CN102417610A - Graphene/carbon nanotube hybrid polymer composite material - Google Patents
Graphene/carbon nanotube hybrid polymer composite material Download PDFInfo
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- CN102417610A CN102417610A CN201110203850.8A CN201110203850A CN102417610A CN 102417610 A CN102417610 A CN 102417610A CN 201110203850 A CN201110203850 A CN 201110203850A CN 102417610 A CN102417610 A CN 102417610A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 106
- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 53
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 53
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 50
- 229920000642 polymer Polymers 0.000 title claims abstract description 19
- 239000002131 composite material Substances 0.000 title claims abstract description 15
- 239000011159 matrix material Substances 0.000 claims abstract description 22
- 229920001971 elastomer Polymers 0.000 claims abstract description 14
- 239000005060 rubber Substances 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000009396 hybridization Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 9
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 238000010297 mechanical methods and process Methods 0.000 claims description 2
- 230000005226 mechanical processes and functions Effects 0.000 claims description 2
- 238000007306 functionalization reaction Methods 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 1
- 239000004677 Nylon Substances 0.000 claims 1
- 239000004642 Polyimide Substances 0.000 claims 1
- 239000000806 elastomer Substances 0.000 claims 1
- 239000003822 epoxy resin Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 239000002048 multi walled nanotube Substances 0.000 claims 1
- 229920001778 nylon Polymers 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 229920003023 plastic Polymers 0.000 claims 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 1
- 229920000647 polyepoxide Polymers 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 229920001721 polyimide Polymers 0.000 claims 1
- 239000004926 polymethyl methacrylate Substances 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229920003048 styrene butadiene rubber Polymers 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000003973 paint Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 238000005987 sulfurization reaction Methods 0.000 description 2
- 238000010408 sweeping Methods 0.000 description 2
- 238000007605 air drying Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000001132 ultrasonic dispersion Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
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Abstract
The invention discloses a graphene/carbon nanotube hybrid polymer composite material and a manufacturing method thereof. Graphene, carbon nanotube and a polymer matrix material are subjected to solution blending or mechanical blending to obtain the graphene/carbon nanotube hybrid polymer composite material. The high-conductivity high-mechanical-property composite material can be used as an antistatic and electromagnetic shielding material, can be made into conductive carpets, electronic product packages, mobile phone components, antistatic tread rubber for tires, electromagnetic shielding paint of aerospace devices and the like, and has wide application value.
Description
Technical field
The polymer composites that the present invention relates to a kind of electroconductibility Graphene carbon nano-tube hybridization with and method of manufacture; The polymer composites of this Graphene carbon nano-tube hybridization can be used as antistatic and electromagnetic shielding material, and the parts, tire that are made into packing, the mobile phone of conduction carpet, electronic product are with the electromagnetic screen coating of antistatic tread rubber and aerospace equipment etc.
Background technology
Since Iijima in 1991 finds that carbon nanotube and Andre Geim in 2004 and Kostya Novoselov are prepared Graphene first; These two kinds of carbon nanomaterials just receive widely and paying attention to; Because the two all has very outstanding physical properties; Be expected to give the polymkeric substance better properties through to polymer modification.But the application of carbon nanotube exists two important problem not solve always, and one is the dispersion of carbon nanotube, because it is very easy to reunite, another problem is exactly expensive.The appearance of Graphene appears as these two difficult problems of solution answer is provided.Graphene is similar with the chemical structure of carbon nanotube, but Graphene is the two-dimensional plane structure, and carbon nanotube is the unidimensional linear structure, and the difference of the two form has caused both unique character just.A large amount of storages of natural graphite make the preparation of Graphene of a large amount of cheapnesss become possibility.And we discover, when carbon nanotube and Graphene made an addition in the polymkeric substance jointly, the tendency that carbon nanotube is reunited also alleviated greatly.Thereby Graphene and carbon nano-tube hybridization become the simple method of effective dispersing Nano carbon tubes.
This invention makes an addition to Graphene and carbon nanotube in the polymeric matrix jointly; Form the polymer nanocomposites that conducts electricity and have high-intensity Graphene carbon nano-tube hybridization; As antistatic and electromagnetic shielding material, the parts, tire that are made into packing, the mobile phone of conduction carpet, electronic product are with the electromagnetic screen coating of antistatic tread rubber and aerospace equipment etc.
Summary of the invention
To achieve these goals; According to claims 1 described the present invention, adopting the Graphene of different degree of oxidations and carbon nanotube is conduction and strongthener, adds in the polymkeric substance; Preparation Graphene content is 0.1-90wt%; Content of carbon nanotubes is 0.1-90wt%, and the total amount of Graphene and carbon nanotube is the polymer composites of the Graphene carbon nano-tube hybridization of 0.1-90wt%, and this material has high electroconductibility and mechanical property; Can be used for antistatic and electromagnetic shielding material, the parts, tire that are made into packing, the mobile phone of conduction carpet, electronic product are with the electromagnetic screen coating of antistatic tread rubber and aerospace equipment etc.
An object of the present invention is to provide a kind of polymer composites, improve the electroconductibility of matrix material based on Graphene and the common modification of carbon nano-tube hybridization material.
Another object of the present invention provides a kind of polymer composites of the common modification based on Graphene and carbon nano-tube hybridization, when improving electroconductibility, also can improve the mechanical property (intensity, hardness etc.) and the thermostability of material.
The method for preparing Graphene carbon nano-tube hybridization polymer composites used in the present invention can adopt solution method, also can adopt mechanical process to realize the compound of Graphene carbon nanotube and polymkeric substance.
The present invention compared with prior art, its significant advantage is: (1) utilizes the good dispersion of Graphene in polymkeric substance, the auxiliary dispersion of carbon nanotube in polymkeric substance, method is simple, has avoided complicated spreading the work.(2) preparation method is last, utilizes the preparation of solution blending or blend technique, and is simple, can realize the dispersion in polymer composites of Graphene and carbon nanotube well.(3) prepared graphene carbon nanotube polymer matrix material not only has good electrical conductivity but also has higher mechanical property.
Description of drawings
Fig. 1 is the surface sweeping electron microscope picture of carbon nanotube in Zylox, explains that carbon nanotube is easy to reunite in Zylox, is not easy to disperse.
Fig. 2 is Graphene and the surface sweeping electron microscope picture of carbon nanometer co-dispersed in Zylox, explains that carbon nanotube is dispersed in the Zylox down the auxiliary of Graphene well, does not form and reunites.
Fig. 3 is in Graphene/carbon nanotube/cis-1,4-polybutadiene rubber matrix material, and when the consumption of Graphene is 1 part, the consumption of cis-1,4-polybutadiene rubber is 100 parts, and the volume specific resistance of system descends along with the increase of carbon nanotube consumption.
Fig. 4 is that carbon nanotube is when adding in the cis-1,4-polybutadiene rubber separately; The relation of consumption and volume specific resistance; Explanation; When Graphene and carbon nanotube added in the cis-1,4-polybutadiene rubber jointly, the consumption of carbon nanotube reduced and just can reach identical conductive effect, was that dispersiveness polymeric matrix is better than carbon nanotube and is distributed in the polymeric matrix separately from another side illustration carbon nanotube and Graphene hydridization.
Specific embodiments
The present invention is polymer-modified jointly with Graphene and carbon nanotube, obtains Graphene carbon nanotube polymer matrix material, has high electroconductibility and mechanical property.Following embodiment further specifies of the present invention, rather than limits scope of the present invention.
Embodiment 1:
With the cis-1,4-polybutadiene rubber is example.According to 1: 9: 100 banburying 10min in Banbury mixer of part by weight, the matrix material of acquisition is at 160 ℃ with Graphene, carbon nanotube and cis-1,4-polybutadiene rubber, and sulfuration 10min obtains Graphene/carbon nanotube/cis-1,4-polybutadiene rubber matrix material.The volume volume specific resistance of this material is 7 * 10
6Ω cm, tensile strength is 3MPa, tear strength 18KN/m.
Embodiment 2:
With Zylox is example.Zylox 100g is dissolved in the THF (THF) of 500ml; Graphene and carbon nanotube were according to 1: 2 part by weight; Gross weight 3g, mixes two kinds of dispersion liquids in 100ml THF through ultra-sonic dispersion then, in air and vacuum drying oven, removes excessive THF.The matrix material that obtains is at 160 ℃, and sulfuration 10min obtains Graphene/carbon nanometer tube/silicon rubber composite.The volume specific resistance of this material is 4.9 * 10
9Ω cm, tensile strength is 1MPa.
Claims (9)
1. the polymer composites of Graphene carbon nano-tube hybridization is characterized in that:
Graphene and carbon nanotube in polymeric matrix material, have been added.
2. matrix material as claimed in claim 1, wherein Graphene accounts for the 0.1-80wt% of the total amount of matrix material, and carbon nanotube accounts for the 0.1-90wt% of matrix material total amount, and Graphene and carbon nanotube account for the 0.1-90wt% of matrix material total amount altogether.
3. matrix material as claimed in claim 1, carbon nanotube wherein comprise the various carbon nano-tube materials of SWCN, multi-walled carbon nano-tubes and functionalization; Graphene is graphene film functionalization and unmodified.
4. matrix material as claimed in claim 1, polymkeric substance wherein comprises macromolecular materials such as plastics, rubber and coating.
5. matrix material as claimed in claim 1; Polymeric matrix wherein comprises materials such as the multipolymer, PS, SE, polymethylmethacrylate, polyacrylic ester, polyester, nylon, polyimide, urethane, epoxy resin of Vilaterm, Vestolen PP 7052, ethene and propylene, or the mixture of one of them kind.
6. matrix material as claimed in claim 1, wherein said polymeric matrix comprise the mixture of various elastomericss such as sulfurized tree elastomer, cis-1,4-polybutadiene rubber, styrene-butadiene rubber(SBR), polystyrene-poly isoprene-PS (SIS), Zylox and one of them kind.
7. method that is used to make Graphene carbon nano-tube hybridization polymer composites, wherein the content of oxide group is 0-95% in the Graphene, the oxide group content in the carbon nanotube is 0-95%.
8. method as claimed in claim 7, wherein the addition of Graphene is 0.1-80wt%, and the addition of carbon nanotube is 0.1-80wt%, and carbon nanotube and Graphene account for the 0.1-90wt% of polymkeric substance total amount altogether.
9. method as claimed in claim 7 is solution method or mechanical process with the method for Graphene and polymer blending.
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| CN201110203850.8A CN102417610A (en) | 2011-07-13 | 2011-07-13 | Graphene/carbon nanotube hybrid polymer composite material |
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| CN201110203850.8A CN102417610A (en) | 2011-07-13 | 2011-07-13 | Graphene/carbon nanotube hybrid polymer composite material |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101558455A (en) * | 2006-10-06 | 2009-10-14 | 普林斯顿大学理事会 | Functional graphene-rubber nanocomposites |
| CN101734650A (en) * | 2009-12-23 | 2010-06-16 | 沈阳建筑大学 | Method for preparing graphene-carbon nano tube hybrid composite |
-
2011
- 2011-07-13 CN CN201110203850.8A patent/CN102417610A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101558455A (en) * | 2006-10-06 | 2009-10-14 | 普林斯顿大学理事会 | Functional graphene-rubber nanocomposites |
| CN101734650A (en) * | 2009-12-23 | 2010-06-16 | 沈阳建筑大学 | Method for preparing graphene-carbon nano tube hybrid composite |
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