CN104372355A - Water-containing rust-removal rust-resistant agent for processing metal surface - Google Patents

Water-containing rust-removal rust-resistant agent for processing metal surface Download PDF

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Publication number
CN104372355A
CN104372355A CN201410352623.5A CN201410352623A CN104372355A CN 104372355 A CN104372355 A CN 104372355A CN 201410352623 A CN201410352623 A CN 201410352623A CN 104372355 A CN104372355 A CN 104372355A
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China
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parts
rust
acid
zinc
raw materials
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CN201410352623.5A
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Chinese (zh)
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梁胜光
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Individual
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Individual
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Priority to CN201410352623.5A priority Critical patent/CN104372355A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

A disclosed water-containing rust-removal rust-resistant agent for processing a metal surface is composed of the following raw materials: 20-25 parts of hydrochloric acid, 23-26 parts of acetic acid, 20-22 parts of tartaric acid, 16-18 parts of a carboxylic acid, 10-11 parts of ferric hydroxide, 11-13 parts of copper sulphate, 12-13 parts of aluminium sulfate, 5-6 parts of gelatin, 6-10 parts of silicone oil, 8-10 parts of ferrous sulfate powder, 3-5 parts of zinc oxide, 5-8 parts of calcium phosphate, 6-8 parts of trisodium phosphate, 3-5 parts of zinc hydroxide, 4-5 parts of potassium sorbate, 6-8 parts of carboxymethylcellulose sodium, 6-7 parts of glycerol, 6-12 parts of succinic acid, 2-6 parts of methanol, 3-5 parts of thiourea dioxide, 2-8 parts of urea, 6-8 parts of thioacetamide, 5-7 parts of fatty alcohol polyoxyethylene ether, 7-8 parts of coconutt diethanol amide, and 10-12 parts of nonylphenoxypoly(ethyleneoxy)ethanol. The water-containing rust-removal rust-resistant agent is capable of improving the comprehensive performances of an antirust film and is safe and free of pollution.

Description

A kind of moisture rust-removing and-preventing agent of metal finishing
Technical field
The present invention relates to a kind of technical field of rust-removing and-preventing agent, particularly relate to a kind of moisture rust-removing and-preventing agent of metal finishing.
Background technology
At present, it is very wide that the protection of metallic substance relates to face, every year owing to corroding one of component 4 parts that account for metal production of scrapping.Hardware protection processing method has single stage method and the method for fractional steps, and single stage method and degreasing derusting rust-proofing once complete, and distribution and degreasing derusting rust-proofing branch complete.Though single stage method treatment agent can complete degreasing derusting rust-proofing several functions simultaneously, generally all contain the strong base substance and other auxiliary materials that steel surface are had to very deep-etching effect in this treatment agent, steel and iron member medium-long term rust-proof effect will be affected.The method of fractional steps is taked first to degrease, and then carries out derusting rust-proofing process, significantly improves the medium-long term rust-proof effect of processed workpiece, but is unfavorable for reducing costs, easily cause surface blistering, and film forming thickness is uneven, the defects such as time of drying is long, and surperficial sagging is serious.
Summary of the invention
The object of the invention is the shortcoming in order to overcome above-mentioned prior art, a kind of moisture rust-removing and-preventing agent of metal finishing is provided, the composition of raw materials aboundresources of the moisture rust-removing and-preventing agent of this metal finishing, cheap, the over-all properties of anti-rust film can be improved, safe and reliable pollution-free, can ensure that film forming is smooth, fine and close, reduce sagging, improve rate of drying and rete heatproof, strengthen anti-rust film water resistant humidity-proof ability, the excessive erosion of workpiece surface can be prevented.
The technical solution adopted for the present invention to solve the technical problems is: a kind of moisture rust-removing and-preventing agent of metal finishing, be made up of the composition of raw materials component of following number: 20-25 part hydrochloric acid, 23-26 part acetic acid, 20-22 part tartrate, 16-18 part carboxylic acid, 10-11 part ironic hydroxide, 11-13 part copper sulfate, 12-13 part Tai-Ace S 150, 5-6 part gelatin, 6-10 part silicone oil, 8-10 part green vitriol powder, 3-5 part zinc oxide, 5-8 part calcium phosphate, 6-8 part tertiary sodium phosphate, 3-5 part zinc hydroxide, 4-5 part potassium sorbate, 6-8 part Xylo-Mucine, 6-7 part glycerol, 6-12 part succsinic acid, 2-6 part methyl alcohol, 3-5 part thiourea peroxide, 2-8 part urea, 6-8 part thioacetamide, 5-7 part fatty alcohol-polyoxyethylene ether, 7-8 part cocoanut fatty acid diethanolamide, 10-12 part polyoxyethylene nonylphenol ether.
Further, each composition of raw materials component is: 20 parts of hydrochloric acid, 23 parts of acetic acid, 20 parts of tartrate, 16 parts of carboxylic acids, 10 parts of ironic hydroxides, 11 parts of copper sulfate, 12 parts of Tai-Ace S 150, 5 parts of gelatin, 6 parts of silicone oil, 8 parts of green vitriol powder, 3 parts of zinc oxide, 5 parts of calcium phosphate, 6 parts of tertiary sodium phosphates, 3 parts of zinc hydroxides, 4 parts of potassium sorbate, 6 parts of Xylo-Mucines, 6 parts of glycerol, 6 parts of succsinic acids, 2 parts of methyl alcohol, 3 parts of thiourea peroxides, 2 parts of urea, 6 parts of thioacetamides, 5 parts of fatty alcohol-polyoxyethylene ether, 7 parts of cocoanut fatty acid diethanolamides, 10 parts of polyoxyethylene nonylphenol ethers.
Or, each composition of raw materials component is: 25 parts of hydrochloric acid, 26 parts of acetic acid, 22 parts of tartrate, 18 parts of carboxylic acids, 11 parts of ironic hydroxides, 13 parts of copper sulfate, 13 parts of Tai-Ace S 150, 6 parts of gelatin, 10 parts of silicone oil, 10 green vitriol powder, 5 parts of zinc oxide, 8 parts of calcium phosphate, 8 parts of tertiary sodium phosphates, 5 parts of zinc hydroxides, 5 parts of potassium sorbate, 8 parts of Xylo-Mucines, 7 parts of glycerol, 12 parts of succsinic acids, 6 parts of methyl alcohol, 5 parts of thiourea peroxides, 8 parts of urea, 8 parts of thioacetamides, 7 parts of fatty alcohol-polyoxyethylene ether, 8 parts of cocoanut fatty acid diethanolamides, 12 parts of polyoxyethylene nonylphenol ethers.
In sum, the invention has the beneficial effects as follows: the composition of raw materials aboundresources of the moisture rust-removing and-preventing agent of metal finishing of the present invention, cheap, the over-all properties of anti-rust film can be improved, safe and reliable pollution-free, can ensure that film forming is smooth, fine and close, reduce sagging, improve rate of drying and rete heatproof, strengthen anti-rust film water resistant humidity-proof ability, the excessive erosion of workpiece surface can be prevented.
Embodiment
Embodiment 1
The moisture rust-removing and-preventing agent of a kind of metal finishing described by the present embodiment 1, be made up of the composition of raw materials component of following number: 20 parts of hydrochloric acid, 23 parts of acetic acid, 20 parts of tartrate, 16 parts of carboxylic acids, 10 parts of ironic hydroxides, 11 parts of copper sulfate, 12 parts of Tai-Ace S 150, 5 parts of gelatin, 6 parts of silicone oil, 8 parts of green vitriol powder, 3 parts of zinc oxide, 5 parts of calcium phosphate, 6 parts of tertiary sodium phosphates, 3 parts of zinc hydroxides, 4 parts of potassium sorbate, 6 parts of Xylo-Mucines, 6 parts of glycerol, 6 parts of succsinic acids, 2 parts of methyl alcohol, 3 parts of thiourea peroxides, 2 parts of urea, 6 parts of thioacetamides, 5 parts of fatty alcohol-polyoxyethylene ether, 7 parts of cocoanut fatty acid diethanolamides, 10 parts of polyoxyethylene nonylphenol ethers.
Embodiment 2
The moisture rust-removing and-preventing agent of a kind of metal finishing described by the present embodiment 2, be made up of the composition of raw materials component of following number: 25 parts of hydrochloric acid, 26 parts of acetic acid, 22 parts of tartrate, 18 parts of carboxylic acids, 11 parts of ironic hydroxides, 13 parts of copper sulfate, 13 parts of Tai-Ace S 150, 6 parts of gelatin, 10 parts of silicone oil, 10 green vitriol powder, 5 parts of zinc oxide, 8 parts of calcium phosphate, 8 parts of tertiary sodium phosphates, 5 parts of zinc hydroxides, 5 parts of potassium sorbate, 8 parts of Xylo-Mucines, 7 parts of glycerol, 12 parts of succsinic acids, 6 parts of methyl alcohol, 5 parts of thiourea peroxides, 8 parts of urea, 8 parts of thioacetamides, 7 parts of fatty alcohol-polyoxyethylene ether, 8 parts of cocoanut fatty acid diethanolamides, 12 parts of polyoxyethylene nonylphenol ethers.
The above is only preferred embodiment of the present invention, not does any pro forma restriction to principle of the present invention.Every above embodiment is done according to technical spirit of the present invention any simple modification, equivalent variations and modification, all still belong in the scope of technical scheme of the present invention.

Claims (3)

1. the moisture rust-removing and-preventing agent of a metal finishing, it is characterized in that, be made up of the composition of raw materials component of following number: 20-25 part hydrochloric acid, 23-26 part acetic acid, 20-22 part tartrate, 16-18 part carboxylic acid, 10-11 part ironic hydroxide, 11-13 part copper sulfate, 12-13 part Tai-Ace S 150, 5-6 part gelatin, 6-10 part silicone oil, 8-10 part green vitriol powder, 3-5 part zinc oxide, 5-8 part calcium phosphate, 6-8 part tertiary sodium phosphate, 3-5 part zinc hydroxide, 4-5 part potassium sorbate, 6-8 part Xylo-Mucine, 6-7 part glycerol, 6-12 part succsinic acid, 2-6 part methyl alcohol, 3-5 part thiourea peroxide, 2-8 part urea, 6-8 part thioacetamide, 5-7 part fatty alcohol-polyoxyethylene ether, 7-8 part cocoanut fatty acid diethanolamide, 10-12 part polyoxyethylene nonylphenol ether.
2. the moisture rust-removing and-preventing agent of a kind of metal finishing according to claim 1, it is characterized in that, each composition of raw materials component is: 20 parts of hydrochloric acid, 23 parts of acetic acid, 20 parts of tartrate, 16 parts of carboxylic acids, 10 parts of ironic hydroxides, 11 parts of copper sulfate, 12 parts of Tai-Ace S 150, 5 parts of gelatin, 6 parts of silicone oil, 8 parts of green vitriol powder, 3 parts of zinc oxide, 5 parts of calcium phosphate, 6 parts of tertiary sodium phosphates, 3 parts of zinc hydroxides, 4 parts of potassium sorbate, 6 parts of Xylo-Mucines, 6 parts of glycerol, 6 parts of succsinic acids, 2 parts of methyl alcohol, 3 parts of thiourea peroxides, 2 parts of urea, 6 parts of thioacetamides, 5 parts of fatty alcohol-polyoxyethylene ether, 7 parts of cocoanut fatty acid diethanolamides, 10 parts of polyoxyethylene nonylphenol ethers.
3. the moisture rust-removing and-preventing agent of a kind of metal finishing according to claim 1, it is characterized in that, each composition of raw materials component is: 25 parts of hydrochloric acid, 26 parts of acetic acid, 22 parts of tartrate, 18 parts of carboxylic acids, 11 parts of ironic hydroxides, 13 parts of copper sulfate, 13 parts of Tai-Ace S 150, 6 parts of gelatin, 10 parts of silicone oil, 10 green vitriol powder, 5 parts of zinc oxide, 8 parts of calcium phosphate, 8 parts of tertiary sodium phosphates, 5 parts of zinc hydroxides, 5 parts of potassium sorbate, 8 parts of Xylo-Mucines, 7 parts of glycerol, 12 parts of succsinic acids, 6 parts of methyl alcohol, 5 parts of thiourea peroxides, 8 parts of urea, 8 parts of thioacetamides, 7 parts of fatty alcohol-polyoxyethylene ether, 8 parts of cocoanut fatty acid diethanolamides, 12 parts of polyoxyethylene nonylphenol ethers.
CN201410352623.5A 2014-07-24 2014-07-24 Water-containing rust-removal rust-resistant agent for processing metal surface Pending CN104372355A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105002516A (en) * 2015-08-10 2015-10-28 苏州科淼新材料有限公司 Mechanical equipment cleaning agent and preparation method thereof
CN107858699A (en) * 2017-11-06 2018-03-30 陈兴 A kind of rust remover of self-locking type smoke-exhaust fire regulating valve and preparation method thereof
WO2019006678A1 (en) * 2017-07-04 2019-01-10 深圳市长宏泰科技有限公司 Antirust agent, metal workpiece, and antirust treatment method therefor
CN112595623A (en) * 2020-11-23 2021-04-02 上海航天化工应用研究所 Method and device for measuring gel content in azide polyether propellant
EP3971174A4 (en) * 2019-06-17 2023-08-09 Chemical Denshi Co., Ltd. Hydrophilic metal-surface treatment agent

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105002516A (en) * 2015-08-10 2015-10-28 苏州科淼新材料有限公司 Mechanical equipment cleaning agent and preparation method thereof
WO2019006678A1 (en) * 2017-07-04 2019-01-10 深圳市长宏泰科技有限公司 Antirust agent, metal workpiece, and antirust treatment method therefor
CN107858699A (en) * 2017-11-06 2018-03-30 陈兴 A kind of rust remover of self-locking type smoke-exhaust fire regulating valve and preparation method thereof
EP3971174A4 (en) * 2019-06-17 2023-08-09 Chemical Denshi Co., Ltd. Hydrophilic metal-surface treatment agent
CN112595623A (en) * 2020-11-23 2021-04-02 上海航天化工应用研究所 Method and device for measuring gel content in azide polyether propellant

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Application publication date: 20150225