CN104371153A - Rubber composite modified by carbon nano tubes and graphene jointly - Google Patents
Rubber composite modified by carbon nano tubes and graphene jointly Download PDFInfo
- Publication number
- CN104371153A CN104371153A CN201410739808.1A CN201410739808A CN104371153A CN 104371153 A CN104371153 A CN 104371153A CN 201410739808 A CN201410739808 A CN 201410739808A CN 104371153 A CN104371153 A CN 104371153A
- Authority
- CN
- China
- Prior art keywords
- graphene
- carbon nanotube
- rubber
- matrix material
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a rubber composite modified by carbon nano tubes and graphene jointly. The rubber composite comprises, by weight, 0.001-20 parts of the graphene, 0.001-20 parts of the carbon nano tubes, 1-5 parts of padding, and 50-80 parts of rubber. Compared with existing rubber, the rubber composite has the advantage that mechanical property and electrical thermal properties are improved greatly. The rubber is better in wear resistance, conductivity effect of the rubber is improved, and antistatic and heat dissipation effect of the rubber is further improved.
Description
Technical field
The present invention relates to field of rubber materials, particularly a kind of rubber composite by carbon nanotube and the common modification of Graphene.
Background technology
Rubber at room temperature has snappiness, and its many performance (comprising tensile strength, hardness, wear resistance, fatigue resistance, conduction, thermal diffusivity etc.) cannot reach polymer materials application requiring when not adopting enhancements.Usually need to add filler (as carbon black, silicon-dioxide etc.) and improve its performance.Because Graphene and carbon nanotube (CNTs) are of a size of nanometer scale, length-to-diameter ratio greatly, there is the advantage that density is little, tensile strength is large, modulus is high, electrical and thermal conductivity performance is good, therefore it becomes the another important filler of rubber reinforcement modification.
Carbon nanotube (CNTs) is by the curling hollow tubular material of hexagonal graphite flake layer.Carbon nanotube has unique topological framework, and the heat conductivility that stability is high, specific tenacity is high, axial expansion coefficient is low, unique and conductivity etc.Just based on these structure and characteristics, carbon nanotube becomes the desirable reinforced filling of polymer matrix composite.China Patent No. CN200510058999, publication date on September 7th, 2005, name is called a kind of carbon nanotube modified powder natural rubber, openly adopt the modified powder natural rubber of spray-drying process preparation containing CNTs, adopt powdered rubber prepared by this method, CNTs is dispersed wherein, and particle diameter is little, and mechanical property comparatively conventional powder rubber is significantly increased.Its weak point is the electric property of carbon nano modification matrix material and imperfect, and along with pulling force increases, the force-sensitive effect of matrix material increases, and matrix material exists obvious relaxation phenomena, and pulling force is larger, and the relaxation time of resistivity is longer; Content of carbon nanotubes is larger, and the relaxation phenomena of matrix material is more not obvious, and thermal conductivity and the electroconductibility rule of rubber are similar.
Graphene (Graphene) is a kind of novel material of the individual layer sheet structure be made up of carbon atom, be a kind of by carbon atom with sp
2hybridized orbital composition hexangle type is the flat film of honeycomb lattice, only has the two-dimensional material of a carbon atom thickness.Graphene thermal conductivity is up to 5300 W/mK, and under normal temperature, its electronic mobility is more than 15000 cm
2/ Vs, again than carbon nanotube or silicon wafer height, and resistivity only about 10
-8Ω m is the material that world resistivity is minimum.China Patent No. CN201410152577, publication date on July 16th, 2014, name is called a kind of conductive graphene/natural rubber nano composite material and preparation method thereof, discloses a kind of preparation method of conductive graphene/natural rubber nano composite material.A kind of conductive graphene/natural rubber nano composite material and preparation method thereof, the modified graphite of chemical reduction is distributed in distilled water and mix with natural rubber latex, drying sulfuration, obtains matrix material.This method adopts effective hybrid mode, Graphene is disperseed preferably in natural rubber matrix, and the matrix material obtained has good conductivity.Its deficiency is the mechanical property not having to consider obtained compounded rubber, and its tensile strength and Young's modulus are unexcellent.
China Patent No. CN201410128419, publication date on 07 23rd, 2014, name is called that a kind of Graphene works in coordination with carbon nanotube-silicon rubber composite material and preparation method thereof, matrix material comprises following component: 100 weight part methyl vinyl silicon kautschuks, 38 ~ 42 weight part white carbon blacks, 10 ~ 15 weight part hexamethyldisilazanes, 1 ~ 3 parts by weight of graphite alkene, 0.7 ~ 1 weight part 2,5-dimethyl-2,5-di-t-butyl hexane peroxide, 2.5 ~ 3 parts by weight of ethylene base silicone oil and 1 ~ 3 parts by weight of carbon nanotubes.Its weak point is only to have studied the modification to silicon rubber, do not relate to other kind rubber, and although this formula effectively can improve the thermo-oxidative stability of silicon rubber composite material, but for mechanical property and other performances of rubber, such as tensile strength and tear strength etc., do not further investigate and illustrate.In existing modified rubber matrix material, also do not possess mechanical property and electric, that thermal characteristics is all excellent method simultaneously.
Summary of the invention
The object of the invention is to solve that existing rubber rub resistance is lower, thermal diffusivity is poor, conductivity still needs the defect that improves and provide a kind of and improve the carbon nanotube of rubber rub resistance, thermal diffusivity and conductivity and the rubber composite of the common modification of Graphene.
To achieve these goals, the present invention is by the following technical solutions:
The rubber composite of a kind of carbon nanotube and the common modification of Graphene, carbon nanotube, Graphene, filler and rubber is added in the rubber composite of described a kind of carbon nanotube and the common modification of Graphene, composition weight number is Graphene 0.001 ~ 20 part, carbon nanotube 0.001 ~ 20 part, rubber 50 ~ 80 parts, filler 1 ~ 5 part.
As preferably, described Graphene is 1 ~ 10 layer graphene.
As preferably, described Graphene is multi-layer graphene, the number of plies at 11 ~ 50 layers, for the hexagonal honeycomb shape lattice of carbon atom sp2 hybridized orbital composition, interlayer are that carbon atom closes with π bond in layer.
As preferably, described Graphene is the modified graphene of various functional group, and described property modifying functional group is one or more in hydroxyl, carboxyl, carbonyl, nitrogen base, amino.
As preferably, in described Graphene, carbon and non-carbon mass ratio are greater than 4:1, non-carbon be selected from fluorine, oxygen, nitrogen, sulphur, hydrogen, chlorine, bromine, iodine one or more.
As preferably, in described carbon nanotube, carbon nanotube is many wall constructions, and described carbon nanotube diameter is 10 ~ 20nm.
As preferably, described filler is one or more in graphitized carbon black, sulphur, stearic acid, anti-aging agent.
As preferably, described rubber is natural rubber, paracril or styrene-butadiene rubber(SBR).
The invention has the beneficial effects as follows: the more existing rubber mechanical property of elastomeric material of a kind of carbon nanotube of the present invention and Graphene common modification that electricity, thermal characteristics have huge raising.Make rubber have better wear resisting property, improve the conductive effect of rubber, and further increase the antistatic and radiating effect of rubber.
Embodiment
Below in conjunction with specific embodiment, the present invention is further explained:
If not refer in particular to adopted raw material in the present invention all to buy from market or this area is conventional, the method in following embodiment is the ordinary method of this area if no special instructions.
Carbon nanotube and Graphene add in elastomeric material simultaneously, there is significant difference in two kinds of nano material microtextures, based on small-size effect and the surface effects of nano material, a kind of nano material has impact to a certain extent to the mechanism of modification of another kind of nano material on rubber.The component of two kinds of nano materials is the keys affecting mechanism of modification, and within the scope of specific components, carbon nanotube and Graphene group tie the physicals forming the state optimization modified rubber complemented each other.
Embodiment 1
Described a kind of rubber composite by carbon nanotube and the common modification of Graphene, composition parts by weight are: Graphene 0.005 part, carbon nanotube 0.01 part, filler 2 parts, natural rubber 50 parts.
Described a kind of rubber composite proportioning mixing by carbon nanotube and the common modification of Graphene is placed in two roller mills in 30 ~ 40
oroll-in 58 minutes under C; With electrothermal plate vulcanizer compressing tablet, hot pressing temperature is 80 ~ 100
oc, 10 minutes, colds pressing 20 minutes, obtains the blend glue stuff of Graphene, carbon nanotube and rubber; Be 45 ~ 60 revs/min by the blend glue stuff of carbon nanotube and rubber in rotor speed, temperature is 50 ~ 60
oreact 2 ~ 5 minutes in the torque rheometer of C; Add stearic acid, anti-aging agent, promotor and sulphur successively mixing 4 ~ 8 minutes, obtain rubber unvulcanizate; Be placed in by the rubber unvulcanizate obtained under normal temperature in two roller mills and supplement mixing 7 ~ 15 minutes, slice, at room temperature parks 24 hours; Sulfuration on vulcanizing press, cure conditions is 150
oc/10MPa, 90min, at room temperature place the natural rubber later obtaining Graphene, carbon nano-tube modification for 24 hours.Embodiment 1 physicals is as following table 1:
Table 1
Embodiment 2
Described a kind of rubber composite by carbon nanotube and the common modification of Graphene, composition parts by weight are: Graphene 0.005 part, carbon nanotube 0.01 part, filler 2 parts, paracril 50 parts.
Described a kind of rubber composite proportioning mixing by carbon nanotube and the common modification of Graphene is placed in two roller mills in 30 ~ 40
oroll-in 58 minutes under C; With electrothermal plate vulcanizer compressing tablet, hot pressing temperature is 80 ~ 100
oc, 10 minutes, colds pressing 20 minutes, obtains the blend glue stuff of Graphene, carbon nanotube and rubber; Be 45 ~ 60 revs/min by the blend glue stuff of carbon nanotube and rubber in rotor speed, temperature is 50 ~ 60
oreact 2 ~ 5 minutes in the torque rheometer of C; Add stearic acid, anti-aging agent, promotor and sulphur successively mixing 4 ~ 8 minutes, obtain rubber unvulcanizate; Be placed in by the rubber unvulcanizate obtained under normal temperature in two roller mills and supplement mixing 7 ~ 15 minutes, slice, at room temperature parks 24 hours; Sulfuration on vulcanizing press, cure conditions is 150
oc/10MPa, 90min, at room temperature place the paracril later obtaining Graphene, carbon nano-tube modification for 24 hours.Embodiment 2 physicals is as following table 2:
Table 2
Embodiment 3
Described a kind of rubber composite by carbon nanotube and the common modification of Graphene, composition parts by weight are: Graphene 0.005 part, carbon nanotube 0.01 part, filler 2 parts, 50 parts, styrene-butadiene rubber(SBR).
Described a kind of rubber composite proportioning mixing by carbon nanotube and the common modification of Graphene is placed in two roller mills in 30 ~ 40
oroll-in 58 minutes under C; With electrothermal plate vulcanizer compressing tablet, hot pressing temperature is 80 ~ 100
oc, 10 minutes, colds pressing 20 minutes, obtains the blend glue stuff of Graphene, carbon nanotube and rubber; Be 45 ~ 60 revs/min by the blend glue stuff of carbon nanotube and rubber in rotor speed, temperature is 50 ~ 60
oreact 2 ~ 5 minutes in the torque rheometer of C; Add stearic acid, anti-aging agent, promotor and sulphur successively mixing 4 ~ 8 minutes, obtain rubber unvulcanizate; Be placed in by the rubber unvulcanizate obtained under normal temperature in two roller mills and supplement mixing 7 ~ 15 minutes, slice, at room temperature parks 24 hours; Sulfuration on vulcanizing press, cure conditions is 150
oc/10MPa, 90min, at room temperature place the styrene-butadiene rubber(SBR) later obtaining Graphene, carbon nano-tube modification for 24 hours.Embodiment 3 physicals is as following table 3:
Table 3
Comparative example 1, commercially available traditional natural rubber, purchased from Yanzhou Hua Qin group, with the implementation method of embodiment 1.
Comparative example 2, commercially available traditional paracril, purchased from Yanzhou Hua Qin group, with the implementation method of embodiment 2.
Comparative example 3, commercially available traditional styrene-butadiene rubber(SBR), purchased from Yanzhou Hua Qin group, with the implementation method of embodiment 3.
The natural rubber of Graphene embodiment 1 ~ 3 obtained, the natural rubber of carbon nano-tube modification and comparative example 1 ~ 3 carries out contrast test, and result is as following table 4:
Table 4
From table 4, the tensile strength of the natural rubber of Graphene of the present invention, carbon nano-tube modification, paracril and styrene-butadiene rubber(SBR) and tear strength will be better than natural rubber, paracril and the styrene-butadiene rubber(SBR) of comparative example 1 ~ 3 respectively.Graphene has that intensity is high, specific surface area is large, the feature of high chemical reactivity, high fillibility, well thermal conductivity, can the radiating effect of effective fortified tyre; Graphene conductive is strong, possesses electrochemicaUy inert, is conducive to transmitting electric charge.Carbon nanotube has good mechanical property, high-tensile, high elastic coefficient, and carbon nanotube length-to-diameter ratio is generally at 1000:1, desirable high fiber strength strains.Therefore the elastomeric material of carbon nanotube and Graphene modification not only possesses good mechanical property, and the electrostatic produced in vehicle travel process effectively can be transmitted to the earth, reduces electrostatic to the potential hazard of vehicle.
The natural rubber surface resistivity of best Recipe reaches 10
5~ 10
4europe, tensile strength brings up to 17.0Mpa by 9.94 Mpa, and tear strength brings up to 39.3kN/m by 26.8 kN/m.The paracril surface resistivity of best Recipe reaches 3 × 10
5europe, tensile strength brings up to 12.1Mpa by 2.32 Mpa, and tear strength brings up to 38.7kN/m by 17.35 kN/m.The styrene-butadiene surface resistance of best Recipe reaches 10
3europe, tensile strength brings up to 9.77Mpa by 2.34 Mpa, and tear strength brings up to 37.5kN/m by 10.12 kN/m.
Above-described embodiment is several preferred version of the present invention, not does any pro forma restriction to the present invention, also has other variant and remodeling under not exceeding right to want the prerequisite of described technical scheme.
Claims (8)
1. carbon nanotube and the common modified rubber matrix material of Graphene, is characterized in that, proportioning is as follows by weight for described a kind of carbon nanotube and Graphene common modified rubber matrix material:
Graphene 0.001 ~ 20 part,
Carbon nanotube 0.001 ~ 20 part,
Filler 1 ~ 5 part,
Rubber 50 ~ 80 parts.
2. a kind of carbon nanotube and the common modified rubber matrix material of Graphene according to claim 1, it is characterized in that, described Graphene is 1 ~ 10 layer graphene.
3. a kind of carbon nanotube and the common modified rubber matrix material of Graphene according to claim 1, it is characterized in that, described Graphene is multi-layer graphene, and the number of plies is at 11 ~ 50 layers.
4. a kind of carbon nanotube and the common modified rubber matrix material of Graphene according to Claims 2 or 3, it is characterized in that, described Graphene is the modified graphene containing various functional group, and described functional group is one or more in hydroxyl, carboxyl, carbonyl, nitrogen base, amino.
5. a kind of carbon nanotube and the common modified rubber matrix material of Graphene according to claim 4, it is characterized in that, in described Graphene, carbon and non-carbon mass ratio are greater than 4:1, and described non-carbon is one or more in fluorine, oxygen, nitrogen, sulphur, hydrogen, chlorine, bromine, iodine.
6. a kind of carbon nanotube and the common modified rubber matrix material of Graphene according to claim 5, it is characterized in that, described carbon nanotube is many wall constructions, and described carbon nanotube diameter is 10 ~ 20nm.
7. a kind of carbon nanotube and the common modified rubber matrix material of Graphene according to claim 6, is characterized in that, described filler is one or more in graphitized carbon black, sulphur, stearic acid, anti-aging agent.
8. a kind of carbon nanotube and the common modified rubber matrix material of Graphene according to claim 7, it is characterized in that, described rubber is natural rubber, paracril or styrene-butadiene rubber(SBR).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410739808.1A CN104371153A (en) | 2014-12-08 | 2014-12-08 | Rubber composite modified by carbon nano tubes and graphene jointly |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410739808.1A CN104371153A (en) | 2014-12-08 | 2014-12-08 | Rubber composite modified by carbon nano tubes and graphene jointly |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104371153A true CN104371153A (en) | 2015-02-25 |
Family
ID=52550362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410739808.1A Pending CN104371153A (en) | 2014-12-08 | 2014-12-08 | Rubber composite modified by carbon nano tubes and graphene jointly |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104371153A (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861244A (en) * | 2015-05-14 | 2015-08-26 | 安徽红太阳新材料有限公司 | Graphene-modified montmorillonite/carbon nanotube/reclaimed rubber composite flexible material and preparation method thereof |
| CN105037830A (en) * | 2015-09-08 | 2015-11-11 | 中北大学 | High-strength low-heat-generation composite material and preparation method thereof |
| CN105111531A (en) * | 2015-04-29 | 2015-12-02 | 宁波职业技术学院 | Graphene-modified wear-resistant rubber |
| CN105419004A (en) * | 2015-12-25 | 2016-03-23 | 张家港大塚化学有限公司 | High-heat-conductive rubber composition, preparation method thereof and tyre |
| CN105542258A (en) * | 2015-12-25 | 2016-05-04 | 张家港大塚化学有限公司 | High anti-wet traction rubber composition, preparing method and tire containing high anti-wet traction rubber composition |
| CN106046436A (en) * | 2016-06-17 | 2016-10-26 | 山东容奈材料设计有限公司 | Graphene rubber compound on basis of electric conduction and heat conduction, application of graphene rubber compound and method for preparing same |
| CN106084355A (en) * | 2015-08-29 | 2016-11-09 | 山东丰源轮胎制造股份有限公司 | Rubber composition and preparation method thereof, semi-steel radial tire |
| CN106084340A (en) * | 2016-06-14 | 2016-11-09 | 航天材料及工艺研究所 | A kind of method preparing the carbon nano-tube filled nitrile rubber of heat oxygen aging resistance |
| CN106317516A (en) * | 2016-08-31 | 2017-01-11 | 青岛大学 | Graphene modification based antistatic rubber composite material and preparation method thereof |
| WO2017005855A1 (en) * | 2015-07-07 | 2017-01-12 | Rythm | Polymer composition and electrode for a device for the non-invasive measurement of biological electrical signals |
| WO2017143619A1 (en) * | 2016-02-24 | 2017-08-31 | 香港纺织及成衣研发中心有限公司 | Rubber for textile roller and preparation method therefor |
| CN107129613A (en) * | 2017-04-28 | 2017-09-05 | 哈尔滨工业大学 | It is a kind of that the method for preparing graphene/rubber composite is combined based on spray drying and hot-press vulcanization |
| CN107501886A (en) * | 2017-08-01 | 2017-12-22 | 湖北运来塑胶科技有限公司 | Carbon nano-tube filled PC/ABS composites of a kind of modified graphene and preparation method thereof |
| CN107746489A (en) * | 2016-09-27 | 2018-03-02 | 钟光 | It is a kind of to use rubber composite of composite nano carbon and preparation method thereof |
| CN107955239A (en) * | 2017-11-29 | 2018-04-24 | 中国航发北京航空材料研究院 | The hydrogenated nitrile-butadiene rubber nanocomposite and preparation method of a kind of graphene-containing |
| CN108461305A (en) * | 2018-03-26 | 2018-08-28 | 新乡学院 | A kind of preparation method of the three-layer laminated combination electrode material of stamen shape carbon nano tube/graphene |
| CN109553829A (en) * | 2018-10-24 | 2019-04-02 | 上海五同同步带有限公司 | A kind of antistatic elastic composition |
| CN109705407A (en) * | 2018-12-17 | 2019-05-03 | 苏州鼎烯聚材纳米科技有限公司 | A kind of production method of graphene rubber concentrate feed and graphene rubber |
| CN110698737A (en) * | 2019-09-26 | 2020-01-17 | 江苏新奥碳纳米材料应用技术研究院有限公司 | Graphene-reinforced antistatic rubber composition and preparation method thereof |
| CN113308030A (en) * | 2021-04-28 | 2021-08-27 | 中国化工株洲橡胶研究设计院有限公司 | Rubber spinning wheel sizing material, preparation method and application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417610A (en) * | 2011-07-13 | 2012-04-18 | 青岛科技大学 | Graphene/carbon nanotube hybrid polymer composite material |
| WO2012100301A1 (en) * | 2011-01-27 | 2012-08-02 | The University Of Queensland | Sulfur-carbon material and use as cathodes for high energy batteries |
| CN102712764A (en) * | 2009-11-18 | 2012-10-03 | 拜耳材料科技股份有限公司 | Method for producing composite materials based on polymers and carbon nanotubes (CNTS), and composite materials produced in this manner and the use thereof |
| CN103937264A (en) * | 2014-04-01 | 2014-07-23 | 天津大学 | graphene coordinated carbon nanotube-silicone rubber composite material and preparation method thereof |
| CN104098834A (en) * | 2013-04-12 | 2014-10-15 | 中国石油化工股份有限公司 | Conductive polymer composite material and preparation method thereof |
-
2014
- 2014-12-08 CN CN201410739808.1A patent/CN104371153A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102712764A (en) * | 2009-11-18 | 2012-10-03 | 拜耳材料科技股份有限公司 | Method for producing composite materials based on polymers and carbon nanotubes (CNTS), and composite materials produced in this manner and the use thereof |
| WO2012100301A1 (en) * | 2011-01-27 | 2012-08-02 | The University Of Queensland | Sulfur-carbon material and use as cathodes for high energy batteries |
| CN102417610A (en) * | 2011-07-13 | 2012-04-18 | 青岛科技大学 | Graphene/carbon nanotube hybrid polymer composite material |
| CN104098834A (en) * | 2013-04-12 | 2014-10-15 | 中国石油化工股份有限公司 | Conductive polymer composite material and preparation method thereof |
| CN103937264A (en) * | 2014-04-01 | 2014-07-23 | 天津大学 | graphene coordinated carbon nanotube-silicone rubber composite material and preparation method thereof |
Cited By (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105111531A (en) * | 2015-04-29 | 2015-12-02 | 宁波职业技术学院 | Graphene-modified wear-resistant rubber |
| CN104861244B (en) * | 2015-05-14 | 2018-08-24 | 安徽世界村新材料有限公司 | A kind of graphene modified montmorillonoid/carbon nanotube/reclaimed rubber composite and flexible material and preparation method thereof |
| CN104861244A (en) * | 2015-05-14 | 2015-08-26 | 安徽红太阳新材料有限公司 | Graphene-modified montmorillonite/carbon nanotube/reclaimed rubber composite flexible material and preparation method thereof |
| WO2017005855A1 (en) * | 2015-07-07 | 2017-01-12 | Rythm | Polymer composition and electrode for a device for the non-invasive measurement of biological electrical signals |
| CN108026313A (en) * | 2015-07-07 | 2018-05-11 | 里思姆公司 | The electrode of polymer composition and device for bioelectrical signals non-invasive measurement |
| CN106084355A (en) * | 2015-08-29 | 2016-11-09 | 山东丰源轮胎制造股份有限公司 | Rubber composition and preparation method thereof, semi-steel radial tire |
| CN105037830A (en) * | 2015-09-08 | 2015-11-11 | 中北大学 | High-strength low-heat-generation composite material and preparation method thereof |
| CN105419004A (en) * | 2015-12-25 | 2016-03-23 | 张家港大塚化学有限公司 | High-heat-conductive rubber composition, preparation method thereof and tyre |
| CN105542258A (en) * | 2015-12-25 | 2016-05-04 | 张家港大塚化学有限公司 | High anti-wet traction rubber composition, preparing method and tire containing high anti-wet traction rubber composition |
| US11371169B2 (en) | 2016-02-24 | 2022-06-28 | The Hong Kong Research Institute Of Textiles And Apparel Limited | Rubber for textile roller and preparation method therefor |
| WO2017143619A1 (en) * | 2016-02-24 | 2017-08-31 | 香港纺织及成衣研发中心有限公司 | Rubber for textile roller and preparation method therefor |
| CN107118406A (en) * | 2016-02-24 | 2017-09-01 | 香港纺织及成衣研发中心有限公司 | A kind of weaving roller rubber and preparation method thereof |
| CN107118406B (en) * | 2016-02-24 | 2019-05-28 | 香港纺织及成衣研发中心有限公司 | A kind of weaving roller rubber and preparation method thereof |
| CN106084340A (en) * | 2016-06-14 | 2016-11-09 | 航天材料及工艺研究所 | A kind of method preparing the carbon nano-tube filled nitrile rubber of heat oxygen aging resistance |
| CN106046436A (en) * | 2016-06-17 | 2016-10-26 | 山东容奈材料设计有限公司 | Graphene rubber compound on basis of electric conduction and heat conduction, application of graphene rubber compound and method for preparing same |
| CN106317516A (en) * | 2016-08-31 | 2017-01-11 | 青岛大学 | Graphene modification based antistatic rubber composite material and preparation method thereof |
| CN107746489A (en) * | 2016-09-27 | 2018-03-02 | 钟光 | It is a kind of to use rubber composite of composite nano carbon and preparation method thereof |
| CN110818977A (en) * | 2016-09-27 | 2020-02-21 | 青岛泰歌新材料科技有限公司 | Rubber composite material using composite nano carbon and preparation method thereof |
| CN110818977B (en) * | 2016-09-27 | 2022-11-04 | 青岛泰歌新材料科技有限公司 | Rubber composite material using composite nano carbon and preparation method thereof |
| CN107746489B (en) * | 2016-09-27 | 2019-12-03 | 青岛泰歌新材料科技有限公司 | A kind of rubber composite material and preparation method thereof using composite nano carbon |
| CN107129613B (en) * | 2017-04-28 | 2019-03-08 | 哈尔滨工业大学 | A method of it combines based on spray drying and hot-press vulcanization and prepares graphene/rubber composite material |
| CN107129613A (en) * | 2017-04-28 | 2017-09-05 | 哈尔滨工业大学 | It is a kind of that the method for preparing graphene/rubber composite is combined based on spray drying and hot-press vulcanization |
| CN107501886A (en) * | 2017-08-01 | 2017-12-22 | 湖北运来塑胶科技有限公司 | Carbon nano-tube filled PC/ABS composites of a kind of modified graphene and preparation method thereof |
| CN107955239A (en) * | 2017-11-29 | 2018-04-24 | 中国航发北京航空材料研究院 | The hydrogenated nitrile-butadiene rubber nanocomposite and preparation method of a kind of graphene-containing |
| CN108461305A (en) * | 2018-03-26 | 2018-08-28 | 新乡学院 | A kind of preparation method of the three-layer laminated combination electrode material of stamen shape carbon nano tube/graphene |
| CN109553829A (en) * | 2018-10-24 | 2019-04-02 | 上海五同同步带有限公司 | A kind of antistatic elastic composition |
| CN109705407B (en) * | 2018-12-17 | 2021-06-08 | 苏州鼎烯聚材纳米科技有限公司 | Graphene rubber concentrated material and production method of graphene rubber |
| CN109705407A (en) * | 2018-12-17 | 2019-05-03 | 苏州鼎烯聚材纳米科技有限公司 | A kind of production method of graphene rubber concentrate feed and graphene rubber |
| CN110698737A (en) * | 2019-09-26 | 2020-01-17 | 江苏新奥碳纳米材料应用技术研究院有限公司 | Graphene-reinforced antistatic rubber composition and preparation method thereof |
| CN113308030A (en) * | 2021-04-28 | 2021-08-27 | 中国化工株洲橡胶研究设计院有限公司 | Rubber spinning wheel sizing material, preparation method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104371153A (en) | Rubber composite modified by carbon nano tubes and graphene jointly | |
| Mondal et al. | Elastomer reinforcement by graphene nanoplatelets and synergistic improvements of electrical and mechanical properties of composites by hybrid nano fillers of graphene-carbon black & graphene-MWCNT | |
| Mensah et al. | Graphene-reinforced elastomeric nanocomposites: A review | |
| Luo et al. | Fabrication of conductive elastic nanocomposites via framing intact interconnected graphene networks | |
| Zhang et al. | In situ shear-induced mercapto group-activated graphite nanoplatelets for fabricating mechanically strong and thermally conductive elastomer composites for thermal management applications | |
| Xu et al. | Effects of functional graphene oxide on the properties of phenyl silicone rubber composites | |
| Zhang et al. | Fundamental researches on graphene/rubber nanocomposites | |
| CN106674657B (en) | A kind of antistatic low fatigue temperature rise tire tread rubber material of high wet-sliding resistant and preparation method thereof | |
| CN108610511A (en) | A kind of functionalization two-dimensional layer transition metal carbide material f-MXene and preparation method thereof and the application in rubber | |
| CN103214850B (en) | A kind of melting silicone rubber base conductance non-linear dielectric materials | |
| Song | Synergistic effect of clay platelets and carbon nanotubes in styrene–butadiene rubber nanocomposites | |
| EP2930204A1 (en) | Rubber composite composition for highly thermally conductive bladder comprising carbon nanotubes and production method for same | |
| CN107325520B (en) | A kind of preparation method of antistatic modified plastics | |
| Liu et al. | Improving thermal conductivity of styrene-butadiene rubber composites by incorporating mesoporous silica@ solvothermal reduced graphene oxide hybrid nanosheets with low graphene content | |
| Liu et al. | Conducting and stretchable composites using sandwiched graphene-carbon nanotube hybrids and styrene-butadiene rubber | |
| CN102417610A (en) | Graphene/carbon nanotube hybrid polymer composite material | |
| Wang et al. | Two-dimensional layered double hydroxides nanoplatelets assembled in situ on SiO2 nanoparticles for high-performing hydrogenated nitrile butadiene rubber | |
| CN103214747B (en) | Ethylene propylene diene copolymer-based conductive nonlinear insulating material | |
| Yang et al. | Challenge of rubber/graphene composites aiming at real applications | |
| Song | The effect of clay/multiwall carbon nanotube hybrid fillers on the properties of elastomer nanocomposites | |
| CN108003626A (en) | conductive silicon rubber and preparation method thereof | |
| Song et al. | Effect of an interface layer on thermal conductivity of polymer composites studied by the design of double-layered and triple-layered composites | |
| CN105111642A (en) | Tetrapropyl fluoro rubber with low-compression permanent deformation performance and preparation method for tetrapropyl fluoro rubber | |
| Pradhan et al. | Graphene and MnO2 decorated graphene filled composites for electromagnetic shielding applications having excellent dielectric properties | |
| Shahamatifard et al. | Thermal and mechanical properties of carbon-based rubber nanocomposites: A review |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150225 |