CN104370421A - Modified pumice bioreactor device - Google Patents
Modified pumice bioreactor device Download PDFInfo
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- CN104370421A CN104370421A CN201410650554.6A CN201410650554A CN104370421A CN 104370421 A CN104370421 A CN 104370421A CN 201410650554 A CN201410650554 A CN 201410650554A CN 104370421 A CN104370421 A CN 104370421A
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- 239000008262 pumice Substances 0.000 title claims abstract description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 238000005273 aeration Methods 0.000 claims abstract description 19
- 239000000945 filler Substances 0.000 claims abstract description 18
- 239000002131 composite material Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 3
- 238000001179 sorption measurement Methods 0.000 abstract description 15
- 238000013032 photocatalytic reaction Methods 0.000 abstract description 5
- 239000006227 byproduct Substances 0.000 abstract description 3
- 239000003344 environmental pollutant Substances 0.000 abstract description 3
- 231100000719 pollutant Toxicity 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 229910010413 TiO 2 Inorganic materials 0.000 abstract 1
- 239000011435 rock Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000005335 volcanic glass Substances 0.000 description 2
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910001603 clinoptilolite Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
- C02F3/2813—Anaerobic digestion processes using anaerobic contact processes
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biological Treatment Of Waste Water (AREA)
Abstract
本发明公开了一种改性浮岩生物反应器装置，包括厌氧池、曝气池和复合流过滤罐，厌氧池内填有软性填料层，曝气池中设置改性浮岩悬浮填料；厌氧池左侧下端进水，右侧上端平口堰出水；曝气池左侧下端进水，右侧上端三角堰出水，底部设置曝气盘；复合流过滤罐的上端为进水端，进水端设置网格状布水管，浮岩经酸改性和固载TiO2，增强了浮岩的吸附能力，提高了光催化反应速率，而且将反应的副产物吸附使污染物完全净化。
The invention discloses a modified pumice bioreactor device, which comprises an anaerobic tank, an aeration tank and a composite flow filter tank. The anaerobic tank is filled with a soft filler layer, and the aeration tank is provided with a modified pumice suspended filler ;The lower end of the left side of the anaerobic tank enters water, and the upper end of the right side of the flat weir discharges water; the lower end of the left side of the aeration tank enters water, the upper end of the right side of the triangular weir discharges water, and the bottom is equipped with an aeration plate; the upper end of the composite flow filter tank is the water inlet end, Grid-shaped water distribution pipes are set at the water inlet, and the pumice is acid-modified and loaded with TiO 2 , which enhances the adsorption capacity of the pumice, improves the photocatalytic reaction rate, and absorbs the by-products of the reaction to completely purify the pollutants.
Description
技术领域 technical field
本发明属水处理装置领域，尤其涉及一种改性浮岩生物反应器装置。 The invention belongs to the field of water treatment devices, in particular to a modified pumice bioreactor device.
背景技术 Background technique
改性浮岩具有较大的比表面积和较强的吸附性能，因此，本研究选用改性浮岩作为主要填料。 Modified pumice has a large specific surface area and strong adsorption performance, so this study chooses modified pumice as the main filler.
浮岩(pulnice)，是火成岩(lava)材料中的一种喷出岩，主要由火山玻璃、矿物组成。火山爆发时，岩浆中产生出的大量火山气体形成泡沫，随后泡沫冷却，气体被“封存”在浮岩中。浮岩中的气泡约占岩石总体积的70%以上，气泡间只有极薄的火山玻璃和矿物，因而可以浮于水面之上。浮岩外形似炉渣，表面多孔成蜂窝状，颜色浅淡，多为白色、灰白色或者灰褐色。浮岩是我国资源量大且分布较广的一类非金属矿产，储量仅次于意大利、希腊，居世界第三位，产地涉及黑龙江、吉林、辽宁、内蒙、山西、新疆、云南、海南等省区，被广泛应用于工业、农业等诸多领域，在化学工业中用作过滤剂、干燥剂、催化剂、填充剂以及农用杀虫剂的载体和肥料的控释剂，也可直接用作建筑材料。 Pumice (pulnice) is an extrusive rock in igneous rock (lava) materials, mainly composed of volcanic glass and minerals. When a volcano erupts, a large amount of volcanic gas is produced in the magma to form a foam, and then the foam cools, and the gas is "sealed" in the pumice. The air bubbles in the pumice rock account for more than 70% of the total volume of the rock, and there are only very thin volcanic glass and minerals between the air bubbles, so they can float on the water. The shape of the pumice is like slag, the surface is porous into a honeycomb shape, and the color is light, mostly white, off-white or taupe. Pumice is a kind of non-metallic mineral with large resources and wide distribution in my country. Its reserves are second only to Italy and Greece, ranking third in the world. Its production areas involve Heilongjiang, Jilin, Liaoning, Inner Mongolia, Shanxi, Xinjiang, Yunnan, Hainan, etc. It is widely used in many fields such as industry and agriculture. In the chemical industry, it is used as a filter, desiccant, catalyst, filler, and a carrier of agricultural pesticides and a controlled release agent for fertilizers. It can also be used directly as a construction agent. Material.
近年来，国内外对浮岩的吸附性能及其应用开展了初步研究，发现浮岩具有独特的气孔结构和良好的吸附能力。 WhithanA.G.等通过浮岩浸水漂浮试验发现，不同密度、大小和产地浮岩的吸水速率虽有明显差异，但其内部气孔的相互连通性较好，因此具有很好的传质效果。Bahri Ersoy等研究了产自土耳其Tatvan地区的浮岩，发现其热稳定性高达900℃，因粒径大小不一，孔径分布在0.05um～2mm之间，其比表面积和总孔隙率随粒径的减小而增加。Maria Rosaria Panucci等研究发现，浮岩对水溶液中Cd2+的去除率与Cd2+的初始浓度成显著正相关。 Fethiye Gode等、Mustafa Yavuz等研究也表明，浮岩对水溶液中重金属Cu2+、Cr3+有较好去除率，并且在pH=8时可达80%。 Feryal Akbal研究发现，浮岩对水溶液中的亚甲基蓝和结晶紫有明显吸附作用，能有效去除水体色度。宋秀环等通过比较几种非金属矿物表面积和硫化氢吸附实验结果，发现物理吸附作用中，由强到弱的顺序为:硅藻土＞麦饭石＞斜发沸石＞浮岩。化学吸附主要是矿物所含过渡金属含量对吸附能力起主导作用，对硫化氢的吸附能力依次为:浮岩＞硅藻土＞麦饭石＞沸石。 In recent years, preliminary studies have been carried out on the adsorption performance and application of pumice at home and abroad, and it is found that pumice has a unique pore structure and good adsorption capacity. WhithanA.G. et al found through pumice immersion and floating tests that although the water absorption rates of pumice with different densities, sizes and origins are significantly different, their internal pores are well interconnected, so they have good mass transfer effects. Bahri Ersoy et al studied the pumice rock produced in the Tatvan region of Turkey, and found that its thermal stability is as high as 900 ° C. Due to the different particle sizes, the pore size distribution is between 0.05um and 2mm, and its specific surface area and total porosity vary with particle size. decrease and increase. Maria Rosaria Panucci et al found that the removal rate of pumice to Cd 2+ in aqueous solution is significantly positively correlated with the initial concentration of Cd 2+ . Studies by Fethiye Gode et al. and Mustafa Yavuz et al. also show that pumice has a good removal rate for heavy metals Cu 2+ and Cr 3+ in aqueous solution, and can reach 80% at pH=8. Feryal Akbal's research found that pumice has obvious adsorption effect on methylene blue and crystal violet in aqueous solution, and can effectively remove the chroma of water body. By comparing the surface area of several non-metallic minerals and the results of hydrogen sulfide adsorption experiments, Song Xiuhuan et al. found that the order of physical adsorption from strong to weak is: diatomite > medical stone > clinoptilolite > pumice. Chemical adsorption is mainly due to the transition metal content contained in minerals playing a leading role in the adsorption capacity, and the adsorption capacity for hydrogen sulfide is in the following order: pumice > diatomaceous earth > medical stone > zeolite.
发明内容 Contents of the invention
本发明的目的是提供一种改性浮岩生物反应器装置，提高了浮岩的吸附能力，吸附剂的吸附能力为光催化反应提供高底物浓度，提高了光催化反应速率，而且将反应的副产物吸附使污染物完全净化。 The object of the present invention is to provide a kind of modified pumice bioreactor device, has improved the adsorption capacity of pumice rock, and the adsorption capacity of adsorbent provides high substrate concentration for photocatalytic reaction, has improved photocatalytic reaction rate, and will react The by-product adsorption makes the pollutants completely purified.
为了实现上述目的本发明采用如下技术方案： In order to achieve the above object, the present invention adopts the following technical solutions:
一种改性浮岩生物反应器装置，包括厌氧池、曝气池和复合流过滤罐，厌氧池内填有软性填料层，曝气池中设置改性浮岩悬浮填料；厌氧池左侧下端进水，右侧上端平口堰出水；曝气池左侧下端进水，右侧上端三角堰出水，底部设置曝气盘；复合流过滤罐的上端为进水端，进水端设置网格状布水管，底部设环状集水沟出水，内部填充多层改性浮岩滤料，并设多层多孔折板。 A modified pumice bioreactor device, comprising an anaerobic tank, an aeration tank and a composite flow filter tank, the anaerobic tank is filled with a soft packing layer, and the aeration tank is provided with modified pumice suspended filler; the anaerobic tank The water enters from the lower end on the left, and the water exits from the flat weir at the upper end on the right; the water enters from the lower end of the aeration tank on the left, and the triangular weir exits from the upper end of the right, and the aeration disc is installed at the bottom; the upper end of the composite flow filter tank is the water inlet, and the water inlet is set Grid-shaped water distribution pipes, with ring-shaped gutters at the bottom, filled with multi-layer modified pumice filter materials, and multi-layer porous folding plates.
所述的软性填料由多层纤维丝编制而成，软性填料单个尺寸为980 mm×500 mm×5 mm，比表面积160-180 m2/m3，下端系铅坠锚固于池底，上端剪成细长条状，悬浮于水池中。 The soft filler is made of multi-layer fiber filaments, the single size of the soft filler is 980 mm×500 mm×5 mm, the specific surface area is 160-180 m 2 /m 3 , and the lower end is anchored to the bottom of the pool by a lead pendant. The upper end is cut into slender strips and suspended in the pool.
所述曝气池中悬浮填料为改性浮岩，密度与水接近，附着生物膜后可悬浮于水体中，粒径0.5~1mm。 The suspended filler in the aeration tank is modified pumice with a density close to that of water, and can be suspended in water after attaching biofilm, with a particle size of 0.5-1mm.
所述复合流过滤罐填充多层改性浮岩滤料，粒径从上往下分别为2-4mm、5-7mm、10-16mm和30-40mm，厚度比为1:3:6:9。 The composite flow filter tank is filled with multi-layer modified pumice filter material, the particle diameters are 2-4mm, 5-7mm, 10-16mm and 30-40mm respectively from top to bottom, and the thickness ratio is 1:3:6:9 .
所述复合流过滤罐内沿高程每20cm设置一折板，且交错固定于左右两侧，折板上设2-3行直径5mm圆孔，孔间距10mm。 A folded plate is arranged every 20cm along the elevation in the composite flow filter tank, and is fixed on the left and right sides alternately. The folded plate is provided with 2-3 rows of round holes with a diameter of 5mm and a hole spacing of 10mm.
本发明的有益效果：提高了浮岩的吸附能力，吸附剂的吸附能力为光催化反应提供高底物浓度，提高了光催化反应速率，而且将反应的副产物吸附使污染物完全净化。开发我国丰富的浮岩资源，提高污水处理效果，降低填料成本。 The beneficial effect of the present invention is that the adsorption capacity of the pumice is improved, the adsorption capacity of the adsorbent provides high substrate concentration for the photocatalytic reaction, improves the photocatalytic reaction rate, and absorbs the by-products of the reaction to completely purify the pollutants. Develop my country's rich pumice resources, improve the sewage treatment effect, and reduce the cost of fillers.
附图说明 Description of drawings
图1为本发明的结构示意图。 Fig. 1 is a structural schematic diagram of the present invention.
图2为本发明的除磷效果图。 Fig. 2 is the dephosphorization effect diagram of the present invention.
图3为本发明的脱氮效果图。 Fig. 3 is a denitrification effect diagram of the present invention.
具体实施方式 Detailed ways
参见附图，一种改性浮岩生物反应器装置，包括厌氧池1、曝气池2和复合流过滤罐3，厌氧池1内填有软性填料层4、导流墙7，曝气池2中设置改性浮岩悬浮填料5、溢流管6；厌氧池1左侧下端进水，右侧上端平口堰出水；曝气池2左侧下端进水，右侧上端三角堰出水，底部设置曝气盘10；复合流过滤罐3的上端为进水端，进水端设置网格状布水管，底部设环状集水沟出水，内部填充多层改性浮岩滤料8，并设多层多孔折板9。 Referring to the accompanying drawings, a modified pumice bioreactor device comprises an anaerobic tank 1, an aeration tank 2 and a composite flow filter tank 3, and the anaerobic tank 1 is filled with a soft packing layer 4 and a diversion wall 7, Aeration tank 2 is provided with modified pumice suspended filler 5 and overflow pipe 6; anaerobic tank 1 has water inflow from the lower end on the left side and water outlet from the flat weir at the upper end on the right side; aeration tank 2 has water intake in the lower end on the left side and triangular The weir discharges water, and the bottom is provided with an aeration pan 10; the upper end of the composite flow filter tank 3 is the water inlet end, and the water inlet end is provided with a grid-shaped water distribution pipe, and the bottom is provided with a ring-shaped water collection ditch for water discharge, and the interior is filled with multi-layer modified pumice filter. Material 8, and multi-layer porous folding plate 9 is established.
软性填料由多层纤维丝编制而成，软性填料单个尺寸为980 mm×500 mm×5 mm，比表面积160-180 m2/m3，下端系铅坠锚固于池底，上端剪成细长条状，悬浮于水池中。曝气池中悬浮填料为改性浮岩，密度与水接近，附着生物膜后可悬浮于水体中，粒径0.5~1mm。复合流过滤罐填充多层改性浮岩滤料8，粒径从上往下分别为2-4mm、5-7mm、10-16mm和30-40mm，厚度比为1:3:6:9。复合流过滤罐内沿高程每20cm设置一折板，且交错固定于左右两侧，折板上设2-3行直径5mm圆孔，孔间距10mm。 The soft filler is made of multi-layer fiber filaments. The single size of the soft filler is 980 mm×500 mm×5 mm, and the specific surface area is 160-180 m 2 /m 3 . Slender strips, suspended in the pool. The suspended filler in the aeration tank is modified pumice, the density is close to that of water, and can be suspended in the water body after attaching biofilm, with a particle size of 0.5~1mm. The composite flow filter tank is filled with multi-layer modified pumice filter material 8, the particle sizes from top to bottom are 2-4mm, 5-7mm, 10-16mm and 30-40mm respectively, and the thickness ratio is 1:3:6:9. A folded plate is arranged every 20cm along the elevation in the composite flow filter tank, and is fixed on the left and right sides alternately. There are 2-3 rows of 5mm diameter round holes on the folded plate, and the hole spacing is 10mm.
Claims (5)
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| CN201410650554.6A CN104370421B (en) | 2014-11-14 | 2014-11-14 | A kind of modified foam bioreactor device |
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| CN106316003A (en) * | 2016-11-07 | 2017-01-11 | 重庆利迪现代水技术设备有限公司 | Unmanned aerial vehicle for pretreatment of rainwater utilization |
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| CN201458895U (en) * | 2009-08-03 | 2010-05-12 | 王玉华 | Integrated type sewage treatment device for hotels and residential quarters |
| CN102206003A (en) * | 2011-05-05 | 2011-10-05 | 江苏大学 | Preparation method of modified pumice packing for purifying sewage |
| CN202011812U (en) * | 2011-03-08 | 2011-10-19 | 四川四通欧美环境工程有限公司 | Integrated equipment for treating high-concentration organic wastewater |
-
2014
- 2014-11-14 CN CN201410650554.6A patent/CN104370421B/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2000246272A (en) * | 1999-02-25 | 2000-09-12 | Kansai Kankyo Kaihatsu Kk | Method for removing nitrogen of sewage |
| CN101456652A (en) * | 2009-01-05 | 2009-06-17 | 北京大学 | Device of depth denitrogen and phosphorus removal composite processing system by micro-power and method thereof |
| CN201458895U (en) * | 2009-08-03 | 2010-05-12 | 王玉华 | Integrated type sewage treatment device for hotels and residential quarters |
| CN202011812U (en) * | 2011-03-08 | 2011-10-19 | 四川四通欧美环境工程有限公司 | Integrated equipment for treating high-concentration organic wastewater |
| CN102206003A (en) * | 2011-05-05 | 2011-10-05 | 江苏大学 | Preparation method of modified pumice packing for purifying sewage |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106316003A (en) * | 2016-11-07 | 2017-01-11 | 重庆利迪现代水技术设备有限公司 | Unmanned aerial vehicle for pretreatment of rainwater utilization |
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| CN104370421B (en) | 2016-08-24 |
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