CN104387798A - Disperse blue-to-black dye composition - Google Patents

Disperse blue-to-black dye composition Download PDF

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Publication number
CN104387798A
CN104387798A CN201410525754.9A CN201410525754A CN104387798A CN 104387798 A CN104387798 A CN 104387798A CN 201410525754 A CN201410525754 A CN 201410525754A CN 104387798 A CN104387798 A CN 104387798A
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component
dye composition
disperse blue
black dye
formula
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CN201410525754.9A
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CN104387798B (en
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高怀庆
吕建君
汪仁良
邱雯
欧其
阮伟祥
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SHANGHAI HONGYUAN XINCHUANG MATERIAL TECHNOLOGY Co Ltd
Zhejiang Longsheng Group Co Ltd
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SHANGHAI HONGYUAN XINCHUANG MATERIAL TECHNOLOGY Co Ltd
Zhejiang Longsheng Group Co Ltd
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Abstract

The invention discloses a disperse blue-to-black dye composition. The disperse blue-to-black dye composition is obtained by mixing of original dye and auxiliary agents. The original dye comprises 40-99wt% of an ingredient A and 1-60wt% of an ingredient B. The ingredient A comprises one or more materials shown in the formulas (I)-(II) and the ingredient B comprises one or more materials shown in the formulas (III)-(V). The disperse blue-to-black dye composition has a wide pH-resistant range and excellent various fastness, has stable color and gloss in a strong base bath, is a hard-won strong base-resistant disperse dye and can be used for alkaline burnt discharge.

Description

A kind of EX-SF DISPERSE BLUE EX-SF 300 is to black dye composition
(1) technical field
The present invention relates to a kind of disperse dye composition, be specifically related to a kind of EX-SF DISPERSE BLUE EX-SF 300 to black dye composition.
(2) background technology
Polyester piece good pre-treatment is carried out in the basic conditions, and what generally adopt in terylene disperse dyeing process is dye under acidic conditions, therefore to need before dyeing first and with abundant washing, make whole wet treatment longer for process period like this.And if refining or alkali decrement treatment improper, or wash insufficient and be with alkali time, dyeing under acidic conditions often there are quality problems, and reproducibility is poor.So the dispersed dye dyeed under being suitable for alkaline condition if can find, will make that dyeing process is simpler and more direct, dyeing is more reasonable.This is factory's energy-saving and emission-reduction, reduces costs and establish good basis.Meanwhile, the oligopolymer traditional acidic conditions dyeing also can being avoided often to occur stains the disadvantage such as specking, color dot, dyeing flower caused.
In addition, the burn-out printing of conventional fabrics utilizes the differences such as the acidproof of fiber or alkali resistance, removes the working method of wherein a kind of fiber with acid or alkali.The alkaline burn-out printing of polyester flannel woven fabrics utilizes the alkali hydrolyzable of trevira, by controlling the local hydrolysis of terylene matte, develops a kind of matte in stereo concave-convex effect.Because the alkali resistance of dispersed dye is not good enough, too responsive to pH value, easily produce cylinder poor, unstable product quality, upper dye can not be stablized in highly basic (as NaOH) system.Therefore, seek that every fastness is excellent, the alkali-resistant disperse dye complex of good level-dyeing property is the significant work of item.
(3) summary of the invention
The invention provides a kind of EX-SF DISPERSE BLUE EX-SF 300 to black dye composition, the resistance to pH scope of this dye composite is wide, and every fastness is excellent, especially color light stabilizing in highly basic (as NaOH) bath, be rare strong basicity resisting dispersion dye, can be used for alkaline etching.
A kind of EX-SF DISPERSE BLUE EX-SF 300 is to black dye composition, and formed by former dyestuff and auxiliary agent Mixed Pinyin, former dyestuff comprises component A and B component, and based on former dyestuff gross weight, the weight percentage of component A is 40 ~ 99%, and the weight percentage of B component is 1 ~ 60%;
Described component A is selected from one or more the combination in lower formula I ~ (II):
In upper formula I ~ (II),
R 1, R 3respective is independently H or C 1~ C 4alkyl;
R 2for cyanoethyl, C 1~ C 4alkyl or benzyl;
R 4for cyanoethyl, C 1~ C 4alkyl, styroyl or hydrocinnamyl;
N is 2 or 3;
Described B component be selected from lower formula III ~ (V) one or more:
In upper formula III ~ (V),
R 5for H, Cl, C 1~ C 4alkyl or C 1~ C 4alkoxyl group;
R 7for H or C 1~ C 4alkyl; R 9for H, Cl or C 1~ C 4alkyl;
R 6, R 8, R 10respective is independently C 1~ C 4alkyl or cyanoethyl;
X 1, X 2respective is independently Cl or Br;
X 3for Cl or Br, X 4for H; Or X 3for NO 2, X 4for H, Cl or Br.
Further, described former dyestuff is made up of component A and B component.
Further, based on former dyestuff gross weight, the weight percentage of component A is preferably 45 ~ 95%, and the weight percentage of B component is preferably 5 ~ 55%.
Further, described component A is preferably from one of following or wherein two or more mixture:
Further, described B component is preferably from one of following or wherein two or more mixture:
Further, EX-SF DISPERSE BLUE EX-SF 300 of the present invention to black dye composition, at least one compound of component A preferably in formula I; At least one of B component preferably in formula III and/or at least one compound in formula (V).
More particularly, described component A is preferably formula (I-1), and described B component is preferably formula (III-1) and/or formula (V-1).
Formula used in the present invention (I), the dye composition shown in (II) can synthesize by mode well known to those skilled in the art easily, also with reference to the method introduced in patent US5824117A, US3502645, CN1036974, CN101117446 or the preparation of similar method, also commercially available prod can be adopted.Due to the singularity of dye industry; be difficult to also there is no need to make sterling; so " the former dyestuff " described in the present invention refers to that dye composition wherein uses the slurries obtained in preparation process to filter through pressure filter or other filter plants the filter cake obtained; usual meeting is with the impurity in some preparation process; disperse dye composition of the present invention also allows containing a small amount of physical impurity in preparation process, is advisable not affect dyeing behavior.
EX-SF DISPERSE BLUE EX-SF 300 of the present invention is to black dye composition, as commodity selling or be applied to textile materials painted time, usually also needing to add auxiliary agent carries out aftertreatment, described auxiliary agent be dispersed dye composite time conventional dispersion agent, diffusant and other tensio-active agent etc., preferred auxiliary agent is selected from one of following or its mixture: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products (as condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF)), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 85A, xylogen 83A) etc.Usually, the ratio of the gross weight of auxiliary agent and former dyestuff is 0.2 ~ 5:1.
EX-SF DISPERSE BLUE EX-SF 300 of the present invention is to black dye composition, and its commercial treatment method is as follows:
By former dye component A and former dye component B by after the mixing of above-mentioned proportioning, under the existence of auxiliary agent, water or other wetting agent, carry out corpusculed with the pulverizer such as sand mill or shredder; Also mix with above-mentioned ratio after former dye component A and former dye component B can being carried out corpusculed process with the pulverizer such as sand mill or shredder respectively under the existence of auxiliary agent, water or other wetting agent in addition.EX-SF DISPERSE BLUE EX-SF 300 of the present invention is to black dye composition, aqueous with can be after sand mill or shredder grinding, can be powdery, particulate state after spraying dry.
EX-SF DISPERSE BLUE EX-SF 300 provided by the invention is to black dye composition, dispersed dye normal dyeing method can be adopted as high-temperature and high pressure dyeing process contaminated the hydrophobic fiber materials such as polyester, polymeric amide or vinegar fibre, there is colour fastness excellence, resistance to pH scope is wide, can be dye in the dye bath of 3.5-13 at pH, alkali resistance is given prominence to, and is also applicable to the features such as alkaline etching.
(4) specific embodiments
Below in conjunction with specific embodiment topic, the invention will be further described, but protection scope of the present invention is not limited in this.
EXAMPLE l:
By 55 grams of formulas (I-1), 45 grams of formulas (III-1), the Dispersant MF of 250 grams, after adding 550 grams of water Mixed Pinyins, grinding distribution is also dry, and get product, this finished product can provide fabric black tone.
Embodiment 2:
By 75 grams of formulas (I-1), 18 grams of formulas (III-1), 7 grams of formulas (V-1), 200 Dispersant MFs, after adding 550 grams of water Mixed Pinyins, grinding distribution is also dry, and get product, this finished product can provide fabric blue color.
Embodiment 3 ~ 32
According to the method described in embodiment 1, unlike adopting the component A of weight shown in table 1, B component and auxiliary agent, slurries are made after the blending that adds water, controlling the solid content of slurries is 35 ~ 45% to be advisable, grinding distribution, drying, obtained dispersed dye, this dyestuff is suitable for trevira and the pre-treatment of BLENDED FABRIC under alkaline condition and dyeing thereof and merges the one-bath one-step dyeing dyeing carried out.
Table 1
Dyeing Example 1
The dispersed dye taking 4 grams of embodiments 1 obtained are dispersed in 500 ml waters, mix, with sheet adjusting PH with base to 12.5 after drawing 20 milliliters with the water of 180 milliliters, put into 4 grams of polyester piece goods, be warming up to 70 DEG C, continue with about 2 DEG C/min gradient increased temperature to 130 DEG C, insulation dyeing 45 minutes.Then be cooled to about 80 DEG C and use hot water wash 10min, dry.The testing method of office (ISO) of adopting international standards and rating scale test its every dyefastness respectively: crock fastness (ISO 105-X12), washing fastness (ISO 105-C03), sublimation fastness (ISO 105-X11), chlorine-resistant water colour fastness (ISO 105-E03), the results are shown in Table 2.
Table 2
Dyeing Example 2
According to the method described in above-mentioned Dyeing Example 1, the dyestuff of preparation in embodiment 2 ~ 32 is adopted to dye respectively, dye level 4.0%, unlike change dyeing pH value, the basically identical indigo plant of dyeing behavior can be obtained equally to black fabric, specifically in table 3.
The composite dispersed black dye that comparative example 1 obtains according to patent CN102161839A embodiment 4 dyes by the mode of Dyeing Example 1 of the present invention, is called for short " D1 ", the results are shown in Table 3.
Comparative example 2: composite dispersed black dye patent CN102746713A embodiment 2 obtained dyes by the mode of Dyeing Example 1 of the present invention, is called for short " D2 ", the results are shown in Table 3.
Comparative example 3: by the dye monomer shown in the dye monomer shown in patent CN101265369A formula (a-1), formula (b-1) and the dye monomer shown in formula (c-2), black dyes is made according to the method for the embodiment of the present application 1, and dye according to the mode of Dyeing Example 1 of the present invention, be called for short " D3 ", the results are shown in Table 3.
Comparative example 4: the composite dispersed deep blue dye that patent CN101649129A embodiment 1 is obtained, and dye according to the mode of Dyeing Example 1 of the present invention, be called for short " D4 ", the results are shown in Table 3.
Comparative example 5 dyes by the mode of the application's Dyeing Example 1 according to the composite dispersed deep blue dye obtained in patent CN101935464A prefabricated 3, is called for short " D5 ", the results are shown in Table 3.
Table 3
Test result shows: not only dyefastness is excellent in acid condition to black dyes for EX-SF DISPERSE BLUE EX-SF 300 of the present invention, and there is excellent dyefastness under strongly alkaline conditions too, in addition, the present invention compares the common alkali resistance dyestuff of documents 1 (D1), when pH > 10, colour fastness is even better.

Claims (10)

1. EX-SF DISPERSE BLUE EX-SF 300 is to a black dye composition, is formed, it is characterized in that: former dyestuff comprises component A and B component by former dyestuff and auxiliary agent Mixed Pinyin, and based on former dyestuff gross weight, the weight percentage of component A is 40 ~ 99%, and the weight percentage of B component is 1 ~ 60%;
Described component A is selected from one or more the combination in lower formula I ~ (II):
In upper formula I ~ (II),
R 1, R 3respective is independently H or C 1~ C 4alkyl;
R 2for cyanoethyl, C 1~ C 4alkyl or benzyl;
R 4for cyanoethyl, C 1~ C 4alkyl, styroyl or hydrocinnamyl;
N is 2 or 3;
Described B component be selected from lower formula III ~ (V) one or more:
In upper formula III ~ (V),
R 5for H, Cl, C 1~ C 4alkyl or C 1~ C 4alkoxyl group;
R 7for H or C 1~ C 4alkyl; R 9for H, Cl or C 1~ C 4alkyl;
R 6, R 8, R 10respective is independently C 1~ C 4alkyl or cyanoethyl;
X 1, X 2respective is independently Cl or Br;
X 3for Cl or Br, X 4for H; Or X 3for NO 2, X 4for H, Cl or Br.
2. EX-SF DISPERSE BLUE EX-SF 300 as claimed in claim 1 is to black dye composition, it is characterized in that: described former dyestuff is made up of component A and B component.
3. EX-SF DISPERSE BLUE EX-SF 300 as claimed in claim 1 is to black dye composition, it is characterized in that: based on former dyestuff gross weight, the weight percentage of component A is preferably 45 ~ 95%, and the weight percentage of B component is preferably 5 ~ 55%.
4. EX-SF DISPERSE BLUE EX-SF 300 as claimed in claim 2 is to black dye composition, it is characterized in that: based on former dyestuff gross weight, the weight percentage of component A is preferably 45 ~ 95%, and the weight percentage of B component is preferably 5 ~ 55%.
5. the EX-SF DISPERSE BLUE EX-SF 300 as described in one of Claims 1 to 4, to black dye composition, is characterized in that: described component A is selected from one of following or wherein two or more mixtures:
6. the EX-SF DISPERSE BLUE EX-SF 300 as described in one of Claims 1 to 4, to black dye composition, is characterized in that: described B component is selected from one of following or wherein two or more mixtures:
7. the EX-SF DISPERSE BLUE EX-SF 300 as described in one of Claims 1 to 4, to black dye composition, is characterized in that: component A is selected from least one compound in formula I; B component is selected from least one compound in formula III and/or at least one compound in formula (V).
8. EX-SF DISPERSE BLUE EX-SF 300 as claimed in claim 7 is to black dye composition, it is characterized in that: described component A is compound shown in formula (I-1), described B component is compound shown in formula (III-1) and/or the shown compound of formula (V-1).
9. the EX-SF DISPERSE BLUE EX-SF 300 as described in one of Claims 1 to 4, to black dye composition, is characterized in that: described auxiliary agent is selected from one of following or its mixture: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products, naphthalene sulfonic acidformaldehyde condensation product, benzyl naphthalene sulfonic formaldehyde condensation compound, sodium lignosulfonate.
10. the EX-SF DISPERSE BLUE EX-SF 300 as described in one of Claims 1 to 4, to black dye composition, is characterized in that: the ratio of the gross weight of auxiliary agent and former dyestuff is 0.2 ~ 5:1.
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101265369A (en) * 2008-05-14 2008-09-17 蓬莱华茂精细化工有限公司 Azo dye composition and application thereof
CN101649129A (en) * 2009-07-30 2010-02-17 浙江龙盛染料化工有限公司 Disperse dye composition suitable for basic dyeing
CN101935464A (en) * 2010-07-30 2011-01-05 杭州吉华江东化工有限公司 Alkali-resistant disperse dye complex
CN102161839A (en) * 2011-02-24 2011-08-24 浙江万丰化工有限公司 Composition of disperse dyes
CN102618079A (en) * 2012-03-07 2012-08-01 浙江万丰化工有限公司 Disperse dye composite, dyeing method and preparation method for disperse dye composite
CN102746713A (en) * 2012-07-10 2012-10-24 浙江龙盛集团股份有限公司 Blue-to-black disperse dye composition

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101265369A (en) * 2008-05-14 2008-09-17 蓬莱华茂精细化工有限公司 Azo dye composition and application thereof
CN101649129A (en) * 2009-07-30 2010-02-17 浙江龙盛染料化工有限公司 Disperse dye composition suitable for basic dyeing
CN101935464A (en) * 2010-07-30 2011-01-05 杭州吉华江东化工有限公司 Alkali-resistant disperse dye complex
CN102161839A (en) * 2011-02-24 2011-08-24 浙江万丰化工有限公司 Composition of disperse dyes
CN102618079A (en) * 2012-03-07 2012-08-01 浙江万丰化工有限公司 Disperse dye composite, dyeing method and preparation method for disperse dye composite
CN102746713A (en) * 2012-07-10 2012-10-24 浙江龙盛集团股份有限公司 Blue-to-black disperse dye composition

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