) UV-cured white curtaining paint and preparation method thereof
CN103589324A (en) UV (ultraviolet) anti-scratch matte finishing paint
CN102140306A (en) UV (Ultraviolet) laser roller coating woodware primer coat
CN103642298B (en) A kind of resistance to soiling epoxy-polyester type powder coating matting agent and preparation method thereof
CN104004395A (en) UV roller coat elastic under-coating paint used for wood veneer and preparing method and construction process of UV roller coat elastic under-coating paint
CN104559698A (en) Yellowing-resistant UV (ultraviolet) transparent primer for electrostatic spraying
CN104387947A (en) UV coating with mirror surface effect
CN107418410A (en) Low-VOC aqueous UV solidification single layer coatings composition, painting method and the substrate through its coating
CN103333603B (en) A kind of UV photo-cured coating for IMF and preparation method thereof and application
CN102206436A (en) Vacuum-plating ultraviolet curing intermediate paint
CN104893534A (en) Polyurethane matte clear finishing coat as well as preparation method and using method thereof
CN105949914A (en) Waterborne glass baking paint and preparation method thereof
CN103589246A (en) Polyethylene paint
CN102234481A (en) Vacuum sputtering UV-curable finish coat
CN104371536B (en) Hardened coating composite and preparation method thereof, and PETG (polyethylene terephthalate glycol) composite membrane and preparation method thereof
CN105670471A (en) Waterborne radiation curing coating decorating plate and preparation method thereof
CN101845244B (en) UV wiping paint

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150304