CN104377367A - Method for preparing a hydrogen fuel cell membrane electrode - Google Patents
Method for preparing a hydrogen fuel cell membrane electrode Download PDFInfo
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- CN104377367A CN104377367A CN201410568683.0A CN201410568683A CN104377367A CN 104377367 A CN104377367 A CN 104377367A CN 201410568683 A CN201410568683 A CN 201410568683A CN 104377367 A CN104377367 A CN 104377367A
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- membrane electrode
- catalyst
- proton exchange
- fuel cell
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8875—Methods for shaping the electrode into free-standing bodies, like sheets, films or grids, e.g. moulding, hot-pressing, casting without support, extrusion without support
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
The invention discloses a method for preparing a hydrogen fuel cell membrane electrode. Catalyst raw materials are all prepared onto a proton exchange membrane, so that the utilization rate of the catalyst in the membrane electrode is increased. The method is simple, easy to operate, high in repeatability, environmentally-friendly, and good in mass production and business promotion. In the finally obtained membrane electrode, the hole diameter is large so that the resistance of gas mass transfer is reduced, and the performance of the membrane electrode is improved.
Description
Technical field
The present invention relates to a kind of preparation method of hydrogen fuel cell membrane electrode.
Background technology
Hydrogen fuel cell take hydrogen as fuel, chemical energy is directly converted to the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of electric energy, have quick startup, can the feature such as high, the environmental friendliness of room temperature-operating, simple, the theoretical specific energy density of structure, be especially suitable for use as compact power, electric motor car power electric source capsule dispersion power station etc., have broad application prospects.
Membrane electrode is the core component of hydrogen fuel cell, and its performance quality directly affects performance and the stability of battery.Membrane electrode is made up of proton exchange membrane and the catalyst layer respectively in these proton exchange membrane both sides and gas diffusion layers usually, catalyst layer is the important place of hydrogen fuel cell generation electrochemical catalysis reaction, therefore, its catalytic efficiency determines the performance of fuel cell to a great extent.The key improving catalyst layer catalyzes efficiency is the three-phase reaction interface that will increase nano-noble metal catalyst particle surface and reacting gas, proton and electronics.Particularly, hydrogen reaction gas arrives noble metal catalyst particles surface by gas passage, through catalytic reaction, produce proton and electronics, the proton produced needs to be transmitted to proton exchange membrane direction by the proton channel of the proton conductor network struction in catalyst layer, the conductive network directional later exhaust diffusion layer that electronics is then built by catalyst carrier, if there is a passage obstructed, then electrochemical reaction of fuel battery will be obstructed.But conventional membrane electrode assembly preparation is difficult to form good three phase boundary between catalyst and proton exchange membrane, this reduces the utilance of catalyst, increases the consumption of catalyst, reduce the performance of battery.In order to improve the performance of fuel cell membrane electrode, the utilance of catalyst need be improved.Simultaneously due to proton exchange membrane easily damage, the feature such as not easy to operate, make the preparation technology of membrane electrode become complicated, reduce the continuous prodution of membrane electrode, improve technique preparation cost.
Catalyst is mainly transferred on diffusion layer and is formed Catalytic Layer by traditional method for preparing membrane electrode, then diffusion layer, Catalytic Layer, proton exchange membrane is forced together through HTHP by heat pressing process, is prepared into membrane electrode.But this kind prepares the method for Catalytic Layer, catalyst feed leaks in the hole of diffusion layer unavoidably, has both affected the pore structure in diffusion layer, again reduces the utilance of catalyst, is difficult to reduce fuel cell cost.Adopt this kind by diffusion layer, the method for Catalytic Layer together with proton exchange membrane hot pressing, improve difficulty of processing, the rate of finished products of battery is low, and product is single simultaneously.
Along with the development of technology, after the nineties in 20th century, people attempt directly Catalytic Layer being applied in proton exchange membrane, namely proton exchange membrane core component CCM (catalyst coated membrane) is prepared, this method can improve the utilance of catalyst, reduces the loading of Pt further.Catalyst granules is directly contacted with film by Nafion ion, thus improves proton-conducting, and CCM technology maintains original gap structure, and gas is spread and is more prone to, the MEA that MEA Performance Ratio obtained like this uses conventional method to obtain increases.
US Patent No. 5211984, US6847518 disclose a kind of transfer printing and prepare membrane electrode, Chinese patent CN1560949, CN1862855 also have similar approach, catalyst slurry is first coated onto on transfer medium by described method, after drying, two panels is scribbled anode, the transfer medium of cathod catalyst and the hot pressing of a slice proton exchange membrane respectively, after peeling off transfer medium, obtain membrane electrode assembly.Catalytic Layer obtained by the method is thinner; reduce the consumption of catalyst; Catalytic Layer and proton exchange membrane have good contact; decrease the impact of solvent on proton exchange membrane; the monocell of assembling has higher power density, but its weak point is that temperature and pressure is on film and have impact to catalyst adhesive strength on film and be difficult to control, and when hot pressing; the edge that film contacts with transfer medium, due to discontinuity, usually can be destroyed.In addition, in transfer process, because hot pressing makes partially catalyzed agent be bonded on transfer medium, the utilance of catalyst is declined, and meanwhile, transfer medium often can not reuse because hot pressing deforms, and increases preparation cost, whole complex technical process.
Chinese patent CN1838456N adopts direct spraying legal system for fuel cell membrane electrode, fixed frame is adopted to fix proton exchange membrane, this proton exchange membrane is through preliminary treatment, then volatilize in spraying process with the solvent of infrared lamp and mercury lamp promoting catalyst slurry, slurries are sprayed on the both sides of film respectively, with vacuum treatment, solidification Catalytic Layer, but still can not effectively solve the swelling of proton exchange membrane, and the Catalytic Layer after cryogenic vacuum process is easier to depart from proton exchange membrane, reduce the useful life of electrode.
Chinese patent CN200610035275.4 discloses a kind of method that direct spraying prepares fuel cell membrane electrode, after described method comprises proton exchange membrane preliminary treatment, be fixed in a film fixture, then under light illumination catalyst slurry is painted on the two sides of proton exchange membrane, obtains through low-temperature vacuum drying.The obtained membrane electrode of the method solves the swelling problem of proton exchange membrane, but due to through low-temperature vacuum drying process, complex process will will be there is after spraying, deficiency not easy to operate, manufacturing cycle is long to proton exchange membrane preliminary treatment.
Chinese patent CN200810024885.3 provides a kind of preparation technology of membrane electrode of fuel batter with proton exchange film, described method is for adopting adhesive tape or rubber slab by proton exchange membrane Four built in boundaries, fix proton exchange membrane at relatively high temperatures, solve the swelling problem of proton exchange membrane.In the spraying process of membrane electrode, by regulating the evaporation rate of catalyst slurry, the heating-up temperature of proton exchange membrane, control the swelling of proton exchange membrane, make catalyst even application on film, improve that proton exchange membrane in preparation process is swelling, crumple, catalyst amount cross high deficiency, but weak point film is fixed film device and is too relied on manual operation, swelling could the taking off with fixed head of proton exchange membrane need be tied up with solvent, there is Catalytic Layer contraposition to be forbidden, complex process and production efficiency low wait not enough.
Therefore though the method preparing hydrogen fuel cell membrane electrode of the prior art is many, but all there is such or such drawback, need improvement badly.
Summary of the invention
For solving the deficiencies in the prior art; the object of the present invention is to provide a kind of preparation method of hydrogen fuel cell membrane electrode; obtained membrane electrode is smooth, catalyst uniformity is good and catalytic amount controllable precision is high; there is the advantages such as technique is simple, repeatable by force, manufacturing cycle is short, environmental pollution is little; be conducive to scale continuous seepage, enhance productivity.
In order to realize above-mentioned target, the present invention adopts following technical scheme:
A preparation method for hydrogen fuel cell membrane electrode, comprises the steps:
S1, catalyst and proton exchange film resin to be added in vessel, then add dispersant in vessel, drop into pore creating material again after mixing, then utilize ultrasonic vibration or cell pulverization method to carry out mechanical mixture and be uniformly dispersed obtaining catalyst slurry; Wherein, the mass ratio of catalyst and proton exchange film resin is 1:1-1:10, dispersant is alcohols and water is the proportions of 1:1-100:1 in mass ratio, and the mass ratio of dispersant and catalyst is 30:1-100:1, and the mass ratio of pore creating material and proton exchange film resin is 10:1-1:10;
S2, to utilize film fixture proton exchange membrane to be fixed smooth, be positioned on heating platform, under air or nitrogen atmosphere, the catalyst slurry adopting automation spray painting apparatus to be prepared by step S1 is painted on the one side of proton exchange membrane, solidify simultaneously, complete the preparation of the membrane electrode of one side spraying catalyst; Wherein, the flow velocity of catalyst slurry is 1-30mL/min, and the temperature of heating platform is 50-150 DEG C;
After S3, the membrane electrode obtained by step S2 overturn, repeat step S2, spray catalyst slurry at the another side of proton exchange membrane and solidify, obtained membrane electrode.
In the spraying of step S2 and S3, keeping membrane electrode smooth, by controlling the technological parameters such as above-mentioned flow velocity, temperature, regulating the evaporation rate of catalyst slurry, the heating-up temperature of proton exchange membrane, thus control the swelling of proton exchange membrane, make catalyst slurry even application on film.
Preferably, in abovementioned steps S1, catalyst is the one in Pt/C, Pt or PtM/C, and wherein M is Ru or Pd.Pt/C represents platinum C catalyst, is a kind of compound of platinum dopant carbon dust.
Alcohols in foregoing dispersant is: one or both in methyl alcohol, ethanol, ethylene glycol, isopropyl alcohol and glycerol.
Aforementioned proton exchange film resin is the polymer with proton exchange function, as the nafion resin of E.I.Du Pont Company.
In abovementioned steps S2, proton exchange membrane is perfluorosulfonic acid proton exchange film.
Preferably, aforementioned pore creating material is: the one in carbonic hydroammonium, ammonium oxalate or sodium chloride.
In abovementioned steps S2, automation spray painting apparatus is ultrasonic spraying apparatus.
In abovementioned steps S3, film fixture is the plane framework of non-metallic material.
Usefulness of the present invention is:
1, in membrane electrode, catalyst utilization is high: by Catalytic Layer preparation on the gas diffusion, catalyst feed leaks in the hole of diffusion layer traditional method unavoidably, has both affected the pore structure in diffusion layer, again reduces the utilance of catalyst; And the present invention is when preparing pole catalyze layer, catalyst raw material is all prepared in proton exchange membrane, avoids the shortcoming of conventional method, reduces catalyst load amount, carries high performancely reducing cost simultaneously, possesses business promotion advantage.
2, preparation technology is simple, is conducive to batch production: it is simple that slurries prepare solvent for use system, directly uses proton exchange membrane, and without the need to carrying out preliminary treatment to proton exchange membrane, spraying terminates rear taking-up product and is membrane electrode product, without the need to reprocessing.
3, membrane electrode can be used as an independently assembly: conventional method prepare using low for the membrane electrode rate of finished products of proton exchange membrane, diffusion layer, catalyst three-in-one structure, affect catalyst layer structure and can only as single product, pole catalyze layer prepared by the inventive method can be used as an independently assembly, have that performance is good, the strong feature of stability, can mate from different diffusion layer and be suitable for.
4, the aperture in membrane electrode is large, and membrane electrode performance is good: the pore creating material heat resolve process added during Kaolinite Preparation of Catalyst slurries forms certain aperture structure in the electrodes, reduces gas transfer resistance, improves membrane electrode performance.
5, the reagent adopted in Kaolinite Preparation of Catalyst slurry method of the present invention has pollution-free, lower-price characteristic, is highly suitable for batch production, is conducive to reducing costs.
6, adopt film fixture, Catalytic Layer contraposition is accurate, simple to operate, and the problems such as swelling, the crumple of proton exchange membrane effectively avoided by heating in vacuum platform.
7, adopt automation spray painting apparatus, by controling parameters, catalyst loading controllable precision is high and homogeneity good.
To sum up, preparation method of the present invention has that technique is simple, easy and simple to handle, repeatable strong, environmental friendliness, catalyst homogeneity are high and the features such as the membrane electrode superior performance of preparation, can carry out producing in batches and business promotion.
Accompanying drawing explanation
Fig. 1 is the polarization curve of the membrane electrode assembling monocell of embodiment 1;
Fig. 2 is the polarization curve of the membrane electrode assembling monocell of embodiment 2;
Fig. 3 is the Performance comparision figure of the membrane electrode assembling monocell of embodiment 2 and embodiment 3;
Fig. 4 is the polarization curve of the membrane electrode assembling monocell of embodiment 4;
Fig. 5 is the polarization curve of the membrane electrode assembling monocell of embodiment 5;
Fig. 6 is the consistency of performance curve chart of the different clipping regions membrane electrode assembling monocell of embodiment 2.
Embodiment
Below in conjunction with the drawings and specific embodiments, concrete introduction is done to the present invention.
Without specified otherwise in the present invention, each raw material is commercial.
In embodiment 1-5, when detecting membrane electrode performance, test condition is: battery temperature is 45 DEG C, directly logical hydrogen and air, H
2/ Air metering is than being 1:7.
embodiment 1
S1, the nafion resin that catalyst Pt Ru and E.I.Du Pont Company produce to be added in vessel, then add dispersant in vessel, after mixing, utilize ultrasonic vibration method to carry out mechanical mixture and be uniformly dispersed obtaining catalyst slurry; Wherein, the mass ratio of catalyst Pt Ru and nafion resin is 1:3.5, and dispersant is isopropyl alcohol and water is the proportions of 5:1 in mass ratio, and the mass ratio of dispersant and catalyst is 60:1;
S2, to utilize film fixture proton exchange membrane to be fixed smooth, be positioned on heating platform, in a nitrogen atmosphere, the catalyst slurry adopting automation spray painting apparatus to be prepared by step S1 is painted on the one side of proton exchange membrane, solidify simultaneously, complete the preparation of the membrane electrode of one side spraying catalyst; Wherein, the flow velocity of catalyst slurry is 12mL/min, and the temperature of heating platform is 50 DEG C;
After S3, the membrane electrode obtained by step S2 overturn, repeat step S2, spray catalyst slurry at the another side of proton exchange membrane and solidify, obtained membrane electrode.
The mea that this embodiment is obtained is filled on monocell, and detect its performance, test result is shown in Fig. 1, and as shown in Figure 1, under above-mentioned test condition, when voltage is 0.6V, the power density of monocell reaches 0.505W/cm
2, superior performance.
embodiment 2
S1, the nafion resin that catalyst Pt and E.I.Du Pont Company are produced to be added in vessel, then add dispersant in vessel, after mixing, then utilize ultrasonic vibration method to carry out mechanical mixture and be uniformly dispersed obtaining catalyst slurry; Wherein, the mass ratio of catalyst Pt and nafion resin is 1:4.2, and dispersant is ethanol and water is the proportions of 10:1 in mass ratio, and the mass ratio of dispersant and catalyst is 80:1;
S2, to utilize film fixture proton exchange membrane to be fixed smooth, be positioned on heating platform, in a nitrogen atmosphere, the catalyst slurry adopting automation spray painting apparatus to be prepared by step S1 is painted on the one side of proton exchange membrane, solidify simultaneously, complete the preparation of the membrane electrode of one side spraying catalyst; Wherein, the flow velocity of catalyst slurry is 18mL/min, and the temperature of heating platform is 95 DEG C;
After S3, the membrane electrode obtained by step S2 overturn, repeat step S2, spray catalyst slurry at the another side of proton exchange membrane and solidify, obtained membrane electrode.
The mea that this embodiment is obtained is filled on monocell, and detect its performance, test result is shown in Fig. 2, and as shown in Figure 2, under above-mentioned test condition, when voltage is 0.6V, the power density of monocell reaches 0.5W/cm
2, superior performance.
embodiment 3
S1, the nafion resin that catalyst Pt and E.I.Du Pont Company are produced to be added in vessel, then add dispersant in vessel, drop into pore creating material carbonic hydroammonium again after mixing, then utilize ultrasonic vibration method to carry out mechanical mixture and be uniformly dispersed obtaining catalyst slurry; Wherein, the mass ratio of catalyst Pt and nafion resin is 1:4.2, and dispersant is ethanol and water is the proportions of 10:1 in mass ratio, and the mass ratio of dispersant and catalyst is 80:1, and the mass ratio of pore creating material and nafion resin is 10:1;
S2, to utilize film fixture proton exchange membrane to be fixed smooth, be positioned on heating platform, in a nitrogen atmosphere, the catalyst slurry adopting automation spray painting apparatus to be prepared by step S1 is painted on the one side of proton exchange membrane, solidify simultaneously, complete the preparation of the membrane electrode of one side spraying catalyst; Wherein, the flow velocity of catalyst slurry is 18mL/min, and the temperature of heating platform is 95 DEG C;
After S3, the membrane electrode obtained by step S2 overturn, repeat step S2, spray catalyst slurry at the another side of proton exchange membrane and solidify, obtained membrane electrode.
The mea that this embodiment is obtained is filled on monocell, and detect its performance, test result is shown in Fig. 3, and when voltage is 0.6V, the power density of monocell reaches 0.545W/cm
2, performance is outstanding especially.
In order to set forth the present invention better, list the test result of embodiment 2 in Fig. 3 in the lump with the test result of embodiment 3 to compare to facilitate, as seen from Figure 3, add carbonic hydroammonium as after pore creating material, the performance of membrane electrode is promoted further, power density under equal voltage conditions is more superior compared to the embodiment 2 not adding pore creating material, this is because after pore creating material adds, along with pore creating material along with spraying-and-heating is decomposed to form more comparatively macroscopic void, be beneficial to ventilation, decrease gas transfer resistance, so performance is had been further upgraded.
embodiment 4
S1, the nafion resin that catalyst Pt/C and E.I.Du Pont Company produce to be added in vessel, then add dispersant in vessel, drop into pore creating material ammonium oxalate again after mixing, then utilize ultrasonic vibration method to carry out mechanical mixture and be uniformly dispersed obtaining catalyst slurry; Wherein, the mass ratio of catalyst Pt/C and nafion resin is 1:1, and dispersant is ethanol and water is the proportions of 80:1 in mass ratio, and the mass ratio of dispersant and catalyst is 30:1, and the mass ratio of pore creating material and nafion resin is 1:1;
S2, to utilize film fixture proton exchange membrane to be fixed smooth, be positioned on heating platform, in air atmosphere, the catalyst slurry adopting automation spray painting apparatus to be prepared by step S1 is painted on the one side of proton exchange membrane, solidify simultaneously, complete the preparation of the membrane electrode of one side spraying catalyst; Wherein, the flow velocity of catalyst slurry is 25mL/min, and the temperature of heating platform is 150 DEG C;
After S3, the membrane electrode obtained by step S2 overturn, repeat step S2, spray catalyst slurry at the another side of proton exchange membrane and solidify, obtained membrane electrode.
The mea that this embodiment is obtained is filled on monocell, and detect its performance, test result is shown in Fig. 4, and as shown in Figure 4, under above-mentioned test condition, when voltage is 0.6V, the power density of monocell is 0.48W/cm
2, superior performance.
embodiment 5
S1, the nafion resin that catalyst Pt/C and E.I.Du Pont Company produce is added in vessel, dispersant is added again in vessel, drop into pore creating material carbonic hydroammonium again after mixing, then utilize ultrasonic vibration method to carry out mechanical mixture and be uniformly dispersed obtaining catalyst slurry; Wherein, the mass ratio of catalyst Pt/C and nafion resin is 1:10, and dispersant is ethylene glycol and water is the proportions of 6:1 in mass ratio, and the mass ratio of dispersant and catalyst is 60:1, and the mass ratio of pore creating material and nafion resin is 1:10;
S2, to utilize film fixture proton exchange membrane to be fixed smooth, be positioned on heating platform, in air atmosphere, the catalyst slurry adopting automation spray painting apparatus to be prepared by step S1 is painted on the one side of proton exchange membrane, solidify simultaneously, complete the preparation of the membrane electrode of one side spraying catalyst; Wherein, the flow velocity of catalyst slurry is 30mL/min, and the temperature of heating platform is 110 DEG C;
After S3, the membrane electrode obtained by step S2 overturn, repeat step S2, spray catalyst slurry at the another side of proton exchange membrane and solidify, obtained membrane electrode.
The mea that this embodiment is obtained is filled on monocell, and detect its performance, test result is shown in Fig. 5, and as shown in Figure 5, under above-mentioned test condition, when voltage is 0.6V, the power density of monocell is 0.47W/cm
2, superior performance.
In addition, as aforementioned, the thickness of the membrane electrode that method of the present invention obtains is homogeneous, the stability of performance is high, as seen from Figure 6, the performance of the membrane electrode of the different Crop Areas that embodiment 2 is obtained is very consistent, and performance test curve is almost overlapping, the membrane electrode that visible the method obtains catalyst homogeneity is everywhere high, and thus membrane electrode stability is strong.
More than show and describe general principle of the present invention, principal character and advantage.The technical staff of the industry should understand, and above-described embodiment does not limit the present invention in any form, the technical scheme that the mode that all employings are equal to replacement or equivalent transformation obtains, and all drops in protection scope of the present invention.
Claims (8)
1. a preparation method for hydrogen fuel cell membrane electrode, is characterized in that, comprises the steps:
S1, catalyst and proton exchange film resin to be added in vessel, then add dispersant in vessel, drop into pore creating material again after mixing, mechanical mixture is also uniformly dispersed and obtains catalyst slurry; Wherein, the mass ratio of catalyst and proton exchange film resin is 1:1-1:10, dispersant is alcohols and water is the proportions of 1:1-100:1 in mass ratio, and the mass ratio of dispersant and catalyst is 30:1-100:1, and the mass ratio of pore creating material and proton exchange film resin is 10:1-1:10;
S2, to utilize film fixture proton exchange membrane to be fixed smooth, be positioned on heating platform, under air or nitrogen atmosphere, the catalyst slurry adopting automation spray painting apparatus to be prepared by step S1 is painted on the one side of proton exchange membrane, solidify simultaneously, complete the preparation of the membrane electrode of one side spraying catalyst; Wherein, the flow velocity of catalyst slurry is 1-30mL/min, and the temperature of heating platform is 50-150 DEG C;
After S3, the membrane electrode obtained by step S2 overturn, repeat step S2, spray catalyst slurry at the another side of proton exchange membrane and solidify, obtained membrane electrode.
2. the preparation method of a kind of hydrogen fuel cell membrane electrode according to claim 1, is characterized in that, in described step S1, catalyst is the one in Pt/C, Pt or PtM/C, and wherein M is Ru or Pd.
3. the preparation method of a kind of hydrogen fuel cell membrane electrode according to claim 1, it is characterized in that, the alcohols in described dispersant is: one or both in methyl alcohol, ethanol, ethylene glycol, isopropyl alcohol and glycerol.
4. the preparation method of a kind of hydrogen fuel cell membrane electrode according to claim 1, is characterized in that, described proton exchange film resin is the polymer with proton exchange function.
5. the preparation method of a kind of hydrogen fuel cell membrane electrode according to claim 4, is characterized in that, in described step S2, proton exchange membrane is perfluorosulfonic acid proton exchange film.
6. the preparation method of a kind of hydrogen fuel cell membrane electrode according to claim 1, it is characterized in that, described pore creating material is: the one in carbonic hydroammonium, ammonium oxalate or sodium chloride.
7. the preparation method of a kind of hydrogen fuel cell membrane electrode according to any one of claim 1-6, is characterized in that, in described step S2, automation spray painting apparatus is ultrasonic spraying apparatus.
8. the preparation method of a kind of hydrogen fuel cell membrane electrode according to claim 7, is characterized in that, in described step S3, film fixture is the plane framework of non-metallic material.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105091897A (en) * | 2015-09-01 | 2015-11-25 | 王小安 | Map interest point setting method |
| CN109560292A (en) * | 2018-10-25 | 2019-04-02 | 芬华氢能研究院江苏有限公司 | A kind of preparation method of hydrogen fuel cell membrane electrode |
| CN109713321A (en) * | 2018-12-29 | 2019-05-03 | 上海交通大学 | A kind of adjustable membrane electrode of pore structure and preparation method thereof |
| CN113066999A (en) * | 2021-03-22 | 2021-07-02 | 上海捷氢科技有限公司 | Porous electrode of proton exchange membrane fuel cell and preparation method thereof |
| CN114264709A (en) * | 2021-11-09 | 2022-04-01 | 深圳航天科技创新研究院 | Method for measuring mass transfer resistance of gas diffusion layer of hydrogen fuel cell and application thereof |
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| JP2003317750A (en) * | 2002-04-24 | 2003-11-07 | Jsr Corp | Manufacturing method of stacked body |
| CN1713424A (en) * | 2004-06-23 | 2005-12-28 | 比亚迪股份有限公司 | Electrode production of fuel battery membrane with proton exchange membrane |
| CN1838456A (en) * | 2006-04-28 | 2006-09-27 | 华南理工大学 | Direct spraying method for preparing fuel cell membrane electrode |
| CN101276919A (en) * | 2008-05-12 | 2008-10-01 | 南京工业大学 | Preparation technique for membrane electrode of proton exchange film fuel cell |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2003317750A (en) * | 2002-04-24 | 2003-11-07 | Jsr Corp | Manufacturing method of stacked body |
| CN1713424A (en) * | 2004-06-23 | 2005-12-28 | 比亚迪股份有限公司 | Electrode production of fuel battery membrane with proton exchange membrane |
| CN1838456A (en) * | 2006-04-28 | 2006-09-27 | 华南理工大学 | Direct spraying method for preparing fuel cell membrane electrode |
| CN101276919A (en) * | 2008-05-12 | 2008-10-01 | 南京工业大学 | Preparation technique for membrane electrode of proton exchange film fuel cell |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105091897A (en) * | 2015-09-01 | 2015-11-25 | 王小安 | Map interest point setting method |
| CN109560292A (en) * | 2018-10-25 | 2019-04-02 | 芬华氢能研究院江苏有限公司 | A kind of preparation method of hydrogen fuel cell membrane electrode |
| CN109713321A (en) * | 2018-12-29 | 2019-05-03 | 上海交通大学 | A kind of adjustable membrane electrode of pore structure and preparation method thereof |
| CN113066999A (en) * | 2021-03-22 | 2021-07-02 | 上海捷氢科技有限公司 | Porous electrode of proton exchange membrane fuel cell and preparation method thereof |
| CN114264709A (en) * | 2021-11-09 | 2022-04-01 | 深圳航天科技创新研究院 | Method for measuring mass transfer resistance of gas diffusion layer of hydrogen fuel cell and application thereof |
| CN114264709B (en) * | 2021-11-09 | 2023-12-19 | 深圳航天科技创新研究院 | Method for measuring mass transfer resistance of gas diffusion layer of hydrogen fuel cell and application thereof |
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Application publication date: 20150225 |