CN104381305A - Special powder for trapping and killing termites - Google Patents

Special powder for trapping and killing termites Download PDF

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Publication number
CN104381305A
CN104381305A CN201410655912.2A CN201410655912A CN104381305A CN 104381305 A CN104381305 A CN 104381305A CN 201410655912 A CN201410655912 A CN 201410655912A CN 104381305 A CN104381305 A CN 104381305A
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termite
powder
pulvis
ant
ivermectin
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CN104381305B (en
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钱掌清
郭建强
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TONGXIANG TERMITE CONTROL OFFICE
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TONGXIANG TERMITE CONTROL OFFICE
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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Abstract

The invention discloses special powder for trapping and killing termites. The special powder is characterized by comprising the following components in percentage by mass: 2%-16% of fipronil, 0.1%-2% of ivermectin, 0.1%-2% of abamectin, 1.2%-2.8% of azone, 0.1%-1% of ant nest powder and 80%-95% of talcum powder. The special powder has the beneficial effects that 1) the reaction sensitivity of termites can be reinforced by compounding the fipronil with the ivermectin and the abamectin, the drug resistance can be prevented, and the prevention and treatment effects are improved; 2) the defect that an existing drug is rapid to degrade wild drugs is overcome, and the overall killing effect on the termite population is enhanced; 3) compared with a single agent, the production cost can be reduced by combination of three single agents, the dosage is small, and the application cost is reduced; and 4) the powder disclosed by the invention is capable of completely replacing termite poisoning agents in the market at present, and the powder is free of environmental pollution and safe to use.

Description

The special pulvis of termite-killing trapping
Technical field
The invention belongs to termiticides technical field, be specifically related to the special pulvis of a kind of termite-killing trapping.
Background technology
Termite is one of the world five major pest, belong to build a nest occupy life social insect, habit keeps in dark place, move in for a long time nest and ant road dark surrounds in, organize rigorous, divide the work meticulous, destructive power is very powerful.Can the whole plant of moth food, Some Animals source material, meanwhile, the endocrine formic acid of its body, also can corrosion reinforcing bar, makes concrete sex change.Its harmfulness is mainly manifested in: 1, to the destruction of building, particularly to the destruction of post and panel structure, timber buildings, termite is hidden at timber structure internal sabotage or destroy its weight bearing area, house is often caused to collapse suddenly, cause property loss and casualties, because its extension is strong, colony is large, destroy rapidly, can bring about great losses in a short time.2, to the destruction of dykes and dams: at south China, many rivers, reservoir have earth dam, termite colony by these earth dams often perch, and they are in dykes and dams, intensively builds a nest, rapid breeding, ant road extends in all direction, some ant road even inside and outside slope of break-through dykes and dams, when flood season level raises, usually there are pipe leakage feelings, even cause the dike that collapses to break down.Here it is so-called " a solid dyke can collapse because of an ant hole in it ".3, to the harm of crops, forest and horticultural crop: termite can endanger the crops such as sugarcane, peanut, especially very serious to the harm of sugarcane.In addition, termite also has fairly widespread property and seriousness to the harm of forest, fruit tree etc.In addition, termite can also endanger books, historical relic, fabric, weapon, book, buried cable etc., causes heavy losses.
For the harm of termite, market there is the various medicine for termite control, as: Niran, mirex, poison upright stone tablet, chloro fat sulfonamide, ethanol borate ester quinones etc. with poison, that only has Niran and mirex in said medicine goes out that to control effect quite a lot of.And current domestic conventional the have poisoning organochlorine insecticide of accumulation property and the violent arsenic element agent of toxicity and organophosphorus insecticide, effect is controlled better although go out, but it is healthy that Long-Time Service affects people, more seriously cause foul pollution to environment, part medicament has been forbidden by national governments or has been about to forbid.Given this, market occurs employing ivermectin or Avermectin kill ant medicament as special efficacy, with the medicament for killing termite of related auxiliaries compatibility, this kind of termite poisoning agent in actual use, its dosing is comparatively large, and controlling object is limited, cost up, and easily makes termite produce drug resistance, cause the insect killing effect of final termite not good enough, limit applying for a long time of product.
Summary of the invention
For problems of the prior art, the present invention adopts ivermectin, Avermectin and fluorine worm cyanogen composite together as effectively killing ant pulvis, and research is carried out further and choose reasonable to its configuration proportion and related auxiliaries, the technical scheme of the special pulvis of a kind of termite-killing trapping is provided.
The present invention passes through technical scheme and is realized:
The special pulvis of described termite-killing trapping, is characterized in that being made up of the component of following weight percentage: fluorine worm cyanogen 2-16%, ivermectin 0.1-2%, Avermectin 0.1-2%, azone 1.2-2.8%, ant nest powder 0.1-1%, talcum powder 80-95%.
The special pulvis of described termite-killing trapping, is characterized in that being made up of the component of following weight percentage: fluorine worm cyanogen 4-12%, ivermectin 0.5-1.5%, Avermectin 0.5-1.5%, azone 1.5-2.5%, ant nest powder 0.3-0.7%, talcum powder 85-90%.
The special pulvis of described termite-killing trapping, is characterized in that being made up of the component of following weight percentage: fluorine worm cyanogen 6-10%, ivermectin 0.8-1.2%, Avermectin 0.8-1.2%, azone 1.5-2%, ant nest powder 0.4-0.6%, talcum powder 86-90%.
The special pulvis of described termite-killing trapping, is characterized in that being made up of the component of following weight percentage: fluorine worm cyanogen 8%, ivermectin 1%, Avermectin 1%, azone 2%, ant nest powder 0.5%, talcum powder 87.5%.
The proportioning that patent application of the present invention relates to is weight percentage.
Prepared by ant nest powder: termite builds the ant nest in tree root or timber, is taken food the city of rear excreta, wood fibre and gastrointestinal secretions by termite, adopts in ant harm, judges it is wooden ant nest by analysis, after putting it into drying in oven, is ground into fine powder with cracker.
Compared with prior art, the present invention has following beneficial effect:
1) by by fluorine worm cyanogen with ivermectin together with abamectin compounded, termite reaction sensibility can be strengthened, stop medicine resistance ability, raising control efficiency;
2) overcome the defect that existing medicament is fast to field drug degradation, enhance the insect killing effect to termite kind of groups entirety;
3) compared with single dose, three kinds of single dose combinations can reduce production cost, and using dosage is little, saves application cost;
4) pulvis of the present invention can substitute the termite poisoning agent that existing market occurs completely, and non-environmental-pollution, use safety.
Embodiment
Below the present invention is described in further detail, and provides embodiment.
Formula 1: fluorine worm cyanogen 8%, ivermectin 1%, Avermectin 1%, azone 2%, ant nest powder 0.5%, talcum powder 87.5%.
Formula 2: fluorine worm cyanogen 2%, ivermectin 2%, Avermectin 2%, azone 2.8%, ant nest powder 0.2%, talcum powder 91%.
Formula 3: fluorine worm cyanogen 4%, ivermectin 1.5%, Avermectin 1.5%, azone 2.5%, ant nest powder 0.7%, talcum powder 89.8%.
Formula 4: fluorine worm cyanogen 10%, ivermectin 0.8%, Avermectin 0.8%, azone 2%, ant nest powder 0.6%, talcum powder 85.8%.
Formula 5: fluorine worm cyanogen 1%, ivermectin 2.5%, Avermectin 2.5%, azone 2.8%, ant nest powder 1%, talcum powder 90.2%.
Formula 6: ivermectin 1%, Avermectin 1%, azone 2%, ant nest powder 0.5%, talcum powder 95.5%.
Above-mentioned each composition and ratio, adopts common process to mix, after testing, packing.Wherein, formula 1-4 is for being prepared from according to proportioning composition of the present invention, and in formula 5, the content of fluorine worm cyanogen, ivermectin, Avermectin departs from formulation content of the present invention, lacks fluorine worm cyanogen composition in formula 6.
laboratory test
Utilize Workers of Coptotermes formosanus Shiraki to do toxic effect test to the special pulvis of termite-killing trapping of formula 1-6 in indoor, result of the test is as follows.
test medicine
This test medicine is termite-killing trapping tailored flour agent prescription 1-6, provided by Tongxiang City termite control, and before test, sample is installed in the vial that lid built.
test method
2.1 test worm kinds
This termite for test of dusting is Workers of Coptotermes formosanus Shiraki coptotermes formosanusshiraki.With luring material to be masson pine before test pinus massonianal. case of luring lures collection to obtain in field, after luring case to be moved to indoor, to be placed in the environment of temperature 26 ± 1 DEG C, humidity 75 ± 5% two weeks, to adapt to indoor environment in order to termite.
test method
2.2.1 1-6 is filled a prescription to the toxic effect of Workers of Coptotermes formosanus Shiraki
In the culture dish that diameter is 9 cm, move into 100 have been cultivated 2 days Workers of Coptotermes formosanus Shiraki worker ant in indoor separation.With ten thousand/ balance accurately take 15mg pulvis, pulvis is sprayed at equably with it these worker ants with the special instrument that dusts, makes the termite in culture dish be stained with pulvis equably.Then, termite is transferred to surrounding be lined with 3 g fine sands (in 40 DEG C of drying boxes process 24 hours, and cross 60 mesh sieves and moistening with 1 mL distilled water) clean culture dish in, build lid, culture dish is placed in the environment of temperature 26 ± 1 DEG C, humidity 75 ± 5%, observe the termite situation of being knocked down by medicinal powder and being poisoned to death, with need not 100 Workers of Coptotermes formosanus Shiraki worker ants of any pulvis process for contrast.Often process repetition 3 times.During inspection, touch examination worm with blunt-ended forceps, if feeler and the still movable but termite of foot can not normally creep, be judged to knock down, if all parts of examination worm health particularly feeler and foot, without any reaction, are judged to death.
formula 1-6 pulvis toxicity is at the intragroup transmission effect of Workers of Coptotermes formosanus Shiraki
In the culture dish that diameter is 9 cm, move into 100 have been cultivated 2 days Workers of Coptotermes formosanus Shiraki worker ant in indoor separation.With ten thousand/ balance accurately take 15mg pulvis, pulvis is sprayed at equably with it these worker ants with the special instrument that dusts, makes the termite in culture dish be stained with pulvis equably.Then, termite is transferred to surrounding be lined with 3 g fine sands (in 40 DEG C of drying boxes process 24 hours, and cross 60 mesh sieves and moistening with 1 mL distilled water) clean culture dish in, build lid, culture dish is placed in the environment of temperature 26 ± 1 DEG C, humidity 75 ± 5%, observe the termite situation of being knocked down by medicinal powder and being poisoned to death, with need not 100 Workers of Coptotermes formosanus Shiraki worker ants of any pulvis process for contrast.When by the worker ant of process of dusting knock down reach 20% with dead individuals sum time, by the worker ant of wherein 15 still normal activities, be transferred to another culture dish being placed with 100 Workers of Coptotermes formosanus Shiraki worker ants ( φ9 cm, bottom is covered with 2 layers of moistening filter paper) interior breeding observing.When the termite in this culture dish knock down also reach 20% with dead individuals sum time, then by the worker ant of wherein 15 still normal activities, be transferred to another culture dish being placed with 100 Workers of Coptotermes formosanus Shiraki worker ants ( φ9 cm, bottom is covered with 2 layers of moistening filter paper) interior breeding observing.Repeat operation, when the termite mortality in the culture dish being moved into termite is less than 90%, terminate test.In above-mentioned processing procedure, all not spray 100 Workers of Coptotermes formosanus Shiraki worker ants of any medicinal powder for contrast, often process and establish 3 repetitions.In process of the test, in regular check culture dish termite hit Reciprocals sums death toll, termite go down with the criterion of being poisoned to death with test 2.2.1 identical.
result of the test
3.1 formula 1-6 pulvis knocking down and killing activity Workers of Coptotermes formosanus Shiraki worker ant
Result of the test shows, formula 1-4 pulvis all has Workers of Coptotermes formosanus Shiraki worker ant stronger knocks down activity, and the knock down activity of formula 5-6 pulvis to Workers of Coptotermes formosanus Shiraki worker ant is weaker than formula 1-4 pulvis and knocks down activity to Workers of Coptotermes formosanus Shiraki worker ant.Result of the test is in table 1.
The quantity of Workers of Coptotermes formosanus Shiraki worker ant knocked down by table 1 different disposal time formula 1-6 pulvis
As can be seen from Table 1, the worker ant of formula 1 process, the down and out ratio in latter 30 minutes that processes is less than 10%, be 6.3%, 100% goes down, and needs 250 minutes, the worker ant of formula 2-4 process, the down and out ratio in latter 30 minutes that processes all is greater than 10%, and 180 minutes all examination individualities that supply all are gone down after treatment.Due to pulvis be used as termite go out control time, need there is the longer stock time by the worker ant of process of being dusted, medicinal powder is taken back in nest, to pass to same nest individual, and therefore, from this angle of knocking down property, 1 pulvis of filling a prescription is more suitable for for the production of upper termite control.And the worker ant of 5-6 process of filling a prescription, after 80 minutes, knock down quantity constant, and illustrate that its drug effect is weak, action time is short.
From lethal, the speed of 1 pulvis lethal Workers of Coptotermes formosanus Shiraki worker ant of filling a prescription is slightly faster than the speed of the lethal Workers of Coptotermes formosanus Shiraki worker ant of formula 2-4 pulvis.Result of the test is in table 2.
The quantity of the lethal Workers of Coptotermes formosanus Shiraki worker ant of table 2 different disposal time formula 1-6 pulvis
As can be seen from Table 2, process after 30 minutes, the worker ant ratio that 1 pulvis of filling a prescription is lethal is 0.3%, and the lethal worker ant ratio of formula 2-4 pulvis is all 0.2%; Process after 80 minutes, the worker ant ratio that 1 pulvis of filling a prescription is lethal is 30.0%, and the worker ant ratio that formula 2-4 pulvis is lethal is respectively 25.6%, 20.6%, 22.5%; Process after 280 minutes, the lethality rate of formula 1-4 pulvis is respectively 99.3%, 92.4%, 93.5%, 93.0%; After 330 minutes, the lethality rate of 1 pulvis of filling a prescription is 100%, and the formula 2-4 pulvis 100% lethality rate time used is 370 minutes.And 5-6 pulvis of filling a prescription, process after 80 minutes, after lethality rate is 0.1%, 250 minutes, lethality rate is respectively 28.1% and 24.1%, and along with the prolongation of time, its lethality rate does not change, and illustrates that the duration of efficacy of formula 5-6 pulvis is shorter.
fill a prescription 1 pulvis toxicity at the intragroup transmission effect of Workers of Coptotermes formosanus Shiraki
Table 3, table 4 and table 5 be formula 1 pulvis toxicity contact in Workers of Coptotermes formosanus Shiraki colony transmit time knock down the situation with lethal Workers of Coptotermes formosanus Shiraki worker ant.In table, data show, the mode that the toxicity of 1 pulvis of filling a prescription can be transmitted by contact in Workers of Coptotermes formosanus Shiraki colony is transmitted once.
What Workers of Coptotermes formosanus Shiraki worker ant after 1 pulvis effect different time filled a prescription by table 3 hits Reciprocals sums death toll
Table 4 fill a prescription 1 pulvis process worker ant first time transfer after Workers of Coptotermes formosanus Shiraki worker ant hit Reciprocals sums death toll
After 1 pulvis process worker ant second time of filling a prescription table 5 shifts, Workers of Coptotermes formosanus Shiraki worker ant hits Reciprocals sums death toll
4 conclusions
Result of the test shows, formula 1-4 pulvis all has stronger ability of knocking down and killing activity to Workers of Coptotermes formosanus Shiraki worker ant, and Comparatively speaking, the ability of knocking down of 1 pulvis of filling a prescription is less better, and it is more suitable for going out for the production of upper termite controlling work.In the identical time, the ratio of formula 1 lethal Workers of Coptotermes formosanus Shiraki worker ant is higher.
Further toxicity is transmitted result of the test and is shown, the toxicity of 1 pulvis of filling a prescription can be transmitted once in Workers of Coptotermes formosanus Shiraki colony (to be transferred to after in 100 other Workers of Coptotermes formosanus Shiraki worker ant colonies with the get along worker ant of a period of time of contamination termite for 15, these worker ants can be caused all dead), illustrate that formula 1 pulvis has larger practical value.
field test
After having applied for " research of strange land attract termites harm building construction prevention and controls " project plan to Jiaxing City Technology Bureau on November 2nd, 2012, I organize seminar personnel to the tight Buddhist temple of same good fortune good fortune, the Tongxiang Feng Ming Buddhist temple of Tongxiang cultural relics protection unit; Crossdrift Feng Zi happy edge edge hall; High bridge San Cun village Zhou Jiaguo villager organizes peasant room; The large of Chinese parasol tree city sends out villa quarter; Community, the middle rainbow world etc. is carried out scene and is gone to the spot to make an investigation, and is familiar with environment, understands and grasp the actions such as the termite damage history of test site, termite activity kind, ant evil degree.
One, the Embedment and installation work of termite monitoring-control device
Use refreshing net board termite monitoring-control device and after being bait with pine, the Embedment and installation work of starting apparatus determining.Each test site adopts burying of planning setting in the building construction of termitid monitoring controller place to put optimum distance and route, mensuration through field attract termites: to have termite damage in building construction, in outdoor from 0.5 to 1 meter, wall, it is a set of that row distance 2 to 3 meters buries termite monitoring-control device underground, burying termite device underground will along building construction surrounding, in newly-built community bury underground termite monitoring-control device can be set as 5 meters a set of, every hundred square meters in greenery patches put four covers.Termite monitoring-control device buries overview underground in table 6.
Overview buried underground by table 6 termite monitoring-control device
Two, termite monitoring-control device lures collection termite situation
Termite monitoring-the control device buried underground is made regular check on, record termite trapping situation, in table 7:
Table 7 termite monitoring---control device lures collection termite information slip
Three, pulvis drug effect situation
Select termite to haunt obvious three tight Buddhist temples of test site good fortune, Feng Ming Buddhist temple, high bridge town San Cun village Zhou Jiaguo villager group, carry out test of dusting.The device luring collection to termite is divided into two groups, be respectively experimental group and control group, on March 31st, 2014, experimental group is dusted process, wherein, the tight Buddhist temple of good fortune is formula 1 pulvis, and Feng Ming Buddhist temple is formula 2 pulvis, San Cun village, high bridge town Zhou Jiaguo villager group is formula 3 pulvis, and control group does not take any measure.Carry out first time drug effect inspection to device after dusting 15-20 days, carry out the inspection of second time drug effect after dusting three months, to represent with or without termite live body in device, pulvis drug effect is in table 8.
Table 8 pulvis drug effect summary sheet
Four, dusting device lures collection rate situation again
In dispenser after 1 month, attractant means is again buried underground on device for administration of drugs limit, further inspection medicine cure of termite whole structure, dispenser checked attractant means again after 3 months, take measures 2 to the device dusted, the dusting device that wherein the tight Buddhist temple of good fortune, San Cun village, high bridge town Zhou Jiaguo villager organize two test sites carries out bait replacing, the dusting device of Feng Ming Buddhist temple Embedment and installation again nearby, within 20 days, check that termite lures collection situation, again in table 9 afterwards.
Table 9 termite monitoring---control device lures collection termite information slip again
Five, conclusion
By organizing three test sites carry out termite monitoring the tight Buddhist temple of good fortune, Feng Ming Buddhist temple, high bridge San Cun village Zhou Jiaguo villager---control device lures collection termite, sees that ant is dusted, again lures the research of collection situation, we find, a small amount of termite live body is still had to exist behind device 15-20 days of spray formula 1 pulvis, exist without termite live body behind spray formula 2 and formula 3 pulvis device 15-20 days, after dusting 3 months, all exist without termite live body in device; After the device of spray formula 1 pulvis changes bait, termite lures collection rate to be zero again, the device of spray formula 2 reinstall and the device that sprays formula 3 pulvis change bait after termite again lure collection rate to be respectively 0.45% and 0.61%.As can be seen here, the fill a prescription killing activity of pulvis dialogue ant of the present invention is all comparatively strong, but the knock down ability of formula 1 pulvis to termite is less better, and therefore, the termite be more suitable in production is gone out and controls.
In addition, we find, check after dusting 3 months that compared with checking with after 15-20 days, control group termite survival rate also obviously declines, we analyze, and may be that cause humidity too high, transfer phenomena appears in termite because moisture is sufficient.

Claims (4)

1. the special pulvis of termite-killing trapping, is characterized in that being made up of the component of following weight percentage: fluorine worm cyanogen 2-16%, ivermectin 0.1-2%, Avermectin 0.1-2%, azone 1.2-2.8%, ant nest powder 0.1-1%, talcum powder 80-95%.
2. the special pulvis of termite-killing trapping according to claim 1, is characterized in that being made up of the component of following weight percentage: fluorine worm cyanogen 4-12%, ivermectin 0.5-1.5%, Avermectin 0.5-1.5%, azone 1.5-2.5%, ant nest powder 0.3-0.7%, talcum powder 85-90%.
3. the special pulvis of termite-killing trapping according to claim 1, is characterized in that being made up of the component of following weight percentage: fluorine worm cyanogen 6-10%, ivermectin 0.8-1.2%, Avermectin 0.8-1.2%, azone 1.5-2%, ant nest powder 0.4-0.6%, talcum powder 86-90%.
4. the special pulvis of termite-killing trapping according to claim 1, is characterized in that being made up of the component of following weight percentage: fluorine worm cyanogen 8%, ivermectin 1%, Avermectin 1%, azone 2%, ant nest powder 0.5%, talcum powder 87.5%.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105211064A (en) * 2015-10-26 2016-01-06 广东省昆虫研究所 A kind of termite bait formulation containing ethyl pleocidin
CN106135259A (en) * 2016-07-01 2016-11-23 安徽喜丰收农业科技有限公司 A kind of efficient insecticide powder killing red fire ant
CN107751223A (en) * 2017-11-07 2018-03-06 江苏克胜作物科技有限公司 A kind of paichongding aqueous suspension agent containing alkaline antioxidant
CN111226960A (en) * 2020-03-23 2020-06-05 邱让先 Siberian cocklebur fruit plant termite killing powder
CN111296503A (en) * 2020-03-23 2020-06-19 邱让先 Pinellia ternate termite-killing powder

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1476758A (en) * 2003-07-01 2004-02-25 德清县白蚁防治研究所 Poison powder preparation for termite
CN1759678A (en) * 2005-11-01 2006-04-19 黄求应 Environmental protection type attractant for killing termites
CN101861876A (en) * 2010-06-02 2010-10-20 柳州市白蚁防治所 Soil termite trapping medicine and soil termite trapping method by using the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1476758A (en) * 2003-07-01 2004-02-25 德清县白蚁防治研究所 Poison powder preparation for termite
CN1759678A (en) * 2005-11-01 2006-04-19 黄求应 Environmental protection type attractant for killing termites
CN101861876A (en) * 2010-06-02 2010-10-20 柳州市白蚁防治所 Soil termite trapping medicine and soil termite trapping method by using the same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105211064A (en) * 2015-10-26 2016-01-06 广东省昆虫研究所 A kind of termite bait formulation containing ethyl pleocidin
CN106135259A (en) * 2016-07-01 2016-11-23 安徽喜丰收农业科技有限公司 A kind of efficient insecticide powder killing red fire ant
CN107751223A (en) * 2017-11-07 2018-03-06 江苏克胜作物科技有限公司 A kind of paichongding aqueous suspension agent containing alkaline antioxidant
CN111226960A (en) * 2020-03-23 2020-06-05 邱让先 Siberian cocklebur fruit plant termite killing powder
CN111296503A (en) * 2020-03-23 2020-06-19 邱让先 Pinellia ternate termite-killing powder

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