CN104370432B - A kind of sewage treatment process for reducing flocculant usage - Google Patents

A kind of sewage treatment process for reducing flocculant usage Download PDF

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Publication number
CN104370432B
CN104370432B CN201410333611.8A CN201410333611A CN104370432B CN 104370432 B CN104370432 B CN 104370432B CN 201410333611 A CN201410333611 A CN 201410333611A CN 104370432 B CN104370432 B CN 104370432B
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China
Prior art keywords
sludge
sedimentation tank
filtrate
pond
pumped
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Expired - Fee Related
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CN201410333611.8A
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CN104370432A (en
Inventor
石建东
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Jiangxi Qinggan Environmental Technology Co.,Ltd.
Jiangxi Qinghuan Natural Environment Technology Co ltd
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Individual
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/122Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using filter presses

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention belongs to technical field of sewage, more particularly to a kind of sewage treatment process for reducing flocculant usage.It comprises the steps:Step 1, sludge is pumped into sludge concentration tank carries out sludge condensation;Thickened sludge in step 1 is pumped into dynamic mixer by sludge pump;Medicinal liquid in medicinal liquid agitating pond is pumped into dosing pond carries out dosing proportioning;Medicinal liquid of the dosing pond after dosing proportioning in step 3 is pumped into dynamic mixer through compound pump;Dynamic mixer enters Mobile state mixing to thickened sludge and medicinal liquid;After step 5 dynamic is mixed sludge will pump into sludge filter press and carry out filter pressing operation;Filter cake after step 6 filter pressing is discharged sludge filter press, remaining filtrate enters filtrate sedimentation tank and carries out concentration precipitation;Supernatant in sedimentation tank is pumped into medicinal liquid agitating pond carries out uniform stirring;The operation of repeat step 3;Precipitate in filtrate sedimentation tank in step 7 is extracted out from bottom of pond, importing sludge concentration tank carries out step 6 and operates.

Description

A kind of sewage treatment process for reducing flocculant usage
Technical field
The invention belongs to technical field of sewage, more particularly to a kind of sewage treatment process for reducing flocculant usage.
Background technology
With the continuous improvement of China's urban wastewater treatment rate, town sewage plant sludge output is also sharply increased.2009 complete State puts into operation urban wastewater treatment firm 1992,280 billion cubic meter of sewage load, produces the sludge 2005 of moisture content 80% or so Ten thousand.With being put into operation in the 2000 Duo Zuo sewage treatment plants for building successively, national sludge yield will break through 30,000,000 tons quickly. China's majority sludge from wastewater treatment plant processing method adopts thickening, and adopts sewage treatment plant's ratio of stabilizing treatment Example less than 20%, the final disposal that have impact on sludge to a great extent not in place that most of sludge of sewage treatment plant is processed. The excess sludge that sewage is produced during biochemical treatment is the negatively charged of moisture content abundant (moisture content up to 95% 99.5%) The population of lotus, therefore dehydrating operations must be carried out to which, the quality and volume of sludge to reduce moisture percentage in sewage sludge, is reduced, so as to In further disposing.At present, maximally effective reduction moisture percentage in sewage sludge approach is to select suitable flocculant according to concrete condition, its Action principle is by adding flocculant, chemically reacts in sludge colloid layer surface, neutralizes the electric charge of sludge gelatinous layer, and leads to Crossing bridging action promotes mud granule to be condensed into big granule flock, while make water spin off from mud granule, so as to Improve dewatering performance of sludge., it is extremely urgent, the technique one of current sewage disposal all the time for how sewage processes this problem It is directly to continue to use traditional handicraft, i.e. agent-feeding treatment, sludge dewatering is arranged outside waste water.In the agent-feeding treatment stage, " flocculant " is sewage Requisite, so-called flocculant refers to the high molecular polymer that scattered fine-grained solids in liquid can be made to form flocculate;Press Inorganic and organic two class can be totally divided into according to its chemical composition.Wherein inorganic flocculating agent includes inorganic flocculant and inorganic polymer Flocculant;Organic flocculant includes Syn-Organic flocculants, natural organic high-molecular flocculant and microbial flocculant, Theoretical basiss are that " coalescence " is theoretical, flocculant mainly by with just (bear) in electrical group with some water in bearing (just) neutralization of detached granule is electrically difficult to, is that granule tends towards stability state in sewage so as to reduce sewage potential, and is utilized which The property of polymerization causes these granules to concentrate, and separates eventually through physics or chemical method, and after agent-feeding treatment Sludge separate after, its waste water is generally directly outer to be arranged, so the problem that prior art is present is:Using flocculant by sewage It is disposable operation to be condensed, and not only makes flocculant cause substantial amounts of waste, also easily causes secondary pollution to environment.
Content of the invention
The technical problem to be solved in the present invention is:There is provided one kind can avoid flocculant from wasting and cause secondary dirt to environment The sewage treatment process of the reduction flocculant usage of dye.
The present invention technical solution be:A kind of sewage treatment process for reducing flocculant usage, it is characterised in that:Bag Include following steps:
Step 1, sludge is pumped into sludge concentration tank carries out sludge condensation operation;
Thickened sludge in step 1 is pumped into dynamic mixer by sludge pump by step 2;
Step 3, the medicinal liquid in medicinal liquid agitating pond is pumped into dosing pond carries out dosing proportioning;
Medicinal liquid of the dosing pond after dosing proportioning in step 3 is pumped into dynamic mixer through compound pump by step 4;
Step 5, dynamic mixer enter Mobile state mixing to thickened sludge and medicinal liquid;
Step 6, after step 5 dynamic is mixed sludge will pump into sludge filter press and carry out filter pressing operation;
Filter cake after step 6 filter pressing is discharged sludge filter press by step 7, and remaining filtrate enters filtrate sedimentation tank Carry out concentration precipitation;
Step 8, the supernatant in sedimentation tank is pumped into medicinal liquid agitating pond carries out uniform stirring;
Step 9, the operation of repeat step 3;
Step 10, the precipitate in filtrate sedimentation tank in step 7 is extracted out from bottom of pond, and importing sludge concentration tank carries out step 6 operations;
After using above scheme, compared with prior art, the present invention has advantages below:Filtrate collection after by mud-water separation Middle precipitation, extracting supernatant carries out the important component part of flocculant decrement production, and volume is bigger, and filtrate settling ratio is higher.? Filtrate sedimentation tank after sludge dewatering after waste water importing filter pressing machine room is precipitated, and installs water pump additional, and pipe laying extracts supernatant Dosing pond between pressure mud is imported, is replaced clear water to mix medicine, is constituted utilization process flow process.Wastewater recycling device, using waste water in " flocculant " molecule content, reduces " flocculant " production consumption, not only can so avoid flocculant from wasting, save flocculant Consumption, and do not have outside industrial wastewater and arrange, be internally circulated all the time, it is to avoid secondary pollution.
Preferably, remaining filtrate enters filtrate sedimentation tank to carry out concentrating precipitation to specifically refer to the dirt produced at sludge pump Mud enters filtrate sedimentation tank through mechanical dehydration, the filtrate by mud, after water is separated;The filtrate so entered in filtrate sedimentation tank contains Some flocculating agent molecules are more, and the supernatant recovery utilization rate after precipitate and separate is higher.
As improvement, it is also equipped with described medicinal liquid agitating pond for detecting the electron concentration of flocculant concentration in stirring pool Measuring instrument;As the presence of electron concentration measuring instrument can be with scientific and effective regulation and control " flocculant " consumption.
Preferably, described filtrate sedimentation tank including water inlet, outlet and mud discharging mouth, described mud discharging mouth is located at The bottom of sedimentation tank, described water inlet and outlet are all located on sedimentation tank pool wall and the height of water inlet is less than outlet Highly;Such structure can ensure that and effectively precipitate filtrate that the mud of bottom can be discharged in time, and be sunk by filtrate It is supernatant in filtrate sedimentation tank that shallow lake pond is sent into when making up a prescription pond.
Used as improvement, also having in described filtrate sedimentation tank is used for detecting the turbid of filtrate muddiness degree in filtrate sedimentation tank Degree detector, in filtrate sedimentation tank, such benefit is can to detect that filtrate is precipitated in time to described Turbidity measurement instrument Muddy degree in pond, enters unnecessary outstanding solidifying agent molecule into dosing pond after float can be caused further to precipitate again.
As improvement, in described filtrate sedimentation tank, there is the chromaticity detector for being used for detecting colourity in filtrate sedimentation tank, The induction apparatuss of described chromaticity detector are installed in the middle part of filtrate sedimentation tank;In sedimentation tank, the colourity of precipitated liquid is also that reflection is heavy One of performance of concentration of suspension in the pond of shallow lake, so it is dense to set up the float that chromaticity detector further can be detected in sedimentation tank Degree.
As improvement, concentration of suspension detector, described concentration of suspension inspection in described filtrate sedimentation tank, is additionally provided with Survey the middle part of the induction apparatuss installed in filtrate sedimentation tank of instrument;Float detector can also further detect the suspension in sedimentation tank The concentration of thing, multinomial detection is so that it is guaranteed that the liquid entered in dosing stirring pool is the supernatant containing outstanding solidifying agent.
Figure of description
Sewage treatment process figure of the accompanying drawing 1 for prior art.
Sewage treatment process figure of the accompanying drawing 2 for the present invention.
Work model of the accompanying drawing 3 for the filtrate sedimentation tank of the present invention.
Description of the drawings:U0, the heavy speed of retention, II, the movement locus of the granule of u0, the movement locus of the granule of II `, u0, A: Filtrate sedimentation tank surface area,
Specific embodiment
As can be seen from Figure 1 in the current sewage disposal of China, sludge treating block technological process is formed after sludge dewatering Mud cake outward transport is disposed, and dumps use after mud-water separation outside filtrate mixing shower water, and some enterprises enter environment the waste water that discharges, or Wastewater inlet is imported, sewage disposal production line is entered, is formed and is repeated to process, cause resource waste and pollution environment.
Sewage disposal used " flocculant " belongs to macromolecular compound, with " pole is dissolved in water " same characteristic, with hydrone For substrate flocculated suspension thing, coagulating sedimentation, stable chemical nature, after " flocculant " is mixed with primary sludge after dilution, trip is formed From molecule, through dewatering technology of mud flow process, mud-water separation, after separating, water body carries a large amount of " flocculant " molecules and is discharged, I With dosing pond " flocculant " levels as reference data, using titrimetry, settling ratio, do chemical content test, calculate After mud-water separation, in filtrate, contained " flocculant " content in more than 0.22mg/L, has very high value.
Experimental comparison:
We are studied from sludge treating block for point of penetration, are keeping, in original sludge treatment technique flow process, creating Invention, newly designs a set of technological process, and waste water recycling reduces the production consumption of " flocculant ".
As shown in Figure 2:A kind of sewage treatment process for reducing flocculant usage, it is characterised in that:Comprise the steps:
Step 1, sludge is pumped into sludge concentration tank carries out sludge condensation operation;
Thickened sludge in step 1 is pumped into dynamic mixer by sludge pump by step 2;
Step 3, the medicinal liquid in medicinal liquid agitating pond is pumped into dosing pond carries out dosing proportioning;
Medicinal liquid of the dosing pond after dosing proportioning in step 3 is pumped into dynamic mixer through compound pump by step 4;
Step 5, dynamic mixer enter Mobile state mixing to thickened sludge and medicinal liquid;
Step 6, after step 5 dynamic is mixed sludge will pump into sludge filter press and carry out filter pressing operation;
Filter cake after step 6 filter pressing is discharged sludge filter press by step 7, and remaining filtrate enters filtrate sedimentation tank Carry out concentration precipitation;
Step 8, the supernatant in sedimentation tank is pumped into medicinal liquid agitating pond carries out uniform stirring;
Step 9, the operation of repeat step 3;
Step 10, the precipitate in filtrate sedimentation tank in step 7 is extracted out from bottom of pond, and importing sludge concentration tank carries out step 6 operations;
Can ensure that the supernatant in filtrate sedimentation tank is again introduced into medicinal liquid agitating pond through above step, maximum is good Place is that of avoiding secondary pollution, so as to reduce " three cause effect " as flocculant secondary pollution is caused (teratogenesis, mutagenesis, Carcinogenic), remaining filtrate enters filtrate sedimentation tank and carries out concentrating precipitation to specifically refer to the sludge produced at sludge pump through machinery Dehydration, the filtrate after mud, water are separated enter filtrate sedimentation tank, and the filtrate for so entering filtrate sedimentation tank contains more flocculation Agent molecule, but remain on also more mud granule thing simultaneously, proceed flocculation process, sludge in filtrate sedimentation tank Particulate matter can sink to the bottom of filtrate sedimentation tank in flocculation process, and supernatant is then to have contained substantially residue without granule Supernatant is pumped into medicinal liquid agitating pond and replaces original clear water to mix medicine by the liquid of flocculant, when dosing again can be greatly reduced, The consumption of flocculant, while be also equipped with described medicinal liquid agitating pond for detecting the electron concentration of flocculant concentration in stirring pool Measuring instrument;Carried out with electronics concentration measuring apparatus real-time Concentration Testing can with the concentration levels in real-time detection medicinal liquid agitating pond, So as to prevent flocculant usage excessive.Described filtrate sedimentation tank including water inlet, outlet and mud discharging mouth, described spoil disposal Mouthful it is located at the bottom of sedimentation tank, described water inlet and outlet is all located on sedimentation tank pool wall and the height of water inlet is less than out The height at the mouth of a river;It is convenient that such structure causes supernatant to extract, and the sedimentation effect of filtrate sedimentation tank is preferable;Described filtrate There are the Turbidity measurement instrument for being used for detecting the filtrate muddiness degree in filtrate sedimentation tank, described Turbidity measurement instrument peace in sedimentation tank It is mounted in filtrate sedimentation tank, such benefit is can to detect the muddy degree in filtrate sedimentation tank in time, can causes to suspend Thing is entered unnecessary outstanding solidifying agent molecule into dosing pond after further precipitating again;Also having in described filtrate sedimentation tank is used for detecting The chromaticity detector of colourity in filtrate sedimentation tank, the induction apparatuss of described chromaticity detector are arranged on the middle part of filtrate sedimentation tank; In sedimentation tank, the colourity of precipitated liquid is also to reflect one of performance of concentration of suspension in sedimentation tank, so set up chromaticity detector can Further to detect the concentration of suspension in sedimentation tank;Concentration of suspension detector, institute is additionally provided with described filtrate sedimentation tank The induction apparatuss of the concentration of suspension detector that states are installed in the middle part of filtrate sedimentation tank;Float detector further can also be examined The concentration of the float that surveys in sedimentation tank, multinomial detection is so that it is guaranteed that the liquid entered in dosing stirring pool is containing outstanding solidifying agent Supernatant;The shape of described sedimentation tank can be square, rectangle, circular or oval.
For filtrate sedimentation tank, the hypothesis condition of preferable sedimentation tank:
1. granule carries out free settling, and size, density, heavy speed are constant;
2. on the bottom horizontal flow sheet cross-section of river, each point flow velocity is equal, keeps constant;
3. granule sinks to bottom of pond and is removed, and does not return again in recirculated water.
Can find out from the work model of filtrate sedimentation tank:
The heavy speed u0 of retention
The movement locus that setting tool has the granule of heavy speed u0 are straight line III.
Consideration bottom horizontal flow sheet:
Consideration sinking direction:
SoAnd ∵
(A:Filtrate sedimentation tank surface area)
Therefore, u0 is numerically equal to the flow of unit area, referred to as " surface loading "
The heavy speed of retention:The heavy speed of smallest particles in the caned granule for all removing of sedimentation tank.
The description does not have restricted, and shown in figure is also one of embodiments of the present invention, and actual structure is not It is confined to this.If generally speaking one of ordinary skill in the art is enlightened by which, in the feelings without departing from the invention objective Under condition, the frame mode similar to the technical scheme and embodiment is designed without creative, all should belong to the guarantor of the present invention Shield scope.

Claims (5)

1. a kind of reduce flocculant usage sewage treatment process, it is characterised in that:Comprise the steps:
Step 1, sludge is pumped into sludge concentration tank carries out sludge condensation operation;
Thickened sludge in step 1 is pumped into dynamic mixer by sludge pump by step 2;
Step 3, the flocculant in medicinal liquid agitating pond is pumped into dosing pond is carried out plus flocculant proportioning;
Medicinal liquid of the dosing pond after dosing proportioning in step 3 is pumped into dynamic mixer through compound pump by step 4;
Step 5, dynamic mixer enter Mobile state mixing to thickened sludge and medicinal liquid;
Step 6, after step 5 dynamic is mixed sludge will pump into sludge filter press and carry out filter pressing operation;
Filter cake after step 6 filter pressing is discharged sludge filter press by step 7, and remaining filtrate enters filtrate sedimentation tank and carries out Concentrate precipitation;There is the Turbidity measurement for being used for detecting the filtrate muddiness degree in filtrate sedimentation tank in described filtrate sedimentation tank Instrument, described Turbidity measurement instrument is in filtrate sedimentation tank;
Step 8, the supernatant in sedimentation tank is pumped into medicinal liquid agitating pond carries out uniform stirring;
Step 9, the operation of repeat step 3;
Step 10, the precipitate in filtrate sedimentation tank in step 7 is extracted out from bottom of pond, and importing sludge concentration tank carries out step 2 and grasps Make.
2. according to claim 1 a kind of reduce flocculant usage sewage treatment process, it is characterised in that:Described medicine It is also equipped with liquid stirring pool for detecting the electron concentration measuring instrument of flocculant concentration in stirring pool.
3. according to claim 1 a kind of reduce flocculant usage sewage treatment process, it is characterised in that:Described filter Liquid precipitate pond includes water inlet, outlet and mud discharging mouth, and described mud discharging mouth is located at the bottom of sedimentation tank, described water inlet and Outlet be all located on sedimentation tank pool wall and water inlet height less than outlet height.
4. according to claim 1 a kind of reduce flocculant usage sewage treatment process, it is characterised in that:Described filter The induction apparatuss for also having the chromaticity detector for being used for detecting colourity in filtrate sedimentation tank, described chromaticity detector in liquid precipitate pond are pacified It is mounted in the middle part of filtrate sedimentation tank.
5. according to claim 1 a kind of reduce flocculant usage sewage treatment process, it is characterised in that:Described filter Concentration of suspension detector is additionally provided with liquid precipitate pond, and the induction apparatuss of described concentration of suspension detector are precipitated installed in filtrate The middle part in pond.
CN201410333611.8A 2014-07-14 2014-07-14 A kind of sewage treatment process for reducing flocculant usage Expired - Fee Related CN104370432B (en)

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Application Number Priority Date Filing Date Title
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Publication number Priority date Publication date Assignee Title
FI20165758A (en) * 2016-10-07 2018-04-08 Kemira Oyj Methods and systems for controlling hydrophobic conditions and soiling in water-intensive processes
CN107399897A (en) * 2017-08-04 2017-11-28 胜利油田龙玺石油工程服务有限责任公司 A kind of drilling mud processing unit for recycling sewage
CN111574020A (en) * 2020-04-20 2020-08-25 广州珞珈环境技术有限公司 River and lake sludge conditioning method and system

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JP5164763B2 (en) * 2008-09-22 2013-03-21 株式会社クボタ Belt type concentrator and belt cleaning method for belt type concentrator
CN101935140B (en) * 2010-07-23 2012-08-29 无锡市通用机械厂有限公司 Dehydration treatment method for tail water sludge of water-work and special apparatus thereof
CN203212445U (en) * 2013-04-12 2013-09-25 浙江金佰利环境科技有限公司 Sludge treatment system

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Inventor after: Pan Jinghong

Inventor before: Shi Jiandong

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Effective date of registration: 20180117

Address after: No. two, No. 5, building No. 5, No. two, Longshan Road, Chengguan Town, Lushi County, Henan Province, 6

Patentee after: Pan Jinghong

Address before: 472200 Lushi City, Sanmenxia Province Chengguan Town, West Street, a neighborhood of No. 115, No.

Patentee before: Shi Jiandong

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Address after: Room 2-1602, Room 10 # 2, Tianxing Hanlin Garden, No. 508 Industrial Second Road, Changqu Industrial Park, Xinjian District, Nanchang City, Jiangxi Province

Co-patentee after: Jiangxi Qinggan Environmental Technology Co.,Ltd.

Patentee after: Jiangxi Qinghuan Natural Environment Technology Co.,Ltd.

Address before: 472200 Unit 6, Building No. 5, Longshan Road, Chengguan Town, Lushi County, Sanmenxia City, Henan Province

Patentee before: Pan Jinghong

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20170315