CN104371685A - Paraffin remover and preparation method thereof - Google Patents
Paraffin remover and preparation method thereof Download PDFInfo
- Publication number
- CN104371685A CN104371685A CN201410682196.7A CN201410682196A CN104371685A CN 104371685 A CN104371685 A CN 104371685A CN 201410682196 A CN201410682196 A CN 201410682196A CN 104371685 A CN104371685 A CN 104371685A
- Authority
- CN
- China
- Prior art keywords
- paraffin remover
- alkali
- paraffin
- ether
- ethylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012188 paraffin wax Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 33
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 17
- 239000012530 fluid Substances 0.000 claims abstract description 17
- 239000003513 alkali Substances 0.000 claims abstract description 16
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 10
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 8
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000005642 Oleic acid Substances 0.000 claims abstract description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002131 composite material Substances 0.000 claims abstract description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000000052 vinegar Substances 0.000 claims abstract description 6
- 235000021419 vinegar Nutrition 0.000 claims abstract description 6
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 5
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 5
- 229960004232 linoleic acid Drugs 0.000 claims description 5
- 229960004418 trolamine Drugs 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 abstract 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 abstract 1
- FUWDFGKRNIDKAE-UHFFFAOYSA-N 1-butoxypropan-2-yl acetate Chemical compound CCCCOCC(C)OC(C)=O FUWDFGKRNIDKAE-UHFFFAOYSA-N 0.000 abstract 1
- 239000001993 wax Substances 0.000 description 19
- 239000003795 chemical substances by application Substances 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 7
- 239000003921 oil Substances 0.000 description 6
- 239000003129 oil well Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000010779 crude oil Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000013043 chemical agent Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
- C09K8/524—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning organic depositions, e.g. paraffins or asphaltenes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a paraffin remover and a preparation method thereof. The paraffin remover comprises the following components (in percentage by weight): 15%-25% of alcohol ether, 7%-12% of fatty alcohol-polyoxyethylene ether, 0.15%-0.25% of alkali, 13%-15% of antifreezing fluids, 5%-10% of ethylene glycol and 30%-40% of emulsifying agents, wherein the emulsifying agent is a mixture of oleic acid, linoleic acid, composite vinegar of resin and triethanolamine, the antifreezing fluids comprise propylene glycol butyl ether acetate and ethylene glycol butyl ether acetate, and the alkali is any one of sodium hydroxide or potassium hydroxide. The preparation method of the paraffin remover comprises the following steps: adding the alkali to the fatty alcohol-polyoxyethylene ether to generate a surface active agent; adding the surface active agent to alcohol ether, and stirring under the condition of normal temperature and pressure; and then sequentially adding the antifreezing fluids, the ethylene glycol and the emulsifying agents so as to obtain the paraffin remover. The paraffin remover provided by the invention has the advantages of safety in use, low possibility in ignition and low solidifying point and meets the requirement for usage under the condition of extreme cold.
Description
Technical field
The invention belongs to oilfield chemistry Application Areas, be specifically related to a kind of paraffin remover and preparation method thereof.
Background technology
Wax is usual under formation conditions to be existed with liquid state.But in recovery process, along with temperature and pressure decline and light component are constantly overflowed, the wax in crude oil can be separated out gradually and is deposited on around the borehole wall and in production casing, damages oil bearing reservoir, the normal production in restriction oil field.According to the literature, China's major part exploitation crude oil is rich in wax, all more than 20%, some even high 40%. therefore, paraffin removal from oil well is the very important technical measures of of ensureing that waxy crude oil normally produces.
The paraffin removal from oil well technology that oil field is conventional, mainly contains mechanical paraffin removal technology, heating power Paraffin Removal technology, surface energy anti-wax technique, chemical agent Paraffin Removal technology, magnetic paraffin control technology and the large class of Microorganism Wax Removal And Paraffin Inhibition 6.Carrying out Paraffin Removal with chemical agent to oil well is current field use more a kind of Paraffin Removal technology.Chemical paraffin removing and inhibitor has oily molten type, water-soluble and emulsion-type three kinds of liquid wax removing agents, and the advantage of oily molten type wax removing agent is: stronger to crude oil adaptability; Molten wax speed is fast, adds instant effect after oil well; Product zero pour is low, uses also very convenient in the winter time.Its shortcoming is: relative density is little, and very unsuitable to moisture high oil, burning-point is low, easily catches fire, and must have rigorous fire measure during use.The advantage relative density of water-soluble wax removing agent is comparatively large, better to high-water-cut oil-producing well effect; Use safety, without ignition hazard.Its shortcoming is that to add the oil well speed that takes effect slower; Although the zero pour of water based dewaxing agent can reach one 20 DEG C now, at the use in winter of severe cold, its mobility is very poor.Emulsion-type wax removing agent has the fireballing advantage of the molten wax of oily molten type wax removing agent, due to this wax removing agent, its foreign minister taking liquid is water, because of and as water-soluble wax removing agent use safety, not easily to catch fire and relative density is larger, but this wax removing agent prepare and storage time must stablize, simultaneously preparation and duration of service conditional request higher.
Summary of the invention
In order to solve the problem, the object of the present invention is to provide and a kind ofly meet wax removal requirement simultaneously its preparation method paraffin remover that is simple, that be extensively suitable for, its specific embodiment is:
A kind of paraffin remover, its feature is being, its moiety (weight ratio) comprises alcohol ether 15 ~ 25%, fatty alcohol-polyoxyethylene ether 7 ~ 12%, alkali content 0.15 ~ 0.25%, deicing fluid 13 ~ 15%, ethylene glycol 5 ~ 10%, emulsifying agent 30 ~ 40%.
Further, described emulsifying agent is the Composite vinegar of oleic acid, linolic acid and resin and the mixture of trolamine.
Further, described deicing fluid is propandiol butyl ether and 2-Butoxyethyl acetate composition, and its weight ratio is 30% ~ 70%:70% ~ 30%.
Described alkali is any one in sodium hydroxide or potassium hydroxide.
A kind of preparation method of paraffin remover: alkali is joined fatty alcohol-polyoxyethylene ether and generate tensio-active agent, joined in alcohol ether and stirred at normal temperature and pressure conditions, stir 10 ~ 30min, stirring velocity 200 ~ 300r/min, then add deicing fluid, ethylene glycol, emulsifying agent successively.Obtain paraffin remover.
Advantage of the present invention is: form water external emulsion after molten for oil type wax removing agent being added water and emulsifying agent and stablizer, after this milk sap adds oil well, carry out breakdown of emulsion and discharge to have excellent dissolution performance to wax under bottom temperature.Because foreign minister is water, because of and as water-soluble wax removing agent use safety, not easily to catch fire and relative density is comparatively large, add the zero pour that deicing fluid and ethylene glycol can reduce paraffin remover, its paraffin remover can well be improved because freeze the non-serviceable difficulty brought.
Embodiment
Embodiment 1:
A kind of paraffin remover, its feature is being, its moiety (weight ratio) comprises alcohol ether 25%, fatty alcohol-polyoxyethylene ether 12%, alkali content 0.2%, deicing fluid 15%, ethylene glycol 10%, emulsifying agent 30%.Described emulsifying agent is the Composite vinegar of oleic acid, linolic acid and resin and the mixture of trolamine.Described deicing fluid is propandiol butyl ether and 2-Butoxyethyl acetate composition, and its weight ratio is 30%:70%.Described alkali is potassium hydroxide.
Embodiment 2:
A kind of paraffin remover, its feature is being, its moiety (weight ratio) comprises alcohol ether 20%, fatty alcohol-polyoxyethylene ether 10%, alkali content 0.25%, deicing fluid 15%, ethylene glycol 10%, emulsifying agent 40%.Described emulsifying agent is the Composite vinegar of oleic acid, linolic acid and resin and the mixture of trolamine.Described deicing fluid is propandiol butyl ether and 2-Butoxyethyl acetate composition, and its weight ratio is 40%:60%.Described alkali is sodium hydroxide.
Embodiment 3:
A kind of paraffin remover, its feature is being, its moiety (weight ratio) comprises alcohol ether 25%, fatty alcohol-polyoxyethylene ether 8%, alkali content 0.25%, deicing fluid 12%, ethylene glycol 10%, emulsifying agent 40%.Further, described emulsifying agent is the Composite vinegar of oleic acid, linolic acid and resin and the mixture of trolamine, and described deicing fluid is propandiol butyl ether and 2-Butoxyethyl acetate composition, and its weight ratio is 50%:50%.Described alkali is potassium hydroxide.
Above embodiment adopts following method to prepare:
Alkali is joined fatty alcohol-polyoxyethylene ether and generate tensio-active agent, joined in alcohol ether and stir, stir 30min, stirring velocity 250r/min, then add deicing fluid, ethylene glycol, emulsifying agent successively, obtain paraffin remover.The performance of the paraffin remover of preparation goes out excellent performance, as following table:
The performance index of paraffin remover
| Sequence number | Project | Index |
| 1 | Density, g/cm 3 | ≥0.870 |
| 2 | Zero pour, DEG C | ≤-5 |
| 3 | Flash-point (remaining silent), DEG C | ≥3 |
| 4 | The speed of paraffin dissolution, g/min | ≥0.016 |
| 5 | Dithiocarbonic anhydride content, % | ≤0.02 |
| 6 | Content of organic chloride, % | ≤0.02 |
The above is only preferred embodiment of the present invention, not does any pro forma restriction to technical scheme of the present invention.Every above embodiment is done according to technical spirit of the present invention any simple modification, equivalent variations and modification, all still belong in the scope of technical scheme of the present invention.
Claims (5)
1. a paraffin remover, its feature is being, its moiety (weight ratio) comprises alcohol ether 15 ~ 25%, fatty alcohol-polyoxyethylene ether 7 ~ 12%, alkali content 0.15 ~ 0.25%, deicing fluid 13 ~ 15%, ethylene glycol 5 ~ 10%, emulsifying agent 30 ~ 40%.
2. a kind of paraffin remover according to claim 1, it is characterized in that, described emulsifying agent is the Composite vinegar of oleic acid, linolic acid and resin and the mixture of trolamine.
3. a kind of paraffin remover according to claim 1, is characterized in that, described deicing fluid is propandiol butyl ether and 2-Butoxyethyl acetate composition, and its weight ratio is 30% ~ 70%:70% ~ 30%.
4. a kind of paraffin remover according to claim 1, is characterized in that, described alkali is any one in sodium hydroxide or potassium hydroxide.
5. the preparation method of a paraffin remover, it is characterized in that, alkali is joined fatty alcohol-polyoxyethylene ether and generate tensio-active agent, joined in alcohol ether and stirred at normal temperature and pressure conditions, stir 10 ~ 30min, stirring velocity 200 ~ 300r/min, then add deicing fluid, ethylene glycol, emulsifying agent successively, obtain paraffin remover.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410682196.7A CN104371685A (en) | 2014-11-24 | 2014-11-24 | Paraffin remover and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410682196.7A CN104371685A (en) | 2014-11-24 | 2014-11-24 | Paraffin remover and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104371685A true CN104371685A (en) | 2015-02-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410682196.7A Pending CN104371685A (en) | 2014-11-24 | 2014-11-24 | Paraffin remover and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104371685A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038749A (en) * | 2015-08-27 | 2015-11-11 | 山东聚鑫化工有限公司 | Oil-in-water paraffin remover |
| CN105238377A (en) * | 2015-09-23 | 2016-01-13 | 山东聚鑫化工有限公司 | Water-based wax cleaning agent |
| CN105255468A (en) * | 2015-10-28 | 2016-01-20 | 中国石油化工股份有限公司 | Emulsion type paraffin remover and inhibitor and preparation method thereof |
| CN105482796A (en) * | 2015-12-03 | 2016-04-13 | 高大元 | Preparation method of environmentally friendly oil well paraffin remover |
| CN108822822A (en) * | 2018-07-19 | 2018-11-16 | 佛山皖阳生物科技有限公司 | A kind of preparation method of heat-resistant salt form biomass paraffin remover |
| CN111410947A (en) * | 2020-03-20 | 2020-07-14 | 克拉玛依新科澳实验检测有限公司 | Composite wax-proofing agent and preparation method thereof |
| CN112094631A (en) * | 2020-09-15 | 2020-12-18 | 郑州德融科技有限公司 | Paraffin remover for oil extraction and production equipment thereof |
| CN112195019A (en) * | 2020-11-11 | 2021-01-08 | 榆林学院 | Emulsion type paraffin removal and prevention agent |
| CN112898621A (en) * | 2021-03-16 | 2021-06-04 | 青岛瑞诺化工有限公司 | Emulsifier, preparation method thereof and application thereof in latex foaming product |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038749A (en) * | 2015-08-27 | 2015-11-11 | 山东聚鑫化工有限公司 | Oil-in-water paraffin remover |
| CN105238377A (en) * | 2015-09-23 | 2016-01-13 | 山东聚鑫化工有限公司 | Water-based wax cleaning agent |
| CN105255468A (en) * | 2015-10-28 | 2016-01-20 | 中国石油化工股份有限公司 | Emulsion type paraffin remover and inhibitor and preparation method thereof |
| CN105482796A (en) * | 2015-12-03 | 2016-04-13 | 高大元 | Preparation method of environmentally friendly oil well paraffin remover |
| CN108822822A (en) * | 2018-07-19 | 2018-11-16 | 佛山皖阳生物科技有限公司 | A kind of preparation method of heat-resistant salt form biomass paraffin remover |
| CN111410947A (en) * | 2020-03-20 | 2020-07-14 | 克拉玛依新科澳实验检测有限公司 | Composite wax-proofing agent and preparation method thereof |
| CN112094631A (en) * | 2020-09-15 | 2020-12-18 | 郑州德融科技有限公司 | Paraffin remover for oil extraction and production equipment thereof |
| CN112195019A (en) * | 2020-11-11 | 2021-01-08 | 榆林学院 | Emulsion type paraffin removal and prevention agent |
| CN112898621A (en) * | 2021-03-16 | 2021-06-04 | 青岛瑞诺化工有限公司 | Emulsifier, preparation method thereof and application thereof in latex foaming product |
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Application publication date: 20150225 |
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