CN104365644A - Herbicide suspending agent containing pentoxazone and amidosulfuron - Google Patents
Herbicide suspending agent containing pentoxazone and amidosulfuron Download PDFInfo
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- CN104365644A CN104365644A CN201410631550.3A CN201410631550A CN104365644A CN 104365644 A CN104365644 A CN 104365644A CN 201410631550 A CN201410631550 A CN 201410631550A CN 104365644 A CN104365644 A CN 104365644A
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- Prior art keywords
- pentoxazone
- amidosulfuron
- killer herbicide
- weed killer
- suspending agent
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Abstract
The invention relates to a herbicide suspending agent containing pentoxazone and amidosulfuron. According to the herbicide disclosed by the invention, effective active ingredients, namely pentoxazone and amidosulfuron, are mixed with each other, so that the herbicide controlling spectrum is broad; the effective ingredients of the herbicide disclosed by the invention have a very good synergistic effect when the effective ingredients are matched in a certain range, the control effect is higher than that of single preparations, and the medicine property duration is long; the herbicide is extremely safe to cereal crops.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron.
Background technology
Pentoxazone, chemical name 3-(the chloro-5-cyclopentyloxy of 4--2-fluorophenyl)-5-isopropyl alkene-1,3-oxazoles quinoline-2,4-diketone, structural formula
, belong to oxazoline ketone, sterling is colourless, tasteless powdery solid; Fusing point 104 DEG C; Density 1.418 (25 DEG C); Vapour pressure is <1.11 × 10-5Pa (25 DEG C).Distribution coefficient LogP=0.67; In water, solvability is 0.216 mg/l (25 DEG C); To light, heat, absolute acid stability, unstable to alkali.Be mainly used in preventing and kill off barnyard grass and annual weed etc.Take p-fluorophenol as initiation material, through the nitrobenzene that chlorination, esterification, nitrated obtained intermediate replace; Through being hydrolyzed the phenol sylvite that obtained intermediate replaces; Again through etherificate, the aniline making replacement that reduces; After last and ethyl chloroformate reacts, namely obtain object with senecioic acid ester condensation.
Amidosulfuron chemical name is 1-(4,6-dimethoxypyridin-2-base)-3-mesyl (methyl) aminosulfonyl urea, and structural formula is
, belong to sulfonylurea, sterling is white granular solid; Fusing point 160 ~ 163 DEG C; Density 1.5 (20 DEG C); Vapour pressure is 2.2 × 10-5Pa (20 DEG C).Distribution coefficient LogP (20 DEG C)=1.63 (pH 2); Solvability (20 DEG C, mg/l) is: 3.3 (pH 3), 9 (pH 5.8), 13500 (pH 10) in water, isopropyl alcohol 99, methyl alcohol 872, acetone 8100; At room temperature deposit and stablize for 24 months; P K a 3.58.Amidosulfuron is the inhibitor of acetolactate synthestase (ALS).Absorbed by weeds root and leaf, conduct in plant body, namely weeds stop growing, leaf look chlorisis, then withered.With methylsulfonamides, dimethoxypyridin amine for initiation material, can obtain.Be mainly used in preventing and kill off broad leaved weed, effective especially to clearvers etc.
Above two kinds of medicines, after long-term being used alone, all easily making plant germ develop immunity to drugs, cause the problems such as dosage increasing, preventive effect reduction, lasting period shortening, be unfavorable for environment sustainable development.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron.Effective active composition pentoxazone, the mutual mixture broad weed-killing spectrum of amidosulfuron in weed killer herbicide of the present invention; Active ingredient in weed killer herbicide of the present invention coordinates good synergistic effect within the specific limits, and preventive effect is higher than single dose, and the property of medicine is held time length; Extremely safe to cereal crop.
A kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron of the present invention is realized by following technical scheme: the active ingredient of described weed killer herbicide comprises: pentoxazone, amidosulfuron.Wherein, pentoxazone, prosulfuron account for 25-50 part of weed killer herbicide gross mass, also comprise dispersant 5-20 part by weight, antifreezing agent 1-5 part, thickener 1-2 part, defoamer 0.5-1 part, water 50-80 part.
Described pentoxazone, the part by weight of amidosulfuron are 1-20:1-20.
Further, the part by weight of pentoxazone, amidosulfuron is 10-20:3.
Preferably, the part by weight of pentoxazone, amidosulfuron is 20:3.
First mixed by other auxiliary agents, mix through high speed shear, add pentoxazone, pyrrole grass ether, abrading-ball 2-3 hour in ball crusher, makes a diameter all at below 5mm, the suspending agent of this weed killer herbicide obtained.
Described dispersant is lignosulfonates.
Described antifreeze glycol.
Described thickener xanthans.
Described defoamer is silicone oil.
This weed killer herbicide suspending agent is for weeding before cereal crop seedling.
Beneficial effect of the present invention:
In weed killer herbicide of the present invention, effective active composition pentoxazone, the mutual mixture of amidosulfuron can not produce conflict; Broad weed-killing spectrum, effectively can improve herbicidal effect relative to single-activity composition; Active ingredient in weed killer herbicide of the present invention coordinates good synergistic effect within the specific limits, and preventive effect is higher than single dose, and the property of medicine is held time length, decreases agricultural chemicals Reusability number of times, reduces Pesticide use amount, reduce the use cost of agricultural chemicals; Extremely safe to cereal crop.Suspensions stability of the present invention is good, easy to use, good dispersion, and the ability sticking to plant surface is stronger, resistance of rainwater washing against, lasting medicine, and penetration is strong, and cost is low, and drug effect is high.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Embodiment 1
A kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron of the present invention comprises by weight: pentoxazone 40 parts, amidosulfuron 6 parts, dispersant 17 parts, antifreezing agent 4 parts, thickener 1 part, defoamer 0.8 part, 70 parts, water.
First mixed by other auxiliary agents, mix through high speed shear, add pentoxazone, pyrrole grass ether, abrading-ball 2-3 hour in ball crusher, makes a diameter all at below 5mm, the suspending agent of this weed killer herbicide obtained.
Described dispersant is lignosulfonates.
Described antifreeze glycol.
Described thickener xanthans.
Described defoamer is silicone oil.
This weed killer herbicide suspending agent is for weeding before cereal crop seedling.
This weed killer herbicide is 93.6% to weeds of wheat control rate, to crop safety, to succession crop corn safety.
Embodiment 2
A kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron of the present invention comprises by weight: pentoxazone 30 parts, amidosulfuron 4.5 parts, dispersant 7 parts, antifreezing agent 2 parts, thickener 1 part, defoamer 0.5 part, 60 parts, water.
First mixed by other auxiliary agents, mix through high speed shear, add pentoxazone, pyrrole grass ether, abrading-ball 2-3 hour in ball crusher, makes a diameter all at below 5mm, the suspending agent of this weed killer herbicide obtained.
Described dispersant is lignosulfonates.
Described antifreeze glycol.
Described thickener xanthans.
Described defoamer is silicone oil.
This weed killer herbicide suspending agent is for weeding before cereal crop seedling.
This weed killer herbicide is 91.9% to cereal crop control of weeds rate, to crop and succession crop safety, has no adverse effects.
Embodiment 3
A kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron of the present invention comprises by weight: pentoxazone 20 parts, amidosulfuron 20 parts, dispersant 10 parts, antifreezing agent 3 parts, thickener 1 part, defoamer 0.5 part, 55 parts, water.
First mixed by other auxiliary agents, mix through high speed shear, add pentoxazone, pyrrole grass ether, abrading-ball 2-3 hour in ball crusher, makes a diameter all at below 5mm, the suspending agent of this weed killer herbicide obtained.
Described dispersant is lignosulfonates.
Described antifreeze glycol.
Described thickener xanthans.
Described defoamer is silicone oil.
This weed killer herbicide suspending agent is for weeding before cereal crop seedling.
This weed killer herbicide is 54.8% to cereal crop control of weeds rate.
Claims (10)
1. one kind contains the weed killer herbicide suspending agent of pentoxazone and amidosulfuron, it is characterized in that, the active ingredient of described weed killer herbicide comprises: pentoxazone, amidosulfuron, wherein, pentoxazone, prosulfuron account for 25-50 part of weed killer herbicide gross mass, also comprise dispersant 5-20 part by weight, antifreezing agent 1-5 part, thickener 1-2 part, defoamer 0.5-1 part, water 50-80 part.
2. a kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron according to claim 1, it is characterized in that, described pentoxazone, the part by weight of amidosulfuron are 1-20:1-20.
3. a kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron according to claim 2, it is characterized in that, the part by weight of pentoxazone, amidosulfuron is 10-20:3.
4. a kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron according to claim 1, it is characterized in that, the part by weight of pentoxazone, amidosulfuron is 20:3.
5. a kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron according to claim 1, it is characterized in that, first other auxiliary agents are mixed, mix through high speed shear, add pentoxazone, pyrrole grass ether, abrading-ball 2-3 hour in ball crusher, makes a diameter all at below 5mm, the suspending agent of this weed killer herbicide obtained.
6. a kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron according to claim 1, it is characterized in that, described dispersant is lignosulfonates.
7. a kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron according to claim 1, is characterized in that, described antifreeze glycol.
8. a kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron according to claim 1, is characterized in that, described thickener xanthans.
9. a kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron according to claim 1, it is characterized in that, described defoamer is silicone oil.
10. a kind of weed killer herbicide suspending agent containing pentoxazone and amidosulfuron according to claim 1, it is characterized in that, this weed killer herbicide suspending agent is for weeding before cereal crop seedling.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410631550.3A CN104365644A (en) | 2014-11-12 | 2014-11-12 | Herbicide suspending agent containing pentoxazone and amidosulfuron |
Applications Claiming Priority (1)
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CN201410631550.3A CN104365644A (en) | 2014-11-12 | 2014-11-12 | Herbicide suspending agent containing pentoxazone and amidosulfuron |
Publications (1)
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CN104365644A true CN104365644A (en) | 2015-02-25 |
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CN201410631550.3A Pending CN104365644A (en) | 2014-11-12 | 2014-11-12 | Herbicide suspending agent containing pentoxazone and amidosulfuron |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1332608A (en) * | 1998-11-10 | 2002-01-23 | 辛根塔参与股份公司 | Herbicidal composition |
CN1382376A (en) * | 2001-04-25 | 2002-12-04 | 陈丰喜 | Herbicide composition |
-
2014
- 2014-11-12 CN CN201410631550.3A patent/CN104365644A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1332608A (en) * | 1998-11-10 | 2002-01-23 | 辛根塔参与股份公司 | Herbicidal composition |
CN1382376A (en) * | 2001-04-25 | 2002-12-04 | 陈丰喜 | Herbicide composition |
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Application publication date: 20150225 |